Search Results (37)

Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO₂) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO₂ severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO₂ thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO₂, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO₂ thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO₂ technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO₂-philic groups. Rheological tests conducted under scCO₂ conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO₂ (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO₂ and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO₂ thickeners. This research lays the foundation for green CO₂-based energy extraction technologies. Full article

With the unconventional energy sector (e.g., shale gas) increasingly focused on precision drilling and cost-effective extraction, slim-hole horizontal well technology is gaining prominence. However, drill string dynamics in narrow, complex fluid environments are not fully understood. This study presents a novel bidirectional fluid–structure interaction (FSI) model, uniquely integrating recursive algorithms with the Moving Particle Semi-implicit (MPS) method to couple drill string–wellbore contact with drilling fluid interactions. Key findings show that drilling fluid significantly impacts drill string behavior; for instance, it can reduce natural frequencies by 20–25%, while stiff formations amplify lateral resonance risks. Optimizing fluid properties can substantially cut energy losses, though TREE is marginally elevated when viscosity exceeds the threshold (2.5 × 10⁻⁵ m²/s). The drill string typically displaces rightward, but higher viscosity can shift it left; a moderate friction coefficient aids centering. Excessive lateral displacement impairs cuttings removal, affecting fracturing. These insights enable actionable strategies: adjusting fluid viscosity and drag reducers can optimize drill string position and enhance cleaning. This research provides a framework for energy-efficient drilling in complex reservoirs, balancing efficiency with wellbore integrity and improving outcomes in the unconventional energy sector. Full article

A technology that directly injects CO₂-rich industrial waste gas (CO₂-rich IWG) into underground spaces for unconventional natural gas extraction and waste gas storage has received increasing attention. The pore characteristics of coal and shale in a coal-bearing rock series before and after CO₂-rich IWG treatment are closely related to gas recovery and storage. In this study, three coals ranging from low to high rank and one shale sample were collected. The samples were treated with CO₂-rich IWG using a high-precision geochemical reactor. The changes in the pore volume (PV), specific surface area (SSA), and pore size distribution of micropores, mesopores, and macropores were analyzed. The correlations between the Langmuir volume and the PV and SSA of the micropores and mesopores were analyzed. It was confirmed that for micropores, SSA was the dominant factor influencing adsorption capacity. The effectively interconnected pore volume was calculated using macropores to characterize changes in the sample’s connectivity. It was found that the PV and SSA of the micropores in the coal samples increased with increasing coal rank. The CO₂-rich IWG treatment increased the PV and SSA of the micropores in all of the samples. In addition, for mesopores and macropores, the treatment reduced the SSA in the coal samples but enhanced it in the shale. The results of this study improve the understanding of the mechanisms of the CO₂-rich IWG treatment method and emphasize its potential in waste gas storage and natural gas extraction. Full article

The rapid expansion of shale gas development has revolutionized global energy markets, yet it has also introduced substantial environmental challenges, particularly concerning groundwater resources. This comprehensive review systematically examines the multifaceted impacts of shale gas extraction on groundwater, with a focus on contamination mechanisms, pollutant sources, and mitigation strategies. The study identifies key operational stages—exploration, drilling, hydraulic fracturing, and flowback—as potential sources of groundwater contamination. Inorganic pollutants, including heavy metals and radionuclides, as well as organic compounds such as hydrocarbons and chemical additives, are identified as primary contaminants. The review critically evaluates current wastewater treatment technologies, including reinjection, internal reuse, and advanced desalination methods, highlighting their efficacy and limitations. Additionally, the study proposes a refined environmental management framework that integrates wellbore integrity optimization, enhanced shale gas wastewater treatment, and stringent monitoring protocols. The adoption of clean fracturing technologies and renewable energy applications is recommended to minimize environmental footprints. By establishing comprehensive baseline data and robust pollution monitoring systems, this research provides a scientific foundation for sustainable shale gas development, ensuring the protection of groundwater resources. This review emphasizes the imperative of balancing energy security with environmental sustainability, offering actionable insights for policymakers, industry stakeholders, and environmental scientists. Full article

