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Keywords = warm-mix asphalts

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18 pages, 3861 KiB  
Article
Investigating the Rheological Impact of USP Warm Mix Modifier on Asphalt Binder
by Yali Liu, Jingfei Ping, Hao Guo, Yikai Kang and Yali Ye
Coatings 2025, 15(7), 784; https://doi.org/10.3390/coatings15070784 - 3 Jul 2025
Viewed by 412
Abstract
USP (usual temperature pitch)-modified asphalt optimizes its rheological properties through reactions between the modifier and the asphalt. This significantly enhances the high- and low-temperature adaptability and environmental friendliness of asphalt. It has now become an important research direction in the field of highway [...] Read more.
USP (usual temperature pitch)-modified asphalt optimizes its rheological properties through reactions between the modifier and the asphalt. This significantly enhances the high- and low-temperature adaptability and environmental friendliness of asphalt. It has now become an important research direction in the field of highway engineering. This article systematically investigates the impact of different dosages of USP warm mix modifier on asphalt binders through rheological and microstructural analysis. Base asphalt and SBS-modified asphalt were blended with USP at varying ratios. Conventional tests (penetration, softening point, ductility) were combined with dynamic shear rheometry (DSR, AASHTO T315) and bending beam rheometry (BBR, AASHTO T313) to characterize temperature/frequency-dependent viscoelasticity. High-temperature performance was quantified via multiple stress creep recovery (MSCR, ASTM D7405), while fluorescence microscopy and FTIR spectroscopy elucidated modification mechanisms. Key findings reveal that (1) optimal USP thresholds exist at 4.0% for base asphalt and 4.5% for SBS modified asphalt, beyond which the rutting resistance factor (G*/sin δ) decreases by 20–31% due to plasticization effects; (2) USP significantly improves low-temperature flexibility, reducing creep stiffness at −12 °C by 38% (USP-modified) and 35% (USP/SBS composite) versus controls; (3) infrared spectroscopy displays that no new characteristic peaks appeared in the functional group region of 4000–1300 cm−1 for the two types of modified asphalt after the incorporation of USP, indicating that no chemical changes occurred in the asphalt; and (4) fluorescence imaging confirmed that the incorporation of USP led to disintegration of the spatial network structure of the control asphalt, explaining the reason for the deterioration of high-temperature performance. Full article
(This article belongs to the Special Issue Surface Treatments and Coatings for Asphalt and Concrete)
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24 pages, 8192 KiB  
Article
Mapping the Relationship Between Diffusion Characteristics of Warm-Mix Recycled Asphalt on Molecular Dynamics (MD) and High-Low Temperature Properties of Mixtures
by Xin Jin, Shanshan Meng, Haoxuan Fu, Qi Zhao, Deli Li, Zhuolin Li, Ye Yang, Yanhai Yang, Jiupeng Zhang and Qingyue Zhou
Materials 2025, 18(12), 2740; https://doi.org/10.3390/ma18122740 - 11 Jun 2025
Viewed by 341
Abstract
Warm-mix recycled asphalt (WMA-R) technology for reclaimed asphalt pavement (RAP) significantly reduces energy consumption and environmental pollution while maintaining the performance of asphalt mixtures. Significant progress has been made at home and abroad in evaluating the impact of regenerated asphalt mixtures on the [...] Read more.
