Search Results (121)

With the depletion of river sand resources and increasing environmental concerns, the development of alternative materials has become an urgent need in the construction industry. Waste concrete and non-waste concrete materials have been widely studied as alternatives to river sand. Although recycled concrete fine aggregates are close to natural sand in terms of mechanical properties, their surface cement adheres and affects the performance of cement, whereas non-recycled concrete fine aggregates perform superiorly in terms of ease of use and compressive properties, but there are challenges of supply stability and standardization. Red mud, as an industrial waste, is a potential alternative material due to its stable supply and high alkaline characteristics. In this paper, a new method is proposed for utilizing the cross-linking reaction between sodium alginate and calcium chloride by the calcium alginate-red mud microsphere preparation technique and the surface modification of red mud to enhance its bonding with cement. The experimental results showed that the mechanical properties of CMC-RM-SiO₂-2.5% were improved by 13.9% compared with those of the benchmark cement mortar, and the encapsulation of red mud by calcium alginate significantly reduced the transfer of hazardous elements in red mud. Full article

Cyclic Solvent Injection (CSI), one of the most promising solvent-based enhanced oil recovery (EOR) methods, has attracted the oil industry’s interest due to its energy efficiency, produced oil quality, and environmental suitability. Previous studies revealed that foamy oil flow is considered as one of the main mechanisms of the CSI process. However, due to the presence of complex high-permeable channels known as wormholes in Post-Cold Heavy Oil Production with Sands (Post-CHOPS) reservoirs, understanding the effect of each operational parameter on the performance of the CSI process in these reservoirs requires a pore-scale investigation of different wormhole configurations. Therefore, in this project, a comprehensive microfluidic experimental investigation into the effect of symmetrical and asymmetrical wormholes during the CSI process has been conducted. A total of 11 tests were designed, considering four different microfluidic systems with various wormhole configurations. Various operational parameters, including solvent type, pressure depletion rate, and the number of cycles, were considered to assess their effects on foamy oil behavior in post-CHOPS reservoirs in the presence of wormholes. The finding revealed that the wormhole configuration plays a crucial role in controlling the oil production behavior. While the presence of the wormhole in a symmetrical design could positively improve oil production, it would restrict oil production in an asymmetrical design. To address this challenge, we used the solvent mixture containing 30% propane that outperformed CO₂, overcame the impact of the asymmetrical wormhole, and increased the total recovery factor by 14% under a 12 kPa/min pressure depletion rate compared to utilizing pure CO₂. Moreover, the results showed that applying a lower pressure depletion rate at 4 kPa/min could recover a slightly higher amount of oil, approximately 2%, during the first cycle compared to tests conducted under higher pressure depletion rates. However, in later cycles, a higher pressure depletion rate at 12 kPa/min significantly improved foamy oil flow quality and, subsequently, heavy oil recovery. The interesting finding, as observed, is the gap difference between the total recovery factor at the end of the cycle and the recovery factor after the first cycle, which increases noticeably with higher pressure depletion rate, increasing from 9.5% under 4 kPa/min to 16% under 12 kPa/min. Full article

