Search Results (113)

This study investigates the microstructural evolution, mechanical behavior, and electrochemical performance of CoCrFeNiNb and CoCrFeNiV HEAs fabricated via mechanical alloying and spark plasma sintering. Microstructural analyses reveal that the alloys have a face-centered cubic (FCC) matrix with Nb-enriched Laves and V-enriched σ phases. The CoCrFeNiNb HEA exhibits superior compressive strength and hardness than CoCrFeNiV due to uniform Laves phases distribution. Fracture surface analysis reveals that at lower sintering temperatures, the fracture is primarily caused by incomplete particle bonding, whereas at higher temperatures, brittle fracture modes dominated via transgranular cracking become predominant. The research results of potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) show that both alloys exhibited superior electrochemical stability in a 3.5 wt.% NaCl solution compared to the CoCrFeNi base alloy. X-ray photoelectron spectroscopy (XPS) analysis confirms the formation of stable oxide layers (Nb₂O₅ and V₂O₃) on the precipitated phases, acting as protective barriers against chloride ion penetration. The selective oxidation of Nb and V improves the integrity of the passive film, reducing the corrosion rates and enhancing the long-term durability. These findings highlight the critical role of precipitated phases in enhancing the corrosion resistance of HEAs, and emphasize their potential for use in extreme environments. Full article

To explore the influence of mine roof on the damage and failure of sandstone surrounding rock under different pressure rates, mechanical experiments with different strain rates were carried out on sandstone rock samples. The strength, deformation, failure, energy and damage characteristics of rock samples with different strain rates were also discussed. The research results show that with the increases in the strain rate, peak stress, and elastic modulus show a monotonically increasing trend, while the peak strain decreases in the reverse direction. At a low strain rate, the proportion of the mass fraction of complete rock blocks in the rock sample is relatively high, and the shape integrity is good, while rock samples with a high strain rate retain more small-sized fragmented rock blocks. This indicates that under high-rate loading, the bifurcation phenomenon of secondary cracks is obvious. The rock samples undergo a failure form dominated by small-sized fragments, with severe damage to the rock samples and significant fractal characteristics of the fragments. At the initial stage of loading, the primary fractures close, and the rock samples mainly dissipate energy in the forms of frictional slip and mineral fragmentation. In the middle stage of loading, the residual fractures are compacted, and the dissipative strain energy keeps increasing continuously. In the later stage of loading, secondary cracks accelerate their expansion, and elastic strain energy is released sharply, eventually leading to brittle failure of the rock sample. Under a low strain rate, secondary cracks slowly expand along the clay–quartz interface and cause intergranular failure of the rock sample. However, a high strain rate inhibits the stress relaxation of the clay, forces the energy to transfer to the quartz crystal, promotes the penetration of secondary cracks through the quartz crystal, and triggers transgranular failure. A constitutive model based on energy damage was further constructed, which can accurately characterize the nonlinear hardening characteristics and strength-deformation laws of rock samples with different strain rates. The evolution process of its energy damage can be divided into the unchanged stage, the slow growth stage, and the accelerated growth stage. The characteristics of this stage reveal the sudden change mechanism from the dissipation of elastic strain energy of rock samples to the unstable propagation of secondary cracks, clarify the cumulative influence of strain rate on damage, and provide a theoretical basis for the dynamic assessment of surrounding rock damage and disaster early warning when the mine roof comes under pressure. Full article

Grain boundary weakening in high-temperature environments significantly influences the fatigue crack growth mechanisms of nickel-based superalloys, introducing challenges in accurately predicting fatigue life. In this study, a dislocation-density-based crystal plasticity phase-field (CP–PF) model is developed to simulate the fatigue crack growth behavior of the GH4169 alloy under both room and elevated temperatures. Grain boundaries are explicitly modeled, enabling the competition between transgranular and intergranular cracking to be accurately captured. The grain boundary separation energy and surface energy, calculated via molecular dynamics simulations, are employed as failure criteria for grain boundary and intragranular material points, respectively. The simulation results reveal that under oxygen-free conditions, fatigue crack propagation at both room and high temperatures is governed by sustained shear slip, with crack advancement hindered by grains exhibiting low Schmid factors. When grain boundary oxidation is introduced, increasing oxidation levels progressively degrade grain boundary strength and reduce overall fatigue resistance. Specifically, at room temperature, oxidation shortens the duration of crack arrest near grain boundaries. At elevated service temperatures, intensified grain boundary degradation facilitates a transition in crack growth mode from transgranular to intergranular, thereby accelerating crack propagation and exacerbating fatigue damage. Full article

