Search Results (23)

Higher olefins are a class of alkenes widely used as intermediates in the production of essential consumer and industrial products. This radiolabel disposition and partial mass balance study investigated the distribution and excretion of four ¹⁴C-radiolabelled alpha higher olefins (i.e., 1-octene, 1-decene, 1-hexadecene, and 1-eicosene) in male Wistar rats following a single oral dose (100 mg/kg). Blood, liver, kidney, adipose tissue, urine, and faeces were collected and analysed for total ¹⁴C-derived radioactivity. Urinary elimination was rapid, with approximately 70% and 90% of total radioactivity recovered in urinary excreted within 24 and 48 h, respectively. Excretion patterns showed a clear chain-length-dependent trend: shorter-chain olefins (C8, C10) exhibited higher urinary excretion, indicating greater systemic absorption, while longer-chain olefins (C16, C20) were primarily eliminated via faeces, suggesting limited intestinal uptake. Tissue distribution was minimal in blood, liver, and kidney, but adipose tissue retention increased with chain length. Total recovery of administered radioactivity in the analysed matrices was low, ranging from 17% to 60%. Importantly, because exhaled ¹⁴CO₂ and volatile parent compounds were not captured, the missing fraction cannot be quantified and the balance cannot be considered closed. All in all, the current study describes the partial disposition of higher olefins and highlights the influence of molecular size and lipophilicity on the biological fat, though further studies are required to fully characterise their metabolic profile and total elimination kinetics. Full article

Food irradiation is a scientifically validated method for improving food safety and shelf life, yet public acceptance remains limited due to persistent misconceptions. This study investigates consumer perceptions of irradiated food in the Abai region of Kazakhstan, an area historically affected by radiation exposure, though this context is not explicitly addressed. A structured questionnaire was administered to 420 adult residents across urban and rural districts, collecting data on familiarity, knowledge, perceived risks and benefits, willingness to consume, and influencing factors such as trust in authorities and preference for natural foods. Descriptive and inferential statistical analyses, including Pearson correlation and Duncan’s test, were employed. Results reveal widespread knowledge gaps—only 20% correctly rejected the myth that irradiated food is radioactive—yet nearly half of respondents expressed willingness to purchase such products. Perceived health risk was high across all food categories, especially infant food, but this did not consistently predict avoidance. Demographic variables such as education and age influenced perceptions of necessity, while gender and trust in authorities had minimal impact. The study concludes that although consumer knowledge is low, moderate openness exists toward irradiated food, suggesting that public education and clear communication could play a pivotal role in building acceptance for this food safety intervention. Full article

The present study examined how consumer awareness of seafood safety in different countries influences their concerns about radioactivity in seafood, focusing on the moderating impact of interest in food safety issues. Data from the 2021 Food Consumption Behavior Survey conducted by the 2021 Korea Rural Economic Institute were analyzed. The survey targeted 3318 primary food purchasers in households with members aged 19–75 years old. Lower safety awareness of Japanese seafood and European seafood correlated with higher levels of concern about radioactivity. Additionally, regarding the moderating effect of interest in food safety issues, lower safety awareness of European seafood correlated with greater concern about radioactivity. However, a positive moderating effect of interest in food safety issues was observed for the interaction between safety awareness of European seafood and concerns about radioactivity in seafood. The findings suggest that consumers’ safety awareness about seafood was associated with their concerns about radioactivity in seafood. Thus, it is necessary to reduce consumers’ concerns about radioactivity and elevate their safety awareness of seafood. The strategies would be suggested to elevate consumers’ perception of seafood safety awareness. The seafood industry invests in the production process to enhance the safety of seafood. The government applies new technologies to analyze seafood safety and radioactivity levels in seafood, which, thus, assures consumers’ seafood consumption. Full article