Warm-mix recycled asphalt (WMA-R) technology for reclaimed asphalt pavement (RAP) significantly reduces energy consumption and environmental pollution while maintaining the performance of asphalt mixtures. Significant progress has been made at home and abroad in evaluating the impact of regenerated asphalt mixtures on the performance of regenerated asphalt. However, the performance improvement of WMA-R depends on the effective diffusion of regenerated agents and their interaction mechanism with aged asphalt, which has not been fully studied. This paper systematically studies the diffusion characteristics of biomimetic-based warm-mix regenerant in aged asphalt and its impact on the high- and low-temperature performance of asphalt mixtures through MD and experimental verification. The results show that biomimetic-based warm-mix regenerant can significantly improve the diffusion performance of aged asphalt. Through the rutting test and low-temperature bending test, the significant improvement of the biomimetic-based warm-mix regenerant in the rutting resistance and crack resistance of asphalt mixtures was verified. Full article
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21 pages, 3164 KiB  
Article
Microscopic Mechanism of Asphalt Mixture Reinforced by Polyurethane and Silane Coupling Agent: A Molecular Dynamics Simulation-Based Study
by Zhi Lin, Weiping Sima, Xi’an Gao, Yu Liu and Jin Li
Polymers 2025, 17(12), 1602; https://doi.org/10.3390/polym17121602 - 9 Jun 2025
Cited by 1 | Viewed by 350
Abstract
Most modified asphalts require high-temperature shearing and prolonged mixing to achieve a uniform structure, often resulting in substantial exhaust gas pollution. This study explores the utilization of polyurethane (PU) as a warm mix asphalt modifier, leveraging its favorable compatibility with asphalt at lower [...] Read more.
Most modified asphalts require high-temperature shearing and prolonged mixing to achieve a uniform structure, often resulting in substantial exhaust gas pollution. This study explores the utilization of polyurethane (PU) as a warm mix asphalt modifier, leveraging its favorable compatibility with asphalt at lower temperatures to mitigate emissions. To address the inherent limitations of PU-modified asphalt mixtures, namely, poor low-temperature performance and susceptibility to water damage, silane coupling agents (SCAs) are introduced to reinforce the asphalt–aggregate interfacial strength. At the microscopic level, the optimal PU content (20.8%) was determined through analysis of micro-viscosity and radial distribution functions (RDFs). SCA effects on interfacial properties were assessed using adhesion work, adhesion depth, and interfacial thermal stability. At the macroscopic level, performance metrics—including strength, high-temperature resistance, low-temperature resistance, and water stability—were evaluated against a benchmark hot mix SBS-modified asphalt mixture. The results indicate that PU-modified asphalts exhibit superior high-temperature performance and strength but slightly lower low-temperature performance and insufficient water stability. The addition of SCAs improved both low-temperature and water stability attributes, enabling the mixtures to meet specification requirements. The simulation results suggest that KH-550, which chemically reacts with isocyanate groups (-OCN) in PU, exhibits a better interfacial reinforcement effect than KH-570. Therefore, KH-550 is recommended as the preferred SCA for PU-modified asphalt mixtures in practical applications. Full article
(This article belongs to the Section Polymer Physics and Theory)
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31 pages, 3743 KiB  
Article
Dynamic Mechanical Characterization of Warm-Mixed Steel Slag-Crumb Rubber Modified Asphalt Mixture in Wide- and Narrow-Frequency Domains
by Fei Zhang, Bingyuan Huo, Chao Li, Heng Liu, Pengzhi Li, Yongming Xing, Lan Wang and Pucun Bai
Polymers 2025, 17(11), 1449; https://doi.org/10.3390/polym17111449 - 23 May 2025
Viewed by 443
Abstract
To investigate the dynamic mechanical properties of warm-mix steel slag-crumb rubber modified asphalt mixtures across wide- and narrow-frequency domains and evaluate the applicability of warm-mix technology, four distinct mixtures were prepared. The dynamic modulus characteristics under measured temperatures and frequencies were initially analyzed [...] Read more.