In the present study, fatigue performance of 6061-T6 and 6082-T6 commercially available extruded aluminum alloys in dry air and 3.5 wt% NaCl-saturated environment was investigated and compared. It was found that the aggressive chloride environment accelerated fatigue failure by up to an order of magnitude compared to laboratory air. Furthermore, alloy 6061-T6 shows more predictable fatigue life, having less scatter in its time to failure in a corrosive environment. The presence of localized pitting corrosion, particularly in Fe-rich intermetallic phases, provides initiation sites for fatigue cracks, leading to premature failure in both alloys. The corrosion fatigue cracks dominantly propagate through the grain interiors rather than along grain boundaries, indicating a tendency to transgranular crack propagation mechanisms. The effect of different loading frequencies (10 Hz and 0.2 Hz) on the corrosion fatigue life of 6061-T6 alloy showed a slightly enhanced fatigue life at the higher frequency. It was also found that alloy 6061-T6 was susceptible to pitting corrosion in NaCl-saturated environments with concentrations ranging between 0.5 wt% and 3.5 wt% without exhibiting significant changes in fatigue life. Full article

This study investigates the microstructural evolution and mechanical degradation mechanisms of cold-drawn 310S stainless steel subjected to repeated thermal cycling between 900 °C and room temperature. The results reveal that thermal cycling induces significant lattice distortion, dislocation accumulation, and recrystallization, leading to grain refinement and increased tensile strength. However, these microstructural changes also initiate subsurface cracks and reduce ductility. TGA analysis confirms thermal weight loss from decarburization, especially under oxidative atmospheres. EPMA analysis and tensile tests after thermal cycling reveal that surface cracks formed during thermal cycling act as origins for transgranular crack propagation under tensile stress, significantly reducing fracture resistance. Bending fatigue tests further demonstrate that thermally fatigued specimens exhibit inferior fatigue life compared to raw material, confirming the deteriorating mechanical properties of 310S stainless steel after thermal cycling. Overall, the combined effects of thermal and mechanical fatigue degrade the structural integrity of 310S stainless steel, revealing that lattice distortion and subsurface cracking are the key factors in its embrittlement and reduced fatigue performance. Full article

Cemented carbides are composite materials that combine both structural and functional properties. However, the inherent trade-off between strength and toughness presents a significant challenge in fully leveraging the synergistic potential of these dual-phase materials. In this study, cemented carbides with coarse and fine-grained heterogeneous structure were fabricated. The effects of nickel (Ni) and iron (Fe) content on the microstructures and mechanical properties of these heterogeneously structured cemented carbides were systematically investigated. Microstructural analysis revealed that the fine-grained granules are uniformly embedded in the coarse-grained region, forming a typical network-like mixed-grain structure. The introduction of the heterogeneous structure enables cemented carbides to achieve a remarkable balance of high strength and toughness. Specifically, the materials exhibit optimal strength–toughness matching with a transverse rupture strength of 2949 MPa, a fracture toughness of 23.65 MPa·m^−1/2, and a hardness of 1430 HV when the proportion of Ni and Fe content reaches 4.2 wt.%. The toughening mechanism is primarily attributed to the increased volume fraction and stabilized dimensions of CoNiFe binder phases, which promote interfacial decohesion at WC/WC and WC/binder boundaries while suppressing transgranular fracture. These mechanisms collectively contribute to enhanced toughening and crack propagation resistance. This study establishes foundational insights into achieving a synergistic combination of strength and toughness in cemented carbides. Full article

