Molybdenum Complexes Derived from 2-Hydroxy-5-nitrobenzaldehyde and Benzhydrazide as Potential Oxidation Catalysts and Semiconductors
Abstract
:1. Introduction
2. Results and Discussion
2.1. Preparation, Spectroscopic Characterization, and Thermal Properties
2.2. Description of Molecular and Crystal Structure
2.3. Electrical Properties Investigation
2.4. Catalytic Investigation
3. Materials and Methods
3.1. Materials
3.1.1. Preparation of the Starting Compounds
3.1.2. Synthesis of Molybdenum(VI) Complexes
3.1.3. Catalytic Protocol
3.2. Methods
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Complex | Coordinated Solvent Loss/°C | Complex Decomposition/°C |
---|---|---|
[MoO2(L)(MeOH)] (1) | 148–180 | 331–442 |
[MoO2(L)(H2O)] (2) | 143–167 | 332–441 |
[(MoO2(L))2(4,4-bpy)] (3) | - | 326–452 |
Complex | /(Ω cm)−1 a | EDC/kJ mol−1 (Heating Run) | EDC/kJ mol−1 (Cooling Run) |
---|---|---|---|
[MoO2(L)(MeOH)] (1) | 2.8 × 10−14 | 58.0 | 60.0 |
[MoO2(L)(H2O)] (2) | 1.0 × 10−12 | - | 102.0 |
[(MoO2(L))2(4,4-bpy)] (3) | 1.7 × 10−13 | 65.0 | 66.0 |
Substrate | Catalytic Parameter | Catalysts | |
---|---|---|---|
[MoO2(L)(MeOH)] (1) | [MoO2(L)(H2O)] (2) | ||
Cis-cyclooctene | Conversion a/% | 75 | 83 |
Epoxide selectivity b/% | 65 | 73 | |
Epoxide yield/% | 48 | 60 | |
TOF20min c | 244 | 276 | |
TON d | 299 | 323 | |
Linalool | Conversion a/% | 43 | 92 |
Furanoid selectivity b/% | 41 | 48 | |
Furanoid yield/% | 18 | 44 | |
Pyranoid selectivity b/% | 25 | 29 | |
Pyranoid yield/% | 11 | 27 | |
TOF20min c | 208 | 445 | |
TON d | 173 | 367 |
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Pisk, J.; Šušković, M.; Topić, E.; Agustin, D.; Judaš, N.; Pavić, L. Molybdenum Complexes Derived from 2-Hydroxy-5-nitrobenzaldehyde and Benzhydrazide as Potential Oxidation Catalysts and Semiconductors. Int. J. Mol. Sci. 2024, 25, 4859. https://doi.org/10.3390/ijms25094859
Pisk J, Šušković M, Topić E, Agustin D, Judaš N, Pavić L. Molybdenum Complexes Derived from 2-Hydroxy-5-nitrobenzaldehyde and Benzhydrazide as Potential Oxidation Catalysts and Semiconductors. International Journal of Molecular Sciences. 2024; 25(9):4859. https://doi.org/10.3390/ijms25094859
Chicago/Turabian StylePisk, Jana, Mia Šušković, Edi Topić, Dominique Agustin, Nenad Judaš, and Luka Pavić. 2024. "Molybdenum Complexes Derived from 2-Hydroxy-5-nitrobenzaldehyde and Benzhydrazide as Potential Oxidation Catalysts and Semiconductors" International Journal of Molecular Sciences 25, no. 9: 4859. https://doi.org/10.3390/ijms25094859