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Keywords = spruce fir wood

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22 pages, 2033 KiB  
Article
The Mechanical Properties of Laminated Veneer Products from Different Stands of Douglas Fir and Norway Spruce in Germany
by Tobias Krenn, Dirk Berthold, Nina Ritter and Carsten Mai
Forests 2025, 16(7), 1040; https://doi.org/10.3390/f16071040 - 21 Jun 2025
Viewed by 288
Abstract
The relationship between silvicultural strategies, manifested in the thinning method and rotation age on sites with different water supply, and the mechanical properties of engineered wood products plywood and laminated veneer lumber has been analyzed. Sample logs from five German sites of Norway [...] Read more.
The relationship between silvicultural strategies, manifested in the thinning method and rotation age on sites with different water supply, and the mechanical properties of engineered wood products plywood and laminated veneer lumber has been analyzed. Sample logs from five German sites of Norway spruce (Picea abies (L.) Karst.) and Douglas fir (Pseudotsuga menziesii (M.) Franco) have been rotary-peeled and processed into boards with a phenol–resorcinol–formaldehyde adhesive to evaluate their performance under flexural, tensile, and compressive loads. Satisfactory coefficients of determination were reached for Norway spruce in regard to the silvicultural framework and the tree characteristics of slenderness and crown base height. Douglas fir products did not achieve comparable determination due to high variance within boards and stands but did achieve significantly better mechanical properties. Norway spruce was observed to be more responsive to thinning measures, while the effect of different thinning regimes was not evident for Douglas fir. The on-site evaluation of Douglas fir stands for veneer product quality based on silvicultural parameters and tree characteristics was shown to be inconclusive, with its naturally higher wood density being the decisive constant. Full article
(This article belongs to the Special Issue Wood Properties: Strength, Density, Hardness)
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18 pages, 5748 KiB  
Article
Influence of Salt Concentration and Treatment Cycles on Nail-Holding Power in Dimension Lumber
by Jia Lei, Jingkang Lin, Zhiyuan Chen, Shuke Jia, Youying Zi and Zeli Que
Forests 2024, 15(8), 1387; https://doi.org/10.3390/f15081387 - 8 Aug 2024
Viewed by 1616
Abstract
To rigorously analyze the effects of high-salt environments on dimension lumber and provide scientific and reliable data to facilitate the advancement of light-frame construction in such environments, this study subjected dimension lumber to salt solution treatment. The study investigated the trend of nail-holding [...] Read more.
To rigorously analyze the effects of high-salt environments on dimension lumber and provide scientific and reliable data to facilitate the advancement of light-frame construction in such environments, this study subjected dimension lumber to salt solution treatment. The study investigated the trend of nail-holding power variations across the radial, tangential, and cross-sections of spruce–pine–fir (SPF) dimension lumber under varying salt concentrations and treatment durations. The experimental results exhibited a significant influence of salt on the nail-holding power across all sections of the SPF dimension lumber. As the concentration of salt solution increased, the holding power gradually decreased across all directions, exhibiting considerable differences across salinity gradients. Specifically, the radial and tangential sections exhibited a 15%–20% higher nail-holding power compared to the cross-section. An increase in the salt solution concentration above 3% corresponded to an approximate 1% decrement in nail-holding power per section for every 0.5% rise in concentration. Additionally, prolonged salt treatment initially resulted in an increase, followed by a subsequent decrease in nail-holding power, demonstrating a consistent pattern across all variations. Post hoc analyses confirmed that the differences between individual salt concentrations, including between 3.5%, 4%, and 4.5%, were statistically significant. These findings provide valuable data for understanding the degradation of timber connectors in high-salt environments, contributing to the development of more durable and resilient wood-frame buildings in such conditions. Full article
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13 pages, 8698 KiB  
Article
Evaluation of Major Physical and Mechanical Properties of Trembling Aspen Lumber
by Dawei Wang, Mengyuan Zhang, Meng Gong and Ying-Hei Chui
Materials 2024, 17(12), 2952; https://doi.org/10.3390/ma17122952 - 17 Jun 2024
Cited by 3 | Viewed by 1121
Abstract
Trembling aspen (Populus tremuloides) is one of the major species within Populus, a predominant genus of hardwoods in North America. However, its utilization has been limited to pulp and paper or wood-based composite boards. This study aimed at evaluating the [...] Read more.