It is imperative to understand the shear mechanical properties and pore evolution of granite under thermal shock to assess the fracturing of hot dry rock reservoirs. In this study, variable-angle shear tests were performed on coarse- and fine-grained granite samples following liquid nitrogen (LN₂) cooling under different high-temperature conditions. The effect of thermal treatment temperature, particle type, and cooling method on the shear strength, cohesion, and angle of internal friction of granite was then analyzed. To this end, low field nuclear magnetic resonance (NMR) and scanning electron microscopy (SEM) were used to investigate the pore size distribution and microstructural evolution of granite. The experimental results indicate that both the shear strength and cohesion of granite initially increase and then decrease with the rise in thermal treatment temperature. The maximum increases in shear strength and cohesion are 38.0% and 36.7%, respectively, while the maximum decreases reach 43.7% and 42.4%. Notably, the most pronounced thermal hardening effect is observed at 200 °C. In contrast, the internal friction angle exhibits a decreasing-then-increasing trend as the temperature rises, with a maximum reduction of 5.4% and a maximum increase of 14.5%. In addition, fine-grained granite exhibits superior shear strength and a more pronounced thermal hardening effect compared to coarse-grained granite. Furthermore, the damage effect caused by thermal shock increases with increasing heat treatment temperature, with the damage effect induced by liquid nitrogen cooling being particularly significant compared to water cooling. Furthermore, for both types of granite at the same shear angle, an increase in the heat treatment temperature results in a corresponding increase in the total fracture area, with the fracture area after liquid nitrogen cooling being more significant. The macroscopic failure mode changes from a mixed compression–shear failure mode to a direct shear failure mode with increasing shear angle. NMR testing shows that liquid nitrogen cooling can effectively increase the proportion of medium pores and large pores in the granite and increase the connectivity of internal pores; specifically, in coarse-grained granite, medium pores and large pores collectively increased by 10.5%, while in fine-grained granite, the total increase in medium pores reached 51%. As the heat treatment temperature increases, the type of crack that develops in granite changes from intragranular to transgranular. In addition, the fracture surface of granite is more prone to form micropores and small pores when cooled with liquid nitrogen, increasing the connectivity of the crack network. The results of this research will be useful for fracturing hot dry rock reservoirs. Full article

This study investigates the tensile properties of granite subjected to cyclic thermal treatment under cyclic loading-unloading conditions, which is of great significance for the modification of hot dry rock reservoirs. Brazilian splitting tests under cyclic loading-unloading were conducted on granite samples exposed to 400 °C cyclic water-cooling shock (applied for 1, 3, 5, and 7 cycles) at different preset load upper limits (65%, 70%, 75%, and 80% of the peak load). The experimental results reveal the evolution of the tensile properties of granite under the combined effects of 400 °C cyclic water-cooling shock and cyclic loading-unloading. The findings indicate that the tensile strength of granite decreases with an increasing number of cyclic water-cooling shocks and further declines as the preset load upper limit decreases. Under typical conditions, the peak displacement of granite exhibits three distinct stages with increasing loading-unloading cycles: rapid increase, slow increase, and eventual failure. During the slow increase stage, peak displacement decreases due to an increase in elastic stiffness. Initially, elastic stiffness increases with the number of cycles, followed by a stabilization phase, and subsequently declines. After granite failure, macroscopic failure cracks gradually deviate from the center as additional cyclic water-cooling shocks are applied. In contrast, cyclic loading-unloading has a minimal effect on macroscopic cracks. Furthermore, as the number of cycles increases, microcrack evolution transitions from intergranular to transgranular cracking. Under cyclic loading-unloading conditions, these cracks continue to propagate, ultimately forming a fracture network. The findings of this study provide a theoretical foundation for the fracturing and modification of hot dry rock reservoirs. Full article

