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Molecules 2018, 23(6), 1311;

Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions

Ural Federal University, 19 Mira Street, Ekaterinburg 620002, Russia
Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Street, Ekaterinburg 620041, Russia
Chemische Biologie, Max-Planck-Institut für Molekulare Physiologie, Otto-Hahn Strasse 11, 44227 Dortmund, Germany
Fakultät Chemie und Chemische Biologie, Technische Universität Dortmund, Otto-Hahn-Strasse 4a, 44227 Dortmund, Germany
Faculty of Science, Peoples’ Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow 117198, Russia
Author to whom correspondence should be addressed.
Received: 14 May 2018 / Revised: 25 May 2018 / Accepted: 25 May 2018 / Published: 30 May 2018
(This article belongs to the Special Issue Ferrocene and Ferrocene-Containing Compounds)
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Novel complexes of 1,2-P,N-bidentate ferrocenyl ligands with AgOAc or with [RuCl2(PPh3)3] as catalysts have been studied in asymmetric synthesis. The catalytic activity of these systems have been studied in [3+2]-cycloaddition of azomethine ylides with olefins and the asymmetric transfer hydrogenation of ketones. View Full-Text
Keywords: ferrocenyl ligands; catalysis; cycloaddition; hydrogen transfer ferrocenyl ligands; catalysis; cycloaddition; hydrogen transfer

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Utepova, I.A.; Serebrennikova, P.O.; Streltsova, M.S.; Musikhina, A.A.; Fedorchenko, T.G.; Chupakhin, O.N.; Antonchick, A.P. Enantiomerically Enriched 1,2-P,N-Bidentate Ferrocenyl Ligands for 1,3-Dipolar Cycloaddition and Transfer Hydrogenation Reactions. Molecules 2018, 23, 1311.

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