Oil shale, an unconventional oil and gas resource, can generate the required hydrocarbons through high-temperature pyrolysis. In situ conversion extraction technology utilizes downhole heaters to directly inject high-temperature heat into the oil shale layer to achieve the effect of oil and gas recovery. For the metal material components of the combustion heaters, the uneven temperature fields experienced during the start of operations, processing, and end of operations can lead to fatigue conditions, such as high-temperature creep, micro-damage, and micro-deformation due to thermal effects. To prevent the occurrence of the aforementioned issues, it is necessary to conduct fatigue life analysis of downhole combustion heaters. By combining actual combustion heater operation experiments with finite element simulation, this paper analyzes the impact of temperature, structure, and stress amplitude on the fatigue life of heaters. The results indicate that the fatigue life of the heaters is most significantly influenced by the metal gaskets, and the higher the exhaust gas temperature, the lower the fatigue life of the heater. Heating operations significantly reduce the fatigue life of the heater, while cooling operations have almost no effect on the fatigue life. Circular-pore metal gaskets have a higher fatigue life than those with a square hole shape. Considering only the thickness of the metal gaskets, the thicker the gasket, the higher the fatigue life. Stress amplitude has the most significant impact on the fatigue life of the heater; when the stress amplitude is doubled, the metal gaskets quickly undergo fatigue damage. Full article

The development of geo-energy resources, including oil, gas, and geothermal reservoirs, is being transformed through the creation of low-energy processes and innovative technologies. This Special Issue compiles cutting-edge research aimed at enhancing efficiency, sustainability, and recovery during geo-energy extraction. The published studies explore a diverse range of methodologies, such as the nanofluidic analysis of shale oil phase transitions, deep electrical resistivity tomography for geothermal exploration, and hybrid AI-driven production prediction models. Their key themes include hydraulic fracturing optimization, CO₂ injection dynamics, geothermal reservoir simulation, and competitive gas–water adsorption in ultra-deep reservoirs, and these studies combine advanced numerical modeling, experimental techniques, and field applications to address challenges in unconventional reservoirs, geothermal energy exploitation, and enhanced oil recovery. By bridging theoretical insights with practical engineering solutions, this Special Issue provides a comprehensive foundation for future innovations in low-energy geo-energy development. Full article

The three-point bending test is a key method for determining parameters related to the mechanical fracture properties of rocks. In this study, shale outcrops from Changning County, Sichuan Province, China, were selected. Three-point bending experiments were performed on shale semi-circular disks with a central straight crack, tested both perpendicular and parallel to the bedding direction. The corresponding load–displacement curves and crack opening displacements were obtained. The opening displacements of the specimens were measured through digital image technology, and the tensile strength and stiffness of the specimens were further calculated. A finite element model of the three-point bending test was developed. By integrating the finite element model with the experimentally obtained load–displacement curves, the anisotropic elastic moduli of the shale were inversely determined. Fracture toughness was calculated using two approaches: a formula from the International Society for Rock Mechanics and numerical methods using the finite element model, which was appropriately configured with the previously obtained elastic modulus values. The stress intensity factors for each specimen were calculated and compared. The energy release rate of shale was computed based on the fracture toughness. Results showed that both the fracture toughness and energy release rate of shale were greater in the perpendicular bedding direction than in the parallel direction. As an example, one specimen’s elastic modulus, opening displacement, and energy release rate obtained from experiments were input into the numerical simulation of the three-point bending test. The simulated load–displacement curve matched the experimental results well. This study provides a comprehensive approach to evaluating the anisotropic mechanical fracture properties of shale formations, which is essential for improving the accuracy of hydraulic fracture prediction models and enhancing the efficiency of shale gas extraction. Full article

As a clean energy source, shale gas plays a crucial role in mitigating the supply–demand imbalance of natural gas and in facilitating the transition to a low-carbon economy. This study employs a system dynamics model to forecast future production trends in shale gas in China, analyze its implications for the natural gas supply–demand structure, and explore pathways for sustainable development. Firstly, by integrating the characteristics of China’s shale gas resources, market dynamics, and policy frameworks, the key factors influencing production are identified, and their interrelationships are systematically analyzed. Subsequently, a causal loop diagram is constructed using the VENSIM software(VENSIM PLE 9.3.5 x64), a set of representative variables is selected, and the logical relationships among these variables are established through a multivariate statistical analysis, culminating in the development of a production forecasting model for China’s shale gas (stock and flow diagram). Finally, based on parameter assumptions, this study predicts the production trends in shale gas in China under multiple scenarios. The forecasting results reveal that China’s shale gas production is expected to grow at an average annual rate of 3.32% to 8.02%, with production under the reference scenario projected to reach 724.22 × 10⁸ m³ by 2040. However, the growth of shale gas production over the next two decades remains limited, accounting for a maximum of 12.07% of the total natural gas consumption, underscoring its transitional role in the low-carbon transformation. To address these challenges, this study proposes four policy recommendations: (1) prioritize the development of shallow, high-quality gas-bearing blocks while gradually transitioning to deeper formations; (2) intensify technological innovation in deep shale gas extraction to enhance recovery rates and mitigate production decline rates; (3) implement flexible production subsidies and moderately increase natural gas sales prices to incentivize production and optimize resource allocation; and (4) strengthen ecological conservation and improve water resource management to ensure the sustainable development of shale gas. Full article

