Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (69)

Search Parameters:
Keywords = volcaniclastic

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
41 pages, 7932 KiB  
Article
Element Mobility in a Metasomatic System with IOCG Mineralization Metamorphosed at Granulite Facies: The Bondy Gneiss Complex, Grenville Province, Canada
by Olivier Blein and Louise Corriveau
Minerals 2025, 15(8), 803; https://doi.org/10.3390/min15080803 - 30 Jul 2025
Viewed by 155
Abstract
In the absence of appropriate tools and a knowledge base for exploring high-grade metamorphic terrains, felsic gneiss complexes at granulite facies have long been considered barren and have remained undermapped and understudied. This was the case of the Bondy gneiss complex in the [...] Read more.
In the absence of appropriate tools and a knowledge base for exploring high-grade metamorphic terrains, felsic gneiss complexes at granulite facies have long been considered barren and have remained undermapped and understudied. This was the case of the Bondy gneiss complex in the southwestern Grenville Province of Canada which consists of 1.39–1.35 Ga volcanic and plutonic rocks metamorphosed under granulite facies conditions at 1.19 Ga. Iron oxide–apatite and Cu-Ag-Au mineral occurrences occur among gneisses rich in biotite, cordierite, garnet, K-feldspar, orthopyroxene and/or sillimanite-rich gneisses, plagioclase-cordierite-orthopyroxene white gneisses, magnetite-garnet-rich gneisses, garnetites, hyperaluminous sillimanite-pyrite-quartz gneisses, phlogopite-sillimanite gneisses, and tourmalinites. Petrological and geochemical studies indicate that the precursors of these gneisses are altered volcanic and volcaniclastic rocks with attributes of pre-metamorphic Na, Ca-Fe, K-Fe, K, chloritic, argillic, phyllic, advanced argillic and skarn alteration. The nature of these hydrothermal rocks and the ore deposit model that best represents them are further investigated herein through lithogeochemistry. The lithofacies mineralized in Cu (±Au, Ag, Zn) are distinguished by the presence of garnet, magnetite and zircon, and exhibit pronounced enrichment in Fe, Mg, HREE and Zr relative to the least-altered rocks. In discrimination diagrams, the metamorphosed mineral system is demonstrated to exhibit the diagnostic attributes of, and is interpreted as, a metasomatic iron and alkali-calcic (MIAC) mineral system with iron oxide–apatite (IOA) and iron oxide copper–gold (IOCG) mineralization that evolves toward an epithermal cap. This contribution demonstrates that alteration facies diagnostic of MIAC systems and their IOCG and IOA mineralization remain diagnostic even after high-grade metamorphism. Exploration strategies can thus use the lithogeochemical footprint and the distribution and types of alteration facies observed as pathfinders for the facies-specific deposit types of MIAC systems. Full article
(This article belongs to the Section Mineral Deposits)
Show Figures

Figure 1

57 pages, 42873 KiB  
Article
The Mazenod–Sue–Dianne IOCG District of the Great Bear Magmatic Zone Northwest Territories, Canada
by A. Hamid Mumin and Mark Hamilton
Minerals 2025, 15(7), 726; https://doi.org/10.3390/min15070726 - 11 Jul 2025
Viewed by 192
Abstract
The Mazenod Lake region of the southern Great Bear Magmatic Zone (GBMZ) of the Northwest Territories, Canada, comprises the north-central portion of the Faber volcano-plutonic belt. Widespread and abundant surface exposure of several coalescing hydrothermal systems enables this paper to document, without ambiguity, [...] Read more.
The Mazenod Lake region of the southern Great Bear Magmatic Zone (GBMZ) of the Northwest Territories, Canada, comprises the north-central portion of the Faber volcano-plutonic belt. Widespread and abundant surface exposure of several coalescing hydrothermal systems enables this paper to document, without ambiguity, the relationships between geology, structure, alteration, and mineralization in this well exposed iron-oxide–copper–gold (IOCG) mineral system. Mazenod geology comprises rhyodacite to basaltic-andesite ignimbrite sheets with interlayered volcaniclastic sedimentary rocks dominated by fine-grained laminated tuff sequences. Much of the intermediate to mafic nature of volcanic rocks is masked by low-intensity but pervasive metasomatism. The region is affected by a series of coalescing magmatic–hydrothermal systems that host the Sue–Dianne magnetite–hematite IOCG deposit and several related showings including magnetite, skarn, and iron oxide apatite (IOA) styles of alteration ± mineralization. The mid to upper levels of these systems are exposed at surface, with underlying batholith, pluton and stocks exposed along the periphery, as well as locally within volcanic rocks associated with more intense alteration and mineralization. Widespread alteration includes potassic and sodic metasomatism, and silicification with structurally controlled giant quartz complexes. Localized tourmaline, skarn, magnetite–actinolite, and iron-oxide alteration occur within structural breccias, and where most intense formed the Sue–Dianne Cu-Ag-Au diatreme-like breccia deposit. Magmatism, volcanism, hydrothermal alteration, and mineralization formed during a negative tectonic inversion within the Wopmay Orogen. This generated a series of oblique offset rifted basins with continental style arc magmatism and extensional structures unique to GBMZ rifting. All significant hydrothermal centers in the Mazenod region occur along and at the intersections of crustal faults either unique to or put under tension during the GBMZ inversion. Full article
Show Figures