The characteristics of interlayer oxidation zones constrain sandstone-type uranium mineralization. This study conducted a quantitative characterization of the interlayer oxidation zones in the uranium-bearing reservoir of the Saihan Formation in the central Wulanchabu Subbasin of the Erlian Basin through sand dispersion system mapping, the analysis of sedimentary debris components, environmentally sensitive parameters, and elemental geochemical characteristics. The formation mechanisms and controlling factors of interlayer oxidation zones were investigated, along with uranium mineralization patterns. Research findings reveal that the sandbodies in the study area primarily consist of red sandstone, yellow sandstone, gray ore-bearing sandstone, and primary gray sandstone, representing strong oxidation zones, weak oxidation zones, transitional zones, and reduction zones, respectively. Although the mineral debris content shows minimal variation among different zones, feldspar dissolution is more prevalent in oxidized zones. During interlayer oxidation, environmentally sensitive parameters exhibit an ascending trend from strong oxidation zones through weak oxidation zones and reduction zones to mineralized transitional zones. Four transition metal elements (Co, Ni, Zn, and Mo) demonstrate enrichment in mineralized transitional zones. The development of interlayer oxidation zones is directly controlled by reservoir heterogeneity and sedimentary environments. Oxidation subzones primarily occur in sandbodies with moderate thickness (40–80 m), sand content ratios of 40%–80%, and 2–10 or 10–18 mudstone barriers (approximately 20 m thick), mainly in braided river channels and channel margin deposits. Reduction zones develop in thicker sandbodies (~100 m) with higher sand contents (~80%), fewer mudstone barriers (2–8 layers), greater thickness (40–80 m), and predominantly channel margin deposits. Transitional zones mainly occur in braided distributary channels and floodplain deposits. When oxygen-bearing uranium fluids infiltrate reservoirs, oxygen reacts with reductants like organic matter, whereFe²⁺ oxidizes to Fe³⁺, S²⁻ reacts with oxygen, and U⁴⁺ oxidizes to U⁶⁺, migrating as uranyl complexes. As oxygen depletes, Fe³⁺ reduces to Fe²⁺, combining with S²⁻ to form pyrite between mineral grains. Uranyl complexes reduce to precipitate as pitchblende, while some U⁴⁺ reacts with SiO₄⁴⁻, forming coffinite, occurring as colloids around quartz debris or pyrite. The concurrent enrichment of certain transition metal elements occurs during this process. Full article

One of the limitations of Cold Heavy Oil Production with Sand (CHOPS) is the low recovery factor (5–15%). To target the remaining 85–95% heavy oil resources, several enhanced oil recovery (EOR) techniques, such as cyclic solvent injection (CSI), have been proposed. Due to its potential success in Canada and elsewhere, this paper reviews the technical and efficiency requirements of CSI EOR in post-CHOPS heavy oil reservoirs. We explain the dominant driving mechanisms of CSI with a focus on the application of CO₂ as a solvent. Limitations of current thermal and non-thermal EOR methods were compared to the CSI in thin oil reservoirs. To complete the assessment, several case studies and lessons learned were included based on the latest laboratory experiments, numerical studies, and CSI pilot/field tests. Specific to thin and shallow heavy oil reservoirs with sand production (e.g., CHOPS), the key to recover incremental oil was found to re-energize depleted reservoirs in a cyclic manner with unexpensive solvents (e.g., CO₂). Regarding the solvent use, laboratory experiences have not been conclusive about what solvent stream could improve oil recovery. To this end, successful field scale CO₂ EOR applications have been reported in several post-CHOPS reservoirs indicating that highly productive wells during primary production might also outperform during a follow up CSI process. Numerical modeling still faces challenges to properly model the main CSI driving mechanisms, including fluid–solvent interaction and the deformation of subsurface reservoirs. Full article

As oil resources continue to be depleted, traditional extraction technologies face significant challenges, and improving remaining oil recovery has become a critical issue in the development of low-permeability oil fields. The study first establishes a stratigraphic framework through a fine stratigraphic correlation of key wells, followed by a comprehensive characterization of the internal arrangement of sand bodies, with a detailed analysis of the distribution of interlayers and the complexity of sand body stacking patterns. Based on field data, including tracer monitoring and water absorption profiles, the distribution of remaining oil is predicted. The results reveal that sandy debris flow deposition plays a key role in the enrichment of remaining oil, particularly considering how its internal structure impacts reservoir connectivity and waterflood efficiency. The sedimentary pattern in the study area is dominated by debris flow deposition, with poor continuity of sand bodies; over 90% of individual sand bodies encountered during horizontal well drilling have a width of less than 60 m. Sand body stacking types are classified into overlapping, splicing, and isolated types, and different stacking types significantly influence reservoir waterflood efficiency and the distribution of remaining oil. The innovation of this study lies not only in the microstructural investigation of sandy debris flow but also in the comprehensive characterization of its strong heterogeneity. By analyzing the internal configuration of sand bodies, sedimentary microfacies, and physical property distributions, this study uncovers how these factors influence the distribution of remaining oil. This approach provides valuable insights for accurately predicting and enhancing remaining oil potential. Full article

