Search Results (9)

Titanium dioxide (TiO₂), a widely used semiconductor in photocatalysis owing to its adequate potential for water hydrolysis, chemical stability, low toxicity, and low cost. However, its efficiency is limited by fast charge-carrier recombination and poor visible light absorption. Coupling TiO₂ with a p-type semiconductor, such as nickel oxide (NiO), forming a p-n heterojunction, decreases the recombination of charge carriers and increases photocatalytic activity. In this work, the surface of TiO₂ modified with NiO nanoparticles (NPs) induced by radiolysis for photocatalytic hydrogen production was studied. The photocatalytic activity of NiO/TiO₂ was evaluated using methanol as a hole scavenger under UV–visible light. All modified samples presented superior photocatalytic activity compared to bare TiO₂. The dynamics of the charge carriers, a key electronic phenomenon in photocatalysis, was investigated by time-resolved microwave conductivity (TRMC). The results highlight the crucial role of Ni-based NPs modification in enhancing the separation of the charge carrier and activity under UV–visible irradiation. Furthermore, the results revealed that under visible irradiation, NiO-NPs inject electrons into the conduction band of titanium dioxide. Full article

Sb₂Se₃ has recently emerged as a promising material for optic-electronic applications. In this work, trapped carrier recombination in Sb₂Se₃ was investigated by joint use of time-resolved microwave conductivity (TRMC) and photoluminescence (PL) spectroscopy. trapped carrier thermal excitation into the continuous band was observed in TRMC kinetics. Based on the exponential band tail model, the depth of the trap state, where trapped carriers are released into a continuous band, was estimated to range from 33.0 meV to 110.0 meV at room temperature. Temperature-varying TRMC and PL were further employed to study the influence of temperature on the trapped carrier recombination. Negative thermal quenchings of PL intensity and quantity of thermal emission carriers were observed and can be well explained by the thermal excitation of deep trapped carriers into shallow trap states and the continuous band. Two thermal activation energies of 12.5 meV and 304.0 meV were also revealed. This work is helpful for understanding the trapped carrier recombination process in polycrystalline Sb₂Se₃ film. Full article

As a newly proposed high resolution computational imaging technique, Microwave Staring Correlated Imaging (MSCI) requires elaborate design of the temporal-spatial stochastic radiation fields (TSSRF). Conventional implementation of MSCI radiation source consists of multiple transmitters configuration and simultaneous emitting scheme, which remains underutilization of the available design resources. In this paper, a time-division MSCI (TD-MSCI) method is proposed to virtually generate the TSSRF and make further use of the available design resources. Different from convention simultaneously transmitting based MSCI, the detection scheme in TD-MSCI is achieved by alternately transmitting of each transmitter, rather than simultaneous transmission of multiple transmitters. Echo enhancement is conducted to improve the SNR level of the echo waveform and to resolve the power coastdown caused by single transmitting scheme. Unused combinations of existing resources are digitally synthesized in computer rather than taking extra observations in actual physical environment. After the processing of time division observation, echo enhancement and digital waveform synthesis, extending TSSRF with better stochastic characteristics are generated, and improved imaging performance is obtained. Numerical imaging experiments and preliminary real-world imaging experiment verify the effectiveness of the proposed TD-MSCI, demonstrating that the proposed method increases the flexibility in radiation source design and decreases the detection costs. Full article

In the last decade, technological advances led to the launch of two satellite missions dedicated to measure the Earth’s surface soil moisture (SSM): the ESA’s Soil Moisture and Ocean Salinity (SMOS) launched in 2009, and the NASA’s Soil Moisture Active Passive (SMAP) launched in 2015. The two satellites have an L-band microwave radiometer on-board to measure the Earth’s surface emission. These measurements (brightness temperatures T_B) are then used to generate global maps of SSM every three days with a spatial resolution of about 30–40 km and a target accuracy of 0.04 m³/m³. To meet local applications needs, different approaches have been proposed to spatially disaggregate SMOS and SMAP T_B or their SSM products. They rely on synergies between multi-sensor observations and are built upon different physical assumptions. In this study, temporal and spatial characteristics of six operational SSM products derived from SMOS and SMAP are assessed in order to diagnose their distinct features, and the rationale behind them. The study is focused on the Iberian Peninsula and covers the period from April 2015 to December 2017. A temporal inter-comparison analysis is carried out using in situ SSM data from the Soil Moisture Measurements Station Network of the University of Salamanca (REMEDHUS) to evaluate the impact of the spatial scale of the different products (1, 3, 9, 25, and 36 km), and their correspondence in terms of temporal dynamics. A spatial analysis is conducted for the whole Iberian Peninsula with emphasis on the added-value that the enhanced resolution products provide based on the microwave-optical (SMOS/ERA5/MODIS) or the active–passive microwave (SMAP/Sentinel-1) sensor fusion. Our results show overall agreement among time series of the products regardless their spatial scale when compared to in situ measurements. Still, higher spatial resolutions would be needed to capture local features such as small irrigated areas that are not dominant at the 1-km pixel scale. The degree to which spatial features are resolved by the enhanced resolution products depend on the multi-sensor synergies employed (at T_B or soil moisture level), and on the nature of the fine-scale information used. The largest disparities between these products occur in forested areas, which may be related to the reduced sensitivity of high-resolution active microwave and optical data to soil properties under dense vegetation. Full article