Predicting rock failure under excavation-induced non-uniform stress remains challenging due to the inability of conventional homogeneous specimens to replicate field-scale stress gradients. A novel trapezoidal sandstone specimen with adjustable top-surface inclinations (S75/S85) is proposed, uniquely simulating asymmetric stress gradients to mimic excavation unloading. Geometric asymmetry combined with multi-scale characterization (CT, SEM, PFC) decouples stress gradient effects from material heterogeneity. The key findings include the following points. (1) Inclination angles > 15° reduce peak strength by 24.2%, transitioning failure from brittle (transgranular cracks > 60) to mixed brittle-ductile modes (2) Stress gradients govern fracture pathways: transgranular cracks dominate high-stress zones, while intergranular cracks propagate along weak cementation interfaces. (3) PFC simulations reveal a 147% stress disparity between specimen sides and validate shear localization angles θ = 52° ± 3°), aligning with field data. This experimental–numerical framework resolves limitations of traditional methods, providing mechanistic insights into non-uniform load-driven failure. The methodology enables targeted support strategies for deep asymmetric roadways, including shear band mitigation and plastic zone reinforcement. By bridging lab-scale tests and engineering stress states, the study advances safety and sustainability in deep roadway excavation. Full article

High-entropy ceramics (HECs) have garnered considerable interest due to their exceptional mechanical properties and high-temperature stability. Nevertheless, their inherent brittleness significantly restricts industrial applications, posing a challenge to improving toughness without compromising hardness. This study investigates the role of SiC whiskers (SiCw) in simultaneously suppressing grain growth and enhancing the toughness of high-entropy (Ti_0.2Zr_0.2Hf_0.2Nb_0.2Ta_0.2)C (HEC) composites, while maintaining high hardness during high-pressure high-temperature (HPHT) sintering. HEC-SiCw composites were fabricated via HPHT (P = 5 GPa, T = 2000 °C), with SiCw contents ranging from 0 to 40 mol%. As the SiCw content increased, the growth of HEC grains was inhibited, and the fracture toughness progressively rose to a peak value (K_IC = 9.4 ± 1.2 MPa·m^1/2), representing an increase of approximately 184% compared to that of pure HEC, while Vickers hardness remained stable at 26 GPa. The enhancement in fracture toughness is attributed to the heterogeneous grain distribution and robust grain boundary strength, which facilitated a synergistic combination of transgranular and intergranular fracture mechanisms. These mechanisms induced crack deflection and whisker pull-out, effectively dissipating fracture energy and impeding crack propagation, thereby enhancing toughness. This study presents a novel approach to simultaneously refine grain size and improve toughness in HECs through HPHT processing, providing valuable insights for the development of next-generation ceramic composites. Full article

This study investigates the mesostructural damage evolution and creep deformation mechanisms in bedded rock salt through integrated scanning electron microscopy (SEM) and multistage creep experiments. Utilizing a self-developed in situ observation system coupled with digital image correlation (DIC) analysis, the microstructural heterogeneity, strain localization, and damage propagation patterns in the rock were systematically characterized. The results revealed distinct microstructural contrasts between rock salt and argillaceous interlayers, with interfacial regions exhibiting pore-rich, interconnected structures due to crystal gradation disparities. Creep damage initiation predominantly occurred in pure rock salt domains, manifesting as transgranular fractures and intercrystalline slip, followed by crack propagation into salt–mudstone interfaces governed by shear dilatancy. The integration of mesoscale structural characterization with macroscopic mechanical behavior establishes a framework for predicting the long-term stability of bedded salt formations under operational loads. Full article

S355 steels are widely used in various applications. However, they may be affected by hydrogen, which can induce hydrogen-induced cracking (HIC). The effects of the quenching temperature (T_wq) on the microstructure variation and HIC susceptibility of S355 steel was investigated by microstructural characterization, hydrogen permeation (HP) test, slow strain rate tensile (SSRT) test, hydrogen microprint technique (HMT) test, and hydrogen-charged cracking test. The results indicate that the microstructure of the treated specimens consisted of predominantly lath martensite (LM) and small amounts of lath bainite (LB) for the T_wq of 950 °C and 1000 °C, while the microstructure of the treated specimens mainly consisted of LM for the T_wq of 1050 °C and 1100 °C. The results indicate that as the T_wq increased, the sample treated at 950 °C exhibited a minimum hydrogen embrittlement index (I_z), while the sample treated at 1050 °C exhibited the maximum I_z. The hydrogen diffusion coefficient was relatively low, while the hydrogen concentration and trap density were relatively high for the T_wq of 1050 °C. The lath interfaces in martensite were effective hydrogen traps with high hydrogen-trapping efficiency. Hydrogen-induced cracks were significantly affected by hydrogen trapping at martensitic lath interfaces, exhibiting a basically transgranular fracture. Full article

