Search Results (47)

Phosphogypsum (PG) is the main by-product of wet-process phosphoric acid production. Its annual global production reaches about 200 million tons, yet its utilization rate remains low. Consequently, long-term stockpiling of large PG volumes poses immense pressure to the ecological environment. To mitigate negative environmental impacts, the utilization of PG is imperative. Despite progress in PG utilization and 3D-printing technology, there is still a significant lack of understanding about the synergistic activation mechanisms in multi-solid-waste systems. In particular, the composition design, microstructure evolution, and structure–property relationships of 3D-printed PG-based composites are not well-studied, which limits their high-value engineering applications. Three-dimensional-printed phosphogypsum concrete (3DPPGC) is proposed here, promoting PG resource utilization by leveraging the expanding applications of 3D-printed concrete (3DPC). However, the strength of 3DPPGC needs to be enhanced to meet engineering requirements. This study designed the mix proportion of 3DPPGC and fabricated the corresponding test specimens. The optimal Cement Replacement Ratio (CRR) was determined through experimental testing, and the mechanism behind the strength enhancement of the 3DPPGC was elucidated. The results indicated that the 3DPPGC’s mechanical properties peaked at the 70% CRR. Compared with cast specimens, 3DPPGC exhibited a 1.52% increase in 28-day flexural strength in the y-direction, reaching 4.69 MPa. The early-age compressive strength, flexural strength, and later-age compressive strength of 3DPPGC were significantly enhanced when PG, blast-furnace slag (BS), fly ash (FA), and silica fume (SF) were used to partially replace cement. This study provides a theoretical and experimental basis for the large-scale, high-value application of PG in intelligent construction. Full article

Addressing the environmental challenges posed by phosphogypsum (PG) stockpiling, this study investigates the synergistic mechanisms of a dual-functional application strategy where PG serves as both cementitious binder and aggregate. Unlike previous research limited to single-mode utilization, this study focuses on the interfacial compatibility between PG-based binders and PG aggregates (PGA). Through a comparative experimental program, the mechanical performance and microstructure of different binder–aggregate combinations were evaluated. The proposed dual-functional formulation achieved a high PG incorporation rate of 38% by mass. While the compressive strength of 39.3 MPa was lower than that of the reference ordinary concrete, it comfortably surpasses the C30 strength requirement for structural applications, validating its engineering feasibility. Comparative analysis revealed that although natural stone aggregates possess higher intrinsic strength, the PG-binder/PGA system exhibits superior interfacial bonding compared to the PG-binder/stone system. Microstructural observations indicated that this synergistic interaction facilitates the formation of interwoven ettringite and C-S-H gel networks, contributing to a structurally integrated interfacial transition zone (ITZ). These findings suggest that the dual-functional strategy offers a viable pathway for developing low-carbon building materials by balancing high-volume waste utilization with mechanical compliance. Full article

The article discusses the issue of improving the management efficiency of spare parts at railway stations to reduce operational costs and enhance the effectiveness of rolling stock maintenance. A comparative analysis was conducted between traditional inventory storage strategies and models involving the redistribution of surplus spare parts between stations. For the quantitative assessment of the proposed approach, a mathematical model based on a multi-criteria decision analysis (MCDA) methodology was developed that includes the calculation of storage, transportation, and redistribution costs. The results show that redistributing spare parts reduces storage costs by 25%, while implementing the proposed strategy shortens the average downtime of railway wagons by 12.5%, confirming its economic feasibility. Moderate savings were achieved at the Zharyk and Zhanaaul stations, where excessive stockpiling of spare parts was reduced, and the main logistics hub—Karaganda Sortirovochnaya—helped minimize the risk of downtime. At the same time, the analysis revealed certain limitations, such as increased transportation costs and reduced network stability when redistribution volumes are high. The practical implications of the study lie in the potential implementation of the developed inventory management improvement model, not only for railway transport but also for other industries such as aviation and automotive logistics. Spare parts redistribution reduces the financial losses associated with frozen capital, increases the capital turnover, and decreases the risk of depreciation of stored components. The proposed approach ensures a more balanced distribution of resources between stations, facilitating an increase in the profitability of railway enterprises. Full article

