Search Results (7)

Stylolites are ubiquitous diagenetic products in carbonate rocks. They play a significant role in enhancing or reducing fluid flow in subsurface reservoirs. This study unravels the relationship between stylolite networks, carbonate microfacies, and the elemental geochemistry of Upper Cretaceous limestones of the Kometan Formation (shallow to moderately deep marine) in Northern Iraq. Stylolites exhibit diverse morphologies across mud- and grain-supported limestone facies. Statistical analyses of stylolite spacing, wavelength, amplitude, and their intersections and connectivity indicate that grain size, sorting, and mineral composition are key parameters that determine the geometrical properties of the stylolites and stylolite networks. Stylolites typically exhibit weak connectivity and considerable vertical spacing when hosted in packstone facies with moderate grain sorting. Conversely, mud-supported limestones, marked by poor sorting and high textural heterogeneity, host well-developed stylolite networks characterized by high amplitude and frequent intersections, indicating significant dissolution and deformation processes. Stylolites in mud-supported facies are closely spaced and present heightened amplitudes and intensified junctions, with suture and sharp-peak type. This study unveils that stylolites can potentially enhance porosity in the studied formation. Full article

Oxygen adsorption at metal oxide (MOX) surfaces and the formation of sub-surface depletion zones in thin nanometric sheets of MOX materials are theoretically investigated. It is shown that—under conditions of sufficient oxygen mobility—the bulk thermal generation of oxygen vacancy donors and the adsorption of surface oxygen ions cooperate in a self-organizing manner to form narrow sub-surface depletion zones which optimally fit into the limited spaces of MOX layers with nanometric cross sections. With this self-organization process in place, both the oxygen adsorption at free surfaces and the bulk generation of oxygen vacancy donors continuously increases as the MOX sheet thickness L is reduced, maintaining at the same time overall electro-neutrality and a state of perfect volume depletion of free carriers in bulk. This process comes to an end when MOX sheet thicknesses of L ≈ 1 nm are approached and when 3d-volumes of about 1 nm³ contain only one single double-donor and two surface oxygen ions on average. It is argued that at this limit of miniaturization, different interpretations of MOX gas sensing phenomena might be required than on larger length scales. Full article

The hydrodynamics of a river confluence generate significant vertical, lateral, and stream-wise gradients in the context of velocity, thereby forming a highly complex three-dimensional flow structure, including the development of large-scale turbulence structures. The above features affect the ecologically important underlying hyporheic zone, where surface and subsurface waters interact, and hence affect biological activity and result in highly varied habitats for organisms as well as the whole river environment. The influence of challenging conditions for in situ monitoring of hyporheic exchange—such as non-sinusoidal temperature signals, uncertainty in thermal parameters, and unsteady flows—have led to the development of hyporheic exchange detection methods that are based on the phase and amplitude changes in transient thermal signals. The use of heat as a tracer can require complex steps, including the isolation of the diurnal component of the temperature signal from other signals as well as stochastic variation. The focus of this study was to investigate a field campaign carried out between the Ninemile Creek and its tributary confluence, located in Marcellus, NY. Temperature data of the shallowest saturated sediment layers were measured from April to May 2019. Flux estimations were calculated using VFLUX 2, a MatLab based code, which performed data filtering and DHR (Dynamic Harmonic Regression). The patterns and rates of vertical flux exchange were then analyzed, and sampling of the temporal thermal profiles was performed. Furthermore, multiple analytical solutions of the one-dimensional heat transport model were analyzed and discussed in order to obtain the confluence hydrodynamic effect as well as the variations in the vertical flux estimation. This was achieved by utilizing different sensor pairs and porous medium characteristics, such as thermal diffusivity and conductivity. The predicted flow field shows that confluence topography—which includes the turbulent kinetic energy downstream of the junction, shear layer formations, bed stratigraphy and water table gradients—affects the magnitude and patterns of hyporheic exchange. The results of this study could help to advance the calibration of one-dimensional heat transport models in order to better understand the key hydrological, hydraulic, and ecological issues associated with river confluence. Full article

Determination of hydrological properties of the aquifer is of fundamental importance in hydrogeological and geotechnical studies. An attempt has been made to refine the hydraulic conductivity values computed from the pumping test by utilizing the hydraulic values computed in the laboratory. This study uses hydraulic conductivity computed in the laboratory of rock samples, pumping test data in conjunction with the empirical equations, and vertical electric sounding (VES) to determine the hydraulic properties of Lower Bari Doab (LBD) in the Indus Basin of Pakistan. The utilized dataset comprises pumping test results (K_pump) from 17 water wells, hydraulic conductivity values (K_lab) of different grain size subsurface lithologies, and 50 VES stations. To this end, the investigated area is divided into 17 polygons by using the Thiessen technique, and equal distribution/weight of conductivities values is assigned to 17 polygons (one polygon around each water well where pumping test is conducted). The true resistivity ranging from 20–90 ohm-m along with an average thickness of the aquifer is computed using the VES data for each polygon. A novel approach has been developed to estimate the hydraulic conductivity of the aquifer by combining laboratory data and pumping test which is used to compute the other hydraulic properties. The calculated hydraulic conductivity, transmissivity, and tortuosity values of the aquifer range from 4.4 to 85.6 m/day, 674 to 8986 m²/day, and 13 to 20, respectively. The porosity ranges from 32 to 45% and the formation factor values fall in the range 4 to 12. Higher hydraulic conductivities were encountered in the southern portion of the area near the junction of the rivers, and it increases with an increase in porosity. The aquifer having T > 5700 m²/day and K > 40 m/day, yields a large quantity of water whereas the portion of an aquifer with T < 1100 m²/day and K < 13 m/day are combatively low yield aquifer. The results of the resistivity method show that the subsurface geological material, as depicted from true resistivity, is composed of layers of sand, clay, and silt mixed with gravel/sand. This study improves the understanding of the aquifer and will help in the development and management of groundwater resources in the area including the prediction of future behavior of the aquifer. Full article