Figure 1

31 pages, 63914 KiB  
Article
Geological Evolution and Volcanostratigraphy of the Wangfu Fault Depression: Insights from Structural and Volcano-Sedimentary Analysis in the Songliao Basin
by Bilal Ahmed, Huafeng Tang, Weihua Qu, Youfeng Gao, Jia Hu, Zhiwen Tian and Shahzad Bakht
Minerals 2025, 15(6), 620; https://doi.org/10.3390/min15060620 - 9 Jun 2025
Viewed by 299
Abstract
The Wangfu Fault Depression (WFD) is located in the southeastern uplift zone of the Songliao Basin and is an important geological site for studying tectonic evolution and volcanic stratigraphy. This study explores the complexity of the structure of the depression and the volcanic [...] Read more.
The Wangfu Fault Depression (WFD) is located in the southeastern uplift zone of the Songliao Basin and is an important geological site for studying tectonic evolution and volcanic stratigraphy. This study explores the complexity of the structure of the depression and the volcanic stratigraphy. The sedimentary sequence is divided into rift period and post-rift deposition, and the volcanic rocks are mainly concentrated in the Huoshiling Formation. Rhyolite deposits mark the bottom of the Yingcheng Formation. The volcanostratigraphic sequences are described by a detailed analysis of the seismic profiles, cutting samples, core data, geochemical, and well logging data, revealing the interaction between tectonic dynamics and volcanic activity. The volcanic facies are divided into vent breccia, pyroclastic, lava flow, and volcaniclastic sedimentary types, highlighting the diversity of depositional environments. In addition, the study identified key volcanic stratigraphic boundaries, such as eruptive and tectonic unconformities, which illustrate the alternation of intermittent volcanic activity with periods of inactivity and erosion. The study highlights the important role of faults in controlling the distribution and tectonic characteristics of volcanic rocks, and clearly distinguishes the western sag, middle slope, and eastern uplift zones. The chronostratigraphic framework supported by published U-Pb zircon dating elucidates the time course of volcanic and sedimentary processes, with volcanic activity peaking in the Early Cretaceous. Overall, the Wangfu Fault Depression is a dynamic geological entity formed by complex tectonic-volcanic interactions, providing valuable insights into the larger context of basin evolution and stratigraphic complexity. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

19 pages, 5499 KiB  
Article
High-Frequency Oolitic Tidal Cycles and Their Geochemical Signatures in the Upper Ediacaran Qigebulake Formation, NW Tarim Basin (China)
by Yan Hao and Shaonan Zhang
Minerals 2025, 15(6), 613; https://doi.org/10.3390/min15060613 - 6 Jun 2025
Viewed by 364
Abstract
The Qigebulake Formation in the northwestern Tarim Basin records high-frequency oolitic tidal flat cycles formed during the Upper Ediacaran, a period marked by tectonic, volcanic, and hydrothermal events. This study presents a detailed petrographic and geochemical characterization of these cycles, focusing on their [...] Read more.
The Qigebulake Formation in the northwestern Tarim Basin records high-frequency oolitic tidal flat cycles formed during the Upper Ediacaran, a period marked by tectonic, volcanic, and hydrothermal events. This study presents a detailed petrographic and geochemical characterization of these cycles, focusing on their lithofacies development and implications for regional geological processes. Seven microfacies were identified, ranging from oolitic dolostone and dolothrombolite to siliciclastic dolomudstone and mudstone. Elemental trends indicate a systematic decline in SiO2, Al2O3, and TiO2 content with decreasing siliciclastic input, suggesting a shallowing-upward sequence. Volcaniclastic quartz grains, exhibiting embayed textures and bright-blue cathodoluminescence, are reported here for the first time in the Ediacaran of Tarim, supporting synsedimentary volcanic input. Positive δEu anomalies, coupled with low Al/(Al+Fe+Mn) and elevated Fe2O3/TiO2 and MnO/TiO2 ratios, reveal hydrothermal influence in upper-cycle dolostones. These signatures, combined with regional stratigraphy, suggest that the Qigebulake tidal flat records the interplay between deposition, volcanism, and fluid migration during the late Ediacaran. The findings provide new constraints on the evolution of peritidal environments and inform deep carbonate reservoir assessments in Tarim and similar cratonic basins. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

