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Correction to Molecules 2022, 27(3), 599.
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Correction

Correction: Mikołajczyk et al. Nucleophilic Substitution at Heteroatoms—Identity Substitution Reactions at Phosphorus and Sulfur Centers: Do They Proceed in a Concerted (SN2) or Stepwise (A–E) Way? Molecules 2022, 27, 599

by
Marian Mikołajczyk
1,*,
Marek Cypryk
2,*,
Bartłomiej Gostyński
2 and
Jakub Kowalczewski
3
1
Department of Organic Chemistry, Centre of Molecular and Macromolecular Studies Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland
2
Department of Structural Chemistry, Centre of Molecular and Macromolecular Studies Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland
3
Faculty of Chemistry, Lodz University of Technology, Żeromskiego 114, 90-543 Łódź, Poland
*
Authors to whom correspondence should be addressed.
Molecules 2022, 27(12), 3820; https://doi.org/10.3390/molecules27123820
Submission received: 13 February 2022 / Accepted: 6 June 2022 / Published: 14 June 2022
(This article belongs to the Special Issue A Commemorative Special Issue Honoring Professor Donald Truhlar)
Browse Figure
Versions Notes
(1) The authors would like to correct mistakes in the title paper [1]. The wrong central atom, P (phosphorus), in Scheme 8 has been corrected to S (sulfur), and the anion in the intermediate ion pair has been changed to CF3SO3−. The corrected Scheme 8 is presented below.
(2) Moreover, in the line below Scheme 9, the word ‘sulfonate’ has been corrected to ‘sulfinate’. The correct sentence should be as follows:
‘Then, the rate of racemization of the methyl sulfinate (+)-(R)−4 and the rate of the isotopic methoxyl–methoxy exchange in methanol in the presence of trifluoroacetic acid have been determined [18]’.
(3) In the References section the title of reference [17] contains the misspelled word: “Stom”. It should be: “Atom”.
The authors apologize for any inconvenience caused and state that the scientific conclusions are unaffected. The original publication has also been updated.

Reference

  1. Mikołajczyk, M.; Cypryk, M.; Gostyński, B.; Kowalczewski, J. Nucleophilic Substitution at Heteroatoms—Identity Substitution Reactions at Phosphorus and Sulfur Centers: Do They Proceed in a Concerted (SN2) or Stepwise (A–E) Way? Molecules 2022, 27, 599. [Google Scholar] [CrossRef] [PubMed]
Molecules 27 03820 sch008 550
Scheme 8. Interconversion of the enantiomers of optically active p-toluenosulfinylpyrrolidyne.
Scheme 8. Interconversion of the enantiomers of optically active p-toluenosulfinylpyrrolidyne.
Molecules 27 03820 sch008
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MDPI and ACS Style

Mikołajczyk, M.; Cypryk, M.; Gostyński, B.; Kowalczewski, J. Correction: Mikołajczyk et al. Nucleophilic Substitution at Heteroatoms—Identity Substitution Reactions at Phosphorus and Sulfur Centers: Do They Proceed in a Concerted (SN2) or Stepwise (A–E) Way? Molecules 2022, 27, 599. Molecules 2022, 27, 3820. https://doi.org/10.3390/molecules27123820

AMA Style

Mikołajczyk M, Cypryk M, Gostyński B, Kowalczewski J. Correction: Mikołajczyk et al. Nucleophilic Substitution at Heteroatoms—Identity Substitution Reactions at Phosphorus and Sulfur Centers: Do They Proceed in a Concerted (SN2) or Stepwise (A–E) Way? Molecules 2022, 27, 599. Molecules. 2022; 27(12):3820. https://doi.org/10.3390/molecules27123820

Chicago/Turabian Style

Mikołajczyk, Marian, Marek Cypryk, Bartłomiej Gostyński, and Jakub Kowalczewski. 2022. "Correction: Mikołajczyk et al. Nucleophilic Substitution at Heteroatoms—Identity Substitution Reactions at Phosphorus and Sulfur Centers: Do They Proceed in a Concerted (SN2) or Stepwise (A–E) Way? Molecules 2022, 27, 599" Molecules 27, no. 12: 3820. https://doi.org/10.3390/molecules27123820

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