Trembling aspen (Populus tremuloides) is one of the major species within Populus, a predominant genus of hardwoods in North America. However, its utilization has been limited to pulp and paper or wood-based composite boards. This study aimed at evaluating the major physical and mechanical properties of trembling aspen lumber, with an ultimate objective of using this species to produce engineered wood products (EWPs). The testing materials consisted of 2 × 4 (38 mm × 89 mm) trembling aspen lumber pieces in lengths of 8, 10, and 12 feet (2.44, 3.05, and 3.66 m) with two visual grades, select structural (SS) and No. 2. Machine Stress-Rated (MSR), and longitudinal stress wave (LSW), edgewise third-point bending (EWB), and axial tension tests were conducted on the lumber. It was found that, (1) by increasing the maximum knot size by a half-inch from one-quarter inch, the minimum modulus of elasticity (MOE) measured using the MSR, the mean, and the fifth-percentile ultimate tensile strength (UTS) decreased by about 8.8%, 20.1%, and 29.8%, respectively. (2) Approximately 44% of the trembling aspen lumber met the 1450f-1.3E grade for MSR lumber, and 62% qualified for the 1200f-1.2E grade. (3) There was a great potential for manufacturing cross-laminated timber (CLT) of grade E3, with a rejection rate of about 29%. (4) The mean UTS and MOE values of the SS-grade trembling aspen lumber were 22.88 MPa and 9519 MPa, respectively, being 25.5% and 11.3% lower than that of Spruce–Pine–Fir (S-P-F) lumber. The fifth-percentile UTS and MOE values were 11.57 MPa and 7404 MPa, respectively, marking a decrease of 13.3% and 1.5% compared to the S-P-F lumber. (5) The oven-dried specific gravity (SG) of the trembling aspen wood was 0.40, which was about 3.5% larger than the value provided in the Wood Handbook. Full article
(This article belongs to the Special Issue Modern Wood-Based Materials for Sustainable Building)
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22 pages, 6892 KiB  
Article
Experimental and Three-Dimensional Numerical Investigations of Dehydration and Pyrolysis in Wood under Elevated and High Temperatures
by Qianyi Li, Biao Xu, Kaixi Chen, Zhaoyan Cui, Yan Liu and Lingfeng Zhang
Buildings 2024, 14(6), 1547; https://doi.org/10.3390/buildings14061547 - 27 May 2024
Cited by 2 | Viewed by 1193
Abstract
Thermal responses of wood significantly depend on the dehydration and pyrolysis processes. However, the dehydration and pyrolysis of wood are not well understood. In this study, the thermal model of wood, considering the temperature-dependent thermo-physical parameters, was presented. Differential scanning calorimetry (DSC) experiments [...] Read more.
