Search Results (15)

Solar-blind ultraviolet (UV) photodetectors based on wide-bandgap oxide semiconductors are highly desirable for environmental monitoring, flame sensing, and secure optical communication. Among them, Ga₂O₃ has attracted extensive attention due to its ultra-wide bandgap and intrinsic solar-blind response; however, its high dark current, weak built-in electric field, and defect-induced instability remain critical challenges, particularly for amorphous films prepared by scalable sputtering processes. Herein, a self-powered solar-blind UV photodetector based on a NiO/Ga₂O₃ heterojunction is demonstrated, in which the oxygen-vacancy concentration and band structure of sputtered Ga₂O₃ are systematically regulated by tailoring the Ar/O₂ sputtering atmosphere. Combined X-ray photoelectron spectroscopy, UV photoelectron spectroscopy, and optical measurements reveal that the variation in oxygen-vacancy concentration simultaneously modulates the Fermi-level position, band-edge alignment, and built-in potential at the NiO/Ga₂O₃ interface. As a result, the optimized heterojunction device exhibits a low dark current, pronounced rectifying behavior, and efficient carrier separation under zero bias, enabling self-powered operation. The photodetector delivers a responsivity of 47 mA W⁻¹, a detectivity of 7.52 × 10¹¹ Jones, and a high rejection ratio exceeding 10⁴ between 254 and 365 nm. Furthermore, stable and high-contrast UV imaging is successfully demonstrated, highlighting the practical applicability of the device. This work provides an effective methodology for modulating defects and band structure in high-performance solar-blind UV photodetectors based on sputtered wide-bandgap oxide heterojunctions. Full article

The implementation of photoelectric conversion in photoelectric integrated systems requires the design of photodetectors (PDs) with quick response times and low power consumption. In this work, the self-powered photodetector was prepared by antimony selenide (Sb₂Se₃) microwires (MW)/Se microtube (MT) heterojunction by coating Ag nanowires (NW). The incorporation of Ag-NW involves dual enhancement mechanisms. First, the surface plasmon resonance (SPR) effect amplifies the light absorption across UV–vis–NIR spectra, and the conductive networks facilitate the rapid carrier transport. Second, the type-II band alignment between Sb₂Se₃ and Se synergistically separates photogenerated carriers, while the Ag-NW further suppress the recombination through built-in electric field modulation. The optimized device achieves remarkable responsivity of 122 mA W⁻¹ at 368 nm under zero bias, with a response/recovery time of 8/10 ms, outperforming most reported Sb₂Se₃-based detectors. The heterostructure provides an effective strategy for developing self-powered photodetectors with broadband spectral adaptability. The switching ratio, responsivity, and detectivity of the Sb₂Se₃-MW/Se-MT/Ag-NW device increased by 260%, 810%, and 849% at 368 nm over the Sb₂Se₃-MW/Se-MT device, respectively. These results show that the addition of Ag-NW effectively improves the photoelectric performance of the Sb₂Se₃-MW/Se-MT heterojunction, providing new possibilities for the application of self-powered optoelectronic devices. Full article

As a vital carrier of human intangible culture, dance plays an important role in cultural transmission through digital generation. However, existing dance generation methods rely heavily on high-precision motion capture and manually annotated datasets, and they fail to effectively model the culturally distinctive movements of Chinese ethnic folk dance, resulting in semantic distortion and cross-modal mismatch. Building on the Chinese traditional ethnic Helou Dance, this paper proposes a culture-aware Chinese ethnic folk dance generation framework, CAFE-Dance, which dispenses with manual annotation and automatically generates dance sequences that achieve high cultural fidelity, precise music synchronization, and natural, fluent motion. To address the high cost and poor scalability of cultural annotation, we introduce a Zero-Manual-Label Cultural Data Construction Module (ZDCM) that performs self-supervised cultural learning from raw dance videos, using cross-modal semantic alignment and a knowledge-base-guided automatic annotation mechanism to construct a high-quality dataset of Chinese ethnic folk dance covering 108 classes of curated cultural attributes without any frame-level manual labels. To address the difficulty of modeling cultural semantics and the weak interpretability, we propose a Culture-Aware Attention Mechanism (CAAM) that incorporates cultural gating and co-attention to adaptively enhance culturally key movements. To address the challenge of aligning the music–motion–culture tri-modalities, we propose a Tri-Modal Alignment Network (TMA-Net) that achieves dynamic coupling and temporal synchronization of tri-modal semantics under weak supervision. Experimental results show that our framework improves Beat Alignment and Cultural Accuracy by 4.0–5.0 percentage points and over 30 percentage points, respectively, compared with the strongest baseline (Music2Dance), and it reveals an intrinsic coupling between cultural embedding density and motion stability. The code and the curated Helouwu dataset are publicly available. Full article