Geopolymer mortar is an eco-friendly type of mortar that is mainly made of fly ash, slag, and sand as common precursors. Recently, the availability of these materials has become limited due to the huge increase in geopolymer constructions. This is aligned with the recent demand for recycling construction and demolition waste (CDW). In this study, brick waste (BW), ceramic tile waste (CTW), roof tile waste (RTW), and glass waste (GW) extracted from CDW were prepared in the following two sizes: one equivalent to the traditional geopolymer mortar binder (fly ash and slag) size and the other one equivalent to the sand size. The prepared CDW was used to partially replace the binder or sand to produce high-strength geopolymer mortar (HSGM). The replacements were carried out at rates of 25% and 50% by volume. The variety of mechanical and durability characteristics were measured, including workability, compressive strength, freezing/thawing resistance, sulfate attack, water sorptivity, and water absorption. Three curing conditions were applied for the proposed HSGM in this study, namely, water, heat followed by water, and heat followed by air. The results showed that the compressive strength of all HSGM mixes containing CDW ranged from 24 to 104 MPa. HSGM mixes cured in heat followed by water showed the highest 28-day compressive strengths of 104 MPa (when using 25% BW binder), 84.5 MPa (when using 25% BW fine aggregate), 91.3 MPa (when using 50% BW fine aggregate), 84 MPa (when using 25% CTW binder), and 94 MPa (when using 25% CTW fine aggregate). The findings demonstrated that using BW provided good resistance to freezing/thawing and sulfate attack. The water absorption of HSGM increased by 57.8% when using 50% CTW fine aggregate and decreased by 26.5% when using 50% GW fine aggregate. The highest water sorptivity of HSGM was recorded when 50% CTW fine aggregate was used. The use of CDW in HSGM helps reduce the depletion of natural resources and minimizes waste accumulation, enhancing environmental sustainability. These benefits make HSGM an eco-friendly alternative that promotes circular economy practices. Full article

An important issue in the sustainable development of agricultural engineering today is the use of biogas plants for the production of electricity and heat from the organic waste of agricultural products and other low-quality products, which also contributes to the improvement of environmental safety. Traditional methods for assessing the apparent severity of the Roslynnytsia campaign based on statistics from the dominions proved to be ineffective. A hypothesis was proposed regarding the possibility of estimating the apparent biomass by averaging the indicators of depletion and assessing the CH₄ and CO emissions based on satellite monitoring data. The aim of this work is to create a methodology for preparing a raw material base in united territorial communities to provide them with electrical and thermal energy using biogas plants. The achievement of this goal was based on solving the following tasks: monitoring biomethane emissions in the atmosphere as a result of rotting organic waste, and monitoring carbon monoxide emissions as a result of burning agricultural waste. Experimental studies were conducted using earth satellites on sites with geometric centers in the village of Gaishin in the Pereyaslav united territorial community, the city of Ovruch in the Zhytomyr region, the Oleshkovsky Sands National Park in the Kherson region (Ukraine), and the city of Jüterbog, which is located in the state of Brandenburg and is part of the Teltow-Fläming district (Germany). The most significant results of this research involve the methodology for the preparation of the raw material base in the united territorial communities for the production of biogas, based on indirect measurements of methane and carbon dioxide emissions using the process of remote sensing. Based on the use of the proposed scientific and methodological apparatus, it was found that the location of the territory with the center in the village of Gaishin has better prospects for collecting plant raw materials for biogas production than the location of the territorial district with the center in the city of Ovruch, the emissions in which are significantly lower. From March 2020–August 2023, a higher CO concentration was recorded on average by 0.0009 mol/m², which is explained precisely by crop growing practices. In addition, as a result of the conducted studies, for the considered emissions of methane and carbon monoxide for monitoring promising raw materials, carbon monoxide has the best prospects, since methane emissions can also be caused by anthropogenic factors. Thus, in the desert (Oleshkivskie Pisky), large methane emissions were recorded throughout the year which could not be explained by crop growing practices or the livestock industry. Full article