Thermal responses of wood significantly depend on the dehydration and pyrolysis processes. However, the dehydration and pyrolysis of wood are not well understood. In this study, the thermal model of wood, considering the temperature-dependent thermo-physical parameters, was presented. Differential scanning calorimetry (DSC) experiments were conducted on the Douglas fir wood with different moisture contents to validate the apparent specific heat capacity submodel. Subsequently, the thermal model was, respectively, implemented in the finite element software Abaqus 6.14 and finite volume software OpenFOAM 5.0 to simulate the three-dimensional temperature profiles within the wood. Dehydration experiment was conducted on the Douglas fir wood to verify the thermal model from room temperature to 200 °C. The thermal model was further validated by the full-scale fire experiment of the cross-laminated timber panel made of Spruce wood. It was found that both latent heat and pyrolysis heat have significant influence on the apparent specific heat capacity which further affected the thermal responses of wood. Moreover, the temperature is more sensitive to the latent heat than to the pyrolysis heat. The gas velocity is rather low in the dehydration and pyrolysis stages due to the low gas pressure. As a result, the gas convection seems to have very limited influence on the temperature progressions. Full article
(This article belongs to the Special Issue Performance Analysis of Timber Composite Structures)
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14 pages, 1000 KiB  
Article
Efficiency of Virucidal Disinfectants on Wood Surfaces in Animal Husbandry
by Martin J. Oettler, Franz J. Conraths, Uwe Roesler, Sven Reiche, Timo Homeier-Bachmann and Nicolai Denzin
Microorganisms 2024, 12(5), 1019; https://doi.org/10.3390/microorganisms12051019 - 17 May 2024
Cited by 1 | Viewed by 1356
Abstract
The aim of this study was to test the inactivation of viruses on germ carriers of different types of wood using a disinfectant in order to assess the biosafety of wood as a building material in animal husbandry. The laboratory disinfectant efficacy tests [...] Read more.
The aim of this study was to test the inactivation of viruses on germ carriers of different types of wood using a disinfectant in order to assess the biosafety of wood as a building material in animal husbandry. The laboratory disinfectant efficacy tests were based on German testing guidelines and current European standards. Five different types of wood germ carriers, i.e., spruce (Picea abies), pine (Pinus sylvestris), poplar (Populus sp.), beech (Fagus sylvatica) and Douglas fir (Pseudotsuga menziesii), were inoculated with enveloped or non-enveloped viruses and then treated with one of three different disinfectants. The results revealed that intact, fine-sawn timber with a low roughness depth can be effectively inactivated. Peracetic acid proved to be the most effective disinfectant across all tests. Regardless of the pathogen and the type of wood, a concentration of 0.1% of the pure substance at a temperature of 10 °C and an exposure time of one hour can be recommended. At a temperature of −10 °C, a concentration of 0.75% is recommended. The basic chemicals formic acid and glutaraldehyde demonstrated only limited effectiveness overall. The synergistic effects of various wood components on the inactivation of viruses offer potential for further investigation. Disinfectant tests should also be conclusively verified in field trials to ensure that the results from standardised laboratory tests can be transferred to real stable conditions. Full article
(This article belongs to the Special Issue Disinfection and Sterilization of Microorganisms)
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13 pages, 3133 KiB  
Article
Tenacity of Animal Disease Viruses on Wood Surfaces Relevant to Animal Husbandry
by Martin J. Oettler, Franz J. Conraths, Uwe Roesler, Sven Reiche, Timo Homeier-Bachmann and Nicolai Denzin
Viruses 2024, 16(5), 789; https://doi.org/10.3390/v16050789 - 15 May 2024
Viewed by 1328
Abstract
The aim of this study was to analyse the hygienic suitability of wood often used in animal husbandry. To this end, the inactivation of viruses (Enterovirus E as a surrogate for non-enveloped viruses and Newcastle disease virus as a surrogate for enveloped viruses) [...] Read more.
