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Synthesis of Phenolic Compounds by Trapping Arynes with a Hydroxy Surrogate
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Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans

Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan
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Academic Editor: Hiroto Yoshida
Molecules 2015, 20(10), 19449-19462; https://doi.org/10.3390/molecules201019449
Received: 1 October 2015 / Revised: 15 October 2015 / Accepted: 20 October 2015 / Published: 23 October 2015
(This article belongs to the Special Issue Development and Application of Aryne Chemistry in Organic Synthesis)
Successive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives. View Full-Text
Keywords: aryne; isobenzofuran; [2+4] cycloaddition; 1,2-dihaloarenes; polyacene; halogen-lithium exchange aryne; isobenzofuran; [2+4] cycloaddition; 1,2-dihaloarenes; polyacene; halogen-lithium exchange
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Eda, S.; Hamura, T. Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans. Molecules 2015, 20, 19449-19462.

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