Echinops gmelinii Turcz. is a winter annual species of the Asteraceae family, distributed in sandy areas of northern China, and is crucial for wind avoidance and sand fixation. To understand the inter- and intra-annual population dynamics of E. gmelinii in its cold desert habitats, we conducted long- and short-term demographic studies to investigate the timing of germination, seedling survival, soil seed bank and seed longevity of natural populations on the fringe of the Tengger Desert. Cypselae (seeds) of E. gmelinii can germinate in both July and August, but this process is heavily affected by precipitation amount and timing. Early emerging seedlings died rapidly under the high temperature and drought stress, before completing their life cycle. Later emerging seedlings could survive to complete their life cycle due to more suitable conditions for plant growth. In short, seedling survival dynamics were affected by precipitation distribution, and the survival rates were low (<4%). In addition, we found that the high seed production (1328 seeds·m⁻²) of E. gmelinii depended mainly on the production of seeds by individuals rather than high plant density (35 individuals·m⁻²). The contribution of newly ripened seeds and soil seed banks to seedlings emergence was 57.7% and 42.3%, respectively. Thus, only a small amount of the newly matured seeds was depleted during the year. Only 23.6% of the annual seeds germinated, and the remainder accumulated in a persistent soil seed bank (seed longevity was ≥2 y). The amount and timing of precipitation distribution were the key factors affecting the population dynamics of E. gmelinii in our study area. This species can cope with the uncertain precipitation patterns though a “cautious” germination strategy, varying the timing of germination and forming a persistent soil seed bank. Full article

The incorporation of desert sand-mineral admixture improves the abrasion resistance of concrete. To prolong the service life of assembled concrete channels and mitigate the depletion of river sand resources, the effects of fly ash (FA), silica fume (SF), desert sand (DS), and basalt fiber (BF) on the mechanical properties and the abrasion resistance of concrete were examined, alongside an analysis of their microstructures to elucidate the underlying mechanisms of influence. The results indicated that the abrasion resistance strength of concrete mixed with 10% FA and 0.05% BF alone increased by 80.19% and 81.59%, respectively, compared with ordinary concrete (OC). When SF was added to the concrete at a dosage of 10%, it improved the mechanical properties and the abrasion resistance of the concrete. Furthermore, adding SF resulted in a 12.50% increase in compressive strength and a 12.27% increase in abrasion resistance strength compared to OC. The addition of DS did not significantly enhance the concrete’s abrasion resistance. The combination of ingredients for desert sand concrete (DSC) that provides excellent abrasion resistance was determined using an orthogonal experiment. The optimal mixture consisted of 10% FA content, 10% SF content, 40% DS content, and 0.05% BF content, which increased the abrasion resistance strength by 112.95% compared to OC. Through microscopic analysis, it is found that the width of the interfacial transition zone (ITZ) is an important factor in determining the abrasion resistance of concrete, and a narrower ITZ enhances the concrete’s abrasion resistance. The study’s findings could function as a theoretical reference for the engineering design of DSC. Full article

In recent years, research on self-compacting concrete (SCC) has gradually shifted towards high-strength development, while high-strength self-compacting concrete has been widely used in applications such as precast bridge components and high-rise building projects. Using manufactured sand as an aggregate can effectively address the challenges posed by the depletion of natural sand resources. This study optimized the mix design for high-strength self-compacting concrete with manufactured sand (MSH-SCC) and explored the effects of the fine aggregate replacement rate, sand ratio, and maximum particle size of coarse aggregate on the performance of MSH-SCC. The results indicated that the optimized mix designs for various strength levels met the performance requirements. The fine aggregate replacement rate and the maximum nominal aggregate size significantly affected the workability of the concrete, while variations in the sand ratio had a smaller impact. The yield stress of the MSH-SCC showed a positive correlation with the fine aggregate replacement rate and the maximum nominal aggregate size, whereas the plastic viscosity reached its maximum value under specific conditions. Additionally, the mix design parameters had a limited effect on the mechanical strength of the MSH-SCC. This study provides a scientific basis for the design of high-strength self-compacting concrete with manufactured sand, contributing to the promotion of manufactured sand use and advancing low-carbon development in the construction industry. Full article