The aim of this study was to analyse the hygienic suitability of wood often used in animal husbandry. To this end, the inactivation of viruses (Enterovirus E as a surrogate for non-enveloped viruses and Newcastle disease virus as a surrogate for enveloped viruses) on germ carriers consisting of various types of wood was studied over an extended period to assess the biosafety of wood as an agricultural building material. The study was designed to assess the intrinsic biocidal activity of the wood itself, without the use of a disinfectant. The laboratory tests were based on German test guidelines and current European standards. Five different types of wood germ carriers, i.e., spruce (Picea abies), pine (Pinus sylvestris), poplar (Populus sp.), beech (Fagus sylvatica) and Douglas fir (Pseudotsuga menziesii), as well as stainless-steel carriers, were inoculated with enveloped and non-enveloped viruses and stored for up to four months, and the remaining infectivity of the viruses was continuously assessed. The results showed that intact, finely sawn timber with a low depth of roughness had an inactivating effect on the viruses up to 7.5 decadal logarithmic levels. For the non-enveloped virus, inactivation was fastest on Douglas fir wood, with the target reduction for effective inactivation (reduction by factor 4.0 log10) being achieved after two weeks, and for the enveloped virus on pine wood, it was already achieved from the day of drying. The hygienic effects of the wood carriers may be due to their hygroscopic properties and wood constituents. These effects offer potential for further investigation, including tests with other wood species rich in extractives. Full article
(This article belongs to the Special Issue Strategies for Preventing Viral Diseases of Domestic Animals)
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16 pages, 5738 KiB  
Article
The Characteristics of Ancient Residence Wood from the Qing Dynasty in Yunnan Province
by Xiaorui Yang, Changzhao Li, Liang Wang, Chunwang Yang, Shang Zhang, Jingran Gao and Jian Qiu
Coatings 2024, 14(2), 200; https://doi.org/10.3390/coatings14020200 - 3 Feb 2024
Cited by 1 | Viewed by 1652
Abstract
This study takes the wooden components of the different parts of the ancient buildings at the site of the Zhuangzishang Conference as the object of study, and investigates the deterioration state of the different wood components. To assess their degree of degradation, the [...] Read more.
This study takes the wooden components of the different parts of the ancient buildings at the site of the Zhuangzishang Conference as the object of study, and investigates the deterioration state of the different wood components. To assess their degree of degradation, the wood anatomy, basic density (BD), maximum water content (MWC), cell wall major components, X-ray diffraction (XRD), infrared spectroscopy (IR), and thermogravimetry (TG) were used to compare the samples of new and old wood from the same species. The window (W) was identified by microscopic characterization as cypress (Cupressus sp.), the footing beam (FB) and the weatherboard (WB) as pine (Pinus spp.), the purlin (P) and the column (C) as Chinses fir (Cunninghamia spp.), and the floor (F) as spruce (Picea sp.). In terms of their physical properties, the old wood had a lower basic density of 2.58%–38.19%, a lower air-dry density of 2.87%–39.81%, and a higher maximum moisture content of 8.52%–41.38% compared to the reference wood. The degradation of the FB, which has been subjected to moisture and sunlight, and the P, which has been subjected to termite damage, was greater than that of their conspecifics. The integrated holocellulose of the ancient wood was 3.34%–16.48% less, and the hemicellulose was 1.6%–21.92% less compared to that of the reference wood, and the lignin was 1.32%–25.07% more. The XRD results showed that the crystallinity of the cellulose was greater in the different species of ancient wood compared to the control wood, which was caused by the decrease in the amorphous zones of the hemicellulose and cellulose in the ancient wood. The IR indicated that the degradation of cellulose and hemicellulose occurred in the old wood of all species, from the new lignin uptake peaks in the UV-exposed W, FB, and WB compared to the control timber. The pyrolytic behavior of the ancient and control timber is mainly related to the degradation of the tree species and the ancient wood holocellulose. These results show that the differences in the wooden components of the different parts of the ancient buildings at the Zhuangzishang Conference site are mainly related to the species of trees used in the components, and are secondly related to the location of the ancient wood members, which provides useful information for the protection and repair of the ancient buildings at the site. Full article
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20 pages, 7822 KiB  
Article
Correction Factors for Sclerometric Test Results in the Technical Assessment of Timber Structural Elements under Diverse Conditions
by Justyna Jaskowska-Lemańska, Daniel Wałach and Monika Górka-Stańczyk
Materials 2023, 16(24), 7582; https://doi.org/10.3390/ma16247582 - 10 Dec 2023
Cited by 1 | Viewed by 1163
Abstract
Research on existing wooden structures relies on non-destructive and semi-destructive techniques. One of the methods enabling the estimation of the physico-mechanical characteristics of wood in building structures based on established correlational relationships is the sclerometric method. The challenge in utilizing these known correlational [...] Read more.
