Search Results (18)

Firstly, this paper reviews the fundamental theories of solid surface wettability and contact angle hysteresis. Subsequently, it further introduces four typical wettability-engineered surfaces with low hysteresis (superhydrophobic, superamphiphobic, super-slippery, and liquid-like smooth surfaces). Finally, it focuses on the latest research progress in the field of droplet manipulation on open planar surfaces with engineered wettability. To achieve droplet manipulation, the core driving forces primarily stem from natural forces guided by bioinspired gradient surfaces or the regulatory effects of external fields. In terms of bioinspired self-propelled droplet movement, this paper summarizes research inspired by natural organisms such as desert beetles, cacti, self-aligning floating seeds of emergent plants, or water-walking insects, which construct bioinspired special gradient surfaces to induce Laplace pressure differences or wettability gradients on both sides of droplets for droplet manipulation. Moreover, this paper further analyzes the mechanisms, advantages, and limitations of these self-propelled approaches, while summarizing the corresponding driving force sources and their theoretical formulas. For droplet manipulation under external fields, this paper elaborates on various external stimuli including electric fields, thermal fields, optical fields, acoustic fields, and magnetic fields. Among them, electric fields involve actuation mechanisms such as directly applied electrostatic forces and indirectly applied electrocapillary forces; thermal fields influence droplet motion through thermoresponsive wettability gradients and thermocapillary effects; optical fields cover multiple wavelengths including near-infrared, ultraviolet, and visible light; acoustic fields utilize horizontal and vertical acoustic radiation pressure or acoustic wave-induced acoustic streaming for droplet manipulation; the magnetic force acting on droplets may originate from their interior, surface, or external substrates. Based on these different transport principles, this paper comparatively analyzes the unique characteristics of droplet manipulation under the five external fields. Finally, this paper summarizes the current challenges and issues in the research of droplet manipulation on the open planar surfaces and provides an outlook on future development directions in this field. Full article

Spraying is currently one of the main methods of pesticide application worldwide. It converts the pesticide solution into fine droplets through a sprayer, which then deposit onto target plants. Therefore, in the process of pesticide application, improving the effectiveness of spraying while minimizing or preventing crop damage has become a key issue. Combining the advantages of electrostatic spraying technology with the characteristics of ground boom sprayers, a contact-type electrostatic boom spraying system based on a rod–plate electrode structure was designed and tested on a self-propelled boom sprayer. The charging chamber was designed based on the characteristics of the rod–plate electrode and theoretical analysis. The reliability of the device was verified through COMSOL numerical simulations, charge-to-mass ratio, droplet size, and droplet size spectrum measurements, and a droplet size prediction model was established. The deposition characteristics in soybean fields were analyzed using the Box–Behnken experimental design method. The results showed that the rod–plate electrode structure demonstrated its superiority with a maximum spatial electric field of 2.31 × 10⁶ V/m. When the spray pressure was 0.3 MPa and the charging voltage was 8 kV, the droplet size decreased by 26.6%, and the charge-to-mass ratio reached 2.88 mC/kg. Field experiments showed that when the charging voltage was 8 kV, the spray pressure was 0.3 MPa, the traveling speed was 7 km/h, and the number of deposited droplets was 8517. This study provides some basis for the application of electrostatic spraying technology in large-scale field operations. Full article

In recent years, slippery liquid-infused porous surfaces (SLIPSs) have gained significant attention in antifouling applications. However, their slippery performance often deteriorates in dynamic environments, limiting their service life. TC4 titanium alloy, commonly used in hulls and propellers, is prone to biofouling. SLIPSs have gained significant attention in antifouling applications. However, their slippery performance often deteriorates in dynamic environments, limiting their service life. To address these issues, a novel slippery liquid-infused surface (STASL) was developed on TC4 through the integration of hydroxyl end-blocked dimethylsiloxane (OH-PDMS), a silane coupling agent (KH550), and nano-titanium dioxide loaded with silver particles (TiO₂-Ag, anatase) and silicone oil, thereby ensuring stable performance in both dynamic and static conditions. The as-prepared surfaces exhibited excellent sliding capabilities for water, acidic, alkaline, and saline droplets, achieving speeds of up to 2.859 cm/s. Notably, the STASL demonstrated superior oil retention and slippery stability compared to SLIPS, particularly at increased rotational speeds. With remarkable self-cleaning properties, the STASL significantly reduced the adhesion of proteins (50.0%), bacteria (77.8%), and algae (78.8%) compared to the titanium alloy. With these outstanding properties, the STASL has emerged as a promising solution for mitigating marine biofouling and corrosion on titanium alloys. Full article

