Search Results (12)

This study investigates the synthesis and characterization of SiO₂-Gd₂O₃-Eu₂O₃ nanomaterials. The sol–gel method was employed using tetraethoxysilane (TEOS), gadolinium nitrate, and europium nitrate as precursors. The influence of rare earth oxide concentration on the hydrolysis kinetics and activation energy was evaluated. Additionally, the acid-base properties of the synthesized materials were examined using the Hammett indicator adsorption method. The results revealed that the addition of Gd₂O₃ and Eu₂O₃ oxides to the system accelerated the hydrolysis process and reduced the activation energy. The formation of a layered structure, consisting of a central Si(OH)₄ nucleus, a Si-O-Si polymer layer, and hydrated metal ion layers, was observed. The acid-base properties of the synthesized nanomaterials were influenced by the drying method and the composition of the system. The findings provide valuable insights into the synthesis and properties of SiO₂-Gd₂O₃-Eu₂O₃ nanomaterials, which have potential applications in various fields such as optoelectronics and catalysis. Full article

Rare earths, scandium, yttrium, and the fifteen lanthanoids from lanthanum to lutetium, are classified as critical metals because of their ubiquity in daily life. They are present in magnets in cars, especially electric cars; green electricity generating systems and computers; in steel manufacturing; in glass and light emission materials especially for safety lighting and lasers; in exhaust emission catalysts and supports; catalysts in artificial rubber production; in agriculture and animal husbandry; in health and especially cancer diagnosis and treatment; and in a variety of materials and electronic products essential to modern living. They have the potential to replace toxic chromates for corrosion inhibition, in magnetic refrigeration, a variety of new materials, and their role in agriculture may expand. This review examines their role in sustainability, the environment, recycling, corrosion inhibition, crop production, animal feedstocks, catalysis, health, and materials, as well as considering future uses. Full article

The exponential growth of electronic waste (e-waste) has raised significant environmental concerns, with projections indicating a surge to 74.7 million metric tons of e-waste generated by 2030. Waste printed circuit boards (WPCBs), constituting approximately 10% of all e-waste, are particularly intriguing due to their high content of valuable metals and rare earth elements. However, the presence of hazardous elements necessitates sustainable recycling strategies. This review explores innovative approaches to sustainable metal nanoparticle synthesis from WPCBs. Efficient metal recovery from WPCBs begins with disassembly and the utilization of advanced equipment for optimal separation. Various pretreatment techniques, including selective leaching and magnetic separation, enhance metal recovery efficiency. Green recovery systems such as biohydrometallurgy offer eco-friendly alternatives, with high selectivity. Converting metal ions into nanoparticles involves concentration and transformation methods like chemical precipitation, electrowinning, and dialysis. These methods are vital for transforming recovered metal ions into valuable nanoparticles, promoting sustainable resource utilization and eco-friendly e-waste recycling. Sustainable green synthesis methods utilizing natural sources, including microorganisms and plants, are discussed, with a focus on their applications in producing well-defined nanoparticles. Nanoparticles derived from WPCBs find valuable applications in drug delivery, microelectronics, antimicrobial materials, environmental remediation, diagnostics, catalysis, agriculture, etc. They contribute to eco-friendly wastewater treatment, photocatalysis, protective coatings, and biomedicine. The important implications of this review lie in its identification of sustainable metal nanoparticle synthesis from WPCBs as a pivotal solution to e-waste environmental concerns, paving the way for eco-friendly recycling practices and the supply of valuable materials for diverse industrial applications. Full article

In this paper, with the help of the method of composite materials science, parallel synthesis and high-throughput screening were used to prepare gas sensors with different molar ratios of rare earths and precious metals modified In₂O₃, which could be used to monitor and warn the early leakage of gasoline and diesel. Through high-throughput screening, it is found that the effect of rare earth metal modification on gas sensitivity improvement is better than other metals, especially 0.5 mol% Gd modified In₂O₃ (Gd_0.5In) gas sensor has a high response to 100 ppm gasoline (R_a/R_g = 6.1) and diesel (R_a/R_g = 5) volatiles at 250 °C. Compared with the existing literature, the sensor has low detection concentration and suitable stability. This is mainly due to the alteration of surface chemisorption oxygen caused by the catalysis and modification of rare earth itself. Full article