Research on existing wooden structures relies on non-destructive and semi-destructive techniques. One of the methods enabling the estimation of the physico-mechanical characteristics of wood in building structures based on established correlational relationships is the sclerometric method. The challenge in utilizing these known correlational relationships is the lack of data regarding the impact of frequently occurring factors in objects on sclerometric test results. This paper presents the influence of selected factors on the results of sclerometric tests, such as temperature, the direction of testing in relation to annual growth rings, and the physical orientation of the measuring device. The research was conducted on pine, spruce, and fir elements, each subjected exclusively to the influence of one of these factors. The study indicates that these factors should not be overlooked in assessing technical conditions using sclerometric testing methods. The impact of temperature on sclerometric test results is relatively small; a change in temperature of 10 °C results in an average test outcome change of approximately 3%. Conversely, changing the orientation of the measuring device from horizontal to vertical can alter the test result by up to 10%. The direction of testing relative to the annual increments of wood also has a significant impact on the test results, but incorporating this factor into practice seems to be quite difficult, and in the case of elements with substantial cross-sections, it is also not required. The obtained results enable the application of established correlational relationships in the structural analysis of wooden elements for which access is challenging, especially under temperature conditions different from the reference, 20 °C. Full article
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21 pages, 5188 KiB  
Article
Using Ground Penetrating Radar (GPR) to Predict Log Moisture Content of Commercially Important Canadian Softwoods
by Isabelle Duchesne, Queju Tong and Guillaume Hans
Forests 2023, 14(12), 2396; https://doi.org/10.3390/f14122396 - 8 Dec 2023
Viewed by 1708
Abstract
The non-destructive testing of wood fibre properties is crucial for informing forest management decisions and achieving optimal resource utilization. Moisture content (MC) is an important indicator of wood freshness and may reveal the presence of wood degradation. However, efficient methods are still needed [...] Read more.
The non-destructive testing of wood fibre properties is crucial for informing forest management decisions and achieving optimal resource utilization. Moisture content (MC) is an important indicator of wood freshness and may reveal the presence of wood degradation. However, efficient methods are still needed to better monitor this property along the forest–wood value chain. The objective of the study was to develop prediction models to evaluate log MC based on the propagation of ground penetrating radar (GPR) signals. A total of 165 trees representing four species (black spruce (Picea mariana (Mill.) B.S.P.), white spruce (Picea glauca (Moench) Voss), red spruce (Picea rubens Sarg.), and balsam fir (Abies balsamea (L.) Mill.)) were harvested in two regions of the province of Quebec. GPR signals were acquired in the green (fresh) state and at three subsequent drying stages. Partial least squares regression (PLSR) and locally weighted PLSR (LWPLSR) were employed to establish relationships between GPR signals (antenna frequency: 1.6 GHz) and log properties. The models were fitted on three calibration sets containing four drying stages and different species mixes. The LWPLSR models performed better than the PLSR models for predicting log MC, with a lower root mean square error (RMSEp range: 10.8%–20.2% vs. 13.0%–20.5%) and a higher R2p (0.63–0.87 vs. 0.62–0.82). Spruce-only models performed considerably better than fir-only models while multi-species models were in-between. Despite the complex anisotropy of wood and the physics of wave propagation, the GPR technology can be successfully used to estimate log moisture content, but the GPR-based MC models should be calibrated for each specific type of wood material. Full article
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17 pages, 1486 KiB  
Article
Use of Pyrolysis–Gas Chromatography/Mass Spectrometry as a Tool to Study the Natural Variation in Biopolymers in Different Tissues of Economically Important European Softwood Species
by David Hentges, Philippe Gérardin, Pierre Vinchelin and Stéphane Dumarçay
Polymers 2023, 15(21), 4270; https://doi.org/10.3390/polym15214270 - 30 Oct 2023
Viewed by 1507
Abstract
Intraspecific macromolecule variation in stemwood, knotwood, and branchwood was studied using analytical pyrolysis with the intention of introducing a rapid working method to assess the variance in lignin content using analytical pyrolysis and highlight variability markers. The study was performed on Picea abies [...] Read more.