The sand–gravel brine deposit in the Mahai Basin is a newly discovered large-scale potassium–bearing brine deposit. The potassium–bearing brine is primarily found at depths exceeding 150 m within the porous alluvial and fluvial sand–gravel reservoir of the Middle to Lower Pleistocene. This deposit is characterized by a relatively shallow water table, moderate–to–strong aquifer productivity, high salinity, and a KCl content that meets the conditions for exploitation, with the advantage of reduced salt crystallization during well mining, making it a potential reserve base for potash development. A geochemical analysis of the sand–gravel brine revealed consistent trends for the major ions K⁺, Na⁺, Mg²⁺, Cl⁻, and SO₄²⁻ along the east–west axis of the alluvial fan, while Ca²⁺ showed an opposite trend compared to Mg²⁺. Along the exploration lines from north to south, the concentrations of the main ions gradually increase. The brine is enriched in Na⁺ and Cl⁻ ions, while SO₄²⁻ and HCO₃⁻ are depleted. In the K⁺-Na⁺-Mg²⁺/Cl⁻-H₂O (25 °C) quaternary phase diagram, the brine falls within the halite stability field, with the hydrochemical type classified as chloride type. The brine coefficient characteristics indicate a multi-source origin involving residual evaporation, salt rock leaching, and metamorphic sedimentary brine. Comparison studies of the ionic composition and isotopic signatures (δD, δ¹⁸O, δ³⁷Cl, and δ⁷Li) of deep sand–gravel brines in the study area with interstitial and confined brines in the southern depression suggest similar geochemical characteristics between them. The genetic analysis of the deposit proposes that during the basin tectonic evolution, the potassium-rich interstitial and confined brines originally located in the southern depression of the Mahai Basin were displaced under compressional forces and migrated northward as the depositional center shifted, eventually backfilling into the loose alluvial and fluvial sand and gravel reservoirs at the front of the Saishiteng Mountains, forming the deep sand–gravel brine deposits in the foreland. Full article

The security of water resources in the desert steppe ecosystem faces threats due to large-scale vegetation restoration. Dynamic changes in soil moisture result from the interplay of precipitation replenishment and evapotranspiration depletion, both directly regulated by vegetation and soil. To achieve sustainable vegetation restoration, understanding the quantifiable impacts of precipitation, evapotranspiration, soil, and vegetation on spatiotemporal soil moisture dynamics is crucial. However, these effects remain insufficiently understood. In this study, against the background of an extreme drought from 2020 to 2022, four typical herbaceous plant communities—Agropyron mongolicum, Sophora alopecuroides, Stipa breviflora, and Achnatherum splendens—were selected for investigation in Yanchi County, Ningxia Province, Northwest China. We analyzed dynamic changes in soil moisture at 0–120 cm during depletion, recovery, and stability periods, quantifying the relative contributions of precipitation, evapotranspiration, soil clay/sand ratio (C/S), and biomass to soil moisture dynamics. The results showed that the 0–120 cm soil moisture of the four plant communities in the depletion, recovery, and stability periods decreased from 7.38% to 6.81%, 11.22% to 8.08%, and 11.70% to 5.84%, respectively. In terms of relative importance, precipitation and evapotranspiration accounted for 25% to 50% and 23.6% to 39.6% of the total explanation for the soil moisture in each plant community, respectively. C/S primarily influenced soil moisture in the S. alopecuroides community, demonstrating a significant positive correlation with soil moisture and accounting for 49.1% of the total explanation. Biomass mainly affected soil moisture in the A. mongolicum, S. breviflora, and A. splendens communities and had a significant negative correlation with soil moisture, accounting for 5.7%, 13.1%, and 9.8% of the total interpretation, respectively. The continuous extreme drought caused the soil moisture deficit to extend from the shallow to the deep layers. The effects of C/S and biomass on soil moisture occurred in leguminous and gramineous communities, respectively. Full article

