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Molecules 2018, 23(6), 1311; https://doi.org/10.3390/molecules23061311

Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions

1
Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
2
Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Street, Ekaterinburg 620041, Russia
3
Chemische Biologie, Max-Planck-Institut für Molekulare Physiologie, Otto-Hahn Strasse 11, 44227 Dortmund, Germany
4
Fakultät Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 4a, 44227 Dortmund, Germany
5
Faculty of Science, Peoples’ Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow 117198, Russia
*
Author to whom correspondence should be addressed.
Received: 14 May 2018 / Revised: 25 May 2018 / Accepted: 25 May 2018 / Published: 30 May 2018
(This article belongs to the Special Issue Ferrocene and Ferrocene-Containing Compounds)
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Abstract

Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl2(PPh3)3] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones. View Full-Text
Keywords: ferrocenyl ligands; catalysis; cycloaddition; hydrogen transfer ferrocenyl ligands; catalysis; cycloaddition; hydrogen transfer
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Utepova, I.A.; Serebrennikova, P.O.; Streltsova, M.S.; Musikhina, A.A.; Fedorchenko, T.G.; Chupakhin, O.N.; Antonchick, A.P. Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions. Molecules 2018, 23, 1311.

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