Shale is a common rock in oil and gas extraction, and the study of its nonlinear mechanical behavior is crucial for the development of engineering techniques such as hydraulic fracturing. This paper establishes a new coupled elastic–plastic damage model based on the second law of thermodynamics, the strain equivalence principle, the non-associated flow rule, and the Drucker–Prager yield criterion. This model is used to describe the mechanical behavior of shale before and after peak strength and has been implemented in ABAQUS via UMAT for numerical computation. The model comprehensively considers the quasi-brittle and anisotropic characteristics of shale, as well as the strength degradation caused by damage during both the elastic and plastic phases. A damage yield function has been established as a criterion for damage occurrence, and the constitutive integration algorithm has been derived using a regression mapping algorithm. Compared with experimental data from La Biche shale in Canada, the theoretical model accurately simulated the stress–strain curves and volumetric–axial strain curves of shale under confining pressures of 5 MPa, 25 MPa, and 50 MPa. When compared with experimental data from shale in Western Hubei and Eastern Chongqing, China, the model precisely fitted the stress–strain curves of shale at pressures of 30 MPa, 50 MPa, and 70 MPa, and at bedding angles of 0°, 22.5°, 45°, and 90°. This proves that the model can effectively predict the failure behavior of shale under different confining pressures and bedding angles. Additionally, a sensitivity analysis has been performed on parameters such as the plastic hardening rate b, damage evolution rate B_ω, weighting factor r, and damage softening parameter a. This research is expected to provide theoretical support for the efficient extraction technologies of shale oil and gas. Full article

In situ conversion presents a viable strategy for exploiting low to moderate maturity shale oil. Traditional methods, however, require dense well patterns and substantial energy, which are major hurdles. This study introduces a novel approach employing low-frequency electrical heating via production wells to enhance heat transfer without necessitating additional heating wells. Utilizing a self-developed simulator, we developed a numerical model to evaluate the efficacy of this method in augmenting reservoir temperature and facilitating substance decomposition. Findings indicate that low-frequency electrical heating significantly elevates reservoir temperatures, accelerates hydrocarbon cracking, and boosts fluid production. A sensitivity analysis on various heating strategies and reservoir characteristics showed that elevated heating power can further pyrolyze the heavy oil in the product to light oil, while higher porosity formations favor increased oil and gas output. The study also explores the effect of thermal conductivity on heating efficiency, suggesting that while better conductivity improves heat distribution, it may increase the proportion of heavy oils in the output. Overall, this investigation offers a theoretical foundation for refining in situ conversion technologies in shale oil extraction, enhancing both energy efficiency and production quality. Full article

This review discusses recent research findings spanning the last two decades concerning ultrasonic technologies applicable to the oil, gas, and coal sectors. Various experiments conducted in laboratories have demonstrated the efficacy, cost-effectiveness, and environmental friendliness of ultrasound in recovering and processing oil, bitumen, coal, and oil shale. Ultrasound enhances formation permeability, coal gas permeability, and oil viscosity, particularly when delivered in short, powerful pulses at medium frequencies. Combining ultrasound with traditional recovery methods has shown promising results, boosting recovery efficiency by up to 100%. At the same time, ultrasonic treatment reduces the use of traditional reagents, thereby reducing environmental pollution. Moreover, ultrasound treatment shows potential in tasks such as separating oil–water emulsions, desulfurization, dewaxing oil, coal enrichment, and extracting valuable metals from metal-bearing shales through hydrometallurgical leaching. However, the widespread industrial implementation of ultrasonic technology necessitates further field and mathematical research. Full article

With the development of unconventional natural gas resources, plunger gas lift technology has gained widespread application. Accurately predicting gas production from unconventional gas reservoirs is a crucial step in evaluating the effectiveness of plunger gas lift technology and optimizing its design. However, most existing prediction methods are mechanism-driven, incorporating numerous assumptions and simplifications that make it challenging to fully capture the complex physical processes involved in plunger gas lift technology, ultimately leading to significant errors in capacity prediction. Furthermore, engineering design factors and production system factors associated with plunger gas lift technology can contribute to substantial deviations in gas production forecasts. This study employs three powerful regression algorithms, XGBoost, Random Forest, and SVR, to predict gas production in plunger gas lift wells. This method comprehensively leverages various types of data, including collected engineering design, production system, and production data, directly extracting the underlying patterns within the data through machine learning algorithms to establish a prediction model for gas production in plunger gas lift wells. Among these, the XGBoost algorithm stands out due to its robustness and numerous advantages, such as high accuracy, ability to effectively handle outliers, and reduced risk of overfitting. The results indicate that the XGBoost algorithm exhibits impressive performance, achieving an R² (coefficient of determination) value of 0.87 for six-fold cross-validation and 0.85 for the test set. Furthermore, to address the “black box” problem (the inability to know the internal working structure and workings of the model and to directly understand the decision-making process), which is commonly associated with conventional machine learning models, the SHAP (Shapley additive explanations) method was utilized to globally and locally interpret the established machine learning model, analyze the main factors (such as starting time of wells, gas–liquid ratio, catcher well inclination angle, etc.) influencing gas production, and enhance the credibility and transparency of the model. Taking plunger gas lift wells in southwest China as an example, the effectiveness and practicality of this method are demonstrated, providing reliable data support for shale gas production prediction, and offering valuable guidance for actual on-site production. Full article

