Glycosylation of a Newly Functionalized Orthoester Derivative
Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan
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Molecules 2014, 19(2), 2602-2611; https://doi.org/10.3390/molecules19022602
Received: 26 January 2014 / Revised: 20 February 2014 / Accepted: 21 February 2014 / Published: 24 February 2014
(This article belongs to the Section Organic Chemistry)
Tandem glycosylation of the 6-O-Fmoc-substituted benzyl orthoester derivative 2a was carried out in moderate yields by electrogenerated acid (EGA). The Fmoc group was effectively removed under mild basic conditions, and the product was submitted to the subsequent glycosylation.
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Keywords:
glycosylation; orthoester; electrogenerated acid (EGA); Fmoc group; selective deprotection
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MDPI and ACS Style
Kawa, K.; Saitoh, T.; Kaji, E.; Nishiyama, S. Glycosylation of a Newly Functionalized Orthoester Derivative. Molecules 2014, 19, 2602-2611. https://doi.org/10.3390/molecules19022602
AMA Style
Kawa K, Saitoh T, Kaji E, Nishiyama S. Glycosylation of a Newly Functionalized Orthoester Derivative. Molecules. 2014; 19(2):2602-2611. https://doi.org/10.3390/molecules19022602
Chicago/Turabian StyleKawa, Kohei; Saitoh, Tsuyoshi; Kaji, Eisuke; Nishiyama, Shigeru. 2014. "Glycosylation of a Newly Functionalized Orthoester Derivative" Molecules 19, no. 2: 2602-2611. https://doi.org/10.3390/molecules19022602
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