27 pages, 12033 KiB  
Article
Unusual Mineralogy of Kimberlites: Alkali Carbonates, Sulfates, and Chlorides Among Groundmass Minerals from Unserpentinized Coherent Kimberlite of the Udachnaya-East Pipe, Siberian Craton
by Alexander V. Golovin
Minerals 2025, 15(6), 586; https://doi.org/10.3390/min15060586 - 30 May 2025
Viewed by 336
Abstract
The paper reports the first findings of a series of alkali carbonate, chloride, and sulfate minerals among the usual groundmass kimberlite minerals, such as olivine, phlogopite, monticellite, calcite, spinel-group minerals, perovskite, ilmenite, rutile, and apatite. The sample was collected from an unserpentinized coherent [...] Read more.
The paper reports the first findings of a series of alkali carbonate, chloride, and sulfate minerals among the usual groundmass kimberlite minerals, such as olivine, phlogopite, monticellite, calcite, spinel-group minerals, perovskite, ilmenite, rutile, and apatite. The sample was collected from an unserpentinized coherent kimberlite dyke that crosscuts earlier volcaniclastic kimberlite in the central part of the Udachnaya-East pipe. This rock can be described as primary/original kimberlite that did not interact with external/internal hydrothermal fluids either during its formation or after its crystallization. At least three alkali-rich carbonates have been found, a previously unknown (and perhaps, a new one) Na-, Ca-, K-, and S-rich carbonate with the calculated empirical formula (Na,K)6Ca4(CO3,SO4)7, shortite Na2Ca2(CO3)3, and nyerereite (Na,K)2Ca(CO3)2. Chlorides in this kimberlite are halite NaCl and sylvite KCl, and the sulfate is aphthitalite K3Na(SO4)2. The content of the Na-Ca-K-S-rich carbonate in the rock is ~15 vol %, that of shortite and halite is ≤5 vol % each, and those of sylvite and aphthitalite are ≤1 vol %. All alkali-rich minerals are of late magmatic origin. This follows from that (i) the studied kimberlite does not contain any secondary water-rich minerals of hydrothermal transformation of the rocks, such as serpentine, chlorite or iowaite; and (ii) crystalline inclusions of such usual kimberlite minerals as olivine, phlogopite, monticellite, calcite, spinel, perovskite, and apatite were found within Na-Ca-K-S-rich carbonate and halite. This publication expands the list of minerals of magmatic origin identified in the groundmass of worldwide kimberlites by at least three minerals: Na-Ca-K-S-rich (new?) carbonate, sylvite, and aphthitalite. It is important to note that all alkali carbonates, chlorides, and sulfates are unstable during secondary hydrothermal alterations of kimberlites, and hence, these minerals cannot be found in serpentinized rocks. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

20 pages, 43321 KiB  
Article
Volcano–Sedimentary Processes on an Ancient Oceanic Seafloor: Insights from the Gimigliano Metaophiolite Succession (Calabria, Southern Italy)
by Federica Barilaro, Andrea Di Capua, Giuseppe Cianflone, Giovanni Turano, Gianluca Robertelli, Fabrizio Brutto, Giuseppe Ciccone, Alessandro Foti, Vincenzo Festa and Rocco Dominici
Minerals 2025, 15(6), 552; https://doi.org/10.3390/min15060552 - 22 May 2025
Viewed by 1027
Abstract
This study investigates the volcano–sedimentary processes that occurred in an oceanic branch of the Western Tethys, now part of the Gimigliano–Monte-Reventino metaophiolite Unit, exposed at the southeastern termination of the Sila Piccola Massif, within the northern sector of the Calabria–Peloritani terrane (Calabria, southern [...] Read more.
This study investigates the volcano–sedimentary processes that occurred in an oceanic branch of the Western Tethys, now part of the Gimigliano–Monte-Reventino metaophiolite Unit, exposed at the southeastern termination of the Sila Piccola Massif, within the northern sector of the Calabria–Peloritani terrane (Calabria, southern Italy). Fieldwork, petrography, and mineralogical analyses on the Gimigliano metaophiolite succession have identified five distinct volcano–sedimentary lithofacies. These lithofacies are characterized by mineral assemblages of epidote, chlorite, quartz, and albite, with minor amounts of muscovite and calcite, resulting from high-pressure–low-temperature (HP-LT) metamorphism followed by low-grade greenschist metamorphism of mid-oceanic ridge basalt (MORB)-type volcanic products. Based on their stratigraphic and textural features, these lithofacies have been interpreted as metabasaltic flow layers emplaced during effusive volcanic eruptions and metahyaloclastic and metavolcaniclastic deposits formed by explosion-driven processes. This lithofacies assemblage suggests that the Gimigliano area likely represented an oceanic sector with high rates of magmatic outflows, where interactions between magma and water facilitated explosive activity and the dispersion of primary volcaniclastic deposits, mainly from the water column, in addition to the emplacement of basaltic lava flow. In contrast, other metaophiolite complexes in the Calabria region, characterized by the presence of pillow basalts, were areas with low effusive rates. The coexistence of these differences, along with the extensive presence of metaultramafites, portrays the Calabrian branch of the Tethys as a slow-spreading oceanic ridge where variations in surficial volcanic processes were controlled by differences in the effusion rates across its structure. This study is a valuable example of how a volcano–sedimentary approach to reconstructing the emplacement mechanisms of metaophiolite successions can provide geodynamic insights into ancient oceanic ridges. Full article
(This article belongs to the Special Issue Volcaniclastic Sedimentation in Deep-Water Basins)
Show Figures

