Search Results (29)

Extreme climatic conditions characterized by drastic temperature fluctuations exacerbate soil erosion through intensified thermo-mechanical weathering processes. Loess-covered regions are particularly vulnerable to such conditions because of the inherent thermo-sensitivity of loess. A comprehensive investigation of mechanisms of thermo-mechanical weathering in loess under extreme temperature regimes holds critical importance for elucidating soil degradation patterns. It is also essential for formulating mitigation strategies in climate-sensitive loess terrains, especially given the increasing frequency of extreme weather events under global warming scenarios. This study employed integrated physical monitoring experiments and numerical modeling. The evolutionary patterns of temperature fields and corresponding thermal stress distributions in loess subjected to both heat shock (rapid heating) and cold shock (rapid cooling) conditions were systematically examined. The key findings are as follows: (1) Soil temperature variations demonstrate phase-lagged responses to ambient thermal variations during both shock scenarios, exhibiting distinct thermal inertia effects. (2) The spatial distribution pattern of thermal stress is predominantly governed by the temperature gradient within the soil matrix. (3) While the magnitude ranges of thermal stress remain comparable between shock types, their directional characteristics fundamentally differ; heat shocks induce surface compressive stresses and internal tensile stresses, whereas cold shocks generate inverse stress patterns. (4) Compared to heat shock, cold shocks trigger obvious surface degradation through tensile stress-induced failure of particle bonds. These mechanically weakened zones establish favorable conditions for subsequent erosion processes in loess landscapes. Full article

The selection of a suitable plasma-facing material (PFM) that must protect the divertor, cooling systems, and structural components is an important challenge in the design of advanced fusion reactors and requires careful consideration. Material degradation due to melting and evaporation may lead to plasma contamination, which must be strictly avoided. Among the candidate materials, tungsten (W) is the most promising because of its thermo-mechanical and physical properties, which allow it to endure repeated exposure to extremely harsh conditions within the reactor. The plasma spraying (PS) technique is gaining increasing interest for the deposition of tungsten (W) coatings to protect heat sink materials, due to its relatively low cost, high deposition rates, and capability to coat complex-shaped surfaces and fix damaged coatings in situ. This review aims to provide a systematic assessment of tungsten (W) coatings produced by PS techniques, evaluating their suitability as PFMs. It discusses W-based materials, plasma spraying technologies, the role of the interface in joining W coating and metallic substrates such as copper alloys and steels, and the main issues related to coating surface erosion under steady-state and transient heat loads associated with advanced fusion reactor operation modes and off-normal events. Quantitative data available in the literature, such as porosity, oxygen content, thermal conductivity of the coatings, residual stresses accumulated in the coating–substrate interface, surface temperature, and material loss following heat load events, were summarized and compared to bulk W ones. The results demonstrate that, following optimization of the fabrication process, PS-W coatings exhibit excellent performance. In addition, previously mentioned advantages of PS technology make PS-W coatings an attractive alternative for PFM fabrication. Full article

Purpose: This study aimed to evaluate the load-bearing capacity of three different millable lithium silicate derivatives compared with lithium disilicate ceramic when used as ultra-thin occlusal veneers on eroded molars. The null hypothesis stated that there would be no significant differences in load-bearing capacity (F_max). Material and Methods: Four groups were tested: three groups with lithium silicate derivatives—“Celt” (Celtra, Dentsply Sirona, Bensheim, Germany), “Vita” (Vita Suprinity PC, Vita Zahnfabrik, Bad Säckingen, Germany), and “Nice” (n!ce, Straumann, Basel, Switzerland)—and a control group with lithium disilicate ceramic, “Emax” (IPS e.max CAD, Ivoclar Vivadent) (n = 20 per group). Extracted molars (n = 80) were prepared to simulate erosion and restored with occlusal veneers designed and milled by using CAD/CAM technology. After thermo-mechanical aging, the specimens were subjected to static load testing until fracture. Failure types were recorded and analyzed. Statistical evaluation included the Wilcoxon rank-sum test for group comparisons and Weibull distribution modeling to assess fracture probabilities. Results: Thermo-mechanical aging caused restoration debonding in three specimens from the “Nice” and “Celt” groups, resulting in fatigue resistance of 100% for “Emax” and “Vita”, 90% for “Celt”, and 95% for “Nice”. The mean F_max values ranged from 892 N to 2087 N, with the “Vita” group demonstrating the highest values. Significant differences in stress values were observed among groups (p < 0.05). Cohesive failure was the most frequent failure mode. Conclusions: All tested lithium silicate derivatives demonstrated high load-bearing capacity and are suitable for ultra-thin occlusal veneers on eroded molars. Cohesive failures dominated, indicating reliable material performance and stable bonding under load. Full article

