Double Photoionization of Nitrosyl Chloride by Synchrotron Radiation in the 24–70 eV Photon Energy Range
Abstract
:1. Introduction
2. Results and Discussion
3. Materials and Methods
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
Sample Availability
References
- Molina, M.J.; Rowland, F.S. Stratospheric Sink for Chlorofluoromethanes: Chlorine Atom-Catalysed Destruction of Ozone. Nature 1974, 249, 810–812. [Google Scholar] [CrossRef]
- Finlayson-Pitts, B.J. Reaction of NO2 with NaCl and Atmospheric Implications of NOCl Formation. Nature 1983, 306, 676–677. [Google Scholar] [CrossRef]
- Finlayson-Pitts, B.J. The Tropospheric Chemistry of Sea Salt: A Molecular-Level View of the Chemistry of NaCl and NaBr. Chem. Rev. 2003, 103, 4801–4822. [Google Scholar] [CrossRef] [PubMed]
- Goodeve, C.F.; Katz, S. The Absorption Spectrum of Nitrosyl Chloride. Proc. R. Soc. Lond. Ser. A Math. Phys. Sci. 1939, 172, 432–444. [Google Scholar] [CrossRef]
- Bai, Y.Y.; Ogai, A.; Qian, C.X.W.; Iwata, L.; Segal, G.A.; Reisler, H. The Electronic Spectrum of NOCl: Photofragment Spectroscopy, Vector Correlations, and ab initio Calculations. J. Chem. Phys. 1989, 90, 3903–3914. [Google Scholar] [CrossRef]
- Schinke, R.; Nonella, M.; Suter, H.U.; Huber, J.R. Photodissociation of ClNO in the S1 State: A Quantum-Mechanical ab initio Study. J. Chem. Phys. 1990, 93, 1098–1106. [Google Scholar] [CrossRef]
- Qian, C.X.W.; Ogai, A.; Brandon, J.; Bai, Y.Y.; Reisler, H. Spectroscopy and Dynamics of Fast Evolving States. J. Phys. Chem. 1991, 95, 6763–6774. [Google Scholar] [CrossRef]
- Vegiri, A.; Untch, A.; Schinke, R. Mapping of Transition-State Wave Functions. II. A Model for the Photodissociation of ClNO(T1). J. Chem. Phys. 1992, 96, 3688–3695. [Google Scholar] [CrossRef]
- Skorokhodov, V.; Sato, Y.; Suto, K.; Matsumi, Y.; Kawasaki, M. Photofragmentation of ClNO in the A-Band: Velocity Distribution and Fine-Structure Branching Ratio of Cl(2Pj) Atoms. J. Phys. Chem. 1996, 100, 12321–12328. [Google Scholar] [CrossRef]
- Guo, H.; Seideman, T. Quantum Mechanical Study of Photodissociation of Oriented ClNO(S1). Phys. Chem. Chem. Phys. 1999, 1, 1265–1272. [Google Scholar] [CrossRef]
- Lacombe, S.; Loudet, M.; Dargelos, A.; Camou, J. Calculation of the Electronic and Photoelectronic Spectra of Nitroso Compounds: A Reinvestigation by Use of Configuration Interaction Methods. Chem. Phys. 2000, 258, 1–12. [Google Scholar] [CrossRef]
- Mackey, J.L.; Johnson, B.R.; Kittrell, C.; Le, L.D.; Kinsey, J.L. Resonance Raman Spectroscopy in the Dissociative A band of Nitrosyl Chloride. J. Chem. Phys. 2001, 114, 6631–6640. [Google Scholar] [CrossRef] [Green Version]
- Yamashita, T.; Kato, S. Excited State Electronic Structures and Dynamics of NOCl: A New Potential Function Set, Absorption Spectrum, and Photodissociation Mechanism. J. Chem. Phys. 2004, 121, 2105–2116. [Google Scholar] [CrossRef] [PubMed]
- Jones, K.M.; Milkiewicz, J.A.; Whitaker, B.J.; Sage, A.G.; Worth, G.A. Photodissociation of ClNO in the 21A′ State: Computational and Experimental NO Product State Distributions. ChemPhysChem 2013, 14, 1479–1487. [Google Scholar] [CrossRef] [Green Version]