With the weathering of iron sulfide minerals, acid rock drainage (ARD) emanates from the 60-millon tonne Main Waste Stockpile (MWS) at the Red Dog Mine. Following completion of the stockpile, a collection trench was constructed in 2012–2013 to capture and treat a portion of the ARD, and a cover system was emplaced from 2021 to 2025 to cover 90% of the stockpile. Select wells in the collection trench are associated with the different cover phases. Analysis of the water chemistry of samples collected at the wells indicates increased pH and decreased dissolved solids with each phase of the cover along with significant changes in flow and solutes such as aluminum, iron, sulfate, and zinc. Although the cover should continue to decrease ARD volume, acidity, and solute concentrations, an evaluation of historical acid production and iron sulfide consumption in the stockpile indicates a likely majority of the iron sulfide content remains available for weathering and acid production. Continued MWS ARD monitoring is necessary to evaluate the multi-year effect of the cover because of the variability of the pre-cover ARD, identification of seasonal and multi-year precipitation influences on ARD generation, and a yet to be determined influence of the cover on the volume of infiltrating precipitation. Full article

Accurate stockpile volume estimation is essential for industries that manage bulk materials across various stages of production. Conventional ground-based methods such as walking wheels, total stations, Global Navigation Satellite Systems (GNSSs), and Terrestrial Laser Scanners (TLSs) have been widely used, but often involve significant safety risks, particularly when accessing hard-to-reach or hazardous areas. Unmanned Aerial Systems (UASs) provide a safer and more efficient alternative for surveying irregularly shaped stockpiles. This study evaluates UAS-based methods for estimating the volume of coal stockpiles at a storage facility near Cadiz, Ohio. Two sensor platforms were deployed: a Freefly Alta X quadcopter equipped with a Real-Time Kinematic (RTK) Light Detection and Ranging (LiDAR, active sensor) and a WingtraOne UAS with Post-Processed Kinematic (PPK) multispectral imaging (optical, passive sensor). Three approaches were compared: (1) LiDAR; (2) Structure-from-Motion (SfM) photogrammetry with a Digital Surface Model (DSM) and Digital Terrain Model (DTM) (SfM–DTM); and (3) an SfM-derived DSM combined with a kriging-interpolated DTM (SfM–intDTM). An automated boundary detection workflow was developed, integrating slope thresholding, Near-Infrared (NIR) spectral filtering, and Canny edge detection. Volume estimates from SfM–DTM and SfM–intDTM closely matched LiDAR-based reference estimates, with Root Mean Square Error (RMSE) values of 147.51 m³ and 146.18 m³, respectively. The SfM–intDTM approach achieved a Mean Absolute Percentage Error (MAPE) of ~2%, indicating strong agreement with LiDAR and improved accuracy compared to prior studies. A sensitivity analysis further highlighted the role of spatial resolution in volume estimation. While RMSE values remained consistent (141–162 m³) and the MAPE below 2.5% for resolutions between 0.06 m and 5 m, accuracy declined at coarser resolutions, with the MAPE rising to 11.76% at 10 m. This emphasizes the need to balance the resolution with the study objectives, geographic extent, and computational costs when selecting elevation data for volume estimation. Overall, UAS-based SfM photogrammetry combined with interpolated DTMs and automated boundary extraction offers a scalable, cost-effective, and accurate approach for stockpile volume estimation. The methodology is well-suited for both the high-precision monitoring of individual stockpiles and broader regional-scale assessments and can be readily adapted to other domains such as quarrying, agricultural storage, and forestry operations. Full article

The cold recycling (CR) technique is gaining traction, with an increasing demand for sustainable pavement construction practices. Cold in-place recycling (CIR) and cold central plant recycling (CCPR) are two strategies under the umbrella of cold recycling. These techniques use reclaimed asphalt pavement (RAP) to rehabilitate pavement, and CCPR offers the added advantage of utilizing stockpiled RAP. While many agencies have expertise in cold recycling techniques including CCPR, the lack of pavement performance data prevented the largescale implementation of these technologies. Recent studies in high-traffic volume applications demonstrate that CCPR technology can be implemented on the entire road network across all traffic levels. This reignited interest in the widespread implementation of CCPR. Therefore, the purpose of this study is to provide agencies with the most up-to-date information on CCPR to help them make informed decisions. To this end, this paper comprehensively reviews the mix-design for CCPR, the structural design of pavements containing CCPR layers, best construction practices, and the agency experience in using this technology on high-traffic volume roads to provide in-depth information on the steps to follow from project selection to field implementation. The findings specify the suitable laboratory curing conditions to achieve the optimum mix design and specimen preparation procedures to accurately capture the material properties. Additionally, this review synthesizes existing quantitative data from previous studies, providing context for the comparison of findings, where applicable. The empirical and mechanistic–empirical design inputs, along with the limitations of AASHTOWare Pavement ME software for analyzing this non-conventional material, are also presented. Full article