(1) Background: The present study examines the effects of fire on the ecosystem services of forest ecosystems in Greece. Being a Mediterranean country, Greece has been affected by fires of increasing intensity and frequency in recent years; (2) Methods: Information was extracted from 56 articles published in the period January 1997–March 2024 that were selected after an extensive literature review; (3) Results: An increasing trend in the number of published articles over time was observed. Studies on regulating and maintenance services prevailed. The majority of studies reported on thermo-Mediterranean ecosystems, with Pinus halepensis Mill forests being the most common ecosystems affected by fires. The effects of fire were primarily negative on provisioning and cultural services, as well as on the control of erosion rates, regulation of the hydrologic cycle, atmospheric composition, and climate regulation. Most effects on plant diversity were found to be positive, while positive and neutral effects were also recorded for pollination. The most pronounced negative or positive effects were noted for the first two years after the fire. The spatial mapping of the results showed that the areas most affected by the fires in Greece are Eastern Attica, Euboea, Western Attica, and most regional units of the Peloponnese; (4) Conclusions: In the era of climate change and changing fire regimes in the Mediterranean, there is a need to further research the impact of fire on ecosystem services, as this will help in the better protection and management of the most vulnerable forest ecosystems. Full article

The aim of this paper is to investigate the aging mechanism of asphalt in the sea salt erosion environment from a rheological point of view. In order to simulate the real pavement aging process in the sea salt erosion environment, base asphalt and Styrene−Butadiene−Styrene (SBS)-modified asphalt were selected for salt environment aging tests. The asphalt samples were aged via a thin film oven test (TFOT) and a pressure aging vessel (PAV) test. Then, thermo-oxidizing conditions were created after the samples were immersed in salt solution, mixed with four different concentrations of sodium chloride (NaCl) and sodium sulphate (Na₂SO₄), to investigate the aging state of asphalt. Temperature scan (TS), frequency scan (FS), and multiple stress creep and recovery (MSCR) tests performed using a Dynamic Shear Rheometer (DSR) were used to investigate the effects on the rheological properties of aged asphalt in a salt environment. The results showed that both base asphalt and SBS-modified asphalt were aged to different degrees under mixed salt solutions. The two asphalt samples aged in a salt environment showed increased hardness. SBS-modified asphalt exhibited higher aging resistance compared with base asphalt in the sea salt environment. However, due to the degradation of the SBS modifier and the aging of base asphalt, the properties of the SBS-modified asphalt showed more obvious complexity with changes in salt solution concentrations. Full article

This study investigated the thermally induced aging effects on a carbon fiber-reinforced composite (CFRP) comprising benzoxazine (BZ) and cycloaliphatic epoxy resin (CER). Herein, we employed various testing methodologies to assess the aging behavior of CFRP samples with differing CER and BZ ratios. Traditional techniques, including weight change quantification and qualitative analysis of surface morphology, reveal that higher CER content correlates with increased aging. Additionally, wettability analysis demonstrates that both BZ and BZ-CER composites exhibit heightened hydrophilicity with thermal aging, potentially exacerbating concerns such as icing and surface erosion. Notably, the BZ-CER composite displays greater hydrophilicity compared to the BZ composite, consistent with weight change trends. These findings underscore the utility of surface wettability analysis as a valuable tool for monitoring thermo-oxidative aging in polymers and their surface behavior in response to fluid interactions, particularly within high glass transition temperature ($T_g$) BZ-CER systems utilized in structural composite applications. Full article

