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Growth of Fullerene Fragments Using the Diels-Alder Cycloaddition Reaction: First Step towards a C60 Synthesis by Dimerization
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Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione

Department of Chemistry, University of Georgia, Athens, GA, 30602, USA
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Molecules 2013, 18(6), 6969-6989; https://doi.org/10.3390/molecules18066969
Received: 1 March 2013 / Revised: 14 May 2013 / Accepted: 30 May 2013 / Published: 14 June 2013
(This article belongs to the Special Issue Diels-Alder Reaction)
12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione (quinone 2) served as the dienophile in numerous intermolecular Diels-Alder reactions. These cycloadditions were conducted either thermally (including microwave heating) or with Lewis acid activation. While most dienes reacted with quinone 2 in good chemical yield, others were incompatible under the experimental conditions used. View Full-Text
Keywords: Diels-Alder reaction; cascade process; one-pot reaction; Lewis acid catalysis Diels-Alder reaction; cascade process; one-pot reaction; Lewis acid catalysis
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MDPI and ACS Style

Majetich, G.; Zhang, Y.; Tian, X.; Zou, G.; Li, Y.; Wang, Y.; Hu, S.; Huddleston, E. Diels-Alder Reactions of 12-Hydroxy-9(10®20)-5aH-abeo-abieta-1(10),8(9),12(13)-triene-11,14-dione. Molecules 2013, 18, 6969-6989.

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