Phosphogypsum, a byproduct of phosphate fertilizer production, poses significant environmental challenges due to its large volume, hazardous composition, and radioactivity. Conventional disposal methods, such as stockpiling and landfilling, contribute to soil and water contamination and present risks to human health. This article explores the potential of integrating phosphogypsum into a circular economy framework, focusing on reducing environmental impacts and extracting value from this industrial waste. A detailed assessment of phosphogypsum’s chemical composition, including trace metals and radionuclides, is essential for effective management. This review paper examines safe handling, storage, and disposal strategies to minimize environmental risks. Additionally, innovative reuse applications are investigated, such as incorporating phosphogypsum into construction materials like cement, plasterboard, and concrete and its use in agriculture as a soil amendment or for land reclamation. The recovery of critical elements, particularly rare earth elements (REEs), highlights its potential to reduce waste and contribute to meeting the growing demand for strategic resources. Despite its promise, challenges remain, including chemical variability and the presence of radioactive components. This article identifies the technological and regulatory steps required to enable safe, large-scale reuse of phosphogypsum, emphasizing its role in advancing sustainable resource management within a circular economy. Full article

This study examines the application of low-cost 1D LiDAR sensors in drone-based stockpile volume estimation, with a focus on indoor environments. Three approaches were experimentally investigated: (i) a multi-drone system equipped with static, downward-facing 1D LiDAR sensors combined with an adaptive formation control algorithm; (ii) a single drone with a static, downward-facing 1D LiDAR following a zigzag trajectory; and (iii) a single drone with an actuated 1D LiDAR in an oscillatory fashion to enhance scanning coverage while following a shorter trajectory. The adaptive formation control algorithm, newly developed in this study, synchronises the drones’ waypoint arrivals and facilitates smooth transitions between dynamic formation shapes. Real-world experiments conducted in a motion-tracking indoor facility confirmed the effectiveness of all three approaches in accurately completing scanning tasks, as per intended waypoints allocation. A trapezoidal prism stockpile was scanned, and the volume estimation accuracy of each approach was compared. The multi-drone system achieved an average volumetric error of 1.3%, similar to the single drone with a static sensor, but with less than half the flight time. Meanwhile, the actuated LiDAR system required shorter paths but experienced a higher volumetric error of 4.4%, primarily due to surface reconstruction outliers and common LiDAR bias when scanning at non-vertical angles. Full article

Background/Objectives: The dietary changes experienced by residents in long-term care facilities (LTCFs) following an earthquake are poorly understood. This study aimed to examine variations in nutritional status among residents of an Integrated Facility for Medical and Long-term Care (IFMLC), a particular type of Japanese LTCF, after the 2024 Noto Peninsula Earthquake. Methods: This descriptive study was conducted at the single IFMLC. A total of 115 residents living at the facility on 1 January 2024, at the time of the earthquake, were recruited for the study. The focus was the body weight and skeletal muscle mass changes observed before and after the earthquake. The observation period lasted for three months following the earthquake. Results: Water outage persisted for over a month, making dishwashing impossible and leading to an extended reliance on disposable dishes with limited capacity. This situation consequently reduced the variety and volume of meal options and overall energy intake meals. Residents’ body weight significantly decreased 3 months after the earthquake, and the prevalence of weight loss and skeletal muscle mass loss was particularly high in residents with normal swallowing function. To address nutritional deficiencies post-earthquake, the registered dietitian enhanced energy sufficiency through food fortification, oral nutritional supplements, and pre-prepared ready-to-hang liquid formulas. Conclusions: To prevent further weight and skeletal muscle mass reduction among IFMLC residents, providing ample water, and a disaster manual that can be used even with limited resources is essential. Furthermore, preparing for disasters by stockpiling foods and implementing strategies to enhance energy sufficiency is crucial. Full article