To investigate the dynamic mechanical properties of warm-mix steel slag-crumb rubber modified asphalt mixtures across wide- and narrow-frequency domains and evaluate the applicability of warm-mix technology, four distinct mixtures were prepared. The dynamic modulus characteristics under measured temperatures and frequencies were initially analyzed through complex modulus testing to elucidate narrow-frequency-domain mechanical behavior. Subsequently, leveraging the linear viscoelastic (LVE) theory and time–temperature superposition principle (TTSP), both the 2 Springs, 2 Parabolic Elements and 1 Dashpot (2S2P1D) mechanical element model and Modified Havriliak–Negami (MHN) mathematical model were established based on experimental data to characterize wide-frequency-domain dynamic responses. The results demonstrate substantial consistency in mechanical interpretation between narrow- and wide-frequency domain datasets, with enhanced information resolution achieved in wide-frequency analysis. Both models demonstrate comparable accuracy in characterizing the thermomechanical behavior of warm-mix steel slag-crumb rubber modified asphalt mixture across extended frequency and temperature ranges, while showing negligible performance discrepancies between the 2S2P1D and MHN formulations. Furthermore, both Cole–Cole and Black diagrams convincingly demonstrate the reliability of model predictions. This systematic investigation confirms the technical viability of warm-mix steel slag-crumb rubber modified asphalt mixture while establishing a dual-validated modeling framework for comprehensive performance prediction. Full article
(This article belongs to the Special Issue Sustainable Polymeric Materials in Building and Construction)
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24 pages, 5501 KiB  
Article
Design and Construction Control of Warm Mix Epoxy Asphalt Mixture with Low Epoxy Content for Service Area Pavements
by Bo Chen, Kai Chen, Xuetang Xiong, Yi Deng, Zicong Chen, Weixiong Li and Huayang Yu
Buildings 2025, 15(10), 1673; https://doi.org/10.3390/buildings15101673 - 15 May 2025
Viewed by 509
Abstract
Highway service area pavements are exposed to severe conditions such as heavy traffic, oil infiltration, and temperature fluctuations, which lead to issues like rutting and cracking in conventional asphalt mixtures. Although warm mix epoxy asphalt mixtures have high strength and corrosion resistance, their [...] Read more.
Highway service area pavements are exposed to severe conditions such as heavy traffic, oil infiltration, and temperature fluctuations, which lead to issues like rutting and cracking in conventional asphalt mixtures. Although warm mix epoxy asphalt mixtures have high strength and corrosion resistance, their high epoxy content and stringent construction requirements limit their engineering applications. To address these challenges, a design and construction method for warm mix epoxy asphalt mixtures with low epoxy content (≤20%) was proposed. The mineral aggregate gradation was optimized using the CAVF volumetric method, and the impact of different epoxy asphalt-aggregate ratios was analyzed through various performance tests, including Marshall stability, high-temperature stability, low-temperature bending, and oil resistance tests. The construction available time was determined using viscosity tests, and process parameters were optimized based on infrared thermography and real-time compaction monitoring. The results show that a 5.4% epoxy asphalt-aggregate ratio yields the best overall performance, with significantly better dynamic stability, tensile strain, and oil resistance compared to SBS-modified asphalt mixtures. The recommended construction parameters, including temperature control and compaction process, ensure optimal performance and durability. The proposed methods provide essential technical support for the effective application of warm mix epoxy asphalt in service area pavements. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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13 pages, 1356 KiB  
Article
Investigating the Impact of Surfactant-Based Warm-Mix Additives on the Performance of Recycled Asphalt Mixtures
by Hao Xiang, Desheng Yang, Shunxian Peng and Wei Gao
Materials 2025, 18(8), 1732; https://doi.org/10.3390/ma18081732 - 10 Apr 2025
Viewed by 421
Abstract
This investigation aimed to assess the influence of warm-mix additives on the performance characteristics of recycled asphalt mixtures. Pressure-aging vessels were employed to simulate the aging of asphalt binders. Warm-mix recycled asphalt (WMRA) and mixtures were prepared by incorporating self-developed plant-oil-based rejuvenators and [...] Read more.