Carbon nanotube field-effect transistors (CNTFETs) are becoming a strong competitor for the next generation of high-performance, energy-efficient integrated circuits due to their near-ballistic carrier transport characteristics and excellent suppression of short-channel effects. However, CNT FETs with large diameters and small band gaps exhibit obvious bipolarity, and gate-induced drain leakage (GIDL) contributes significantly to the off-state leakage current. Although the asymmetric gate strategy and feedback gate (FBG) structures proposed so far have shown the potential to suppress CNT FET leakage currents, the devices still lack scalability. Based on the analysis of the conduction mechanism of existing self-aligned gate structures, this study innovatively proposed a design strategy to extend the length of the source–drain epitaxial region (L_ext) under a vertically stacked architecture. While maintaining a high drive current, this structure effectively suppresses the quantum tunneling effect on the drain side, thereby reducing the off-state leakage current (I_off = 10⁻¹⁰ A), and has good scaling characteristics and leakage current suppression characteristics between gate lengths of 200 nm and 25 nm. For the sidewall gate architecture, this work also uses single-walled carbon nanotubes (SWCNTs) as the channel material and uses metal source and drain electrodes with good work function matching to achieve low-resistance ohmic contact. This solution has significant advantages in structural adjustability and contact quality and can significantly reduce the off-state current (I_off = 10⁻¹⁴ A). At the same time, it can solve the problem of off-state current suppression failure when the gate length of the vertical stacking structure is 10 nm (the total channel length is 30 nm) and has good scalability. Full article

Photoelectrochemical devices have garnered extensive research attention in the field of smart and multifunctional photoelectronics, owing to their lightweight nature, eco-friendliness, and cost-effective manufacturing processes. In this work, Bi₂S₃/Bi₂O₃/TiO₂ heterojunction film was successfully fabricated and functioned as the photoelectrode of photoelectrochemical devices. The designed Bi₂S₃/Bi₂O₃/TiO₂ photoelectrochemical photodetector possesses a broad light detection spectrum ranging from 400 to 900 nm and impressive self-powered characteristics. At 0 V bias, the device exhibits an on/off current ratio of approximately 1.3 × 10⁶. It achieves a commendable detectivity of 5.7 × 10¹³ Jones as subjected to a 0.8 V bias potential, outperforming both bare TiO₂ and Bi₂O₃/TiO₂ photoelectrochemical devices. Moreover, the Bi₂S₃/Bi₂O₃/TiO₂ photoelectrode film shows great promise in pollutant decomposition, achieving nearly 97.7% degradation efficiency within 60 min. The appropriate band energy alignment and the presence of an internal electric field at the interface of the Bi₂S₃/Bi₂O₃/TiO₂ film serve as a potent driving force for the separation and transport of photogenerated carriers. These findings suggest that the Bi₂S₃/Bi₂O₃/TiO₂ heterojunction film could be a viable candidate as a photoelectrode material for the development of high-performance photoelectrochemical optoelectronic devices. Full article

