Chromium-Based Polypyrrole/MIL-101 Nanocomposite as an Effective Sorbent for Headspace Microextraction of Methyl tert-Butyl Ether in Soil Samples
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of the PPy@MIL-101(Cr) Nanocomposite Sorbent
2.2. Optimization of the Extraction Procedure
2.2.1. Extraction Time
2.2.2. Extraction Temperature
2.2.3. Desorption Condition
2.3. Comparison of the PPy@MIL-101(Cr)-Coated Fiber with Commercial Fibers
2.4. Analytical Performances
2.5. Determination of MTBE in Contaminated Soil Samples
3. Experimental
3.1. Materials
3.2. Instruments and Conditions
3.3. Preparation of MIL-101(Cr)
3.4. Fabrication of the SPME Fiber Coated by PPy@ MIL-101(Cr)
3.5. HS-SPME Procedure
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample Availability: Not available. |
Method | Fiber | RSD% | LOD | LDR | Sample | Ref. |
---|---|---|---|---|---|---|
HS-SPME–GC-FID | IL-mediated PDMS-MWCNTs | 6.5 | 0.007 ng·mL−1 | 0.03–200 ng·mL−1 | Water | [25] |
HS-SPME–GC–MS | DVB/CAR/PDMS | <10 | 0.03 μg·L−1 | 0.10–40 μg·L−1 | Blood serum | [26] |
HS-SPME–GC-FID | DVB/CAR/PDMS | 6–8 | 0.02 μg·L−1 | 0.1–400 μg·L−1 | Water | [27] |
HS-SPME-IMS | PDMS/CAR | 8.3 | 5 mg·L−1 | 10–1390 ng·L−1 | Water | [28] |
HS-SPME–GC–MS | Carboxen-PDMS | 10–11 | 10 ng·L−1 | 5–250 ng·L−1 | Water | [29] |
HS-SPME–GC–MS | SWCNTs | <15 | 10 ng·L−1 | 100–5000 ng·L−1 | Urine | [30] |
HS-SPME–GC–MS | Carboxen-PDMS | 5 | 1.5 ng·L−1 | 0.3–2.4 ng·L−1 | Whole blood | [31] |
HS-SPME–GC–FID | PDMS/DVB | 6.3 | 0.45 μg·L−1 | 5–500 μg·L−1 | Water | [32] |
HS-SPME–GC-FID | PPy@MIL-101(Cr) | 8.4 | 0.01 ng·g−1 | 5–40,000 ng·g−1 | Soil | This work |
Soil Sample | Added (µg ·g−1) | Determined ± SD a (µg·g−1) | Recovery (%) |
---|---|---|---|
Kermanshah Oil Refinery Company (sampling from the surface of soil) | 0 | 1.16 ± 0.51 | - |
2 | 3.30 ± 0.08 | 107 | |
Kermanshah Oil Refinery Company (sampling from the depth of soil) | 0 | 1.54 ± 0.25 | - |
2 | 3.61 ± 0.17 | 103 | |
Kabir gas station (sampling from surface soil behind the official building) | 0 | 1.41 ± 0.25 | - |
0.5 | 1.98 ± 0.17 | 117 | |
Besat gas station (sampling from surface soil of gas station area) | 0 | 0.92 ± 0.48 | - |
1 | 1.89 ± 0.05 | 96 | |
Shahrvand gas station (sampling from surface soil of gas station area) | 0 | 2.09 ± 0.34 | - |
2 | 4.03 ± 0.09 | 97 | |
Shahrvand gas station (sampling from firefighting soil bucket) | 0 | 2.72 ± 0.50 | - |
2 | 4.48 ± 0.08 | 88 |
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Darabi, J.; Ghiasvand, A. Chromium-Based Polypyrrole/MIL-101 Nanocomposite as an Effective Sorbent for Headspace Microextraction of Methyl tert-Butyl Ether in Soil Samples. Molecules 2020, 25, 644. https://doi.org/10.3390/molecules25030644
Darabi J, Ghiasvand A. Chromium-Based Polypyrrole/MIL-101 Nanocomposite as an Effective Sorbent for Headspace Microextraction of Methyl tert-Butyl Ether in Soil Samples. Molecules. 2020; 25(3):644. https://doi.org/10.3390/molecules25030644
Chicago/Turabian StyleDarabi, Jila, and Alireza Ghiasvand. 2020. "Chromium-Based Polypyrrole/MIL-101 Nanocomposite as an Effective Sorbent for Headspace Microextraction of Methyl tert-Butyl Ether in Soil Samples" Molecules 25, no. 3: 644. https://doi.org/10.3390/molecules25030644