Figure 1

15 pages, 5205 KiB  
Article
Discussion on the Geochemical Characteristics and Enrichment Process of Li-Rich Layers in Xian’an Coalfield, Guangxi Province, China
by Li Zhang, Degao Zhang, Fuqiang Zhang, Zhongyue Lin, Jie Sun, Xiaoyun Yan, Huiheng Xu, Shaobo Di, Shaoqing Huang, Xiaotao Xu and Zhuo Zou
Minerals 2025, 15(4), 404; https://doi.org/10.3390/min15040404 - 11 Apr 2025
Cited by 1 | Viewed by 337
Abstract
As a rare metal, lithium plays a pivotal role in strategic critical metal mineral resources and is one of the critical metals for developing the contemporary social economy. The Li-rich layers in the Xian’an coalfield in Guangxi Province were taken as a typical [...] Read more.
As a rare metal, lithium plays a pivotal role in strategic critical metal mineral resources and is one of the critical metals for developing the contemporary social economy. The Li-rich layers in the Xian’an coalfield in Guangxi Province were taken as a typical study area in this research, the material sources of Li-rich strata were discussed, and the enrichment process of Li-rich layers was revealed through geochemical research methods. The coal seams in this area have abnormal enrichment points with high lithium content, but there is a certain inhomogeneity in the plane and longitudinal distribution. This research studies the causes and material sources around the multi-layer lithium-extruded layers in the longitudinal distribution of coal-based strata. Through mineralogy and geochemical research methods, this research shows that Li-rich mineralization results from the combined action of terrigenous material and volcaniclastic source inputs, water–rock processes, and fluid inputs. The Li-bearing rocks formed over three periods, which are the weathering, sedimentation, and diagenesis stages. Based on factors such as provenance and geological processes, this study analyzes the genesis of Li-rich layers and provides a theoretical basis for the future prospecting of lithium ore deposits. Full article
Show Figures

Figure 1

21 pages, 3815 KiB  
Article
Paleoenvironmental Controls and Economic Potential of Li-REY Enrichment in the Upper Carboniferous Coal-Bearing “Si–Al–Fe” Strata, Northeastern Qinshui Basin
by Ning Wang, Jun Zhao, Yingxia Xu, Mangen Mu, Shangqing Zhang, Libo Jing, Guoshu Huang, Liang Liu and Pengfei Tian
Minerals 2025, 15(3), 269; https://doi.org/10.3390/min15030269 - 5 Mar 2025
Viewed by 706
Abstract
Critical metals in coal-bearing strata have recently emerged as a frontier hotspot in both coal geology and ore deposit research. In the Upper Carboniferous coal-bearing “Si–Al–Fe” strata (Benxi Formation) of the North China Craton (NCC), several critical metals, including Li, Ga, Sc, V, [...] Read more.
Critical metals in coal-bearing strata have recently emerged as a frontier hotspot in both coal geology and ore deposit research. In the Upper Carboniferous coal-bearing “Si–Al–Fe” strata (Benxi Formation) of the North China Craton (NCC), several critical metals, including Li, Ga, Sc, V, and rare earth elements and Y (REY or REE + Y), have been discovered, with notable mineralization anomalies observed across northern, central, and southern Shanxi Province. However, despite the widespread occurrence of outcrops of the “Si–Al–Fe” strata in the northeastern Qinshui Basin of eastern Shanxi, there has been no prior report on the critical metal content in this region. Traditionally, the “Si–Al–Fe” strata have been regarded as a primary source of clastic material for the surrounding coal seams of the Carboniferous–Permian Taiyuan and Shanxi Formations, which are known to display critical metal anomalies (e.g., Li and Ga). Given these observations, it is hypothesized that the “Si–Al–Fe” strata in the northeastern Qinshui Basin may also contain critical metal mineralization. To evaluate this hypothesis, new outcrop samples from the “Si–Al–Fe” strata of the Benxi Formation in the Yangquan area of the northeastern Qinshui Basin were collected. Detailed studies on critical metal enrichment were assessed using petrographic observations, mineralogy (XRD, X-ray diffractometer), and geochemistry (XRF, X-ray fluorescence spectrometer, and ICP-MS, inductively coupled plasma mass spectrometer). The results indicate that the siliceous, ferruginous, and aluminous rocks within the study strata exhibit varying degrees of critical metal mineralization, mainly consisting of Li and REY, with minor associated Nb, Zr, and Ga. The Al2O3/TiO2, Nb/Y vs. Zr/TiO2, and Nb/Yb vs. Al2O3/TiO2 diagrams suggest that these critical metal-enriched layers likely have a mixed origin, comprising both intermediate–felsic magmatic rocks and metamorphic rocks derived from the NCC, as well as alkaline volcaniclastics associated with the Tarim Large Igneous Province (TLIP). Furthermore, combined geochemical parameters, such as the CIA (chemical index of alteration), Sr/Cu vs. Ga/Rb, Th/U, and Ni/Co vs. V/(V + Ni), indicate that the “Si–Al–Fe” strata in the northeastern Qinshui Basin were deposited under warm-to-hot, humid climate conditions, likely in suboxic-to-anoxic environments. Additionally, an economic evaluation suggests that the “Si–Al–Fe” strata in the northeastern Qinshui Basin hold considerable potential as a resource for the industrial extraction of Li, REY, Nb, Zr, and Ga. Full article
Show Figures

