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Open AccessArticle

First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides

Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, Ufa 450075, Russia
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Academic Editor: Alexander O. Terent’ev
Molecules 2020, 25(8), 1874; https://doi.org/10.3390/molecules25081874
Received: 23 March 2020 / Revised: 13 April 2020 / Accepted: 15 April 2020 / Published: 18 April 2020
(This article belongs to the Special Issue Chemistry of Peroxides)
An efficient method for the synthesis of tetraoxathiaspiroalkanes, tetraoxathiocanes, and hexaoxathiadispiroalkanes was developed by reactions of pentaoxacanes, pentaoxaspiroalkanes, and heptaoxadispiroalkanes with hydrogen sulfide in the presence of a catalyst, Sm(NO3)3·6H2O. We found that the synthesized S-containing di- and triperoxides exhibit high cytotoxic activity against Jurkat, K562, U937, and HL60 tumor cultures, and fibroblasts. View Full-Text
Keywords: catalysis; lanthanide salts; hydrogen sulfide; thia-peroxides; cytotoxic activity catalysis; lanthanide salts; hydrogen sulfide; thia-peroxides; cytotoxic activity
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MDPI and ACS Style

Makhmudiyarova, N.; Ishmukhametova, I.; Dzhemileva, L.; D’yakonov, V.; Ibragimov, A.; Dzhemilev, U. First Example of Catalytic Synthesis of Cyclic S-Containing Di- and Triperoxides. Molecules 2020, 25, 1874.

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