Solar cell (SC) technologies, which are essential in the transition toward sustainable energy, utilize photovoltaic cells to convert solar energy into electricity. Of the available technologies, heterojunction with intrinsic thin-layer (HIT) solar cells offers high efficiency and reliability. The current study explored the enhancement of HIT solar cell performance through the use of 3-aminopropyltrimethoxysilane (APTMS) self-assembled monolayers (SAMs) on the surface of the cells’ indium tin oxide (ITO) layer. Photoluminescence mapping revealed greater brightness and photocurrent in the HIT sample treated with APTMS SAMs, with the results indicating more favorable optical and electrical properties. The application of APTMS SAMs led to higher open-circuit voltage, fill factor, maximum power output, and efficiency by passivating the ITO surface and achieving energy level alignment, thereby enhancing the charge carrier dynamics. These findings demonstrate the potential of APTMS SAMs to improve HIT solar cell efficiency and reliability. Full article

The growing demand for wearable and attachable displays has sparked significant interest in flexible quantum-dot light-emitting diodes (QLEDs). However, the challenges of fabricating and operating QLEDs on flexible substrates persist due to the lack of stable and low-temperature processable charge-injection/-transporting layers with aligned energy levels. In this study, we utilized NiO_x nanoparticles that are compatible with flexible substrates as a hole-injection layer (HIL). To enhance the work function of the NiO_x HIL, we introduced a self-assembled dipole modifier called 4-(trifluoromethyl)benzoic acid (4–CF₃–BA) onto the surface of the NiO_x nanoparticles. The incorporation of the dipole molecules through adsorption treatment has significantly changed the wettability and electronic characteristics of NiO_x nanoparticles, resulting in the formation of NiO(OH) at the interface and a shift in vacuum level. The alteration of surface electronic states of the NiO_x nanoparticles not only improves the carrier balance by reducing the hole injection barrier but also prevents exciton quenching by passivating defects in the film. Consequently, the NiO_x-based red QLEDs with interfacial modification demonstrate a maximum current efficiency of 16.1 cd/A and a peak external quantum efficiency of 10.3%. This represents a nearly twofold efficiency enhancement compared to control devices. The mild fabrication requirements and low annealing temperatures suggest potential applications of dipole molecule-modified NiO_x nanoparticles in flexible optoelectronic devices. Full article

The separation of photogenerated electron–hole pairs is crucial for the construction of high-performance and wide-band responsive photodetectors. The type-I heterojunction as a photodetector is seldomly studied due to its limited separation of the carriers and narrow optical response. In this work, we demonstrated that the high performance of type-I heterojunction as a broadband photodetector can be obtained by rational design of the band alignment and proper modulation from external electric field. The heterojunction device is fabricated by vertical stacking of non-layered MnS and WSe₂ flakes. Its type-I band structure is confirmed by the first-principles calculations. The MnS/WSe₂ heterojunction presents a wide optical detecting range spanning from 365 nm to 1550 nm. It exhibits the characteristics of bidirectional transportation, a current on/off ratio over 10³, and an excellent photoresponsivity of 108 A W⁻¹ in the visible range. Furthermore, the response time of the device is 19 ms (rise time) and 10 ms (fall time), which is much faster than that of its constituents MnS and WSe₂. The facilitation of carrier accumulation caused by the interfacial band bending is thought to be critical to the photoresponse performance of the heterojunction. In addition, the device can operate in self-powered mode, indicating a photovoltaic effect. Full article

Reducing the interfacial defects between the perovskite/electron transport layer (ETL) is the key point to improving the efficient and stable performance of perovskite solar cells (PSCs). In this study, two self-assembled molecules ((aminomethyl)phosphonic acid and glycine) with different functional groups (phosphonic acid (-H₂PO₃) and carboxylic acid (-COOH)) were mixed to form the buried bottom interface of PSCs. The synergistic effect of -H₂PO₃ with its higher anchoring ability and -COOH with its fast carrier transport improved the performance of PSCs. Additionally, the SnO₂ modified by mixed self-assembly molecules (M-SAM) showed a more appropriate energy level alignment, favoring charge transport and minimizing energy loss. In addition, the amine group (-NH₂) on the two small molecules effectively interacted with uncoordinated Pb²⁺ in perovskite and improved the quality of the perovskite films. Consequently, the (FAPbI₃)_0.992(MAPbBr₃)_0.008 PSCs with M-SAM reached a PCE of 24.69% (0.08 cm²) and the perovskite modules achieved a champion efficiency of 18.57% (12.25 cm² aperture area). Meanwhile, it still maintained more than 91% of its initial PCE after being placed in nitrogen atmosphere at 25 °C for 1500 h, which is better than that of the single-SAM and control devices. Further reference is provided for the future commercialization of perovskite with efficient and stable characteristics. Full article