Accurate estimation of in-situ stresses is a critical parameter for geo-mechanical modelling. In-situ stresses are estimated in the field from logs and frac tests. Laboratory tests are performed with cored material to estimate horizontal stress changes under defined boundary conditions to complement field data. Horizontal stress path coefficient is used to estimate a change in in-situ stresses as the reservoir undergoes depletion or injection. Uniaxial Strain boundary conditions are representative of far field stress state. The laboratory data provides the change in horizontal stress with a change in pore pressure. It is used to complement the field data acquisition of absolute stress values to predict the value of total stresses. This experimental study provides a novel method of simulating geological compaction for fabricating representative samples from unconsolidated sands. It investigates the variability of horizontal stress path coefficient as a function of changing pore pressure (depressurization and re-pressurization) in unconsolidated sandstone reservoirs. Synthetic sandstones samples were made from sand packs by consolidating them under an isostatic stress path at ambient pore pressure. After getting to initial reservoir conditions, a series of pore pressure depletion and injection tests with varying magnitudes (injection and depletion) were performed to study the effects of stress path direction and associated hysteresis. The magnitude of the stress path coefficient under depletion is lower than that under injection for the first load-unload cycle. In subsequent load-unload cycles, the stress path coefficient values remain constant until the sample is depleted to a new level of pore pressure. A Modified Cam Clay model is fit to the data to map the expansion of the yield surface and quantify the model parameters. Application of this research includes accurate prediction of changes in-situ stresses during depletion and injection stress paths for simulating unconsolidated reservoirs behavior under fluid injection or further depletion. Full article

This study investigated the hydrogeological characteristics and groundwater dynamics in the shallow aquifer zones of inner Guwahati city, Assam, India. Sixteen dug wells spread across the city, specifically used for domestic purposes, were selected for this study. Additionally, ten wells were selected for trend analysis. The borehole lithology reveals predominant compositions of clay, sand, and granules, with thin clay cappings indicating significant groundwater potential. Depth-to-water level analysis revealed varying water levels across the study area, with shallow levels in the northern and western regions and gradual deepening toward the eastern and southern parts. The groundwater flow directions show nonuniform patterns and reflect the influence of topography and domestic pumping in urban residential zones. The general groundwater flow direction is toward the Brahmaputra River. Trends in groundwater level, assessed using the Mann–Kendall test and Sen’s slope, suggest both falling and rising trends across different locations, indicating complex groundwater dynamics influenced by factors such as recharge, extraction, and topography. However, the long-term rainfall data indicate no significant trend over the studied period, suggesting limited natural influence on groundwater level trends. These findings may contribute to a comprehensive understanding of groundwater dynamics in the study area and are essential for sustainable water resource management and mitigation of groundwater depletion risks. Full article

Hydrogen is increasingly recognized as a viable solution to meet the growing global energy demand, making large-scale hydrogen storage essential for successfully realizing a full-scale hydrogen economy. Geological formations, such as depleted oil and gas reservoirs, salt caverns, and aquifers, have been identified as potential storage options. Additionally, unconventional methods like manufactured lined rock caverns and abandoned coal mines are gaining interest. This study introduces polymerized sulfur concrete (PSC) as a promising alternative to replace the current construction systems, which rely on Portland cement concrete and lining materials like stainless steel or polypropylene plastic liners. The paper presents the formulation of PSC, optimization of its compositional design, and evaluation of its physico-mechanical-chemical properties. The results demonstrate that PSC offers excellent mechanical strength, chemical resistance, and low permeability, making it highly suitable for underground hydrogen storage in lined rock caverns. The results showed that the manufactured PSC exhibits excellent physicochemical properties in terms of compressive strength (35–58 MPa), density (2.277–2.488 g/cm³), setting time (30–60 min), curing time (24 h), air content (4–8%), moisture absorption potential (0.17–0.3%), maximum volumetric shrinkage (1.69–2.0%), and maximum service temperature (85–90 °C). Moreover, the PSC is nonconductive and classified with zero flame spread classification and fuel contribution. In addition, the SPC was found to be durable in harsh environmental conditions involving pressure, humidity, and pH variations. It is also capable of resisting corrosive environments. In addition, the statistical modeling indicates that an overall mixture proportion of 32.5 wt.% polymerized sulfur, 32.5 wt.% dune sands, 17.5 wt. % LFS, and 17.5 wt.% GGBFS appear optimal for density values ranging from 2.43 to 2.44 g/cm³ and compressive strength ranging from 52.0 to 53.2 MPa, indicating that the PSC can sustain formation pressure up to about 5.3 km below the ground surface. Therefore, by addressing the critical limitations of traditional materials, PSC proves to be a durable, environmentally sustainable solution for lined rock caverns, reducing the risk of hydrogen leakage and ensuring the integrity of storage systems. Full article