Synthesis of a Novel Chitosan/Basil Oil Blend and Development of Novel Low Density Poly Ethylene/Chitosan/Basil Oil Active Packaging Films Following a Melt-Extrusion Process for Enhancing Chicken Breast Fillets Shelf-Life
Abstract
:1. Introduction
2. Results
2.1. XRD Analysis
2.2. FTIR Results
2.3. Thermogravimetric (TG)/Differential Thermal Analysis (DTA) Results
2.4. DSC Results
2.5. SEM Morphology
2.6. Tensile Measurements
2.7. Water Sorption
2.8. Water Vapor Transmission Rate (WVTR)
2.9. Oxygen Permeability (OP)
2.10. Overall Migration Rate
2.11. Antioxidant Activity
2.12. Lipid Oxidation
2.13. Statistical Analysis of the Experimental Data
3. Materials and Methods
3.1. Materials
3.2. Preparation Methods
3.2.1. Preparation of CS_BO Hybrid Blend
3.2.2. Preparation of LDPE/CS_BO Active Films
3.3. XRD Analysis
3.4. FTIR Spectrometry
3.5. Thermal Studies TG-DTA/DSC
3.6. Scanning Electron Microscopy (SEM) of LDPE/CS_BO Blends
3.7. Tensile Properties
3.8. Water Sorption
3.9. Water Vapor Transmission Rate (WVTR)
3.10. Oxygen Permeability (OP)
3.11. Overall Migration Test
3.12. Antioxidant Activity
3.13. Lipid Oxidation Test
3.14. Statistical Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Code Name | Melting Point T (°C) | Fusion Enthalpy ΔΗf (J/g) | Young’s Modulus E (St. Dev.) (MPa) | Tensile Strength σ (St. Dev.) (MPa) | % Elongation at Break (ε) (St. Dev.) |
---|---|---|---|---|---|
LDPE | 110.8 | 113.5 | 203.3 ± 42.4 | 13.7 ± 1.3 | 161.0 ± 72.0 |
LDPE/CS_BO5 | 108.4 | 97.2 | 240.7 ± 39.6 | 11.6 ± 0.7 | 58.3 ± 10.6 |
LDPE/CS_BO10 | 109.3 | 103.4 | 271.3 ± 47.1 | 9.7 ± 1.5 | 61.3 ± 25.0 |
LDPE/CS_BO20 | 107.8 | 81.6 | 355.7 ± 49.1 | 9.5 ± 0.9 | 29.3 ± 9.4 |
LDPE/CS_BO30 | 108.5 | 79.1 | 346.0 ± 57.4 | 9.3 ± 0.6 | 19.0 ± 11.2 |
Code Name | WVTR (St. Dev.) (g/m2·day) | % Water Sorption (St. Dev.) | OP (St. Dev.) cm3·mm/m2·day | Total Migration (St. Dev.) (mg/L) | Antioxidant Activity after 24 h (St. Dev.) |
---|---|---|---|---|---|
LDPE | 19.49 ± 1.5 | 0.00 ± 0.00 | 182.4 ± 3.4 | 12.4 ± 0.1 | - |
LDPE/CS_BO5 | 14.35 ± 1.2 | 0.12 ± 0.05 | 115.4 ± 2.8 | 15.5 ± 0.1 | 6.4 ± 0.9 |
LDPE/CS_BO10 | 13.45 ± 1.8 | 0.17 ± 0.05 | 83.3 ± 3.5 | 17.6 ± 0.1 | 12.8 ± 1.2 |
LDPE/CS_BO20 | 19.12 ± 1.5 | 0.27 ± 0.05 | 78.4 ± 2.5 | 25.3 ± 0.1 | 22.4 ± 1.4 |
LDPE/CS_BO30 | 20.71 ± 2.2 | 1.15 ± 0.60 | 81.8 ± 5.4 | 45.4 ± 0.1 | 34.6 ± 1.5 |
Sig. | IA | |
---|---|---|
E | 0.002 | 96 |
σuts | 0.006 | 88 |
%ε | 0.002 | 96 |
WVP | 0.003 | 94 |
% water sorption | 0.005 | 90 |
OP | 0.004 | 92 |
Total migration | 0.002 | 96 |
TBARS | 0.003 | 94 |
% Antioxidant activity after 24 h | 0.000 | 100 |
Code Name | LDPE (g) | CS_BO (g) | Extrusion Temperature (°C) | Extrusion Rotation Speed (rpm) | Extrusion Total Processing Time (min) |
---|---|---|---|---|---|
LDPE | 5.00 | - | 140 | 100 | 5 |
LDPE/CS_BO5 | 4.75 | 0.25 | 140 | 100 | 5 |
LDPE/CS_BO10 | 4.50 | 0.50 | 140 | 100 | 5 |
LDPE/CS_BO20 | 3.00 | 1.00 | 140 | 100 | 5 |
LDPE/CS_BO30 | 3.50 | 1.50 | 140 | 100 | 5 |
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Giannakas, A.E.; Salmas, C.E.; Leontiou, A.; Baikousi, M.; Moschovas, D.; Asimakopoulos, G.; Zafeiropoulos, N.E.; Avgeropoulos, A. Synthesis of a Novel Chitosan/Basil Oil Blend and Development of Novel Low Density Poly Ethylene/Chitosan/Basil Oil Active Packaging Films Following a Melt-Extrusion Process for Enhancing Chicken Breast Fillets Shelf-Life. Molecules 2021, 26, 1585. https://doi.org/10.3390/molecules26061585
Giannakas AE, Salmas CE, Leontiou A, Baikousi M, Moschovas D, Asimakopoulos G, Zafeiropoulos NE, Avgeropoulos A. Synthesis of a Novel Chitosan/Basil Oil Blend and Development of Novel Low Density Poly Ethylene/Chitosan/Basil Oil Active Packaging Films Following a Melt-Extrusion Process for Enhancing Chicken Breast Fillets Shelf-Life. Molecules. 2021; 26(6):1585. https://doi.org/10.3390/molecules26061585
Chicago/Turabian StyleGiannakas, Aris E., Constantinos E. Salmas, Areti Leontiou, Maria Baikousi, Dimitrios Moschovas, Georgios Asimakopoulos, Nikolaos E. Zafeiropoulos, and Apostolos Avgeropoulos. 2021. "Synthesis of a Novel Chitosan/Basil Oil Blend and Development of Novel Low Density Poly Ethylene/Chitosan/Basil Oil Active Packaging Films Following a Melt-Extrusion Process for Enhancing Chicken Breast Fillets Shelf-Life" Molecules 26, no. 6: 1585. https://doi.org/10.3390/molecules26061585