The need for environmentally benign portable energy storage drives research on organic batteries and catalytic systems. These systems are a promising replacement for commonly used energy storage devices that rely on limited resources such as lithium and rare earth metals. The redox-active TEMPO (2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) fragment is a popular component of organic systems, as its benefits include remarkable electrochemical performance and decent physical properties. TEMPO is also known to be an efficient catalyst for alcohol oxidation, oxygen reduction, and various complex organic reactions. It can be attached to various aliphatic and conductive polymers to form high-loading catalysis systems. The performance and efficiency of TEMPO-containing materials strongly depend on the molecular structure, and thus rational design of such compounds is vital for successful implementation. We discuss synthetic approaches for producing electroactive polymers based on conductive and non-conductive backbones with organic radical substituents, fundamental aspects of electrochemistry of such materials, and their application in energy storage devices, such as batteries, redox-flow cells, and electrocatalytic systems. We compare the performance of the materials with different architectures, providing an overview of diverse charge interactions for hybrid materials, and presenting promising research opportunities for the future of this area. Full article

Rare earth metal oxides (REMOs) have gained considerable attention in recent years owing to their distinctive properties and potential applications in electronic devices and catalysts. Particularly, cerium dioxide (CeO₂), also known as ceria, has emerged as an interesting material in a wide variety of industrial, technological, and medical applications. Ceria can be synthesized with various morphologies, including rods, cubes, wires, tubes, and spheres. This comprehensive review offers valuable perceptions into the crystal structure, fundamental properties, and reaction mechanisms that govern the well-established surface-assisted reactions over ceria. The activity, selectivity, and stability of ceria, either as a stand-alone catalyst or as supports for other metals, are frequently ascribed to its strong interactions with the adsorbates and its facile redox cycle. Doping of ceria with transition metals is a common strategy to modify the characteristics and to fine-tune its reactive properties. DFT-derived chemical mechanisms are surveyed and presented in light of pertinent experimental findings. Finally, the effect of surface termination on catalysis by ceria is also highlighted. Full article

Rare earth elements (REEs) are strategic materials widely used in different applications from Information and Communication Technologies (ICT) to catalysis, which are expected to grow more in the future. In order to reduce the impact of market price and reduce the environmental effect from soil extraction, recovery/purification strategies should be exploited. This paper presents a combined acid-leaching/oxalate precipitation process to recover lanthanum from spent FCC catalyst using nitric acid. Preferred to hydrochloric and sulphuric acid (preliminary assessed), HNO₃ showed a good capability to completely leach lanthanum. The combination with an oxalate precipitation step allowed demonstrating that a highly pure (>98% w/w) lanthanum solid can be recovered, with a neglectable amount of poisoning metals (Ni, V) contained into the spent catalyst. This could open a reliable industrial perspective to recover and purify REE in the view of a sustainable recycling strategy. Full article

Most of the commonly used Ionic Liquids (ILs) contain bulky organic cations with suitable anions. With our COMPLET (Concept of Melting Point Lowering due to Ethoxylation), we follow a different approach. We use simple, low-toxic, cheap, and commercially available anions of the type C_x(EO)_yCH₂COO^– to liquefy presumably any simple metal ion, independently of its charge. In the simplest case, the cation can be sodium or lithium, but synthesis of Ionic Liquids is also possible with cations of higher valences such as transition or rare earth metals. Anions with longer alkyl chains are surface active and form surface active ionic liquids (SAILs), which combine properties of ionic and nonionic surfactants at room temperature. They show significant structuring even in their pure state, i.e., in the absence of water or any other added solvent. This approach offers new application domains that go far beyond the common real or hypothetical use of classical Ionic Liquids. Possible applications include the separation of rare earth metals, the use as interesting media for metal catalysis, or the synthesis of completely new materials (for example, in analogy to metal organic frameworks). Full article