Figure 1

30 pages, 9786 KiB  
Article
Petrography and Geochemistry of the Upper Cretaceous Volcaniclastic Deposits of the Haţeg Basin (Southern Carpathians): Inferences on Petrogenesis and Magma Origin
by Violeta M. Vornicu and Ioan Seghedi
Minerals 2025, 15(2), 111; https://doi.org/10.3390/min15020111 - 23 Jan 2025
Cited by 1 | Viewed by 1153
Abstract
Upper Cretaceous volcaniclastic deposits of the Haţeg Basin (VDHB) (Southern Carpathians, Romania) consist of relatively poorly exposed products of multiple phreatomagmatic volcanic eruptions of andesitic to rhyolitic composition and crop out around Densuş, Răchitova, Peşteniţa, and Ciula Mică localities. These deposits are commonly [...] Read more.
Upper Cretaceous volcaniclastic deposits of the Haţeg Basin (VDHB) (Southern Carpathians, Romania) consist of relatively poorly exposed products of multiple phreatomagmatic volcanic eruptions of andesitic to rhyolitic composition and crop out around Densuş, Răchitova, Peşteniţa, and Ciula Mică localities. These deposits are commonly associated with the Late Cretaceous Neotethyan magmatic activity that developed in Central-Eastern Europe, forming the Apuseni–Banat–Timok–Srednogorie (ABTS) belt. Since the geochemistry of these deposits has been investigated very little so far, this study provides petrographic and whole-rock geochemical analysis for twenty new different volcaniclastic rock samples, out of which sixteen samples represent lava clasts and the other four are samples of pyroclastic flow deposits. According to our geochemical data, the VDHB have a calc-alkaline and high-K calc-alkaline character, similar to the majority of rock samples from all sectors of the ABTS belt. A comparison between the Haţeg rock samples and Banat and Apuseni samples reveals comparable major and trace element abundances and REE patterns, supporting the idea that they originate from similar magmas. Trace element patterns suggest that the parental magmas were mostly derived from the melting of a metasomatized lithospheric mantle source, previously modified by an earlier subduction event. A combination of crystal fractionation and variable degrees of crustal assimilation during storage at higher and lower pressures was the principal mechanism driving calc-alkaline differentiation. Our geochemical analyses indicate that the VDHB were produced by magmas generated during two different magmatic events. Older, silica-rich melts produced the Peştenita and Răchitova ignimbrite deposits, while the Densuş and Răchitova andesitic–dacitic–rhyolitic rock suite was generated by younger, intermediate magmas. The individual melt production episodes are evidenced by the emergence of two different crystal fractionation trends: an amphibole-controlled trend at mid-crustal levels and an upper-crust plagioclase-dominated trend. The hydrous, calc-alkaline magmas arguably occurred in a post-collisional setting, in agreement with the orogenic collapse model, among others, proposed for the origin of the ABTS magmatic activity. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

