(S)-1-(Ethoxycarbonyl)ethyl(2R,5S)-2,5-dimethyl-1,3-dioxolan-4-one-2-carboxylate
EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife KY16 9ST, UK
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Molbank 2021, 2021(1), M1178; https://doi.org/10.3390/M1178
Received: 23 December 2020 / Revised: 29 December 2020 / Accepted: 30 December 2020 / Published: 2 January 2021
(This article belongs to the Special Issue Heterocycle Reactions)
The title compound was obtained in low yield in the condensation of ethyl pyruvate and lactic acid. Its structure is determined by NMR methods and x-ray diffraction and the mechanism for formation of this 1:2 adduct from the initial 1:1 adduct is considered.
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Keywords:
1,3-dioxolan-4-ones; ethyl pyruvate; lactic acid; X-ray structure
This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
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MDPI and ACS Style
Aitken, R.A.; Haslett, O.E.; Slawin, A.M.Z. (S)-1-(Ethoxycarbonyl)ethyl(2R,5S)-2,5-dimethyl-1,3-dioxolan-4-one-2-carboxylate. Molbank 2021, 2021, M1178.
AMA Style
Aitken RA, Haslett OE, Slawin AMZ. (S)-1-(Ethoxycarbonyl)ethyl(2R,5S)-2,5-dimethyl-1,3-dioxolan-4-one-2-carboxylate. Molbank. 2021; 2021(1):M1178.
Chicago/Turabian StyleAitken, R. A.; Haslett, Oliver E.; Slawin, Alexandra M.Z. 2021. "(S)-1-(Ethoxycarbonyl)ethyl(2R,5S)-2,5-dimethyl-1,3-dioxolan-4-one-2-carboxylate" Molbank 2021, no. 1: M1178.
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