We review the solution-based synthesis routes to cerium oxide materials where one or more elements are included in place of a proportion of the cerium, i.e., substitution of cerium is performed. The focus is on the solvothermal method, where reagents are heated above the boiling point of the solvent to induce crystallisation directly from the solution. This yields unusual compositions with crystal morphology often on the nanoscale. Chemical elements from all parts of the periodic table are considered, from transition metals to main group elements and the rare earths, including isovalent and aliovalent cations, and surveyed using the literature published in the past ten years. We illustrate the versatility of this synthesis method to allow the formation of functional materials with applications in contemporary applications such as heterogeneous catalysis, electrodes for solid oxide fuel cells, photocatalysis, luminescence and biomedicine. We pick out emerging trends towards control of crystal habit by use of non-aqueous solvents and solution additives and identify challenges still remaining, including in detailed structural characterisation, the understanding of crystallisation mechanisms and the scale-up of synthesis. Full article

Herein, silicon-protected, ortho-methylated hydroxy-pyridines were reported as initiators in 2-aminoalkoxy-bis(phenolate)yttrium complexes for rare earth metal-mediated group-transfer polymerization (REM-GTP) of Michael-type monomers. To introduce these initiators, C−H bond activation was performed by reacting [(ONOO)^tBuY(X)(thf)] (X = CH₂TMS, thf = tetrahydrofuran) with tert-butyl-dimethyl-silyl-functionalized α-methylpyridine to obtain the complex [(ONOO^tBuY(X)(thf)] (X = 4-(4′-(((tert-butyldimethylsilyl)oxy)methyl)phenyl)-2,6-di-methylpyridine). These initiators served as functional end-groups in polymers produced via REM-GTP. In this contribution, homopolymers of 2-vinylpyridine (2VP) and diethyl vinyl phosphonate (DEVP) were produced. Activity studies and end-group analysis via mass spectrometry, size-exclusion chromatography (SEC) and NMR spectroscopy were performed to reveal the initiator efficiency, the catalyst activity towards both monomers as well as the initiation mechanism of this initiator in contrast to commonly used alkyl initiators. In addition, 2D NMR studies were used to further confirm the end-group integrity of the polymers. For all polymers, different deprotection routes were evaluated to obtain hydroxyl-terminated poly(2-vinylpyridine) (P2VP) and poly(diethyl vinyl phosphonate) (PDEVP). Such hydroxyl groups bear the potential to act as anchoring points for small bioactive molecules, for post-polymerization functionalization or as macroinitiators for further polymerizations. Full article

A simple, efficient, and environmentally benign approach for the synthesis of β-amino alcohols is herein described. YCl₃ efficiently carried out the ring opening of epoxides by amines to produce β-amino alcohols under solvent-free conditions at room temperature. This catalytic approach is very effective, with several aromatic and aliphatic oxiranes and amines. A mere 1 mol % concentration of YCl₃ is enough to deliver β-amino alcohols in good to excellent yields with high regioselectivity. Full article

Catalytic asymmetric Corey-Chaykovsky epoxidation of various ketones with dimethyloxosulfonium methylide using a heterobimetallic La-Li₃-BINOL complex (LLB) is described. The reaction proceeded smoothly at room temperature in the presence of achiral phosphine oxide additives, and 2,2-disubstituted terminal epoxides were obtained in high enantioselectivity (97%–91% ee) and yield ( > 99%–88%) from a broad range of methyl ketones with 1–5 mol% catalyst loading. Enantioselectivity was strongly dependent on the steric hindrance, and other ketones, such as ethyl ketones and propyl ketones resulted in slightly lower enantioselectivity (88%–67% ee). Full article