Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality
Abstract
:1. Introduction
2. Methods
2.1. Materials
2.2. Equipment
2.3. Experimental Procedure
2.4. Analytical Methods
3. Results and Discussion
3.1. Density at 15 °C and Kinematic Viscosity at 40 °C
3.2. Content of Methyl Esters, Mono-, di-, Triglycerides, and Total Glycerol
3.3. Behavior of Biodiesel-Diacetinmonoglyceride Blends at Low Temperatures
3.4. Distillation Curve
3.5. Solubility in Conventional Diesel
4. Conclusions
- −
- The density and viscosity limits of the European standard EN 14214 [8] allow a maximum content of triacetin and diacetinmonoglyceride in biodiesel of 5 to 10% by weight, and 3 to 4% by weight, respectively. The density is not limited by the ASTM D6751 [7] standard, and the kinematic viscosity has a less restrictive limit (6 cSt).
- −
- According to chromatographic tests, if triacetin is considered a methyl ester there would be no limitation for its use in EN 14214 [8] or ASTM D6751 [7]. On the other hand, if the diacetinmonoglyceride is assimilated to a monoglyceride, the value of 0.15–0.7% by weight (EN 14214 [8]) or 0.4% by weight (ASTM D6751 [7]) could not be exceeded.
- −
- The presence of low concentrations of diacetinmonoglyceride (up to 2% by weight) does not adversely affect the cold behavior of the starting biodiesel.
- −
- The distillation temperature (for 90% volume of distillate collected) is not affected by the addition of triacetin or amounts less than 5% by weight of diacetinmonoglyceride.
- −
- Although the solubility of triacetin in diesel is very low (2% by weight), once mixed with biodiesel in quantities that do not exceed 20% by weight, it would not have this problem.
- −
- The solubility of triacetin in diesel is slightly favored by the presence of diacetinmonoglyceride.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Property | Units | ASTM D6751 [7] | EN 14214 [8] |
---|---|---|---|
Density at 15 °C | kg/m3 | - | 860–900 |
Kinematic viscosity at 40 °C | mm2/s (cSt) | 1.9–6 | 3.5–5 |
Cold filter plugging point | °C | - | Limits are determined by the climatic region. |
Cloud point | °C | Report | Limits are determined by the climatic region. |
Methyl ester content | wt.% | - | ≥96.5 |
Monoglycerides content | wt.% | ≤0.4 | ≤0.15–0.7 |
Total glycerol content | wt.% | ≤0.24 | ≤0.25 |
Distillation temperature (V90) * | °C | ≤360 | - |
Acid Group of Methyl Ester: | Lipid Numbers * (A:B) | Palm | Soybean | Sunflower | Rapeseed |
---|---|---|---|---|---|
Erucic | 22:1 | 0.0 | 0.1 | 0.2 | 0.0 |
Behenic | 22:0 | 0.0 | 0.2 | 0.3 | 0.2 |
Gadoleic | 20:1 | 0.2 | 0.2 | 0.2 | 1.1 |
Arachidic | 20:0 | 0.2 | 0.2 | 0.2 | 0.4 |
Linolenic | 18:3 | 0.0 | 6.9 | 0.1 | 8.5 |
Linoleic | 18:2 | 10.7 | 54.5 | 57.5 | 21.2 |
Oleic | 18:1 | 41.1 | 24.1 | 31.8 | 62.4 |
Stearic | 18:0 | 3.6 | 2.9 | 2.9 | 1.4 |
Palmitic | 16:0 | 43.4 | 10.9 | 6.8 | 4.8 |
Myristic | 14:0 | 0.8 | 0.0 | 0.0 | 0.0 |
Biodiesel | Triacetin * (wt.%) | Density (kg/m3) | Kinematic Viscosity (cSt) |
---|---|---|---|
Rapeseed | 5 | 898.124 | 4.69 |
Rapeseed | 10 | 908.079 | 4.76 |
Palm | 5 | 890.355 | 4.84 |
Palm | 10 | 900.864 | 5.02 |
Soybean | 5 | 899.264 | 4.44 |
Soybean | 10 | 910.025 | 4.51 |
Sunflower | 5 | 898.219 | 4.53 |
Sunflower | 10 | 909.986 | 4.62 |
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Casas, A.; Pérez, Á.; Ramos, M.J. Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality. Energies 2023, 16, 6146. https://doi.org/10.3390/en16176146
Casas A, Pérez Á, Ramos MJ. Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality. Energies. 2023; 16(17):6146. https://doi.org/10.3390/en16176146
Chicago/Turabian StyleCasas, Abraham, Ángel Pérez, and María Jesús Ramos. 2023. "Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality" Energies 16, no. 17: 6146. https://doi.org/10.3390/en16176146
APA StyleCasas, A., Pérez, Á., & Ramos, M. J. (2023). Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality. Energies, 16(17), 6146. https://doi.org/10.3390/en16176146