Search Results (5)

Double-shell ZnO/Al₂O₃ submicron hollow fibers were successfully fabricated through a combined electrospinning and atomic layer deposition (ALD) approach. Polyvinyl alcohol (PVA) fibers were first produced by electrospinning and subsequently coated with a conformal Al₂O₃ barrier layer via low-temperature ALD employing trimethylaluminum (TMA) and deionized (DI) H₂O to preserve the integrity of the temperature-sensitive polymer core. The inner polymer was then removed using two different techniques—thermal annealing and water dissolution—to compare their effects on the fiber morphology. Finally, a functional ZnO layer was deposited by thermal ALD with diethylzinc (DEZ) and DI H₂O. It was found that the polymer removal method critically determined the final structural and morphological characteristics of the fibers. Thermal annealing resulted in smooth, shrunken fibers, while water dissolution led to diameter expansion and the formation of a highly rough, bubble-like surface structure due to swelling-induced micro-cracking. The selection of the polymer removal method offers a precise and controllable route for tailoring the fiber morphology. The resulting high-aspect-ratio (HAR) structures, particularly the rough and expanded fibers, exhibit enhanced specific surface area, making them highly promising for applications in sensing, catalysis, and filtration. Full article

Hollow coaxial double-shell submicron fibers were fabricated by combining electrospinning and atomic layer deposition (ALD). Polyvinyl alcohol (PVA) fibers were electrospun to serve as templates for the subsequent atomic layer deposition (ALD) of ZnO doped with transition metals (TM: Ni, Co, and Fe). An inner shell of amorphous Al₂O₃ was first deposited at low-temperature ALD to protect the polymer template. The PVA core was then removed through high-temperature annealing in air. Finally, a top shell of TM-doped ZnO was deposited at an elevated temperature within the ALD window for ZnO. The morphology, microstructure, elemental composition, and crystallinity of these submicron hollow double-shell fibers were thoroughly investigated using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Full article

This scientific publication presents a novel modification of the liquid–liquid displacement porosimetry (LLDP) method, aiming for the non-destructive automated analysis of water purification membrane filtration devices in the microfiltration (MF) and ultrafiltration (UF) range. The technical adaptation of LLDP enables the direct in-line porosimetric analysis of commercial filtration devices, avoiding the filtration devices’ destruction. Six commercially available filtration devices with polyethersulfone (PES) and polysulfone (PS) membranes were studied using an improved device developed by the IFTS, which was based on a commercial LLDP instrument. The filtration devices were evaluated in three different configurations: flat disks, hollow fibers, and pleated membranes. The results obtained using the proposed method were compared with other characterization techniques, including submicronic efficiency retention, image analysis of scanning electron microscopy (SEM), and gas–liquid displacement porosimetry (GLDP). The comparison of the results demonstrated that the proposed method accurately determined the porosimetric characteristics of the filters. It proved to be a precise technique for the non-destructive in-line evaluation of filter performance, as well as for periodic quality control and the fouling degree assessment of commercial filtration devices. This modified LLDP approach offers significant potential for the advanced characterization and quality assessment of water purification membrane filtration devices, contributing to improved understanding and optimization of their performance. Full article

Aerogel fiber, with the characteristics of ultra-low density, ultra-high porosity, and high specific surface area, is the most potential candidate for manufacturing wearable thermal insulation material. However, aerogel fibers generally show weak mechanical properties and complex preparation processes. Herein, through firstly preparing a cellulose acetate/polyacrylic acid (CA/PAA) hollow fiber using coaxial wet-spinning followed by injecting the silk fibroin (SF) solution into the hollow fiber, the CA/PAA-wrapped SF aerogel fibers toward textile thermal insulation were successfully constructed after freeze-drying. The sheath (CA/PAA hollow fiber) possesses a multiscale porous structure, including micropores (11.37 ± 4.01 μm), sub-micron pores (217.47 ± 46.16 nm), as well as nanopores on the inner (44.00 ± 21.65 nm) and outer (36.43 ± 17.55 nm) surfaces, which is crucial to the formation of a SF aerogel core. Furthermore, the porous CA/PAA-wrapped SF aerogel fibers have many advantages, such as low density (0.21 g/cm³), high porosity (86%), high strength at break (2.6 ± 0.4 MPa), as well as potential continuous and large-scale production. The delicate structure of multiscale porous sheath and ultra-low-density SF aerogel core synergistically inhibit air circulation and limit convective heat transfer. Meanwhile, the high porosity of aerogel fibers weakens heat transfer and the SF aerogel cellular walls prevent infrared radiation. The results show that the mat composed of these aerogel fibers exhibits excellent thermal insulating properties with a wide working temperature from −20 to 100 °C. Therefore, this SF-based aerogel fiber can be considered as a practical option for high performance thermal insulation. Full article

In this work, SiO2/ZnO composite hollow sub-micron fibers were fabricated by a facile single capillary electrospinning technique followed by calcination, using tetraethyl orthosilicate (TEOS), polyvinylpyrrolidone (PVP) and ZnO nanoparticles as raw materials. The characterization results of the scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) spectra indicated that the asprepared composite hollow fibers consisted of amorphous SiO2 and hexagonal wurtzite ZnO. The products revealed uniform tubular structure with outer diameters of 400–500 nm and wall thickness of 50–60 nm. The gases generated and the directional escaped mechanism was proposed to illustrate the formation of SiO2/ZnO composite hollow sub-micron fibers. Furthermore, a broad blue emission band was observed in the photoluminescence (PL) of SiO2/ZnO composite hollow sub-micron fibers, exhibiting great potential applications as blue light-emitting candidate materials. Full article