Electrochemical Detection of Dopamine at a Gold Electrode Modified with a Polypyrrole–Mesoporous Silica Molecular Sieves (MCM-48) Film
Abstract
:1. Introduction
2. Results and Discussion
2.1. Formation and Electrochemical Properties of the Modified Electrodes
2.2. Voltammetric Behaviors of Dopamine at the Bare Gold Electrode
2.3. Electrochemical Detection of Dopamine at the Gold Electrode Modified with the Polypyrrole—MCM-48 Nanocomposite
2.4. Interference by Ascorbic Acid and Uric Acid
2.5. The Influence of Ascorbic Acid or Uric Acid on the Determination of Dopamine
2.6. Simultaneous Detection of Dopamine, Ascorbic Acid, and Uric Acid
3. Conclusions
4. Experimental Section
4.1. Materials
4.2. Instrumentation
4.3. Preparation of the Polypyrrole—MCM-48 Nanocomposite
Author Contributions
Funding
Conflicts of Interest
References
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Modified Electrode | Method | Linear Relationship | Correlation Coefficient | Limit Detection | Reference |
---|---|---|---|---|---|
PPyox/graphene/GCE | CV | 0.5–10 μM 25 μM–1.0 mM | 0.997 0.996 | 0.1 μM | [31] |
PPy-RGO core-shell microspheres/GCE | DPV | 10 μM–10 mM | 0.9996 | 1 nM | [32] |
PPy/ferrocyanide/carbon paste electrode | LSV DPV | 0.1–1.2 mM 0.2–0.95 mM | 0.9984 0.9998 | 38.6 μM 15.1 μM | [52] |
Au/PPy/Ag/GCE | Amperometric response | 0.1–5 mM | - | 50 μM | [53] |
PPy/-cyclodextrin/GCE | CV | 2–10 μM | - | 6 μM | [54] |
ZnO-CuxO-PPy/GCE | DPV | 0.1–130 μM | 0.9922 | 0.04 μM | [55] |
PPy doped with sulfonated-cyclodextrin/GCE | Constant potential amperometry | 7.5–40 μM | 0.999 | 3.2 μM | [56] |
PPy—MCM-48/Au electrode | CV SWV | 10 μM–1.2 mM 2–250 μM | 0.9989 0.9996 | 2.5 μM 0.7 μM | This work |
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Zablocka, I.; Wysocka-Zolopa, M.; Winkler, K. Electrochemical Detection of Dopamine at a Gold Electrode Modified with a Polypyrrole–Mesoporous Silica Molecular Sieves (MCM-48) Film. Int. J. Mol. Sci. 2019, 20, 111. https://doi.org/10.3390/ijms20010111
Zablocka I, Wysocka-Zolopa M, Winkler K. Electrochemical Detection of Dopamine at a Gold Electrode Modified with a Polypyrrole–Mesoporous Silica Molecular Sieves (MCM-48) Film. International Journal of Molecular Sciences. 2019; 20(1):111. https://doi.org/10.3390/ijms20010111
Chicago/Turabian StyleZablocka, Izabela, Monika Wysocka-Zolopa, and Krzysztof Winkler. 2019. "Electrochemical Detection of Dopamine at a Gold Electrode Modified with a Polypyrrole–Mesoporous Silica Molecular Sieves (MCM-48) Film" International Journal of Molecular Sciences 20, no. 1: 111. https://doi.org/10.3390/ijms20010111