This study aimed to evaluate the efficiency of air assistance associated with electrostatic spraying in terms of spray deposition and yield (Experiment 1), and the coverage and droplet density on soybean crops at different working speeds (Experiment 2). The treatments in Experiment 1 corresponded to combinations of electrostatic systems associated with air assistance at three airspeeds (21, 25, and 30 m·s⁻¹) plus a conventional treatment without electrostatic or air assistance. The treatments in Experiment 2 corresponded to three working speeds (3.3, 4.2, and 5.0 m·s⁻¹) with or without the use of an electrostatic system. All applications were performed with a self-propelled sprayer, delivering 75 L·ha⁻¹ with ATR 2.0 nozzles. A blue tracer, detectable as absorbance with a spectrophotometer, was added to the spray solution to evaluate deposition. The results indicate that an air assistance at 21 m·s⁻¹ plus electrostatic system increased the amount of spray deposited on the middle and top leaves of the plants in relation to the conventional system, with yield increments of up to 621 kg·ha⁻¹. The slowest working speed (3.3 m·s⁻¹) combined with air assistance and an electrostatic system provided the greatest spray deposition, droplet coverage, and density on the bottom leaves of soybean crops. Full article

Binary droplet collision is a basic fluid phenomenon for many spray processes in nature and industry involving lots of discrete droplets. It exists an inherent mirror symmetry between two colliding droplets. For specific cases of the collision between two identical droplets, the head-on collision and the off-center collision, respectively, show the axisymmetric and rotational symmetry characteristics, which is useful for the simplification of droplet collision modeling. However, for more general cases of the collision between two droplets involving the disparities of size ratio, surface tension, viscosity, and self-spin motions, the axisymmetric and rotational symmetry droplet deformation and inner flow tend to be broken, leading to many distinct phenomena that cannot occur for the collision between two identical droplets owing to the mirror symmetry. This review focused on interpreting the asymmetric droplet deformation and the collision-induced internal mixing that was affected by those symmetry breaking factors, such as size ratio effects, Marangoni Effects, non-Newtonian effects, and droplet self-spin motion. It helps to understand the droplet internal mixing for hypergolic propellants in the rocket engineering and microscale droplet reactors in the biological engineering, and the modeling of droplet collision in real combustion spray processes. Full article

Plant protection unmanned aircraft vehicles (UAVs) were developed rapidly in China. The operation performances of different models of UAVs were different. This paper systematically studied droplet deposition distribution; pesticide-mixture utilization rate; operational efficiency; wheat-disease control efficacy; and a comprehensive score of three types of UAVs, a boom sprayer, and a knapsack sprayer. The results showed the descending order of the droplet penetration rate of the pesticide application equipment (PAE) was boom sprayer; UAVs; and knapsack sprayer. The pesticide-mixture utilization rates of the UAVs and boom sprayer were more than 50% while that of the knapsack electric sprayer was only 27.8%. The UAVs’ average labor productivity was 5.75 ha per man-hour, which was slightly less than that of the boom sprayer and 21.3 times that of the knapsack sprayer. The control efficacy of each machine on wheat Fusarium head blight was more than 90%. The average performance comprehensive score of the UAVs was 0.812, which was slightly lower than the score of 0.929 for the 3WPZ-700 self-propelled boom sprayer but much higher than the score of 0.399 for the 3WBD-18 knapsack electric sprayer. The results clearly showed the potential of UAVs for improving the pesticide-mixture utilization rate and operational efficiency, as well as the wheat Fusarium head blight control efficacy. Full article

Triethylaluminum Al(C₂H₅)₃, TEA, and triethylborane, B(C₂H₅)₃, TEB, are transparent, colorless, pyrophoric liquids with boiling points of approximately 190 °C and 95 °C, respectively. Upon contact with ambient air, TEA, TEB, as well as their mixtures and solutions, in hydrocarbon solvents, ignite. They can also violently react with water. TEA and TEB can be used as hypergolic rocket propellants and incendiary compositions. In this manuscript, a novel scheme of the heterogeneous interaction of gaseous oxygen with liquid TEA/TEB microdroplets accompanied by the release of light hydrocarbon radicals into the gas phase is used for calculating the self-ignition of a spatially homogeneous mixture of fuel microdroplets in ambient air at normal pressure and temperature (NPT) conditions. In the primary initiation step, TEA and TEB react with oxygen, producing an ethyl radical, which can initiate an autoxidation chain. The ignition delay is shown to decrease with the decrease in the droplet size. Preliminary experiments on the self-ignition of pulsed and continuous TEA–TEB sprays in ambient air at NPT conditions are used for estimating the Arrhenius parameters of the rate-limiting reaction. Experiments confirm that the self-ignition delay of TEA–TEB sprays decreases with the injection pressure and provide the data for estimating the activation energy of the rate-limiting reaction, which appears to be close to 2 kcal/mol. Full article

