β-Cyclodextrin-Polyacrylamide Hydrogel for Removal of Organic Micropollutants from Water
Abstract
:1. Introduction
2. Experimental Section
2.1. Materials
2.2. Synthesis of β-Cyclodextrin-Methacrylate (β-CD-MA)
2.3. Synthesis of β-Cyclodextrin-Polyacrylamide (β-CD-PAAm) Gel
2.4. Synthesis of Polyacrylamide (PAAm) Gel
2.5. Characterizations
2.6. Swelling Studies
2.7. Kinetic Studies of Pollutant Removal
2.8. Thermodynamic Studies of Pollutant Removal
2.9. Hydrogel Recycling Studies
3. Results and Discussion
3.1. Synthesis of β-Cyclodextrin-Methacrylate
3.2. Synthesis and Characterizations of Hydrogels
3.3. Kinetic Studies of Pollutant Removal
3.4. Thermodynamic Studies of Pollutant Removal
3.5. Hydrogel Recycling Studies
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Sample Availability
References
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Sample | Atomic Concentration (%) | ||
---|---|---|---|
C | O | N | |
PAAm gel | 65.72 | 17.11 | 17.17 |
β-CD-PAAm gel | 64.42 | 22.01 | 13.57 |
Sample | Weight (mg) | Swelling Ratio | |
---|---|---|---|
Swollen (Ws) | Dry (Wd) | ||
PAAm gel | 590.1 ± 22.3 | 43.1 ± 1.0 | 12.7 ± 0.6 |
β-CD-PAAm gel | 1272.3 ± 45.4 | 42.0 ± 2.6 | 29.4 ± 2.4 |
Pollutant | MW | k2 (g/mg min) | Correlation Coefficient R2 | qe,cal (mg/g) | qe,exp (mg/g) |
---|---|---|---|---|---|
Php | 318.32 | 0.0051 | 0.9999 | 6.21 | 6.07 |
BPA | 228.29 | 0.0096 | 0.9999 | 4.86 | 4.78 |
PR·HCl | 295.80 | 0.0266 | 0.9999 | 3.84 | 3.83 |
2-NO | 144.17 | 0.0203 | 0.9997 | 2.32 | 2.29 |
Pollutant | K (M−1) | Correlation Coefficient R2 | qmax,e (mg/g) |
---|---|---|---|
Php | 22,000 | 0.9946 | 34.97 |
BPA | 19,882 | 0.9559 | 29.59 |
PR·HCl | 34,824 | 0.9673 | 8.45 |
2-NO | 811 | 0.9965 | 55.56 |
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Song, X.; Mensah, N.N.; Wen, Y.; Zhu, J.; Zhang, Z.; Tan, W.S.; Chen, X.; Li, J. β-Cyclodextrin-Polyacrylamide Hydrogel for Removal of Organic Micropollutants from Water. Molecules 2021, 26, 5031. https://doi.org/10.3390/molecules26165031
Song X, Mensah NN, Wen Y, Zhu J, Zhang Z, Tan WS, Chen X, Li J. β-Cyclodextrin-Polyacrylamide Hydrogel for Removal of Organic Micropollutants from Water. Molecules. 2021; 26(16):5031. https://doi.org/10.3390/molecules26165031
Chicago/Turabian StyleSong, Xia, Nana Nyarko Mensah, Yuting Wen, Jingling Zhu, Zhongxing Zhang, Wui Siew Tan, Xinwei Chen, and Jun Li. 2021. "β-Cyclodextrin-Polyacrylamide Hydrogel for Removal of Organic Micropollutants from Water" Molecules 26, no. 16: 5031. https://doi.org/10.3390/molecules26165031