The rapid expansion of reservoir fractures and the enlargement of the area affected by working fluids can be accomplished solely through fracturing operations of oilfield working fluids in geological reservoirs. Supercritical CO₂ is regarded as an ideal medium for shale reservoir fracturing owing to the inherent advantages of environmental friendliness, excellent capacity, and high stability. However, CO₂ gas channeling and complex propagation of fractures in shale reservoirs hindered the commercialization of Supercritical CO₂ fracturing technology. Herein, a simulation method for Supercritical CO₂ fracturing based on cohesive force units is proposed to investigate the crack propagation behavior of CO₂ fracturing technology under different construction parameters. Furthermore, the shale fracture propagation mechanism of Supercritical CO₂ fracturing fluid is elucidated. The results indicated that the propagation ability of reservoir fractures and Mises stress are influenced by the fracturing fluid viscosity, fracturing azimuth angle, and reservoir conditions (temperature and pressure). An azimuth angle of 30° can achieve a maximum Mises stress of 3.213 × 10⁷ Pa and a crack width of 1.669 × 10⁻² m. However, an apparent viscosity of 14 × 10⁻⁶ Pa·s results in a crack width of only 2.227 × 10⁻² m and a maximum Mises stress of 4.459 × 10⁷ Pa. Additionally, a weaker fracture propagation ability and reduced Mises stress are exhibited at the fracturing fluid injection rate. As a straightforward model to synergistically investigate the fracture propagation behavior of shale reservoirs, this work provides new insights and strategies for the efficient extraction of shale reservoirs. Full article

Carbon dioxide geological storage is one of the key measures to control and alleviate atmospheric carbon dioxide content. To better grasp the developmental dynamic and trend of carbon dioxide geological storage research over the world, promoting the research of CO₂ storage theory and technology, 5052 related studies published in the past 22 years were collected from the Web Of Science database. The annual published articles on carbon dioxide geological storage research, partnerships, research hotspots, and frontiers were analyzed by using the knowledge map method of article analysis. The results show that the articles on the carbon dioxide geological storage are increasing yearly. The United States, China, and the United Kingdom are the most active countries; meanwhile, Tianfu Xu and Xiaochun Li from China are experts with the most achievements in the field of carbon dioxide geological storage. Although the theoretical and research frameworks for geological storage of CO₂ are abundant, the field of enhanced gas formation recovery, shale gas extraction and subsurface storage, methane reservoirs, and methane adsorption are still challenging frontier science and technology topics. Full article

Shale gas reservoirs generally exhibit characteristics such as low porosity, permeability, and pore throat radius, with high airflow resistance. Currently, hydraulic fracturing is a commonly used method for commercial shale gas extraction; however, the hydraulic fracturing method has exhibited a series of issues, including water sensitivity and reservoir pollution in shale reservoirs. Therefore, the development of anhydrous fracturing technology suitable for shale gas reservoirs has become an urgent requirement. The supercritical carbon dioxide fracturing technique has the merits of reducing reservoir damage, improving recovery and backflow rates, and saving water resources. Moreover, this technique has broad application prospects and can achieve the effective extraction of shale gas. To enhance the understanding of the supercritical carbon dioxide fracturing technique, this review summarizes the progress of current research on this technique. Furthermore, this study analyzes the stage control technology of supercritical carbon dioxide during the fracturing process, the interaction characteristics between supercritical carbon dioxide and rocks, and the laws of rock initiation and crack growth in supercritical carbon dioxide fracturing. The outcomes indicate that after SC-CO₂ enters the reservoir, CO₂ water–rock interaction occurs, which alters the mineral composition and pore throat framework, weakens the mechanical characteristics of shale, reduces the rock fracturing pressure, and increases the complexity of the fracturing network. This article provides a reference for research related to supercritical carbon dioxide fracturing technology and is greatly significant for the development of shale gas reservoirs. Full article