This study explores the fatigue properties of EN AW-6082-T6 aluminum alloy in the gigacycle range (10⁶–10⁹ cycles), using ultrasonic resonance fatigue testing at 20 kHz in a push–pull mode with a symmetric load cycle (R = −1). A custom-built ultrasonic fatigue machine, developed at TU-Varna, comprising a generator, ultrasonic train (including a high-power transducer, booster, custom-made sonotrode, and specimen), monitoring, data logging systems, and an air-cooling capability, was used for the experiments conducted. A Bezier curve sonotrode, with an amplification ratio of 1:6, was designed and produced for the test. Hourglass-shaped specimens were designed on the base of the dynamic Young’s modulus E = 71.3 GPa, determined through the impulse resonance method (ASTM E1876-01), and validated with FEM analysis for resonance length and stress amplitude. The fatigue testing revealed a fatigue strength reduction of approximately 60 MPa between 10⁶ and 10⁹ cycles. The percentile of failure curves based on a Cactillo–Canteli model fits well with the experimental data and gives a fatigue limit at 10⁹ cycles σl = 104 MPa and “endurance strength” σw = 84 MPa. Surface crack initiation was consistently observed with predominately cleavage transgranular fractures in the fatigue zone. The present research highlights the utility of ultrasonic testing for examining fatigue behavior in the gigacycle regime. Full article

The resistance to near-threshold fatigue crack growth and its correlation with the microstructure of the Ti-5Al-3Mo-3V-2Zr-2Cr-1Nb-1Fe alloy were investigated. K-decreasing fatigue crack propagation rate tests were conducted on compact tension samples (ASTM standard) with a stress ratio R of 0.1 and a frequency of 15 HZ in a laboratory atmosphere. At a similar strength level of 1200 MPa, the sample with a fine basket-weave microstructure (F-BW) displayed the slowest near-threshold fatigue crack propagation rate compared with the samples with equiaxed (EM) and basket-weave (BW) microstructures. The fatigue threshold value (ΔK_th) was 4.4 MPa·m^1/2 for F-BW, 3.6 for BW, and 3.2 for EM. The fracture surfaces and crack profiles were observed by scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD) to elucidate the mechanism of fatigue crack propagation in the near-threshold regime. The results revealed that the near-threshold crack growth in the three samples was primarily transgranular. The crack always propagated parallel to the crystal plane, with a high Schmid factor. In addition, the near-threshold fatigue crack growth behavior was synergistically affected by the crack tip plastic zone and crack bifurcation. The increased fatigue crack propagation resistance in F-BW was attributed to the better stress/strain compatibility and greater number of interface obstacles in the crack tip plastic zone. Full article

The effects of microstructure and mechanical properties on the wear resistance of B₄C-TiB₂ ceramic composite were studied. The composite was hot pressed from a B₄C-TiO₂ precursor at a temperature range of 1800 and 1850 °C. Both the relative density and amount of TiB₂ secondary phase of the B₄C-TiB₂ composite increased with the amount of TiO₂ sintering additive in B₄C-TiO₂ precursor. The hardness of the composite increased with a secondary phase portion up to 29.8 vol.% TiB₂. However, the positive effect of TiB₂ secondary phase on the fracture toughness of B₄C-TiB₂ composite was measured in the complete experimental range, with the highest average attained value of 7.51 MPa·m^1/2. The wear resistance of B₄C-TiB₂ composite increased with both the hardness and fracture toughness. The best wear resistance was achieved with the composite with a higher hardness value of 29.74 GPa. This sample consisted of 29.8 vol.% TiB₂ secondary phase and reached a fracture toughness value of 6.91 MPa·m^1/2. The fracture-induced mechanical wear of B₄C-TiB₂ composite was the main wear mechanism during the pin-on-disc wear test. Transgranular fracture with pullout of the surface and micro-crack formation in the direction perpendicular to the wear direction was observed on the worn surfaces. Full article