Due to changes in the German government’s energy concept, the amount of gypsum produced in flue gas desulfurisation plants (FGD gypsum) will fall from 5 million tons per year to 1 million tons or less by 2038 at the latest. As of 2016, FGD gypsum accounts for 55% of German gypsum mix. The resulting raw material gap must be closed through innovative recycling concepts, such as the processing of existing mine dumps. The process development aims to achieve a calcium sulfate dihydrate content of 85% and a reduction in the stockpile volume by 50%. The main components of the stockpiles are calcium sulfate in the form of gypsum stone as well as clay minerals and organic matter. Successful laboratory tests were transferred to a pilot scale jigging machine with dewatering screening. The process water is circulated throughout the entire process. The gypsum content in the heavy fraction is 76% when measured with ICP OES and 87% when measured via thermogravimetric methods. Furthermore, pilot-scale dry screening on the stockpile took place, and up to 1500 tons of material could be processed. Due to fluctuating weather conditions, the screening quality was subject to significant variations. Under optimal conditions, up to 60% of the feed could be recovered as gypsum stone; however, the screening process was nearly impossible during rain; therefore, a process combination of screening and a downstream jigging machine is recommended. Full article

As a large-volume industrial solid waste generated during the production of wet-process phosphoric acid, the primary disposal method for phosphogypsum (PG) currently involves centralized stockpiling, which requires substantial land use. Additionally, PG contains impurities, such as phosphorus, fluorine, and alkali metals, that may pose potential pollution risks to the surrounding environment. However, the mechanisms governing the co-release of phosphorus and fluorine impurities alongside valuable metal cations during leaching remain unclear, posing challenges to efficient disposal and utilization. This study compares the leaching characteristics of cations and anions in PG of different particle sizes through static pH leaching experiments. Using Visual MINTEQ simulation combined with XRD, XPS, and FT-IR characterization methods, we analyzed the leaching mechanisms and key controlling factors for various metal elements and inorganic elements, like phosphorus and fluorine, under different pH conditions. The experimental results show that Ca, Al, Fe, Ti, Ba, Sr, Y, and PO₄³⁻ in PG are more easily released under acidic conditions, while Si, Zn, Co, and F are primarily influenced by the content of soluble components. The dynamic “dissolution–crystallization” reaction of CaSO₄·H₂O significantly impacts the leaching of fluorine, and the XRD, XPS, and FT-IR characterization results confirm the presence of this reaction during the leaching process. This research provides theoretical guidance for the environmental risk assessment of stockpiled PG and the recovery of phosphorus, fluorine, and valuable metal resources from PG. Full article

The process of purifying agricultural products, at various food processing plants, generates waste materials that consist of precipitated calcium carbonate, organic debris, and trace amounts of soil and agricultural contaminants. A specific food-processing waste, hereafter referred to as a food industry byproduct, FIBP, is typically stockpiled on land adjacent to the corresponding food processing facilities due to its large volume and chemical composition. The FIBP also contains commercially available unspent lime products, which makes its reuse viable in various applications. An example is construction applications where an organic content of up to 5% by weight is allowed, such as treating expansive clays. Traditionally, lime stabilization has been used for improving the properties of expansive clays, where ground improvement methods are necessary for a large area. However, the process of producing lime is resource- and energy-intensive as it includes crushing and heating limestone in kilns to extract lime. Therefore, one specific doubly sustainable application is the treatment of expansive clays using the FIBP instead of lime. The main application tested here is the treatment of expansive clayey soils underneath a stretch of State Highway 95 near Marsing, ID. Other potential applications are in road and embankment construction. To evaluate the potential of expansive clay stabilization utilizing the FIBP, a series of geotechnical and environmental laboratory testing were conducted to measure the engineering properties (e.g., swell potential, permeability, and strength properties) of expansive clay amended with FIBP. Preliminary testing on blends with an expansive clay suggests benefits such as decreased swelling potential, increased density, and leachate immobilization. Full article