Laser fabrication of metallic superhydrophobic surfaces (SHSs) for anti-frosting has recently attracted considerable attention. Effective anti-frosting SHSs require the efficient removal of condensed microdroplets through self-propelled droplet jumping, which is strongly influenced by the surface morphology. However, detailed analyses of the condensate self-removal capability of laser-structured surfaces are limited, and guidelines for laser processing parameter control for fabricating rationally structured SHSs for anti-frosting have not yet been established. Herein, a series of nanostructured copper-zinc alloy SHSs are facilely constructed through ultrafast laser processing. The surface morphology can be properly tuned by adjusting the laser processing parameters. The relationship between the surface morphologies and condensate self-removal capability is investigated, and a guideline for laser processing parameterization for fabricating optimal anti-frosting SHSs is established. After 120 min of the frosting test, the optimized surface exhibits less than 70% frost coverage because the remarkably enhanced condensate self-removal capability reduces the water accumulation amount and frost propagation speed (<1 μm/s). Additionally, the material adaptability of the proposed technique is validated by extending this methodology to other metals and metal alloys. This study provides valuable and instructive insights into the design and optimization of metallic anti-frosting SHSs by ultrafast laser processing. Full article

This study proposes a visual sensing system to investigate the self-propelled motions of droplets. In the visual sensing of self-propelled droplets, large field-of-view and high-resolution images are both required to investigate the behaviors of multiple droplets as well as chemical reactions in the droplets. Therefore, we developed a view-expansive microscope system using a color camera head to investigate these chemical reactions; in the system, we implemented an image processing algorithm to detect the behaviors of droplets over a large field of view. We conducted motion tracking and color identification experiments on the self-propelled droplets to verify the effectiveness of the proposed system. The experimental results demonstrate that the proposed system is able to detect the location and color of each self-propelled droplet in a large-area image. Full article

In most Asian countries, farmers have smallholdings ranging from one to two hectares. The tractor-mounted boom sprayers cannot practically be used in small size farms with divided plots and complex terrain. To cope with these issues, a prototype self-propelled crop sprayer was developed, including a 20-hp engine, 300 L liquid tank, and hydraulically-controlled spray boom with eight hollow cone nozzles. The spray symmetry of the hollow cone nozzle was evaluated under four pressures (2.5, 3, 3.5, and 4 bar) in the laboratory. The operating parameters of the sprayer, such as forward speed (4, 6, and 8 km h⁻¹), spray height (40, 55, and 70 cm), and pressure (3, 5, and 7 bar) were optimized by measuring three spray characteristics including droplet density, coverage percentage, and Volume Median Diameter (VMD) in the cotton field. The results revealed that the nozzle spray was symmetrical at 2.5 and 3 bar pressure as the R² value was higher than 0.96. The field test result showed that in all treatments, treatments T14 (6 km h⁻¹, 55 cm, 5 bar) and T22 (8 km h⁻¹, 55 cm, 3 bar) were suitable for spraying medium-to-low concentration solution (post-emergence herbicides and fungicides) and high concentration solution (insecticides and pre-emergence herbicides), respectively. The spray characteristics at treatments T14 and T22 were 64.7 droplets cm⁻², 26.7%, 230 µm, and 39 droplets cm⁻², 14.9%, and 219.8 µm respectively. The field efficiency of the sprayer was 61%. The spraying cost per unit area was 55–64% less compared to manual labor cost. In conclusion, a prototype self-propelled crop sprayer is an efficient and environment-friendly technology for small farms. Operating the sprayer at the optimal parameters also saves operational costs and time. Full article

The number of spray deposits plays an important role in effective and efficient spraying. The spraying equipment is one of the most significant factors that affect the number of spray deposits. Therefore, the study was focused on the parameter optimization of a newly developed self-propelled variable height crop sprayer. Response surface methodology (RSM) along with Box–Behnken design (BBD) was used to study the effect of the independent variables (forward speed, spray height, and spray pressure) on response variables such as droplet density, coverage per-centage, and Volume Median Diameter (VMD). The experiment was conducted in the cotton field. Additionally, the RSM model was validated in this research. The results revealed that the coefficient of determination (R2) values was good for all response variables in the quadratic polynomial model. The optimized parameters were 6.5 km/h, 60 cm, 4 bar for fungicide application, and 8 km/h, 70 cm, 3 bar for insecticide and herbicide application. The predicted response variable values at the optimal conditions were 60.4 droplet/cm², 27%, 230 µm for fungicides and 37.8 droplet/cm², 19.1%, 225.4 µm for insecticide and herbicides application. The model validation is confirmed by the mean of actual response variable values at the optimal condition for insecticide and herbicides application, which was 41.35 ± 3.67 droplet/cm², 21.10 ± 1.72%, 227.43 ± 1.22 µm, and the prediction error was 8.46%, 9.2%, and 0.9% for droplet density, coverage percentage, and VMD, respectively. This study can provide support for further optimizing the parameters of the sprayer. Full article