Intraspecific macromolecule variation in stemwood, knotwood, and branchwood was studied using analytical pyrolysis with the intention of introducing a rapid working method to assess the variance in lignin content using analytical pyrolysis and highlight variability markers. The study was performed on Picea abies, Abies alba, and Pseudotsuga menziesii. Lignin determined via analytical pyrolysis–GC/MS (Py-lignin) can be used to identify variations in lignin content, compared to using classical Klason lignin values as a reference method for lignin determination, which requires a correction factor. Principal component analysis (PCA) was performed to identify biopolymer pyrolysis product markers for different species, tissues, or heights that could help highlight structural differences. Douglas fir was differentiated from spruce and silver fir in the levoglucosan amount. Guaiacol was more present in spruce wood, and creosol was more present in Douglas fir. Knotwood was structurally close to stemwood in spruce and silver fir, but there was a clear transition between stemwood and branchwood tissue in Douglas fir. Knotwood was differentiated by higher furan compounds. Branchwood was clearly separate from stemwood and knotwood and presented the same markers as compression wood in the form of phenylpropanoid lignins (H-lignin) as well as isoeugenol and vinyl guaiacol, the two most produced lignin pyrolysis products. Full article
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12 pages, 3999 KiB  
Article
Lightweight Solid Wood Panels Made of Paulownia Plantation Wood
by Marius Cătălin Barbu, Helmut Radauer, Alexander Petutschnigg, Eugenia Mariana Tudor and Markus Kathriner
Appl. Sci. 2023, 13(20), 11234; https://doi.org/10.3390/app132011234 - 12 Oct 2023
Cited by 4 | Viewed by 2764
Abstract
Light Paulownia seamless-edged glued solid wood panels (SWPs), single-layered and three-layered, were analyzed in this study. Both panel types were calibrated at a thickness of 19 mm, a dimension very often in demand on the SWP market, but produced with other wood species [...] Read more.
Light Paulownia seamless-edged glued solid wood panels (SWPs), single-layered and three-layered, were analyzed in this study. Both panel types were calibrated at a thickness of 19 mm, a dimension very often in demand on the SWP market, but produced with other wood species (for example, spruce, pine, larch and fir). The panels were bonded with melamine-urea formaldehyde, polyurethane and polyvinyl acetate resins. The panels were tested for their physical (density) and mechanical (modulus of rupture, modulus of elasticity, compressive shear strength and wood breakage rate) properties. For the single-layered panels, the mechanical and physical properties did not differ significantly and were similar to massive Paulownia wood. For the three-layered panels, the adhesive application of polyurethane influenced positively all SWP properties. Considering the differences in density, these composites failed to achieve the performance of one- and single-layered panels made of spruce. The results of these findings recommend Paulownia SWPs to be used as lightweight and sustainable core materials in sandwich structures for the furniture and packaging industry, sport articles or non-load-bearing constructions. Full article
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20 pages, 11691 KiB  
Article
Assessment of the Technical Condition of Timber Structural Elements Using Sclerometric Tests
by Justyna Jaskowska-Lemańska and Daniel Wałach
Materials 2023, 16(18), 6152; https://doi.org/10.3390/ma16186152 - 10 Sep 2023
Cited by 4 | Viewed by 1560
Abstract
The technical assessment of wooden elements is the primary step in their repair and reinforcement design. Normative requirements currently mandate additional tests, including semi-destructive ones, beyond traditional visual assessment. Despite the growing feasibility of semi-destructive tests for qualitative assessments, there remains a paucity [...] Read more.