This investigation aimed to assess the influence of warm-mix additives on the performance characteristics of recycled asphalt mixtures. Pressure-aging vessels were employed to simulate the aging of asphalt binders. Warm-mix recycled asphalt (WMRA) and mixtures were prepared by incorporating self-developed plant-oil-based rejuvenators and surfactant-based warm-mix additives. The rheological properties of asphalt were tested by a dynamic shear rheometer (DSR). Furthermore, the pavement performance of the asphalt mixture was evaluated by a rutting test, beam bending test, Marshall stability test, and freeze–thaw splitting test. The experimental results demonstrated that the addition of warm-mix additives reduces the penetration and softening point of recycled asphalt while enhancing its ductility. Performance improvement was quantitatively evaluated using a recovery index. The complex modulus and rutting factor of the WMRA were found to be lower than those of recycled asphalt, indicating a decrease in the asphalt’s resistance to deformation owing to the surfactant. Both the hot-mix and warm-mix recycled asphalt mixtures met the specified requirements for various performance indicators. The warm-mix rejuvenator outperformed the regular rejuvenator in evaluating water stability using the soaked Marshall residual stability method, whereas the evaluation based on the freeze–thaw splitting strength ratio demonstrated the opposite trend. Full article
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15 pages, 6157 KiB  
Article
Preliminary Characterization of Lignin-Modified Binder for Half-Warm-Mix Asphalt
by Ana M. Rodríguez Pasandín, Pablo Orosa Iglesias, Ignacio Pérez Pérez and Ana M. Rodríguez-Alloza
Polymers 2025, 17(8), 1019; https://doi.org/10.3390/polym17081019 - 9 Apr 2025
Viewed by 524
Abstract
There is a growing trend to promote circular economy practices and reduce petroleum-derived product consumption in the paving sector. In this context, a liquid lignin-rich industrial waste was incorporated at 0% (control), 5%, 10%, 15%, and 20% into a bitumen emulsion to manufacture [...] Read more.
There is a growing trend to promote circular economy practices and reduce petroleum-derived product consumption in the paving sector. In this context, a liquid lignin-rich industrial waste was incorporated at 0% (control), 5%, 10%, 15%, and 20% into a bitumen emulsion to manufacture a lignin-based biobinder for half-warm-mix asphalt (HWMA). The mix of the bitumen emulsion and the industrial waste was made using an Ultra-turrax device, with the final mixing temperature monitored using a thermographic camera. Microstructure analysis was conducted using scanning electron microscopy (SEM). The bitumen was extracted and characterized using needle penetration tests at several temperatures. Additionally, the ring-and-ball softening point, penetration index, and ductility were assessed. Incorporating up to 5% of lignin-rich industrial waste led to a lignin-based biobinder that could be used for a more sustainable and bitumen-efficient HWMA production. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
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29 pages, 3472 KiB  
Article
Study on Composition Design and Performance Characteristics of Warm-Mixed Rubber–Asphalt Mixture for Cold-Region Stress Absorption Layers
by Rui Pan, Jifeng Chang and Yu Chen
Buildings 2025, 15(7), 1164; https://doi.org/10.3390/buildings15071164 - 2 Apr 2025
Viewed by 372
Abstract
Reflection cracks significantly compromise the service life of half-rigid asphalt pavements in cold regions. This study introduces SAKIII warm-mixed rubber–asphalt mixture (SAKIII WMRA Mix) as a stress absorption layer to address this issue. Through orthogonal tests, regression analysis, and performance comparisons with SBS-modified [...] Read more.
Reflection cracks significantly compromise the service life of half-rigid asphalt pavements in cold regions. This study introduces SAKIII warm-mixed rubber–asphalt mixture (SAKIII WMRA Mix) as a stress absorption layer to address this issue. Through orthogonal tests, regression analysis, and performance comparisons with SBS-modified asphalt, the material composition, low-temperature cracking resistance, and fatigue performance of WMRAM were systematically evaluated. The results show that SAKIII WMRA Mix maintains superior road performance with 30 °C lower mixing/compaction temperatures compared to traditional hot-mix asphalt mixture. At −10 °C, its low-temperature cracking resistance improves by 40% and fatigue life extends by 35% over the SBS-modified asphalt mixture. Mechanistically, SAKIII WMRA Mix reduces reflection crack propagation by 30% and prolongs pavement service life by over 25% under equivalent traffic/climate conditions. Additionally, it decreases energy consumption by 15–20% and provides a sustainable solution for cold-region road construction. This research establishes optimized mix design methods and performance criteria for WMRAM, offering theoretical support and practical guidance for reflective crack mitigation in cold climates. The proposed technology effectively balances mechanical properties, energy efficiency, and environmental benefits, making it especially suitable for cold areas where thermal stress dominates road damage. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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17 pages, 28066 KiB  
Article
Performance Evaluation of Warm-Mix Asphalt Binders with an Emphasis on Rutting and Intermediate-Temperature Cracking Resistance
by Jiangbo Pang, Yu Chen, Longfei Jing, Haoran Song and Ziyang Liu
Materials 2025, 18(7), 1571; https://doi.org/10.3390/ma18071571 - 30 Mar 2025
Viewed by 477
Abstract
Warm-mix asphalt (WMA) technology is gaining popularity worldwide due to its benefits of considerable emissions reduction and energy savings when compared with hot-mix asphalt (HMA). Currently, there is a wide range of WMA products with considerable variability in the corresponding pavement performances. It [...] Read more.