Two classes of thermal protection systems composed of a carbon-fibre-reinforced (CFRP) layer and an ablative material layer joined with a thermo-resistant ceramic adhesive were developed. The two classes differ in the composition of the ablative material reinforcing compound. In the first class, the ablative material is based on micronic-sized cork granules, and in the second class, the ablative material is reinforced with carbonic felt. For both classes of thermal protection systems, the reinforcement material was impregnated in simple phenolic resin, and nanometric additive, consisting of silicon carbide nanoparticles added in two different weight contents (1 and 2% by weight) relative to the resin. The thermal conductivity for the ablative materials in the thermal protection systems structure was determined. A test facility using oxy-butane flame was developed through which the thermal protection systems developed were tested at extreme temperatures, to simulate some thermal conditions in space applications. The materials were characterised from a morphostructural point of view using optical and scanning electron microscopy after thermal testing. The TPS composed of the carbon-felt-based ablative layer showed improved behaviour compared to the cork-based ablative ones in terms of the temperature increase rate during thermal conductivity testing, mass loss, as well as morphostructural appearance and material erosion after oxy-butane testing. The nSiC-based samples in both sets of TPSs showed improved behaviour compared to the un-filled ones, considering the temperature increase, mass loss, and morphostructure of the eroded material. Full article

This work studied the effect of cellulose nanocrystal (NCC) content on the biodegradation kinetics of PLA-based multiscale cellulosic biocomposites (PLAMCBs). To facilitate biodegradation, the materials were subjected to thermo-oxidation before composting. Biodegradation was carried out for 180 days under controlled thermophilic composting conditions according to the ASTM D 5338 standard. A first-order model based on Monod’s kinetics under limiting substrate conditions was used to study the effect of cellulose nanocrystal (NCC) content on the biodegradation kinetics of multiscale composite materials. It was found that thermo-oxidation at 70 °C for 160 h increased the biodegradability of PLA. Also, it was found that the incorporation of cellulosic fibrous reinforcements increased the biodegradability of PLA by promoting hydrolysis during the first stage of composting. Likewise, it was found that partial substitution of micro cellulose (MFC) by cellulose nanocrystals (NCCs) increased the biodegradability of the biocomposite. This increase was more evident as the NCC content increased, which was attributed to the fact that the incorporation of cellulose nanocrystals facilitated the entry of water into the material and therefore promoted the hydrolytic degradation of the most recalcitrant fraction of PLA from the bulk and not only by surface erosion. Full article

Thermo-erosion gullies (TGs) are typical thermokarst features in upland permafrost; the soil organic carbon (SOC) of TGs has an important influence on soil quality in cold regions. The objectives of this study were to estimate the spatial distribution of SOC content in a typical TG on the northeastern Tibetan Plateau in China by using soil properties from seven different TGs and covariates from unmanned aerial vehicle (UAV) images, and to characterize the SOC content changes in four representative landscape regions (NO-Slumping, Slumping1, Slumping2, and Slumped) within this typical TG. The support vector machine (SVM) was the optimal machine learning algorithm for SOC content prediction, which explained 53.06% (R²) of the SOC content variation. Silt content was the most influential factor which demonstrated a positive relationship with SOC content in different TGs. In addition, the SOC content in the TGs was related to the landscapes. Severe Slumping (Slumping2: 150.79 g·kg⁻¹) had a lower SOC content than NO-Slumped (163.29 g·kg⁻¹) and the initial slumping stage (Slumping1: 169.08 g·kg⁻¹). The results suggested that SVM was an effective algorithm to obtain a profound understanding of the SOC content over space, while future research needs to pay more attention to the SOC content distribution in the different TGs. Full article