As marine-dredged mud and waste steel slag in coastal port cities continue to soar, the traditional treatment method of land stockpiling has caused ecological problems. Thus, it is necessary to find a large-scale resource-comprehensive utilization method for dredged mud and waste steel slag. This study uses waste steel slag and composite solidifying agents (cement, lime, fly ash) to physically and chemically improve marine-dredged mud. The physical improvement effect of the particle size and dosage of waste steel slag was studied by the shear strength test under the effect of freeze–thaw cycle. Then, based on the Box–Behnken design of the response surface method, the interaction effects of the solidifying agent components on the unconfined compressive strength were studied. Then, the water stability under dry–wet cycles and a microscopic mechanism were analyzed by XRD and SEM tests. The results show that the waste steel slag with a dosage of 30% and a particle size of 1.18~2.36 mm has the best improvement. The interaction between cement and lime and lime and fly ash has a significant effect on the linear effect and surface effect of 7d unconfined compressive strength, and the strength increases first and then decreases with the increase in its dosage. For the 14d unconfined compressive strength, only the interaction between cement and lime is still significant. The unconfined compressive strength prediction model is established to optimize the mix ratio of the composite solidifying agent. In the water stability, the water stability coefficients of the 7d and 14d tests are 0.68 and 0.95, respectively, and the volume and mass loss rates are all below 1.5%, showing a good performance in dry–wet resistance and durability. Microscopic mechanism analysis shows that waste steel slag provides an ‘anchoring surface’ as a skeleton, which improves the pore structure of dredged mud, and the hydration products generated by the solidifying agent play a role in filling and cementation. The results of the study can provide an experimental and technical basis for the resource engineering of marine-dredged mud and waste steel slag, helping the construction of green low-carbon and resource-saving ports. Full article

Construction spoil (CS), a prevalent type of construction and demolition waste, is characterized by high production volumes and substantial stockpiles. It contaminates water, soil, and air, and it can also trigger natural disasters such as landslides and debris flows. With the advent of alkali activation technology, utilizing CS as a precursor for alkali-activated materials (AAMs) or supplementary cementitious materials (SCMs) presents a novel approach for managing this waste. Currently, the low reactivity of CS remains a significant constraint to its high-value-added resource utilization in the field of construction materials. Researchers have attempted various methods to enhance its reactivity, including grinding, calcination, and the addition of fluxing agents. However, there is no consensus on the optimal calcination temperature and alkali concentration, which significantly limits the large-scale application of CS. This study investigates the effects of the calcination temperature and alkali concentration on the mechanical properties of CS–cement mortar specimens and the ion dissolution performance of CS in alkali solutions. Mortar strength tests and ICP ion dissolution tests are conducted to quantitatively assess the reactivity of CS. The results indicate that, compared to uncalcined CS, the ion dissolution performance of calcined CS is significantly enhanced. The dissolution amounts of active aluminum, silicon, and calcium are increased by up to 420.06%, 195.81%, and 256.00%, respectively. The optimal calcination temperature for CS is determined to be 750 °C, and the most suitable alkali concentration is found to be 6 M. Furthermore, since the Al O bond is weaker and more easily broken than the Si O bond, the dissolution amount and release rate of active aluminum components in calcined CS are substantially higher than those of active silicon components. This finding indicates significant limitations in using CS solely as a precursor, emphasizing that an adequate supply of silicon and calcium sources is essential when preparing CS-dominated AAMs. Full article

Red mud (RM), a hazardous solid waste generated in the alumina production process, of which the mineral composition is mainly hematite, is unable to be applied directly in the cement industry due to its high alkalinity. With the rise of geopolymers, RM-based grouting materials play an essential role in disaster prevention and underground engineering. To adequately reduce the land-based stockpiling of solid wastes, ultrafine calcium oxide, red mud, and slag were utilized as the main raw materials to prepare geopolymers, the C-R-S (calcium oxide–red mud–slag) grouting cementitious materials. The direct impact of red mud addition on the setting time, fluidity, water secretion, mechanical properties, and rheological properties of C-R-S were also investigated. In addition, a scanning electron microscope (SEM), X-ray diffraction (XRD), three-dimensional CT (3D-CT), Fourier transform infrared spectroscopy (FT-IR), and other characterization techniques were used to analyze the microstructure and polymerization mechanism. The related results reveal that the increase in red mud addition leads to an enhanced setting time, and the C-R-S-40 grouting cementitious material (40% red mud addition) exhibits the best fluidity of 27.5 cm, the lowest water secretion rate of 5.7%, and a high mechanical strength of 57.7 MPa. The C-R-S polymer grout conforms to the Herschel–Bulkley model, and the fitted value of R² is above 0.99. All analyses confirm that the preparation process of C-R-S grouting cementitious material not only substantially improves the utilization rate of red mud, but also provides a theoretical basis for the high-volume application of red mud in the field of grouting. Full article