Search Results (8)

This comprehensive review highlights the growing significance of graphitic carbon nitride (g-C₃N₄) as a multifunctional material with applications spanning diverse scientific and technological domains. Based on an extensive literature from electronic databases such as Web of Science, PubMed and Google Scholar, we provide an in-depth discussion of the fundamental structural configurations of g-C₃N₄, namely the triazine- and heptazine-based frameworks, which form the basis of its unique physicochemical and electronic properties. The two predominant synthesis strategies—thermal polymerization and solvothermal/hydrothermal routes—are examined in detail and illustrated through representative schematic models to elucidate their underlying mechanisms and resulting structural variations. Advanced surface characterization techniques, such as atomic force microscopy (AFM) and scanning tunneling microscopy (STM), are also discussed in the context of their application to materials, including Highly Oriented Pyrolytic Graphite (HOPG), graphene oxide, and carbon nitride. These analyses provide insights into nanoscale surface topography and structural attributes, with HOPG serving as a well-established reference material for comparison. The review also addresses the biological activities and potential applications of g-C₃N₄, particularly in the context of its photocatalytic, antimicrobial, and biocompatible properties. Despite substantial progress in other research fields, a notable gap remains in the exploration of g-C₃N₄ for oral and dental applications. This limitation is largely attributed to the scarcity of systematic studies and limited published data in this emerging area. Accordingly, this review identifies promising opportunities for future research aimed at harnessing the distinctive properties of g-C₃N₄ for innovative developments in oral healthcare and dental material science. Full article

The concept of synthetic aperture radar (SAR) has the advantage of being able to obtain high-quality images even when the target area is at night or covered with obstacles such as clouds or fog. These imaging capabilities have led to a rapid increase in demand for space SAR imagery across a variety of sectors, including government, military, and commercial sectors. The SAR-based deployable reflector antenna was developed in this series of paper. The satellite performance is influenced by the aperture size of an antenna. To improve the image acquisition performance, the SAR antenna has the configuration of several foldable CFRP reflectors. In this paper, the experimental investigation of the Structural-thermal model deployable reflector antenna is performed. During the launch condition, the satellite and payload are subjected to the dynamic load. In the STM phase, the acoustic test was conducted to evaluate the structural stability of the deployable reflector antenna within the acoustic environment. The sinusoidal vibration test was implemented to investigate the fundamental frequency for inplane/normal directions and evaluate the structural stability of reflector antenna. By using experimental data obtained from the thermal-balance test, the well-correlated thermal analysis model was established to execute the orbital thermal analysis. The experimental results of the environmental test in STM phase show that the deployable reflector antenna has structural stability for the structural/thermal environments. The configuration of the deployable reflector antenna determined in STM phase can be applied to the qualification model. Full article

The X-ray satellite “Einstein Probe” of the Chinese Academy of Sciences (CAS) was successfully launched on 9 January 2024 at 15:03 Beijing Time from the Xichang Satellite Launch Center in China with a “Long March-2C” rocket. The Einstein Probe is equipped with two scientific X-ray telescopes. One is the Wide-field X-ray Telescope (WXT), which uses lobster-eye optics. The other is the Follow-up X-ray Telescope (FXT), a Wolter-I type telescope. These telescopes are designed to study the universe for high-energy X-rays associated with transient high-energy phenomena. The FXT consists of two modules based on 54 thin X-ray Wolter-I grazing incidence Ni-replicated mirrors produced by the Italian Media Lario company, as contributions from the European Space Agency and the Max Planck Institute for Extraterrestrial Physics (MPE), which also provided the focal-plane detectors. Meanwhile, the Institute of High Energy Physics (IHEP), together with the Harbin Institute of Technology and Xi’an Institute of Optics and Precision Mechanics, has also completed the development and production of the structural and thermal model (STM), qualification model (QM) and flight model (FM) of FXT mirrors for the Einstein Probe (EP) satellites for demonstration purposes. This paper introduces the precision manufacturing adopted in China of Wolter-I X-ray mirror mandrels similar to those used for the EP-FXT payload. Moreover, the adopted electroformed nickel replication process, based on a chemical nickel–phosphorus alloy, is reported. The final results show that the surface of the produced mandrels after demolding and the internal surface of the mirrors have been super polished to the roughness level better than 0.3 nm RMS and the surface accuracy is better than 0.2 μm, and the mirror angular resolution for single mirror shells may be as good as 17.3 arcsec HPD (Half Power Diameter), 198 arcsec W90 (90% Energy Width) @1.49 keV (Al-K line). These results demonstrate the reliability and advancement of the process. As the first efficient X-ray-focusing optics manufacturing chain established in China, we successfully developed the first focusing mirror prototype that could be used for future X-ray satellite payloads. Full article