Warm-mix asphalt (WMA) technology is gaining popularity worldwide due to its benefits of considerable emissions reduction and energy savings when compared with hot-mix asphalt (HMA). Currently, there is a wide range of WMA products with considerable variability in the corresponding pavement performances. It has also been difficult to reach a unified conclusion regarding the effects of various WMA additives on asphalt binder properties. In this study, two categories of warm-mix additives, including six organic additives and three chemical additives, were evaluated in terms of their effects on asphalt binder properties, with a focus on rutting and intermediate-temperature cracking. It was found that the viscosity-reducing effect of organic additives was more significant in comparison to chemical additives. In addition, the binders modified with the organic additives obtained enhanced rutting resistance at high temperatures but compromised cracking resistance at intermediate temperatures, as shown by the increasing complex modulus (G*) and non-recoverable creep compliance (Jnr) and decreasing binder fracture energy (BFE). Meanwhile, the very limited effect of chemical additives on rutting resistance was observed while the cracking resistance was slightly improved. The findings will assist in the selection and application of WMA additives for the production of asphalt mixture. Full article
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21 pages, 5339 KiB  
Article
Contribution of Oxygen and Ultraviolet Light to the Adhesion Properties of Warm Mix Asphalt During the Light-Oxidative Coupling Ultraviolet Aging Process
by Jianbing Ma, Bo Li, Yongning Wang, Xiaomin Li, Dongna Li, Xiaoyu Ren and Mingxing Fu
Materials 2025, 18(6), 1345; https://doi.org/10.3390/ma18061345 - 18 Mar 2025
Cited by 1 | Viewed by 385
Abstract
Objective: We investigated the contribution of oxygen and UV light to the UV aging process of warm mix asphalt (WMA). Methods: In this paper, warm mix asphalt was prepared with different aging methods (RTFOT, PAV and UV) and UV aging times (50 h, [...] Read more.
Objective: We investigated the contribution of oxygen and UV light to the UV aging process of warm mix asphalt (WMA). Methods: In this paper, warm mix asphalt was prepared with different aging methods (RTFOT, PAV and UV) and UV aging times (50 h, 100 h, 150 h and 200 h). The cohesion and bonding functions of WMA were tested using surface free energy theory. In addition, the UV aging functional groups of WMA were analyzed using Fourier transform infrared spectroscopy (FTIR). On this basis, the contribution of oxygen and ultraviolet light to the UV aging of WMA was analyzed using the random forest model. Results and conclusions: The results showed that UV aging had the greatest effect on the adhesion property index and functional group index of WMA, followed by PAV aging, and RTFOT aging had the least effect. With the extension of UV aging time, the adhesion and cohesion functions of WMA showed a decreasing trend, while the carbonyl index and sulfoxide index showed an increasing trend. When the UV aging time exceeded 150 h, the adhesion function and functional group index of WMA gradually tended to stabilize. The effect of UV aging on the adhesive properties of WMA was mainly due to adhesive damage. There were significant differences in the effects of oxygen isolation and light–oxygen-coupled UV aging on the adhesive properties and functional group index of WMA. In the light–oxygen-coupled UV aging of warm mix asphalt, the contribution of UV radiation was 79.9%, and the contribution of oxygen was 20.1%. Full article
(This article belongs to the Special Issue Development of Sustainable Asphalt Materials)
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21 pages, 5465 KiB  
Article
Effects of Untreated Waste Lignin as a Sustainable Asphalt Emulsion Substitute on Water Resistance and Environmental Impacts in Reclaimed Half-Warm Asphalt Mixtures
by Ana María Rodríguez Pasandín, Pablo Orosa, Ana María Rodríguez-Alloza, Edoardo Nardi and Natalia Pérez-Barge
Coatings 2025, 15(3), 304; https://doi.org/10.3390/coatings15030304 - 5 Mar 2025
Cited by 1 | Viewed by 1355
Abstract
Polymers are known to produce beneficial effects on asphalt mixtures, and lignin biopolymers could further improve them while contributing to sustainability and circularity. In this research, conventional asphalt emulsion was replaced with liquid waste containing lignin from the wood industry in half-warm mix [...] Read more.