The technical assessment of wooden elements is the primary step in their repair and reinforcement design. Normative requirements currently mandate additional tests, including semi-destructive ones, beyond traditional visual assessment. Despite the growing feasibility of semi-destructive tests for qualitative assessments, there remains a paucity of data enabling quantitative assessments. This study investigated the hardness of structural timber, specifically pine, spruce, and fir, from Central Europe using sclerometric methods. The outcomes of these tests were compared with those of conventional destructive tests and correlational relationships were established. A strong correlation was found between the sclerometric tests and density (r = 0.62 ÷ 0.82), while a range of strong to moderate correlations was found (r = 0.40 ÷ 0.70) for mechanical characteristics (bending and compressive strength). The correlation strength varied among different wood species, with the strongest for pine and the weakest for spruce. All established relationships were compiled into 40 functions to facilitate their future utilization in quantitative assessments during the technical evaluation of wooden objects. The study also examined the influence of wood defects on the derived correlations by considering the knot index. Sclerometric methods accurately reflect the physico-mechanical properties of elements with a small or medium defect content. However, for wood with a high proportion of defects (knots), the correlations are very weak (r = 0.23 ÷ 0.52, including statistically insignificant results). This research offers new insights into the potential of semi-destructive methods in the structural evaluation of wooden elements, highlighting the need to account for wood species and defect content. Full article
(This article belongs to the Special Issue New Advances in Strengthening of Structural Timber)
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13 pages, 2880 KiB  
Article
Knotwood and Branchwood Polyphenolic Extractives of Silver Fir, Spruce and Douglas Fir and Their Antioxidant, Antifungal and Antibacterial Properties
by Pauline Gérardin, David Hentges, Philippe Gérardin, Pierre Vinchelin, Stéphane Dumarçay, Coralie Audoin and Christine Gérardin-Charbonnier
Molecules 2023, 28(17), 6391; https://doi.org/10.3390/molecules28176391 - 1 Sep 2023
Cited by 6 | Viewed by 2061
Abstract
The extractive contents of three softwood species largely used in the wood industry, namely Abies alba (Silver fir), Picea abies (spruce) and Pseudotsuga menziesii (Douglas fir), have been determined quantitatively for knots and at different points chosen along their branches, before analysis using [...] Read more.
The extractive contents of three softwood species largely used in the wood industry, namely Abies alba (Silver fir), Picea abies (spruce) and Pseudotsuga menziesii (Douglas fir), have been determined quantitatively for knots and at different points chosen along their branches, before analysis using high-performance liquid chromatography coupled with Mass Spectrometry (HPLC-MS). The results indicated that branchwood samples located in close proximity to the stem present high contents of extractives similar to those recorded for the knots. HPLC analysis showed quite similar chemical compositions, indicating that first cm of the branches could be considered as an additional source of knotwood. The antibacterial, antifungal and antioxidant activities of knot’s extractives have been investigated with the dual objective of better understanding the role of high levels of secondary metabolites present in the knot and evaluating their potential for biorefinery applications. The antioxidant activity study showed that crude extracts of Douglas fir knotwood presented higher radical scavenging activity levels than the extracts of Silver fir and spruce, which presented more or less the same activities. Silver fir and spruce knotwood extracts presented higher antibacterial activity levels than the Douglas fir knotwood extracts did, while Douglas fir knotwood extracts presented more fungal growth inhibition than the spruce and fir knotwood extracts did. The structure–activity relationships indicate that radical scavenging and antifungal activities are associated with a higher relative quantity of flavonoids in the crude extracts, while higher relative quantities of lignans are associated with antibacterial activity. Full article
(This article belongs to the Special Issue Phytochemicals: Extraction, Bioactivities and Applications)
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20 pages, 3083 KiB  
Article
Modelling the Development of Above-Ground Biomass Energy Reserves of Four Economically Important Coniferous Woody Species
by Rudolf Petráš, Julian Mecko, Ján Kukla, Margita Kuklová, František Hnilička, Helena Hniličková and Ivica Pivková
Forests 2023, 14(2), 388; https://doi.org/10.3390/f14020388 - 14 Feb 2023
Cited by 1 | Viewed by 1753
Abstract
The goal of renewable energy is to replace energy production from fossil fuels. In that sense, forest biomass is essential renewables. This article presents the results of the development of energy reserves in fractions, increments and the total above-ground biomass of coniferous stands [...] Read more.