Realizing the high molecular orientation and structurally ordered microstructure of organic semiconductor polymer thin films is beneficial for enhancing the charge transport of conjugated polymers and achieving high-performance organic electronic devices. In this work, we successfully developed large-area highly aligned films of a thiophene-based polymer, namely poly(2,5-bis(3-alkylthiophen-2-yl) thieno [3,2-b] thiophene) (PBTTT), using the magnetic alignment method at a low magnetic field (0.12 T), which was assisted by superparamagnetic nanoparticles Fe₃O₄@C. The aligned microstructure of the composite films is confirmed by systematic analysis that includes polarized optical microscopy, polarized UV–visible absorption spectroscopy, and an atomic force microscope. Organic field effect transistors based on magnetic aligned composite film exhibit a 2.8-fold improvement in carrier mobility compared with the unaligned films. We hold a formation mechanism that the rapid magnetically induced self-assembly property of Fe₃O₄@C and its intermolecular interaction with polymer chains are key to the new method of preparing oriented thin films. Full article

Parental rejection has been consistently empirically implicated in a wide array of developmental, behavioural and psychological problems worldwide. However, the interaction effect between parental rejection in childhood and the oxytocin receptor genotype on psychological adjustment has yet to be investigated. The present study aimed to investigate gene–environment interaction effects between parental rejection (maternal and paternal) and oxytocin receptor (OXTR) gene polymorphisms (rs53576 and rs2254298) on depressive symptoms in adults in different cultural contexts. Adults from Italy and Japan (N = 133, age = 18–27 years, females = 68) were preliminarily genotyped and then completed the Parental Acceptance-Rejection Questionnaire for mothers and fathers and the Beck Depression Inventory. Hierarchical multiple regression analysis showed that paternal rejection was related to self-reported depression and that the effect of parental rejection was moderated by OXTR gene polymorphisms and nationality. Among Italians, OXTR rs2254298 A-carriers showed resilience to negative early parental care, whereas among Japanese, OXTR rs53576 non-A-carriers showed resistance to negative early paternal care. These findings align with expected relations between perceived acceptance–rejection and an individual’s psychological adjustment, as proposed by interpersonal acceptance–rejection theory, and indicate the need for future studies adopting a multicultural and multilevel approach to better understand how the effects of parental rejection extend into adulthood. Full article

It is difficult to rapidly and accurately achieve alignment under complicated interferential environmental conditions with a marine strapdown inertial navigation system (SINS) subject to angular swaying interference and linear motion interference. To solve this problem, an SINS self-alignment algorithm in a complex interference environment is presented in this article. For the angular motion disturbance problem, we used the attitude-updating algorithm in the coagulation inertial coordinate system to reflect the carrier’s attitude change in real time under the swaying interference so as to eliminate the influence of angular motion disturbance. To solve the problem of linear motion interference, we first use Fourier transform analysis (FFT) to analyze the frequency characteristics of linear motion interference signals. We then adaptively decompose the original signal into a series of signal components with different time scales and local characteristics according to the amplitude and frequency using the modified ensemble empirical mode decomposition (MEEMD) algorithm. Finally, we remove and reconstruct the disturbing signal components according to the frequency characteristics of the disturbing signal to filter the line motion disturbing signal. We use the MEEMD algorithm to conduct a ship alignment test. After pre-filtering by MEEMD, high accuracy can be achieved after 100 s of alignment, and the mean square error of the heading angle is 2.85${}^{\prime }$. The test results show that the MEEMD method has a good noise removal effect. The anti-jamming initial alignment algorithm based on the MEEMD algorithm has the ability to suppress the interference of angular motion and linear motion and achieve high-precision anti-jamming initial alignment under the complicated interferential environmental conditions with angular swaying interference and linear motion interference. Full article