Junction networks made of longitudinally connected metal oxide nanowires (MOx NWs) have been widely utilized in resistive-type gas sensors because the potential barrier at the NW junctions leads to improved gas sensing performances. However, conventional MOx–NW-based gas sensors exhibit limited gas access to the sensing sites and reduced utilization of the entire NW surfaces because the NW networks are grown on the substrate. This study presents a novel gas sensor platform facilitating the formation of ZnO NW junction networks in a suspended architecture by growing ZnO NWs radially on a suspended carbon mesh backbone consisting of sub-micrometer-sized wires. NW networks were densely formed in the lateral and longitudinal directions of the ZnO NWs, forming additional longitudinally connected junctions in the voids of the carbon mesh. Therefore, target gases could efficiently access the sensing sites, including the junctions and the entire surface of the ZnO NWs. Thus, the present sensor, based on a suspended network of longitudinally connected NW junctions, exhibited enhanced gas response, sensitivity, and lower limit of detection compared to sensors consisting of only laterally connected NWs. In addition, complete sensor structures consisting of a suspended carbon mesh backbone and ZnO NWs could be prepared using only batch fabrication processes such as carbon microelectromechanical systems and hydrothermal synthesis, allowing cost-effective sensor fabrication. Full article

The quartz-K-feldspar-cemented breccia of Berglia-Glassberget in the Lierne municipality in central Norway forms an ellipsoid structure 250 m × 500 m in size. The hydrothermal breccia is barren in terms of economic commodities but famous among mineral collectors for being a large and rich site of crystal quartz of various colours and habits. Despite being a famous collector site, the mineralization is rather unique in respect to its geological setting. It occurs within Late Palaeoproterozoic metarhyolites of the Lower Allochthon of the Norwegian Caledonides regionally isolated from any other contemporaneous hydrothermal or magmatic event. In order to understand better the formation of the Berglia-Glassberget breccia, the chemistry, fluid inclusion petrography and age of the breccia cement were determined. Structural features indicate that the Berglia-Glassberget is a fault-related, fluid-assisted, hydraulic breccia which formed by single pulse stress released by a seismic event. ⁴⁰Ar-³⁹Ar dating of K-feldspar cement revealed a middle Triassic age (240.3 ± 0.4 Ma) for this event. The influx into the fault zone of an aqueous CO₂-bearing fluid triggered the sudden fault movement. The high percentage of open space in the breccia fractures with cavities up 3 m × 3 m × 4 m in size, fluid inclusion microthermometry, and trace element chemistry of quartz suggests that the breccia was formed at depths between 4 and 0.5 km (1.1 to 0.1 kbar). The origin of the breccia-cementing, CO₂-bearing Na-HCO₃-SO₄ fluid may have been predominantly of metamorphic origin due to decarbonation reactions (T > 200 °C) of limestones of the underlying Olden Nappe. The decarbonation reactions were initiated by deeply derived, hot fluids channelled to sub-surface levels by a major fault zone, implying that the breccia is situated on a deep-seated structure. Regionally, the Berglia-Glassberget occurs at a supposed triple junction of long-lived fault zones belonging to the Møre-Trøndelag, Lærdal-Gjende and the Kollstraumen fault complexes. These fault systems and the associated Berglia-Glassberget earthquake are the expression of rifting and faulting in northern Europe during the middle/late Triassic. Full article

In this work, a novel method is put forward to quantitatively simulate the subsurface damages microstructural alteration of titanium alloy components subjected to microscale cutting. A trans-scale numerical framework is conducted with the purpose of revealing the underlying influence mechanism of tool structure parameters on subsurface dislocation configurations using a dislocation dynamics-based model, which considers both dislocation structural transformation and grain refining. Results showed that the developed framework not only captured the essential features of workpiece microstructure, but also predicted the subsurface damages layer states and their modifications. A series of defects were found in the material subsurface during the orthogonal cutting of titanium alloy, such as edge and screw dislocations, junctions, parallel slip lines, intersection dislocation bands, vacancy defects, and refinement grains. Particularly, in the process of micro-cutting, the depth of subsurface damages layer increased significantly with cutting length at the beginning, and then remained unchanged in the stable removal phase. Moreover, smaller edge radius and larger rake angle can greatly weaken the squeezing action and heat diffusion effect between the tool tip and workpiece, which further prevents the formation of subsurface defects and enhances finished surface quality. In addition, although increasing tool clearance angle could drastically lighten the thickness of subsurface damages layer, it is noteworthy that its performance would be decreased significantly when the clearance angle was greater than or equal to 5°. The micro-end-milling experiment was performed to validate the existing simulation results, and the results show very good agreement. Full article