23 pages, 3422 KiB  
Article
Heavy Metal Spatial Variation Mechanism and Ecological Health Risk Assessment in Volcanic Island Soils: A Case Study of Weizhou Island, China
by Ran Bi, Wei Fu and Xuanni Fu
Land 2025, 14(1), 35; https://doi.org/10.3390/land14010035 - 27 Dec 2024
Cited by 4 | Viewed by 1260
Abstract
Heavy metals in volcanic island soils are key for assessing pollution risks and guiding environmental management strategies. However, research on heavy metals in volcanic island soils remains limited. In this study, the concentrations of heavy metals (Cu, Zn, Pb, Cr) in surface soil [...] Read more.
Heavy metals in volcanic island soils are key for assessing pollution risks and guiding environmental management strategies. However, research on heavy metals in volcanic island soils remains limited. In this study, the concentrations of heavy metals (Cu, Zn, Pb, Cr) in surface soil samples from Weizhou Island, China, were determined using ICP-OES, with average concentrations of 59.18 mg/kg, 119.06 mg/kg, 35.63 mg/kg, and 159.78 mg/kg, respectively. The basalt profiles generally exhibit higher heavy metal content and pH values compared to volcaniclastic rock profiles, as basalt accumulates higher concentrations of heavy metals. However, surface soils over volcaniclastic rocks show significantly higher heavy metal concentrations than those over basalt, indicating spatial variability in metal accumulation. Heavy metal concentrations in Weizhou Island soils are notably elevated at both the western wharf and the island’s tail, both characterized by volcaniclastic rock lithology, with human activities further increasing concentrations at the western wharf compared to the island’s tail. Land use types influence heavy metal content, with higher concentrations in abandoned land and lower concentrations in forest land with dense vegetation and organic matter. Principal component analysis reveals that heavy metals are primarily derived from natural parent material, with the first two principal components comprising 59.77% of the variance. Ecological risk assessment indicates that Weizhou Island soil is generally considered relatively clean, but Pb presents an ecological hazard, with 86.54% of the sites at risk. Overall, heavy metals in volcanic island soil mainly come from natural sources but lead contamination and human-impacted areas require attention. Full article
Show Figures

Figure 1

12 pages, 2598 KiB  
Article
Characterisation of Pelletal Lapilli in Explosive Melilitite–Carbonatite Eruptions: An Example from Mt. Vulture Volcano (Southern Italy)
by Gabriele Carnevale and Vittorio Zanon
Geosciences 2024, 14(12), 349; https://doi.org/10.3390/geosciences14120349 - 18 Dec 2024
Cited by 1 | Viewed by 1229
Abstract
Among the volcaniclastic products of melilitite–carbonatite eruptions, pelletal lapilli are often found, resulting in them being particularly useful for characterising the interface between the erupting magma and its volatile component. Pelletal lapilli, which were erupted during the most recent melilitite–carbonatite volcanic activity of [...] Read more.
Among the volcaniclastic products of melilitite–carbonatite eruptions, pelletal lapilli are often found, resulting in them being particularly useful for characterising the interface between the erupting magma and its volatile component. Pelletal lapilli, which were erupted during the most recent melilitite–carbonatite volcanic activity of the Mt. Vulture volcano, are characterised by a predominantly wehrlitic core with CO2-rich fluid inclusions and a Ca-rich outer portion composed of fine-grained xenocrystic debris of olivine and clinopyroxene, with microcrysts of haüyne and melilite laths (± calcite). The chemical composition of the olivine reflects the interaction with a proto-melilitite–carbonatite melt, which is the main metasomatic agent. The whole-rock analyses of the external portion of pelletal lapilli show values that are comparable with those of extrusive carbonatites. This evidence supports the hypothesis that the primary carbonatite melt was a significant contributor to the CO2-rich magma source that transported the lapilli to the surface. The modelling of the geometric data of the pelletal lapilli structure, together with inferences regarding the role of the CO2 gas phase, the main propellant in an ascending gas-dominated medium, allowed for the reconstruction of a possible scenario where the CO2 expansion and the fluidised spray granulation process are crucial during the volcanic conduit dynamics. Full article
(This article belongs to the Section Geochemistry)
Show Figures

Figure 1

10 pages, 4030 KiB  
Article
Genesis of an Inorganic CO2 Gas Reservoir in the Dehui–Wangfu Fault Depression, Songliao Basin, China
by Changli Liu, Yunliang Yu, Hongchen Cai, Yingchun Liu and Xiangwei Gao
Processes 2024, 12(11), 2429; https://doi.org/10.3390/pr12112429 - 4 Nov 2024
Viewed by 861
Abstract
This study systematically examines the origins and formation mechanisms of inorganic CO2 gas reservoirs located within the Dehui–Wangfu Fault in the southeastern uplift region of the Songliao Basin. The research aims to clarify the primary sources of inorganic CO2, along [...] Read more.
This study systematically examines the origins and formation mechanisms of inorganic CO2 gas reservoirs located within the Dehui–Wangfu Fault in the southeastern uplift region of the Songliao Basin. The research aims to clarify the primary sources of inorganic CO2, along with its migration and accumulation processes. The identification of the Wanjinta gas reservoir within the Dehui–Wangfu Fault Zone, abundant in inorganic CO2, has sparked significant interest in the pivotal roles of volcanism and tectonic activity in gas generation and concentration. To analyze the release characteristics of CO2, this study conducted degassing experiments on volcanic and volcaniclastic rock samples from various boreholes within the fault trap. It evaluated CO2 release behaviors and controlling factors across varying temperatures (150 °C to 600 °C) and particle sizes (20, 40, and 100 µm). The findings indicated a negative correlation between CO2 release and particle size, with a notable transition at 300 °C—marking this temperature as critical for the release of adsorbed and lattice gases. Moreover, volcaniclastic rocks exhibited higher CO2 release compared to volcanic rocks, attributable to their larger specific surface area and higher porosity. At 600 °C, the decomposition of the rock crystal structure results in substantial gas escape. These observations suggest that the inorganic CO2 in this area derives not only from mantle sources but is also influenced by crustal components. Elevated temperatures prompted by tectonic activity and magmatic intrusion facilitated the degassing of the surrounding rocks, allowing released CO2 to migrate upwards through the fracture system and accumulate in the shallow crust, ultimately forming a gas reservoir. This study enhances the understanding of volcanic rock’s roles in inorganic CO2 gas generation and migration, highlighting the fracture system’s critical controlling influence on gas transport and aggregation. The findings indicate that inorganic CO2 gas reservoirs in the Dehui–Wangfu Fault Zone primarily originate from mantle sources with a mixture of crustal gases. This discovery offers new theoretical insights and practical guidance for the exploration and development of gas reservoirs in the Songliao Basin and similar regions. Full article
Show Figures