- Bruno, A.E.; Bruhlmann, U.; Huber, J. Photofragmentation LIF Spectroscopy of NOCl at Dissociation Wavelengths > 450 nm. Parent Electronic Spectrum and Spin State and Λ-Doublet Populations of Nascent NO and Cl fragments. Chem. Phys. 1988, 120, 155–167. [Google Scholar] [CrossRef]
- Bixby, T.J.; Patterson, J.D.; Reid, P.J. Femtosecond TRIR Studies of ClNO Photochemistry in Solution: Evidence for Photoisomerization and Geminate Recombination. J. Phys. Chem. A 2009, 113, 3886–3894. [Google Scholar] [CrossRef]
- Patterson, J.D.; Reid, P.J. Time-Resolved Infrared Absorption Studies of the Solvent-Dependent Photochemistry of ClNO. J. Phys. Chem. B 2012, 116, 10437–10443. [Google Scholar] [CrossRef] [PubMed]
- Falcinelli, S.; Rosi, M. Production and Characterization of Molecular Dications: Experimental and Theoretical Efforts. Molecules 2020, 25, 4157. [Google Scholar] [CrossRef]
- Price, S.D.; Eland, J.H.D.; Fournier, P.G.; Fournier, J.; Millié, P. Electronic States and Decay Mechanisms of the N2O2+ Dication. J. Chem. Phys. 1988, 88, 1511–1515. [Google Scholar] [CrossRef]
- Thissen, R.; Delwiche, J.; Robbe, J.M.; Duflot, D.; Flament, J.P.; Eland, J.H.D. Dissociations of the Ethyne Dication C2H2+2. J. Chem. Phys. 1993, 99, 6590–6599. [Google Scholar] [CrossRef]
- Slattery, A.E.; Field, T.A.; Ahmad, M.; Hall, R.I.; Lambourne, J.; Penent, F.; Lablanquie, P.; Eland, J.H.D. Spectroscopy and Metastability of CO22+ Molecular Ions. J. Chem. Phys. 2005, 122, 084317. [Google Scholar] [CrossRef]
- Eland, J.H.D. Dynamics of Double Photoionization in Molecules and Atoms. In Advances in Chemical Physics; Rice, S.A., Ed.; JohnWiley & Sons, Inc.: Hoboken, NJ, USA, 2009; Volume 141, pp. 103–150. [Google Scholar]
- Herman, Z. Dynamics of Charge Transfer and Chemical Reactions of Doubly-Charged Ions at Low Collision Energies. Int. Rev. Phys. Chem. 1996, 15, 299–324. [Google Scholar] [CrossRef]
- Sabzyan, H.; Keshavarz, E.; Noorisafa, Z. Diatomic Dications and Dianions. J. Iran. Chem. Soc. 2013, 11, 871–945. [Google Scholar] [CrossRef]
- Price, S.D.; Fletcher, J.D.; Gossan, F.E.; Parkes, M.A. Bimolecular Reactions of the Dications and Trications of Atoms and Small Molecules in the Gas-Phase. Int. Rev. Phys. Chem. 2017, 36, 145–183. [Google Scholar] [CrossRef]
- Schio, L.; Li, C.; Monti, S.; Salén, P.; Yatsyna, V.; Feifel, R.; Alagia, M.; Richter, R.; Falcinelli, S.; Stranges, S.; et al. NEXAFS and XPS Studies of Nitrosyl Chloride. Phys. Chem. Chem. Phys. 2015, 17, 9040–9048. [Google Scholar] [CrossRef]
- Salén, P.; Schio, L.; Richter, R.; Alagia, M.; Stranges, S.; Zhaunerchyk, V. Investigating Core-Excited States of Nitrosyl Chloride (ClNO) and Their Break-Up Dynamics Following Auger Decay. J. Chem. Phys. 2018, 149, 164305. [Google Scholar] [CrossRef]
- Salén, P.; Schio, L.; Richter, R.; Alagia, M.; Stranges, S.; Falcinelli, S.; Zhaunerchyk, V. Electronic State Influence on Selective Bond Breaking of Core-Excited Nitrosyl Chloride (ClNO). J. Chem. Phys. 2022, 157, 124306. [Google Scholar] [CrossRef]
- Wannier, G.H. The Threshold Law for Single Ionization of Atoms or Ions by Electrons. Phys. Rev. 1953, 90, 817–825. [Google Scholar] [CrossRef]
