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Sensors 2014, 14(10), 19115-19127;

Hot Plate Annealing at a Low Temperature of a Thin Ferroelectric P(VDF-TrFE) Film with an Improved Crystalline Structure for Sensors and Actuators

Low Dimensional Materials Research Centre, Department of Physics, University of Malaya, Kuala Lumpur 50603, Malaysia
Nanotechnology and Advanced Materials Research Centre, University of Technology, Baghdad 10066, Iraq
Authors to whom correspondence should be addressed.
Received: 28 August 2014 / Revised: 8 October 2014 / Accepted: 9 October 2014 / Published: 14 October 2014
(This article belongs to the Section Chemical Sensors)
Full-Text   |   PDF [2739 KB, uploaded 14 October 2014]


Ferroelectric poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) copolymer 70/30 thin films are prepared by spin coating. The crystalline structure of these films is investigated by varying the annealing temperature from the ferroelectric phase to the paraelectric phase. A hot plate was used to produce a direct and an efficient annealing effect on the thin film. The dielectric, ferroelectric and pyroelectric properties of the P(VDF-TrFE) thin films are measured as a function of different annealing temperatures (80 to 140 °C). It was found that an annealing temperature of 100 °C (slightly above the Curie temperature, Tc) has induced a highly crystalline β phase with a rod-like crystal structure, as examined by X-ray. Such a crystal structure yields a high remanent polarization, Pr = 94 mC/m2, and pyroelectric constant, p = 24 μC/m2K. A higher annealing temperature exhibits an elongated needle-like crystal domain, resulting in a decrease in the crystalline structure and the functional electrical properties. This study revealed that highly crystalline P(VDF-TrFE) thin films could be induced at 100 °C by annealing the thin film with a simple and cheap method. View Full-Text
Keywords: ferroelectric copolymers; crystallinity; dielectric; pyroelectric ferroelectric copolymers; crystallinity; dielectric; pyroelectric
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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Mahdi, R.I.; Gan, W.C.; Majid, W.H.A. Hot Plate Annealing at a Low Temperature of a Thin Ferroelectric P(VDF-TrFE) Film with an Improved Crystalline Structure for Sensors and Actuators. Sensors 2014, 14, 19115-19127.

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