Ice–rich Pleistocene permafrost deposits (Yedoma) store large amounts of nitrogen (N) and are susceptible to rapid thaw. In this study, we assess whether eroding Yedoma deposits are potential sources of N and gaseous carbon (C) losses. Therefore, we determined aerobic net ammonification and nitrification, as well as anaerobic production of nitrous oxide (N₂O), carbon dioxide (CO₂), and methane (CH₄) in laboratory incubations. Samples were collected from non-vegetated and revegetated slump floor (SF) and thaw mound (TM) soils of a retrogressive thaw slump in the Lena River Delta of Eastern Siberia. We found high nitrate concentrations (up to 110 µg N (g DW)⁻¹) within the growing season, a faster transformation of organic N to nitrate, and high N₂O production (up to 217 ng N₂O-N (g DW)⁻¹ day⁻¹) in revegetated thaw mounds. The slump floor was low in nitrate and did not produce N₂O under anaerobic conditions, but produced the most CO₂ (up to 7 µg CO₂-C (g DW)⁻¹ day⁻¹) and CH₄ (up to 65 ng CH₄-C (g DW)⁻¹ day⁻¹). Nitrate additions showed that denitrification was substrate limited in the slump floor. Nitrate limitation was rather caused by field conditions (moisture, pH) than by microbial functional limitation since nitrification rates were positive under laboratory conditions. Our results emphasize the relevance of considering landscape processes, geomorphology, and soil origin in order to identify hotspots of high N availability, as well as C and N losses. High N availability is likely to have an impact on carbon cycling, but to what extent needs further investigation. Full article

The Arctic is greatly affected by climate change. Increasing air temperatures drive permafrost thaw and an increase in coastal erosion and river discharge. This results in a greater input of sediment and organic matter into nearshore waters, impacting ecosystems by reducing light transmission through the water column and altering biogeochemistry. This potentially results in impacts on the subsistence economy of local people as well as the climate due to the transformation of suspended organic matter into greenhouse gases. Even though the impacts of increased suspended sediment concentrations and turbidity in the Arctic nearshore zone are well-studied, the mechanisms underpinning this increase are largely unknown. Wave energy and tides drive the level of turbidity in the temperate and tropical parts of the world, and this is generally assumed to also be the case in the Arctic. However, the tidal range is considerably lower in the Arctic, and processes related to the occurrence of permafrost have the potential to greatly contribute to nearshore turbidity. In this study, we use high-resolution satellite imagery alongside in situ and ERA5 reanalysis data of ocean and climate variables in order to identify the drivers of nearshore turbidity, along with its seasonality in the nearshore waters of Herschel Island Qikiqtaruk, in the western Canadian Arctic. Nearshore turbidity correlates well to wind direction, wind speed, significant wave height, and wave period. Nearshore turbidity is superiorly correlated to wind speed at the Beaufort Shelf compared to in situ measurements at Herschel Island Qikiqtaruk, showing that nearshore turbidity, albeit being of limited spatial extent, is influenced by large-scale weather and ocean phenomenons. We show that, in contrast to the temperate and tropical ocean, freshly eroded material is the predominant driver of nearshore turbidity in the Arctic, rather than resuspension, which is caused by the vulnerability of permafrost coasts to thermo-erosion. Full article

To enhance the surface of a material with the desired qualities for diverse applications in service, a variety of thermal and thermo-chemical surface treatment processes are used. Due to the high-velocity impact inherent in the process, high-velocity oxy-fuel (HVOF) spray is now frequently employed in industrial applications for its ability to generate a high-quality coating with appropriate hardness and low oxide content. In this investigation, a high-velocity oxy-fuel (HVOF) thermal spraying process was utilized to coat WC-10Co powders on a 35CrMo steel substrate. A water jet erosion test was also used to examine the substrate and coated samples’ erosion behavior. The erosion rate was systematically investigated using water jet variables such as the angle of impingement, water jet velocity, standoff distance, and erodent discharge. For the development of multiple regression models, experiments were performed utilizing the central composite rotatable design and the response surface methodology. The angle of impingement had the most impact on the rate of coating erosion, leading to the water jet velocity, standoff distance, and erodent discharge. Full article

