Next Article in Journal
2-(Bicyclo[4.2.0]octa-1,3,5-trien-3-yl)-adamantan-2-ol
Previous Article in Journal
N′-Acetyl-3-methyl-1,6-diphenyl-1H-pyrazolo[3,4-b]pyridine-4-carbohydrazide
Open AccessCommunication

(2Sp,4R,8Sp)-4-Methyl-1-phenyl-diferroceno-5-Z-ethylene-1-phosphinoxide

1
Institute of Computational Biological Chemistry, University of Vienna, Währingerstraße 17, 1090 Vienna, Austria
2
Institute of Chemical Catalysis, University of Vienna, Währingerstraße 38, 1090 Vienna, Austria
*
Author to whom correspondence should be addressed.
Molbank 2020, 2020(1), M1105; https://doi.org/10.3390/M1105
Received: 14 December 2019 / Revised: 29 December 2019 / Accepted: 7 January 2020 / Published: 8 January 2020
(This article belongs to the Section Organic Synthesis)
We present a synthesis of the title compound, a homochiral diferroceno cycle intended for use in asymmetric catalysis. We present a hydrovinylation protocol, which allows the production of the title compound in two steps from a known diferrocenyl precursor. We obtained one of two possible diastereomers selectively and propose a plausible regio- and stereoselective reaction mechanism. View Full-Text
Keywords: ferrocene; 8-membered cycle; planar chirality; hydrovinylation; titanium(IV) chloride ferrocene; 8-membered cycle; planar chirality; hydrovinylation; titanium(IV) chloride
Show Figures

Graphical abstract

MDPI and ACS Style

Honegger, P.; Widhalm, M. (2Sp,4R,8Sp)-4-Methyl-1-phenyl-diferroceno-5-Z-ethylene-1-phosphinoxide. Molbank 2020, 2020, M1105.

Show more citation formats Show less citations formats
Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Article Access Map by Country/Region

1
Back to TopTop