Octahedral anatase particles (OAP) with eight exposed and thermodynamically most stable (101) facets were prepared by an ultrasonication-hydrothermal (US-HT) reaction from potassium titanate nanowires (TNW). The precursor (TNW) and the product (OAP) of US-HT reaction were modified with nanoparticles of noble metals (Au, Ag or Pt) by photodeposition. Samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS), scanning transmission electron microscopy (STEM) and time-resolved microwave conductivity (TRMC). The photocatalytic activity was investigated in three reaction systems, i.e., anaerobic dehydrogenation of methanol and oxidative decomposition of acetic acid under UV/vis irradiation, and oxidation of 2-propanol under vis irradiation. It was found that hydrogen liberation correlated with work function of metals, and thus the most active were platinum-modified samples. Photocatalytic activities of bare and modified OAP samples were much higher than those of TNW samples, probably due to anatase presence, higher crystallinity and electron mobility in faceted NPs. Interestingly, noble metals showed different influence on the activity depending on the semiconductor support, i.e., gold-modified TNW and platinum-modified OAP exhibited the highest activity for acetic acid decomposition, whereas silver- and gold-modified samples were the most active under vis irradiation, respectively. It is proposed that the form of noble metal (metallic vs. oxidized) as well as the morphology (well-organized vs. uncontrolled) have a critical effect on the overall photocatalytic performance. TRMC analysis confirmed that fast electron transfer to noble metal is a key factor for UV activity. It is proposed that the efficiency of plasmonic photocatalysis (under vis irradiation) depends on the oxidation form of metal (zero-valent preferable), photoabsorption properties (broad localized surface plasmon resonance (LSPR)), kind of metal (silver) and counteraction of “hot” electrons back transfer to noble metal NPs (by controlled morphology and high crystallinity). Full article

Coupling metal-organic frameworks (MOFs) with inorganic semiconductors has been successfully tested in a variety of photocatalytic reactions. In this work we present the synthesis of TiO₂/HKUST-1 composites by grinding, solvothermal, and chemical methods, using different TiO₂ loadings. These composites were used as photocatalysts for hydrogen production by the photoreforming of a glycerol-water mixture under simulated solar light. Several characterization techniques were employed, including X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), infrared spectroscopy (FTIR), and time-resolved microwave conductivity (TRMC). A synergetic effect was observed with all TiO₂/HKUST-1 composites (mass ratio TiO₂/MOF 1:1), which presented higher photocatalytic activity than that of individual components. These results were explained in terms of an inhibition of the charge carrier (hole-electron) recombination reaction after photoexcitation, favoring the electron transfer from TiO₂ to the MOF and creating reversible Cu¹⁺/Cu⁰ entities useful for hydrogen production. Full article

Climate change and anthropogenic activities, including agricultural irrigation have significantly altered the global and regional hydrological cycle. However, human-induced modification to the natural environment is not well represented in land surface models (LSMs). In this study, we utilize microwave-based soil moisture products to aid the detection of under-represented irrigation processes throughout China. The satellite retrievals used in this study include passive microwave observations from the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E) and its successor AMSR2, active microwave observations from the Advanced Scatterometer (ASCAT), and the blended multi-sensor soil moisture product from the European Space Agency (i.e., ESA CCI product). We first conducted validations of the three soil moisture retrievals against in-situ observations (collected from the nationwide agro-meteorological network) in irrigated areas in China. It is found that compared to the conventional Spearman’s rank correlation and Pearson correlation coefficients, entropy-based mutual information is more suitable for evaluating soil moisture anomalies induced by irrigation. In general, around 60% of uncertainties in the anomaly of “ground truth” time series can be resolved by soil moisture retrievals, with ASCAT outperforming the others. Following this, the potential utility of soil moisture retrievals in mapping irrigation patterns in China is investigated by examining the difference in probability distribution functions (detected by two-sample Kolmogorov-Smirnov test) between soil moisture retrievals and benchmarks of the numerical model ERA-Interim without considering the irrigation process. Results show that microwave remote sensing provides a promising alternative to detect the under-represented irrigation process against the reference LSM ERA-Interim. Specifically, the highest performance in detecting irrigation intensity is found when using ASCAT in Huang-Huai-Hai Plain, followed by advanced microwave scanning radiometer (AMSR) and ESA CCI. Compared to ASCAT, the irrigation detection capabilities of AMSR exhibit higher discrepancies between descending and ascending orbits, since the soil moisture retrieval algorithm of AMSR is based on surface temperature and, thus, more affected by irrigation practices. This study provides insights into detecting the irrigation extent using microwave-based soil moisture with aid of LSM simulations, which has great implications for numerical model development and agricultural managements across the country. Full article