Polymers are known to produce beneficial effects on asphalt mixtures, and lignin biopolymers could further improve them while contributing to sustainability and circularity. In this research, conventional asphalt emulsion was replaced with liquid waste containing lignin from the wood industry in half-warm mix asphalt (HWMA) at varying substitution levels of 0% (control), 5%, 10%, 15%, and 20%. Additionally, 100% reclaimed asphalt pavement (RAP) was used as aggregate. The impact of asphalt emulsion substitution on the mixtures’ adhesion, cohesion, and water resistance was analyzed. Indirect tensile strength tests evaluated the HWMA’s resistance to moisture damage and ductility. Rolling bottle and boiling water tests were conducted to assess the binder-aggregate affinity. Moreover, a Life Cycle Assessment (LCA) was performed to compare the environmental benefits of HWMA with those of Hot Mix Asphalt (HMA). The findings revealed that substituting asphalt emulsion with the waste lignin up to 15% enhances the mixture’s cohesion, while only substitutions up to 5% produce mixtures with enhanced water resistance. Environmental impacts were significantly reduced for all the HWMA studied, with the Global Warming Potential (GWP) showing up to 33.5% reduction compared to a conventional HMA. Full article
(This article belongs to the Special Issue Recent Research in Asphalt and Pavement Materials)
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28 pages, 6455 KiB  
Article
Optimizing Bitumen Performance in Warm Mix Asphalt Using Cecabase RT BIO10: A Taguchi-Based Experimental Approach
by Mustafa Çakı and Fatih İrfan Baş
Appl. Sci. 2025, 15(4), 1761; https://doi.org/10.3390/app15041761 - 9 Feb 2025
Cited by 1 | Viewed by 1614
Abstract
Flexible pavements stand out as the most commonly used worldwide, compared to rigid and composite pavements, owing to their versatility and widespread application. The use of hot mix asphalt (HMA) in flexible pavements causes significant environmental concerns due to high CO2 emissions [...] Read more.