We report on self-propelled rotating liquid marbles fabricated using droplets of alcoholic solution encapsulated in hollow microtetrapods of GaN with hydrophilic free ends of their arms and hydrophobic lateral walls. Apart from stationary rotation, elongated-spheroid-like liquid marbles were found, for the first time, to exhibit pulsed rotation on water surfaces characterized by a threshold speed of rotation, which increased with the weight of the liquid marble while the frequency of pulses proved to decrease. To throw light upon the unusual behavior of the developed self-propelled liquid marbles, we propose a model which takes into account skimming of the liquid marbles over the water surface similar to that inherent to flying water lily beetle and the so-called helicopter effect, causing a liquid marble to rise above the level of the water surface when rotating. Full article

Spray sprinklers enable to operate at low pressures (<103 kPa) in self-propelled irrigation machines. A number of experiments were performed to characterize the water distribution pattern of an isolated rotator spray plate sprinkler operating at very low pressure under different experimental conditions. The experiments were performed under two pressures (69 kPa and 103 kPa) and in calm and windy conditions. The energy losses due to the impact of the out-going jet with the sprinkler plate were measured using an optical technique. The adequacy to reproduce the measured water distribution pattern under calm conditions of two drop size distribution models was evaluated. A ballistic model was used to simulate the water distribution pattern under wind conditions evaluating three different drag models: (1) considering solid spherical drops; (2) a conventional model based on wind velocity and direction distortion pattern, and (3) a new drag coefficient model independent of wind speed. The energy losses measured with the optical method range from 20% to 60% from higher to lower nozzle sizes, respectively, for both evaluated working pressures analyzing over 16,500 droplets. For the drop size distribution selected, Weibull accurately reproduced the water application with a maximum root mean square error (RMSE) of 19%. Up to 28% of the RMSE could be decreased using the wind-independent drag coefficient model with respect to the conventional model; the difference with respect to the spherical model was 4%. Full article

As a new low volume application technology, unmanned aerial vehicle (UAV) application is developing quickly in China. The aim of this study was to compare the droplet deposition, control efficacy and working efficiency of a six-rotor UAV with a self-propelled boom sprayer and two conventional knapsack sprayers on the wheat crop. The total deposition of UAV and other sprayers were not statistically significant, but significantly lower for run-off. The deposition uniformity and droplets penetrability of the UAV were poor. The deposition variation coefficient of the UAV was 87.2%, which was higher than the boom sprayer of 31.2%. The deposition on the third top leaf was only 50.0% compared to the boom sprayer. The area of coverage of the UAV was 2.2% under the spray volume of 10 L/ha. The control efficacy on wheat aphids of UAV was 70.9%, which was comparable to other sprayers. The working efficiency of UAV was 4.11 ha/h, which was roughly 1.7–20.0 times higher than the three other sprayers. Comparable control efficacy results suggest that UAV application could be a viable strategy to control pests with higher efficiency. Further improvement on deposition uniformity and penetrability are needed. Full article

In this study, a self-propelled high-energy ultrasonic atomizer was evaluated in terms of deposition on the canopy, the loss to the ground, and fungicide residues in cherry tomato and tomato. Artificial collectors fixed to the upper side and underside of the leaves at different depths and heights were used to collect the depositions. A reliable analytical method for determination of azoxystrobin and tebuconazole in artificial collectors and residue samples was developed by using liquid chromatography triple-quadrupole mass spectrometry. The results showed that the atomizer distributed the droplets evenly throughout the greenhouse with good uniformity (CVs below 39%). The ratio of depositions on the internal and external sides was 66–83%, and the ratio of depositions on the underside and upper side was 39–50%. There were no significant differences in depositions between two different height crops. The residues of azoxystrobin and tebuconazole in tomato and cherry tomato fruits were far below the maximum residue limits at harvest time. In general, self-propelled high-energy ultrasonic atomizer used in a greenhouse could increase the depositions, especially on the underside and internal side of the canopies, and lead to a reduction of operator exposure risk. Full article