The influence of changes in structural and physical properties on the photocatalytic activity of octahedral anatase particles (OAPs), exposing eight equivalent {101} facets, caused by calcination (2 h) in air or grinding (1 h) in an agate mortar was studied with samples prepared by ultrasonication (US; 1 h)–hydrothermal reaction (HT; 24 h, 433 K). Calcination in air at temperatures up to 1173 K induced particle shape changes, evaluated by aspect ratio (AR; d₀₀₁/d₁₀₁ = depth vertical to anatase {001} and {101} facets estimated by the Scherrer equation with data obtained from X-ray diffraction (XRD) patterns) and content of OAP and semi-OAP particles, without transformation into rutile. AR and OAP content, as well as specific surface area (SSA), were almost unchanged by calcination at temperatures up to 673 K and were then decreased by elevating the calcination temperature, suggesting that calcination at a higher temperature caused dull-edging and particle sintering, the latter also being supported by the analysis of particle size using XRD patterns and scanning electron microscopic (SEM) images. Time-resolved microwave conductivity (TRMC) showed that the maximum signal intensity (I_max), corresponding to a product of charge-carrier density and mobility, and signal-decay rate, presumably corresponding to reactivity of charge carriers, were increased with increase in AR, suggesting higher photocatalytic activity of OAPs than that of dull-edged particles. Grinding also decreased the AR, indicating the formation of dull-edged particles. The original non-treated samples showed activities in the oxidative decomposition of acetic acid (CO₂ system) and dehydrogenation of methanol (H₂ system) comparable to and lower than those of a commercial anatase titania (Showa Denko Ceramics FP-6), respectively. The activities of calcined and ground samples for the CO₂ system and H₂ system showed almost linear relations with AR and I_max, respectively, suggesting that those activities may depend on different properties. Full article

There is a need for low-cost, high-accuracy measurement of water content in various materials. This study assesses the performance of a new microwave swept frequency domain instrument (SFI) that has promise to provide a low-cost, high-accuracy alternative to the traditional and more expensive time domain reflectometry (TDR). The technique obtains permittivity measurements of soils in the frequency domain utilizing a through transmission configuration, transmissometry, which provides a frequency domain transmissometry measurement (FDT). The measurement is comparable to time domain transmissometry (TDT) with the added advantage of also being able to separately quantify the real and imaginary portions of the complex permittivity so that the measured bulk permittivity is more accurate that the measurement TDR provides where the apparent permittivity is impacted by the signal loss, which can be significant in heavier soils. The experimental SFI was compared with a high-end 12 GHz TDR/TDT system across a range of soils at varying soil water contents and densities. As propagation delay is the fundamental measurement of interest to the well-established TDR or TDT technique; the first set of tests utilized precision propagation delay lines to test the accuracy of the SFI instrument’s ability to resolve propagation delays across the expected range of delays that a soil probe would present when subjected to the expected range of soil types and soil moisture typical to an agronomic cropping system. The results of the precision-delay line testing suggests the instrument is capable of predicting propagation delays with a RMSE of +/−105 ps across the range of delays ranging from 0 to 12,000 ps with a coefficient of determination of r² = 0.998. The second phase of tests noted the rich history of TDR for prediction of soil moisture and leveraged this history by utilizing TDT measured with a high-end Hewlett Packard TDR/TDT instrument to directly benchmark the SFI instrument over a range of soil types, at varying levels of moisture. This testing protocol was developed to provide the best possible comparison between SFI to TDT than would otherwise be possible by using soil moisture as the bench mark, due to variations in soil density between soil water content levels which are known to impact the calibration between TDR’s estimate of soil water content from the measured propagation delay which is converted to an apparent permittivity measurement. This experimental decision, to compare propagation delay of TDT to FDT, effectively removes the errors due to variations in packing density from the evaluation and provides a direct comparison between the SFI instrument and the time domain technique of TDT. The tests utilized three soils (a sand, an Acuff loam and an Olton clay-loam) that were packed to varying bulk densities and prepared to provide a range of water contents and electrical conductivities by which to compare the performance of the SFI technology to TDT measurements of propagation delay. For each sample tested, the SFI instrument and the TDT both performed the measurements on the exact same probe, thereby both instruments were measuring the exact same soil/soil-probe response to ensure the most accurate means to compare the SFI instrument to a high-end TDT instrument. Test results provided an estimated instrumental accuracy for the SFI of +/−0.98% of full scale, RMSE basis, for the precision delay lines and +/−1.32% when the SFI was evaluated on loam and clay loam soils, in comparison to TDT as the bench-mark. Results from both experiments provide evidence that the low-cost SFI approach is a viable alternative to conventional TDR/TDT for high accuracy applications. Full article