This article systematizes research data on the natural radioactivity of fossil coals and of ash and slag waste from coal power engineering in the context of radioecological safety. The relatively low energy efficiency of the operating thermal power plants in Kazakhstan has a significant impact on the environment. In addition to natural radioactive elements (U²³⁸ and its decay products, Th²³² and its decay products, and K⁴⁰), coal combustion waste also contains a significant amount of trace elements that have a negative impact on the atmosphere and the environment. In Kazakhstan, about 67% of electricity is generated by coal power engineering. However, in the process of burning coals, radioactive nuclides are concentrated in ash and slag waste. In the fuel power industry of Kazakhstan, high-ash coals with low concentrations of radionuclides are mainly used. The average contents of uranium and thorium are close to the clarke values. The natural radioactivity of coal and of ash and slag waste from Karaganda GRES-1, which consumes Ekibastuz coals with an ash content of 32–39%, was studied. The average values of the specific activities of U²³⁸, Th²³², and K⁴⁰ in 25 coal samples were 27.9 Bq/kg, 19.5 Bq/kg, and 81.0 Bq/kg, respectively. In ash and slag waste, the concentrations of these radionuclides were several times higher. The concentration coefficients of the studied radionuclides varied within the ranges of 4.7–5.5 for U, 3.8–5.7 for Th, and 4.2–8.6 for K⁴⁰. It was established that during coal combustion in thermal power plants, due to carbon combustion and the removal of volatile compounds, not only natural radionuclides but also many microelements, including toxic ones (Mn, Cd, Ni, Co, Zn, etc.), are concentrated in the ash. Full article

This paper presents the results of a multidisciplinary study with the aim of assessing the potential combined risk from consuming locally harvested food products in the Euro-Arctic region of Norway, Finland, and Russia. The three important contaminant groups—radioactive substances, heavy metals, and persistent organic pollutants (POPs)—were measured in food samples such as berries, mushrooms, fish, birds, reindeer, and moose; they were sampled in 2013–2015. To assess the combined pollution levels and investigate the trends, similarities, and variations between different contaminant groups, subsequent multivariate statistical analysis was performed. The results showed that, in general, the levels of radioactive substances, toxic elements, and POPs were below the permitted EU maximum content in food products. However, statistical analysis revealed some correlations, similarities, and peculiarities between the accumulation of different contaminants in various species, which allowed for a better understanding of the mechanisms of accumulation and interaction between different contaminant groups. It also gave a better insight into the possible added risks and helped pinpoint species that could serve as reference markers for the accumulation of different contaminants in food. Mushrooms, fish, and reindeer were found to be important markers in the combined risk assessments for the contents of metals and radioactive substances. Further research, as well as the development of methodologies for combined assessments, are recommended. Full article

Ultra-low-radioactivity titanium alloys are promising materials for the manufacture of low-background detectors which are being developed for experiments in astroparticle physics and neutrino astrophysics. Structural titanium is manufactured on an industrial scale from titanium sponge. The ultra-low-background titanium sponge can be produced on an industrial scale with a contamination level of less than 1 mBq/kg of uranium and thorium isotopes. The pathways of contaminants during the industrial production of structural titanium were analyzed. The measurements were carried out using two methods: inductively coupled plasma mass spectroscopy (ICP-MS) and gamma spectroscopy using high-purity germanium detectors (HPGes). It was shown that the level of contamination with radioactive impurities does not increase during the remelting of titanium sponge and mechanical processing. We examined titanium alloy samples obtained at different stages of titanium production, namely an electrode compaction, a vacuum arc remelting with a consumable electrode, and a cold rolling of titanium sheets. We found out that all doped samples that were studied would be a source of uranium and thorium contamination in the final titanium alloys. It has been established that the only product allowed obtaining ultra-low-background titanium was the commercial VT1-00 alloy, which is manufactured without master alloys addition. The master alloys in the titanium production process were found cause U/Th contamination. Full article

There is widespread use of nuclear radiation for medical imagery and treatments. Worldwide, almost 40 million treatments are performed per year. There are also applications of radiation sources in other commercial fields, e.g., for weld inspection or steelmaking processes, in consumer products, in the food industry, and in agriculture. The large number of neutrons generated in a fusion reactor such as DEMO could potentially contribute to the production of the required radioactive isotopes. The associated commercial value of these isotopes could mitigate the capital investments and operating costs of a large fusion plant. The potential of producing various radioactive isotopes was studied from material pieces arranged inside a DEMO equatorial port plug. In this location, they are exposed to an intensive neutron spectrum suitable for a high isotope production rate. For this purpose, the full 3D geometry of one DEMO toroidal sector with an irradiation chamber in the equatorial port plug was modeled with an MCNP code to perform neutron transport simulations. Subsequent activation calculations provide detailed information on the quality and composition of the produced radioactive isotopes. The technical feasibility and the commercial potential of the production of various isotopes in the DEMO port are reported. Full article