While the CuBi₂O₄-based photocathode has emerged as an ideal candidate for photoelectrochemical water splitting, it is still far from its theoretical values due to poor charge carrier transport, poor electron–hole separation, and instability caused by self-photoelectric-corrosion with electrolytes. Establishing synthesis methods to produce a CuBi₂O₄ photocathode with sufficient cocatalyst sites would be highly beneficial for water splitting. Here, the platinum-enriched porous CuBi₂O₄ nanofiber (CuBi₂O₄/Pt) with uniform coverage and high surface area was prepared as a photocathode through an electrospinning and electrodeposition process for water splitting. The prepared photocathode material was composed of a CuBi₂O₄ nanofiber array, which has a freestanding porous structure, and the Pt nanoparticle is firmly embedded on the rough surface. The highly porous nanofiber structures allow the cocatalyst (Pt) better alignment on the surface of CuBi₂O₄, which can effectively suppress the electron–hole recombination at the electrolyte interface. The as-fabricated CuBi₂O₄ nanofiber has a tetragonal crystal structure, and its band gap was determined to be 1.8 eV. The self-supporting porous structure and electrocatalytic activity of Pt can effectively promote the separation of electron–hole pairs, thus obtaining high photocurrent density (0.21 mA/cm² at 0.6 V vs. RHE) and incident photon-to-current conversion efficiency (IPCE, 4% at 380 nm). This work shows a new view for integrating an amount of Pt nanoparticles with CuBi₂O₄ nanofibers and demonstrates the synergistic effect of cocatalysts for future solar water splitting. Full article

This paper proposes a fast, decentralized method for self-aligning the carriers of a multiphase/multilevel converter operating on the basis of phase-shifted pulse width modulation or level-shifted pulse width modulation. In the proposed method, each cell of the converter synchronizes and updates simultaneously its own carrier angle or carrier level based on the information shared with its neighboring cell, such as its angle/level, its index number, and the total number of activated cells of the converter. Different from the conventional decentralized method (with basic and modified updating rules), which requires some conditions in terms of cell number and initial carrier angles to start up and operate properly, the proposed method can be applied to the system with any number of cells and does not require special conditions of initial carrier angles. Further, while the conventional method needs an iteration process to adjust the inter-carrier phase-shifts and can be applied only to a multiphase converter which uses phase-shifted pulse width modulation, the proposed method offers an accurate and fast alignment of phases (for phase-shifted pulse width modulation) or levels (for level-shifted pulse width modulation) and thus can be applied to both multiphase and multilevel converter types. The simulations and the experimental results are presented in detail to show the validity and the effectiveness of the proposed methods. Further, thorough simulations on multiphase converters with different number of cells also show that the proposed method is much faster than the conventional method in both configuration and reconfiguration processes, especially in case the system has a large number of cells. Full article

To effectively improve photocatalytic activity, the morphology and crystallinity of semiconductor photocatalysts must be precisely controlled during the formation process. Self-aligned Nb₂O₅ nanotube arrays have been successfully fabricated using the electrochemical anodization method. A novel growth mechanism of Nb₂O₅ nanotubes has been proposed. Starting from the initial oxidation process, the “multi-point” corrosion of fluoride ions is a key factor in the formation of nanotube arrays. The inner diameter and wall thickness of the nanotubes present a gradually increasing trend with increased dissociative fluorine ion concentration and water content in the electrolyte. With dehydroxylation and lattice recombination, the increased crystallinity of Nb₂O₅ represents a reduction of lattice defects, which effectively facilitates the separation and suppresses the recombination of photo-generated carriers to enhance their catalytic degradation activity. Full article