- Alagia, M.; Biondini, F.; Brunetti, B.G.; Candori, P.; Falcinelli, S.; Teixidor, M.M.; Pirani, F.; Richter, R.; Stranges, S.; Vecchiocattivi, F. The Double Photoionization of HCl: An Ion–Electron Coincidence Study. J. Chem. Phys. 2004, 121, 10508–10512. [Google Scholar] [CrossRef]
- Alagia, M.; Brunetti, B.G.; Candori, P.; Falcinelli, S.; Teixidor, M.M.; Pirani, F.; Richter, R.; Stranges, S.; Vecchiocattivi, F. Threshold-Photoelectron-Spectroscopy-Coincidence Study of the Double Photoionization of HBr. J. Chem. Phys. 2004, 120, 6980–6984. [Google Scholar] [CrossRef]
- Alagia, M.; Candori, P.; Falcinelli, S.; Mundim, M.S.P.; Pirani, F.; Richter, R.; Rosi, M.; Stranges, S.; Vecchiocattivi, F. Dissociative Double Photoionization of Singly Deuterated Benzene Molecules in the 26–33 eV Energy Range. J. Chem. Phys. 2011, 135, 144304. [Google Scholar] [CrossRef] [Green Version]
- Yao, L.; Ge, M.-F.; Wang, D.-X.; Wu, C.-Y.; Xu, N.; Gong, Q.-H. Ionization and Dissociation of Nitrosyl Chloride Molecule in the Intense Femtosecond Laser Field. Chin. J. Chem. 2006, 24, 867–871. [Google Scholar] [CrossRef]
- Wang, P. Electron Impact Dissociative Ionization of Nitrosyl Chloride. Mod. Phys. Lett. B. 2012, 26, 1250065. [Google Scholar] [CrossRef]
- Abbas, M.I.; Dyke, J.M.; Morris, A. Photoelectron Spectrum of Nitrosyl Chloride. J. Chem. Soc. Faraday Trans. 2 1976, 72, 814–819. [Google Scholar] [CrossRef]
- Alagia, M.; Bodo, E.; Decleva, P.; Falcinelli, S.; Ponzi, A.; Richter, R.; Stranges, S. The Soft X-Ray Absorption Spectrum of the Allyl Free Radical. Phys. Chem. Chem. Phys. 2013, 15, 1310–1318. [Google Scholar] [CrossRef]
- Lavollée, M. A New Detector for Measuring Three-Dimensional Momenta of Charged Particles in Coincidence. Rev. Sci. Instrum. 1999, 70, 2968–2974. [Google Scholar] [CrossRef]
- Derossi, A.; Lama, F.; Piacentini, M.; Prosperi, T.; Zema, N. High Flux and High Resolution Beamline for Elliptically Polarized Radiation in the Vacuum Ultraviolet and Soft X-ray Regions. Rev. Sci. Instrum. 1995, 66, 1718–1720. [Google Scholar] [CrossRef]
Product Ions | Average Abundance (%) | Energy Threshold (eV) |
---|---|---|
NO+ + Cl+ | 52.7 | 30.1 ± 0.1 |
N+ + Cl+ | 18.1 | 40.5 ± 0.1 |
N+ + O+ | 13.5 | 39.0 ± 0.2 |
O+ + Cl+ | 9.8 | 39.0 ± 0.2 |
ClN+ + O+ | 5.3 | 34.5 ± 0.2 |
NO+ + Cl2+ | 0.6 | 63.5 ± 0.3 |
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Schio, L.; Alagia, M.; Richter, R.; Zhaunerchyk, V.; Stranges, S.; Pirani, F.; Vecchiocattivi, F.; Parriani, M.; Falcinelli, S. Double Photoionization of Nitrosyl Chloride by Synchrotron Radiation in the 24–70 eV Photon Energy Range. Molecules 2023, 28, 5218. https://doi.org/10.3390/molecules28135218
Schio L, Alagia M, Richter R, Zhaunerchyk V, Stranges S, Pirani F, Vecchiocattivi F, Parriani M, Falcinelli S. Double Photoionization of Nitrosyl Chloride by Synchrotron Radiation in the 24–70 eV Photon Energy Range. Molecules. 2023; 28(13):5218. https://doi.org/10.3390/molecules28135218
Chicago/Turabian StyleSchio, Luca, Michele Alagia, Robert Richter, Vitali Zhaunerchyk, Stefano Stranges, Fernando Pirani, Franco Vecchiocattivi, Marco Parriani, and Stefano Falcinelli. 2023. "Double Photoionization of Nitrosyl Chloride by Synchrotron Radiation in the 24–70 eV Photon Energy Range" Molecules 28, no. 13: 5218. https://doi.org/10.3390/molecules28135218