The goal of renewable energy is to replace energy production from fossil fuels. In that sense, forest biomass is essential renewables. This article presents the results of the development of energy reserves in fractions, increments and the total above-ground biomass of coniferous stands (spruce, fir, pine, larch) during their economic cycle. The experimental material comes from 22 forest stands located mainly in Central Slovakia, to a lesser extent also in Western and Eastern Slovakia. Energy reserves of coniferous stands were calculated based on the volume production of above-ground biomass fractions taken from mathematical models of yield tables and average values of their basic density and calorific value were determined. The research showed that as the age of the stands increased, the share of energy in the wood fraction increased, while it decreased in the bark fraction, and especially the branch fraction. The curves constructed in relation to the age of the stand and site index have a very similar shape to the curves of the total current annual energy increment of coniferous stands. The energy reserves of stands grew faster at the age of 40 to 80 years than at the age of 80 to 140 years. Spruce had the highest total mean energy increment, followed by fir, larch and pine. As the age of the stands increases, the energy reserves of the increments slightly decrease and the efficiency of solar energy significantly decreases. It peaks practically at the age of reaching the maximum annual energy increment. Full article
(This article belongs to the Special Issue Modelling Forest Ecosystems)
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13 pages, 784 KiB  
Communication
Kinetic Study of Pyrolysis of Coniferous Bark Wood and Modified Fir Bark Wood
by Olga Yu. Fetisova, Nadezhda M. Mikova, Anna I. Chudina and Aleksandr S. Kazachenko
Fire 2023, 6(2), 59; https://doi.org/10.3390/fire6020059 - 8 Feb 2023
Cited by 12 | Viewed by 2141
Abstract
We report on the kinetics of pyrolysis of bark wood of four coniferous tree species: fir (Abies sibirica), larch (Larix sibirica), spruce (Picea obovata), and cedar (Pinus sibirica) denoted as FB, LB, SB, and CB, [...] Read more.
We report on the kinetics of pyrolysis of bark wood of four coniferous tree species: fir (Abies sibirica), larch (Larix sibirica), spruce (Picea obovata), and cedar (Pinus sibirica) denoted as FB, LB, SB, and CB, respectively. Thermogravimetry (TG) and differential scanning calorimetry (DSC) methods were used to study the influence of KCl and K3PO4 compounds on the process of thermal decomposition of fir bark and determine the main thermal effects accompanying this process. As a result of the studies carried out, it was found that KCl additives practically do not affect the decomposition of hemicelluloses, but they shift the maximum decomposition of the cellulose peak in the direction of decreasing temperature to 340.9 °C compared to untreated bark (357.5 °C). K3PO4 promotes the simultaneous decomposition of hemicelluloses and cellulose in the temperature range with a maximum of 277.8 °C. In both cases, the additions of KCl and K3PO4 reduce the maximum rate of weight loss, which leads to a higher yield of carbon residues: the yield of char from the original fir bark is 28.2%, in the presence of K3PO4 and KCl it is 52.6 and 65.0%, respectively. Using the thermogravimetric analysis in the inert atmosphere, the reaction mechanism has been established within the Criado model. It is shown that the LB, SB, and CB thermal decomposition can be described by a two-dimensional diffusion reaction (D2) in a wide range (up to 0.5) of conversion values followed by the reactions with orders of three (R3). The thermal decomposition of the FB occurs somewhat differently. The diffusion mechanism (D2) of the FB thermal decomposition continues until a conversion value of 0.6. As the temperature increases, the degradation of the FB sample tends to R3. It has been found by the thermogravimetric analysis that the higher cellulose content prevents the degradation of wood. The bark wood pyrolysis activation energy has been calculated within the Coats–Redfern and Arrhenius models. The activation energies obtained within these models agree well and can be used to understand the complexity of biomass decomposition. Full article
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