Figure 1

17 pages, 17665 KiB  
Article
Genesis of the Mahour Base Metal Deposit, Iran: Constraints from Fluid Inclusions and Sulfur Isotopes
by Zahra Moradiani, Majid Ghaderi, Hossein-Ali Tajeddin and Pura Alfonso
Minerals 2024, 14(4), 435; https://doi.org/10.3390/min14040435 - 22 Apr 2024
Viewed by 1817
Abstract
The Mahour base metal deposit is located northeast of Badroud in the middle of the Urumieh–Dokhtar magmatic arc in the Isfahan province of Iran. The main host rocks to the ores are Eocene volcanic and volcaniclastic rocks. Hypogene ore minerals constituting the main [...] Read more.
The Mahour base metal deposit is located northeast of Badroud in the middle of the Urumieh–Dokhtar magmatic arc in the Isfahan province of Iran. The main host rocks to the ores are Eocene volcanic and volcaniclastic rocks. Hypogene ore minerals constituting the main ore body are galena, sphalerite, pyrite, and chalcopyrite. In addition to gangue quartz, a variety of supergene minerals comprising gypsum, goethite, hematite, “limonite”, malachite, azurite, covellite, and chalcocite are also present; gangue minerals are quartz, barite, calcite, sericite, and chlorite. Silicification, intermediate argillic, and propylitic are the main wall-rock alteration types. The presence of fluid inclusions with different vapor/liquid ratios in quartz and sphalerite could indicate a boiling process. The primary liquid-rich fluid inclusions suggest that the homogenization temperature was between 107 and 298 °C from fluids with salinities from 1.5 to 13.7 wt.% NaCl equiv. These data suggest that the ore-forming fluids were magmatic with a contribution from meteoric waters. The δ34S values of sulfides range from 1.9 to 3.4‰, those of barite range from 12.1 to 13.2‰, and those of gypsum range from 4.3 to 5.6‰. These data suggest that sulfur was mostly of magmatic origin with a minor contribution from sedimentary rocks. Our data suggest that the boiling of fluids formed an intermediate-sulfidation style of epithermal mineralization for the Mahour deposit. Full article
(This article belongs to the Special Issue New Insights into Porphyry, Epithermal, and Skarn Deposits)
Show Figures

Figure 1

21 pages, 15627 KiB  
Article
Discovery of Pseudomorph Scapolite and Diagenetic Indication from the Permian Volcaniclastic Rocks in Western Sichuan (SW China)
by Xiaohong Liu, Yue’e Li, Cong Tan, Zhenglin Cao, Hui Jin, Mingyou Feng, Maolong Xia and Junlang Chen
Minerals 2024, 14(2), 200; https://doi.org/10.3390/min14020200 - 15 Feb 2024
Cited by 1 | Viewed by 1646
Abstract
Volcaniclastic rocks are important unconventional oil and gas reservoirs from which it is difficult to determine the protolith due to strong metasomatic alteration. Intensive alteration has occurred in much of western China, but few robustly documented examples are known from which to assess [...] Read more.
Volcaniclastic rocks are important unconventional oil and gas reservoirs from which it is difficult to determine the protolith due to strong metasomatic alteration. Intensive alteration has occurred in much of western China, but few robustly documented examples are known from which to assess the alteration processes. Further recognition from the petrological and mineralogical record is essential to quantify the diagenetic environment, the degree of alteration, and its impacts. Permian volcanic rocks are widely developed in the western Sichuan Basin (southwestern China), with a thickness of more than 200 m. The thickness of volcaniclastic rocks in the Permian Emeishan Basalt Formation is up to 140 m, with a 5600~6000 m burial depth. In this study, we demonstrate an approach to recognizing hydrothermal alteration by the occurrence of scapolite megacryst mineral pseudomorphs (SMMPs) in Permian volcaniclastic rocks in the Sichuan Basin (southwestern China). The results show that SMMPs in the Permian volcaniclastic rocks in the western Sichuan Basin mainly occur in the lower part of the Permian basalts as intragranular minerals and rock inclusions. Scapolite is transformed into quartz and albite, and only the pseudomorph is preserved, indicating secondary hydrothermal fluid metasomatic alteration. Scapolite is formed after microcrystalline titanite and is the product of the high-temperature pneumatolytic metasomatism of plagioclase from the mafic protolith during the post-magmatic stage. The mixing of meteoric water and barium-rich hydrothermal fluid leads to the precipitation of barite; additionally, the pores are filled with barite and halite after the alteration of scapolite. The silicification and hydrothermal dissolution of scapolite and the albitization of sodium-rich matrix minerals increase the pore volume, which is conducive to the later recharge by hydrothermal fluids. The discovery of SMMPs can serve as an indicator of the high-temperature pneumatolytic metasomatism and mixing of meteoric water and deep hydrothermal fluid. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
Show Figures