Nanoscale tuning of the surface properties of graphene-like materials is essential to optimize their application in electronic devices and protective technologies. The covalent modification method has recently been established as the most effective approach for tailoring the interface structure and properties, which are key aspects for fine-tuning the processability and performance of graphene-like materials. In this work, we demonstrate systematic exploration of the reversible covalent functionalization of a highly oriented pyrolytic graphite (HOPG) surface, a model system of multi-layered graphene, at the molecular scale. This is achieved using 3,5-trifluoromethyl benzenediazonum (3,5-TFD) and experimental investigations via cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), scanning tunneling microscopy (STM), and Raman spectroscopy. The degree of functionalization could be tuned by varying the concentration of 3,5-TFD dissolved in the grafting electrolyte. The covalently functionalized layer of 3,5-TFD was either locally degrafted by the STM tip or globally detracted upon thermal treatment, leaving the defect-free graphitic surfaces behind. Our findings open a new pathway for reversibly and robustly functionalizing graphene and other 2D materials for multiple uses in high-end applications. Full article

In a launch environment, all satellites are subjected to severe random vibration and acoustic loads owing to rocket separation, airflow, and injection/combustion of the fuel. Structural vibrations induced by mechanical loads cause the malfunction of vibration-sensitive components in a satellite, leading to failures during the launch process or an on-orbit mission. Therefore, in this study, a shape memory alloy-based vibration isolator was used on the connection between the launch vehicle and satellite to reduce the vibration transmission to a satellite. The vibration isolator exhibited a high performance in the vibration isolation, owing to the dynamic properties of super-elasticity and high damping. The vibration-reduction performance of the vibration isolator was experimentally verified using random vibration and acoustic tests in a structural thermal model of the satellite developed in the synthetic aperture radar technology experimental project. Owing to the super-elasticity and high attenuation characteristics of the vibration isolator, it was possible to significantly reduce the random vibration of the satellite in the launch environment. Although the mechanical load of the acoustic test mainly excited the antenna on the upper side of the satellite rather than the bottom side, the results of the acoustic test showed the same trend as the random vibration test. From this perspective, the vibration isolator can contribute to saving the costs required for satellite development. These advantages have made it possible to develop satellites according to the new space paradigm, which is a trend in the space industry worldwide. Full article

Metal atoms were deposited on an Si (111)-7 × 7 surface, and they were adsorbed with alcohol gases (CH₃OH/C₂H₅OH/C₃H₇OH). Initially, C_nH_2n+1OH adsorption was simply used as an intermediate layer to prevent the chemical reaction between metal and Si atoms. Through scanning tunneling microscopy (STM) and a mass spectrometer, the C_nH_2n+1OH dissociation process is further derived as the construction of a surface quasi-potential with horizontal and vertical directions. With the help of three typical metal depositions, the surface characteristics of CH₃OH adsorption are more clearly presented in this paper. Adjusting the preheating temperature, the difference of thermal stability between CH₃O^– and H⁺ could be obviously derived in Au deposition. After a large amount of H⁺ was separated, the isolation characteristic of CH₃O^– was discussed in the case of Fe deposition. In the process of building a new metal-CH₃O^–-H⁺ model, the dual characteristics of CH₃OH were synthetically verified in Sn deposition. CH₃O^– adsorption is prone to influencing the interaction between the metal deposition and substrate surface in the vertical direction, while H⁺ adsorption determines the horizontal behavior of metal atoms. These investigations lead one to believe that, to a certain extent, the formation of regular metal atomic structures on the Si (111)-7 × 7-CH₃OH surface is promoted, especially according to the dual characteristics and adsorption models we explored. Full article

STM results showed that Fe atoms were deposited on a Si(111)-7 × 7 reconstructed surface, which was saturated with CH₃OH molecules. Fe atomic linear structure was composed of stable clusters and in-situ observed by the scanning tunneling microscopy (STM). The aim to improve its application of magnetic memory material, both formation process and models, has been explored in this paper. By combining surface images and mass spectrometer data, an intermediate layer model was established. In terms of thermal stability, the most favorable adsorption sites of CH₃OH were further explored. After that, Fe atoms were deposited on the Si(111)-7 × 7-CH₃OH surface, forming a linear cluster structure. On the one hand, a new Fe cluster model was put forward in this paper, which was established with height measurement and 3D surface display technology. This model is also affected by the evaporation temperature, which can be consistent with the atomic stacking pattern of face centered cubic structures. On the other hand, the slight height change suggested the stability of linear structures. Even in the condition of thin air introduction, Fe cluster showed a good performance, which suggested the possibility of magnetic memory application in the future. These investigations are believed to have, to a certain extent, increased the probability of forming Fe linear clusters on the surface of silicon substrate, especially according to the models and surface technology we adjusted. Full article

We have investigated the adsorption of H₂O onto the A and B type steps on an Ag single crystal by temperature programmed desorption. For this study, we have used a curved crystal exposing a continuous range of surface structures ranging from [5(111) × (100)] via (111) to [5(111) × (110)]. LEED and STM studies verify that the curvature of our sample results predominantly from monoatomic steps. The sample thus provides a continuous array of step densities for both step types. Desorption probed by spatially-resolved TPD of multilayers of H₂O shows no dependence on the exact substrate structure and thus confirms the absence of thermal gradients during temperature ramps. In the submonolayer regime, we observe a small and linear dependence of the desorption temperature on the A and B step density. We argue that such small differences are only observable by means of a single curved crystal, which thus establishes new experimental benchmarks for theoretical calculation of chemically accurate binding energies. We propose an origin of the observed behavior based on a “two state” desorption model. Full article