Concrete surface treatment is one of effective methods to increase the durability of concrete. This study chose tetraethyl orthosilicate (TEOS), lithium silicate (Li₂SiO₃), SiO₂ nanoparticles (nano-SiO₂) as surface treatment agents, tested their resistance to water penetration, chloride ion penetration, frost, sulfate erosion and abrasion of concrete specimens with different strengths, compared and evaluated the impacts to the durability of concrete by using three surface treatment agents, researched the impact of concrete strength on the surface treatment effects, and analyzed the mechanism of these surface treatment agents in connection with microscopic tests. It was found that all three agents can improve the durability of concrete, of which, the treatment effect from using tetraethyl orthosilicate (TEOS) was the best; however, along with the improvement of concrete strength, its other effects were gradually reinforced except for some small improvement effect in resistance to frost, which means it is an ideal concrete surface treatment agent; for lithium silicate (Li₂SiO₃), the improvement effect of resistance to frost was the best with little impact on the strength of the concrete, however, the other performance improvement effects were a little bit worse than that of tetraethyl orthosilicate (TEOS), which means it is more suitable for airport pavement with a higher concrete resistance to frost; For SiO₂ nanoparticles (Nano-SiO₂), the surface treatment effect was extreme limited, not recommended to be solely used for airport pavement with its requirement of high resistance to frost. Upon scanning electron microscope (SEM), X-ray diffraction (XRD), fourier transform infrared radiation (FTIR) and thermo gravimetric analyzer (TGA) tests, the surfaced concrete specimens did not produce any new substances, and the effect of the surface treatment agents was mainly to improve the concrete performance by physical filling, or by filling the cavities with the hydrated calcium silicate gel produced in the chemical reaction. These results may direct the selection of surface treatment agents in airport engineering. Full article

The type of modelling of gully erosion for the projects of land management depend on the targets and degree of details of these projects, as well as on the availability of input data. The set of four models cover a broad range of possible applications. The most detailed information about predicted gullies, change of their depth, width, and volume throughout the gully lifetime is obtained with the gully erosion and thermoerosion dynamic model. The calculation requires the time series of surface runoff, catchment relief, and lithology and the complex of coefficients and parameters, some of which can be estimated only by model calibration on the measurements. The difficulty in obtaining some of these coefficients makes it necessary to use less complicated models. The stable gully model predicts final gully depths and widths and is useful for projects where only stable gully geometry is used. The modified area–slope approach is used in the two simplest models, where the position on the slopes of possible gullies is calculated without details of the gully geometry. One of these models calculates total erosion potential, taking into account all water runoff transforming a gully. The second calculates gully erosion risk, using the information about slope inclination, contributing area and maximum surface runoff. Full article

Observational data of coastal change over much of the Arctic are limited largely due to its immensity, remoteness, harsh environment, and restricted periods of sunlight and ice-free conditions. Barter Island, Alaska, is one of the few locations where an extensive, observational dataset exists, which enables a detailed assessment of the trends and patterns of coastal change over decadal to annual time scales. Coastal bluff and shoreline positions were delineated from maps, aerial photographs, and satellite imagery acquired between 1947 and 2020, and at a nearly annual rate since 2004. Rates and patterns of shoreline and bluff change varied widely over the observational period. Shorelines showed a consistent trend of southerly erosion and westerly extension of the western termini of Barter Island and Bernard Spit, which has accelerated since at least 2000. The 3.2 km long stretch of ocean-exposed coastal permafrost bluffs retreated on average 114 m and at a maximum of 163 m at an average long-term rate (70 year) of 1.6 ± 0.1 m/yr. The long-term retreat rate was punctuated by individual years with retreat rates up to four times higher (6.6 ± 1.9 m/yr; 2012–2013) and both long-term (multidecadal) and short-term (annual to semiannual) rates showed a steady increase in retreat rates through time, with consistently high rates since 2015. A best-fit polynomial trend indicated acceleration in retreat rates that was independent of the large spatial and temporal variations observed on an annual basis. Rates and patterns of bluff retreat were correlated to incident wave energy and air and water temperatures. Wave energy was found to be the dominant driver of bluff retreat, followed by sea surface temperatures and warming air temperatures that are considered proxies for evaluating thermo-erosion and denudation. Normalized anomalies of cumulative wave energy, duration of open water, and air and sea temperature showed at least three distinct phases since 1979: a negative phase prior to 1987, a mixed phase between 1987 and the early to late 2000s, followed by a positive phase extending to 2020. The duration of the open-water season has tripled since 1979, increasing from approximately 40 to 140 days. Acceleration in retreat rates at Barter Island may be related to increases in both thermodenudation, associated with increasing air temperature, and the number of niche-forming and block-collapsing episodes associated with higher air and water temperature, more frequent storms, and longer ice-free conditions in the Beaufort Sea. Full article