Figure 1

53 pages, 8761 KiB  
Article
Marker Minerals in Volcanics and Xenoliths—An Approach to Categorize the Inferred Magmatic Rocks Underneath the Present-Day Volcanic Landscape of Tenerife, Spain (NW African Rare Mineral Province)
by Harald Gerold Dill and Kurt Anton Rüsenberg
Minerals 2023, 13(11), 1410; https://doi.org/10.3390/min13111410 - 3 Nov 2023
Cited by 5 | Viewed by 4803
Abstract
A mineralogical mapping (terrain analysis) based on micro-mounts has been performed in the Archipelago of the Canary Islands, Spain. The rare elements Be, F, Li, Nb, Ta, Zr, Hf, and rare earth elements (REE) were investigated on the largest island of the Canary [...] Read more.
A mineralogical mapping (terrain analysis) based on micro-mounts has been performed in the Archipelago of the Canary Islands, Spain. The rare elements Be, F, Li, Nb, Ta, Zr, Hf, and rare earth elements (REE) were investigated on the largest island of the Canary Islands Archipelago, Tenerife, Spain. This study forms a contribution to the metallogenetic evolution of the offshore area of the NW African Rare Mineral Province. The finds made at Tenerife were correlated by means of minero-stratigraphy with the adjacent islands La Gomera, Gran Canaria and Fuerteventura, where typical critical element host rocks, e.g., carbonatites, are exposed. At Tenerife, these hidden rock types are only indicated by a wealth of 128 compositional first-order marker minerals hosting Be, F, Zr, Nb, Ta, Zr, Hf, Li, Cs, Sn, W, Ti and REE plus Y and another 106 structural second-order marker minerals describing the geodynamic and morpho-structural evolution of Tenerife (Mn, Fe, Pb, U, Th, As, Sb, V, S, B, Cu, Zn, Mo, Au). Based upon the quantitative micro-mineralogical mapping of lithoclasts and mineralogical xenoliths (foid-bearing monzodiorite/gabbro, (nepheline) syenite, phonolite trachyte) in volcanic and volcaniclastic rocks, hidden intrusive/subvolcanic bodies can be delineated that are associated with contact-metasomatic, zeolitic and argillic alteration zones, as well as potential ore zones. Two potential types of deposits are determined. These are pegmatite-syenites with minor carbonatites bound to a series of agpaitic intrusive rocks that are genetically interlocked with rift zones and associated with a hotspot along a passive continental margin. Towards the east, the carbonatite/alkali magmatite ratio reverses at Fuerteventura in favor of carbonatites, while at Gran Canaria and La Gomera, shallow hypogene/supergene mineral associations interpreted as a marginal facies to Tenerife occur and a new REE discovery in APS minerals has been made. There are seven mineralizing processes different from each other and representative of a peculiar metallogenic process (given in brackets): Protostage 1 (rifting), stages 2a to 2d (differentiation of syenite–pegmatite), stages 3 to 4b (contact-metasomatic/hydrothermal mineralization), stages 5a to 5b (hydrothermal remobilization and zeolitization), stage 6 (shallow hypogene-supergene transition and kaolinization), and stage 7 (auto-hydrothermal-topomineralic mineralization). The prerequisites to successfully take this holistic approach in economic geology are a low maturity of the landscapes in the target area, a Cenozoic age of endogenous and exogenous processes amenable to sedimentological, geomorphological, volcano-tectonic and quantitative mineralogical investigations. The volcanic island’s mineralogical mapping is not primarily designed as a proper pre-well-site study on the Isle of Tenerife, but considered a reference study area for minero-stratigraphic inter-island correlation (land–land) and land–sea when investigating the seabed and seamounts around volcanic archipelagos along the passive margin, as exemplified by the NW African Craton and its metallogenic province. This unconventional exploration technique should also be tested for hotspot- and rift-related volcanic islands elsewhere on the globe for mineral commodities different from the ones under study. Full article
Show Figures

Figure 1

Back to TopTop