Flexible pavements stand out as the most commonly used worldwide, compared to rigid and composite pavements, owing to their versatility and widespread application. The use of hot mix asphalt (HMA) in flexible pavements causes significant environmental concerns due to high CO2 emissions and energy consumption, whereas warm mix asphalt (WMA) technologies have gained popularity in recent decades, offering a more sustainable alternative by enabling asphalt production at lower temperatures. WMA technologies can be categorized into three main groups: foaming, organic additives, and chemical additives, with each offering distinct benefits for performance and environmental impact. One of the chemical additives used in WMA production is Cecabase RT BIO10. In this study, virgin bitumen with 50/70 penetration was modified by adding Cecabase RT BIO10 at four levels: 0%, 0.3%, 0.4%, and 0.5% by weight. The experimental design employed a Taguchi L16 orthogonal array to systematically evaluate the effects of various factors on modified bitumen performance. Binders were prepared at four temperatures (110 °C, 120 °C, 130 °C, and 140 °C), four mixing durations (15, 20, 25, and 30 min), and four mixing speeds (1000, 2000, 3000, and 4000 rpm), enabling an efficient analysis of each parameter’s impact. The prepared binders were subjected to a series of tests, including penetration, softening point, flash point, rotational thin film oven test (RTFOT), elastic recovery, Marshall stability, ultrasonic pulse velocity (UPV), and FTIR analysis. These tests were conducted to investigate the effects of various parameters and levels on the binder properties. Additionally, stiffness and seismic modules were evaluated to provide a more comprehensive understanding of the binder’s performance. The experiment results revealed that the penetration, elastic recovery percentage, and Marshall stability increased with increasing additive content while the softening point and RTFOT mass loss decreased. At a high service temperature of 40 °C, the stiffness modulus of the modified bitumen decreased slightly. At a low service temperature of −10 °C, it decreased further. Additionally, the incorporation of Cecabase RT BIO10 led to an increase in the seismic modulus. Through optimization using the Taguchi method, the optimal levels were determined to be a 0.4% Cecabase RT BIO10 ratio, 140 °C mixing temperature, 30 min mixing time, and 1000 RPM mixing speed. The optimal responses for each test were identified and integrated into a unified optimal response, resulting in a comprehensive design guide with 95% confidence level estimates for all possible level combinations. Full article
(This article belongs to the Section Civil Engineering)
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24 pages, 7247 KiB  
Article
Molecular Dynamics Investigation of the Diffusion Mechanisms and Thermodynamic Behaviors in Warm Mix Recycled Asphalt Binders with and Without Rejuvenators
by Qisheng Hu, Derun Zhang and Peixin Xu
Materials 2025, 18(3), 703; https://doi.org/10.3390/ma18030703 - 5 Feb 2025
Cited by 1 | Viewed by 1037
Abstract
In recent years, the employment of rejuvenators and warm mix asphalt (WMA) additives for reclaimed asphalt pavement (RAP) has been recognized as a popular approach to increase the recycling rate of waste materials and promote the sustainable development of pavement engineering. However, the [...] Read more.
In recent years, the employment of rejuvenators and warm mix asphalt (WMA) additives for reclaimed asphalt pavement (RAP) has been recognized as a popular approach to increase the recycling rate of waste materials and promote the sustainable development of pavement engineering. However, the composition of warm mix recycled asphalt binder is complicated, and the microstructural changes brought about by the rejuvenators and WMA additives are critical in determining its macroscopic mechanical properties. This research focuses on the atomic modeling of the rejuvenators and WMA additives diffusion behavior of the warm mix recycled asphalt binder. The objective is to reveal the thermodynamic performance and diffusion mechanism of the WMA binder under the dual presence of rejuvenators and WMA additives. Three types of mutual diffusion systems (Aged and oil + virgin + wax, Aged + virgin + wax, and Aged and oil + virgin) were established, respectively, for a comparative investigation of the glass transition temperature, viscosity, thermodynamics, free volume, and diffusion behavior. The results indicate a 44.27% and 31.33% decrease in the glass transition temperature and apparent viscosity, respectively, after the incorporation of 5% oil rejuvenators in the Aged + virgin + wax asphalt binder, demonstrating the improved cracking resistance and construction workability. The presence of the RAP binder and organic WMA additives raised the cohesion of the asphalt binder and decreased self-healing ability and free volume, and these detrimental influences can be offset by the introduction of rejuvenators. The combined use of rejuvenators and organic WMA additives remarkably enhanced the de-agglomeration to asphaltenes, stimulated the activity of aged RAP macromolecular components, and ultimately improved the blending efficiency of virgin binders with the overall structure of RAP binders. Full article
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14 pages, 4669 KiB  
Article
Cool Mix Asphalt—Redefining Warm Mix Asphalt with Implementations in Korea, Italy and Vietnam
by Hosin (David) Lee, Lan Ngoc Nguyen, Elena Sturlini and Young-ik Kim
Infrastructures 2025, 10(1), 24; https://doi.org/10.3390/infrastructures10010024 - 20 Jan 2025
Viewed by 1673
Abstract
During the past decades, to minimize Greenhouse Gas (GHG) emissions and asphalt fumes during the asphalt mix production and construction process, various warm mix asphalt (WMA) additives have been developed and successfully applied. Currently, as production of WMA reaches close to that of [...] Read more.
