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Article

New Hybrid Polyurea-Polyurethane Elastomers with Antistatic Properties and an Influence of Various Additives on Their Physicochemical Properties

1
Department of Analytical Chemistry, Faculty of Chemistry, Adam Mickiewicz University, 61-614 Poznań, Poland
2
STI Chemsampler, sp. z o. o. sp. k., 61-371 Poznań, Poland
*
Author to whom correspondence should be addressed.
Molecules 2021, 26(19), 5778; https://doi.org/10.3390/molecules26195778
Submission received: 3 September 2021 / Revised: 19 September 2021 / Accepted: 20 September 2021 / Published: 24 September 2021
(This article belongs to the Special Issue Hybrid Materials for Advanced Applications)

Abstract

Polyurea is a synthetic high-strength elastomeric material that can be sprayed as a coating over existing structures in order to protect against weathering effects. It is ideal for anti-corrosion protection and is characterized by excellent mechanical properties and adhesion to various surfaces. Further development of this technology may allow obtaining new coatings with improved antistatic properties, which would be an excellent alternative compared to used antistatic epoxy paints. This paper will examine the influence of tetraalkylammonium salt (1), potassium hexafluorophosphate solution (2) and imidazolium-based ionic liquid (3) on the improvement of antistatic properties of the polyurea-polyurethane coatings. In addition, the modified samples were also verified in terms of changes in mechanical properties and the appearance of functional groups other than in the reference sample, as well as surface defects that may arise due to incompatibility of the antistatic additive with the polymer matrix. In order to obtain information about the properties mentioned above, the electrical resistance was determined, the tensile strength and elongation were measured, FT-IR spectra were made, and images were taken with the use of scanning electron microscopy. The conducted research showed that the antistatic properties of the tested hybrid coatings could be improved, but their use may be associated with certain limitations that should be taken into account when designing such materials.
Keywords: polyurea; polyurethane; coatings; antistatic additives; ionic liquids; resistance; tensile stress; Fourier transform infrared spectroscopy; scanning electron microscopy polyurea; polyurethane; coatings; antistatic additives; ionic liquids; resistance; tensile stress; Fourier transform infrared spectroscopy; scanning electron microscopy

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MDPI and ACS Style

Kosiński, S.; Gonsior, M.; Krzyżanowski, P.; Rykowska, I. New Hybrid Polyurea-Polyurethane Elastomers with Antistatic Properties and an Influence of Various Additives on Their Physicochemical Properties. Molecules 2021, 26, 5778. https://doi.org/10.3390/molecules26195778

AMA Style

Kosiński S, Gonsior M, Krzyżanowski P, Rykowska I. New Hybrid Polyurea-Polyurethane Elastomers with Antistatic Properties and an Influence of Various Additives on Their Physicochemical Properties. Molecules. 2021; 26(19):5778. https://doi.org/10.3390/molecules26195778

Chicago/Turabian Style

Kosiński, Szymon, Marcin Gonsior, Piotr Krzyżanowski, and Iwona Rykowska. 2021. "New Hybrid Polyurea-Polyurethane Elastomers with Antistatic Properties and an Influence of Various Additives on Their Physicochemical Properties" Molecules 26, no. 19: 5778. https://doi.org/10.3390/molecules26195778

APA Style

Kosiński, S., Gonsior, M., Krzyżanowski, P., & Rykowska, I. (2021). New Hybrid Polyurea-Polyurethane Elastomers with Antistatic Properties and an Influence of Various Additives on Their Physicochemical Properties. Molecules, 26(19), 5778. https://doi.org/10.3390/molecules26195778

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