During the past decades, to minimize Greenhouse Gas (GHG) emissions and asphalt fumes during the asphalt mix production and construction process, various warm mix asphalt (WMA) additives have been developed and successfully applied. Currently, as production of WMA reaches close to that of Hot Mix Asphalt (HMA) in the US, the varied definition of WMA is questioned in this paper. Not only are the temperature reduction ranges from HMA defined by various studies too wide, but also the minimum threshold to be classified as WMA is often too small. In this paper, a new category of “Cool Mix Asphalt (CMA)” is proposed to distinguish it from the newly defined WMA based not on the reduction amount from HMA temperature but its actual production temperature. It is proposed that HMA should be defined as asphalt mixtures produced at temperatures between 140 and 160 °C (between 284 and 320 °F), WMA as production temperatures between 120 and 140 °C (between 248 and 284 °F), and CMA as production temperatures between 100 and 120 °C (212 to 248 °F). By defining their actual production temperatures rather than reduction temperatures from HMA, WMA and CMA will be clearly defined. This paper then presents a new Polymer Cool Mix Asphalt (PCMA) additive called “Zero-M”, which was developed to lower the mixing temperature to around 110 °C (203 °F). Recently, test sections using Zero-M were successfully constructed in Korea, Italy and Vietnam, and their laboratory test results of field cores and production and construction experiences are described in this paper. The chemistry and compositions of Zero-M are discussed along with its mechanism to significantly lower the production temperature of PCMA. All test sections constructed in three countries met the in-place compaction density requirements of their respective countries, which were close to or higher than those of the control HMA test sections. Full article
(This article belongs to the Special Issue Cool Mix Asphalt: Redefining Warm Mix Asphalt)
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24 pages, 2756 KiB  
Review
Mitigation Strategies Based on Life Cycle Assessment for Carbon Dioxide Reduction in Asphalt Pavements: Systematic Review
by Diego Flores-Ruiz, Marco Montoya-Alcaraz, Leonel García, Manuel Gutiérrez and Julio Calderón-Ramírez
Sustainability 2025, 17(2), 695; https://doi.org/10.3390/su17020695 - 17 Jan 2025
Cited by 2 | Viewed by 1479
Abstract
Expanding the road network is inevitable due to the accelerated economic growth of countries. However, the development of road infrastructure has generated considerable concern among society, governments, and environmental organizations. This concern mainly stems from the significant environmental effects and the omission of [...] Read more.
Expanding the road network is inevitable due to the accelerated economic growth of countries. However, the development of road infrastructure has generated considerable concern among society, governments, and environmental organizations. This concern mainly stems from the significant environmental effects and the omission of the sustainability of materials associated with road construction. Current literature suggests Life Cycle Assessment (LCA) as a solution to address greenhouse gas emissions and other environmental impacts of road infrastructure. This research uses the PRISMA-SCR methodology to identify strategies to mitigate environmental impact during the life cycle stages of asphalt pavements and emission-generating activities. This study identifies the critical life cycle stages responsible for the largest amount of emissions, highlighting “material extraction and production” and “transportation” as key areas of intervention. The results demonstrate how the incorporation of recycled materials (RAPs) and warm mix asphalts (WMAs) can reduce between 15% and 45% of total emissions. It is concluded that it is possible to develop asphalt pavement construction projects with a sustainability perspective, allowing not only to identify opportunities to optimize construction processes but also to establish a reference framework for transportation agencies to integrate more sustainable practices, including the reduction of emissions, the responsible use of non-renewable resources and proper waste management. Full article
(This article belongs to the Special Issue Urban Pavement Design and Road Sustainability)
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