Over 10 years have passed since the Fukushima Daiichi Nuclear Power Plant accident. This study verifies the efficacy of longitudinal regulation on internal exposure doses and analyzes food group contributions to radiation doses using accumulated monitoring test results. The committed effective doses in 10,000 virtual persons from fiscal year (FY) 2012 to 2021, with and without regulation, were estimated as products of radioactivity concentrations randomly sampled from the test results, food intake, and dose coefficient. The distributed values of food intake rather than a mean value in dose estimation were assumed to reflect food intake variations and avoid underestimation of internal exposure doses for high-intake consumers. Furthermore, the ingestion of radioactive cesium from the calculation was analyzed per food group. The 95th percentile of the internal exposure dose (the dose of a “representative person”) was less than 1 mSv/year in both FYs. The regulation effect was substantial in FY 2012, and no noticeable difference in radiation doses was found between the regulation and no regulation conditions after FY 2016. Internal exposure doses decreased until approximately FY 2016 and then remained constant. It was also shown that not only radioactivity concentration but also food intake is a major factor affecting cesium intake. In summary, it was confirmed that Japan had ensured food safety regarding radioactive materials. Full article

The possibility of enrichment and radioactivity reduction of zirconium concentrate obtained at the Obukhovsky mining and processing plant, located in the North Kazakhstan region, was investigated. The zircon concentrate was enriched and deactivated by dry magnetic separation and centrifugal air separation. The elements distribution over the grain surface of the obtained fractions was studied and the particle size distribution was determined by energy dispersive X-ray spectroscopy. The characteristics of the initial zircon concentrate were determined. The average particle size was 70 µm, the bulk density was 2.21 g/cm³, the true density was 4.05 g/cm³, the activity was 10.3 ± 0.6 kBq/kg, and the ZrO2 content was 44.85 wt.%. Dry magnetic separation was carried out at a magnetic induction value of 1.3 T in the separator working area and a feed rate of 5 g/min. Centrifugal air separation was carried out using a rotary classifier at rotor speeds of 3000, 980, and 600 rpm, consuming 2000 Nm³ of air per hour and a concentrate flow of 20 kg/h. The scheme of zircon concentrate processing to produce three final products was proposed. The first is the zircon concentrate having a low activity (ZrO₂ content = 55.4 wt.%, P = 5.8 ± 0.6 kBq/kg). The second is the titanium-containing fraction having a low zirconium content (ZrO₂ content = 17.7 wt.%, P = 14.2 ± 0.6 kBq/kg). The third is the concentrate having a considerable zirconium content and high activity (ZrO₂ content = 23.5 wt.%, P = 12.8 ± 0.6 kBq/kg). Full article

Although antimicrobials are generally found in trace amounts in meat, the human health risk they bear cannot be ignored. With the ultimate aim of making a better assessment of consumer exposure, this study explored the effects of pan cooking on sulfonamides and tetracyclines in meat. Screening of these antimicrobials in cooked meat was first performed by the European Union Reference Laboratory on the basis of HPLC-MS/MS analyses. A proof of concept approach using radiolabeling was then carried out on the most cooking-sensitive antimicrobial—sulfamethoxazole—to assess if a thermal degradation could explain the observed cooking losses. Degradation products were detected thanks to separation by HPLC and monitoring by online radioactivity detection. HPLC-Orbitrap HRMS analyses completed by 1D and 2D NMR experiments allowed the structural characterization of these degradation compounds. This study revealed that cooking could induce significant antimicrobial losses of up to 45% for sulfamethoxazole. Six potential degradation products of ¹⁴C-sulfamethoxazole were detected in cooked meat, and a thermal degradation pattern was proposed. This study highlights the importance of considering the cooking step in chemical risk assessment procedures and its impact on the level of chemical contaminants in meat and on the formation of potentially toxic breakdown compounds. Full article

After the accident at the Fukushima Daiichi Nuclear Power Station, food products from the areas affected by the accident suffered reputational damage worldwide. Therefore, the present study aimed to identify the factors associated with people refraining from purchasing foods produced in affected areas to avoid radioactive materials. The study also aimed to clarify the time trends for the avoidance of foods produced in Fukushima Prefecture. We used data from “A survey on consumer awareness of reputational damages” conducted by the Japanese Consumers Customer Agency and implemented statistical analysis. Even if the year since the accident differed, “living with children”, “knowing detailed information about food inspections”, and “not being able to accept radiation risk even if the level is below the standard” were commonly associated. Not only did this study reveal that some people’s risk perceptions are fixed even when new knowledge is provided, but it also suggests that the implementation of food inspection can promote reputational damage. Additionally, the avoidance of Fukushima food products was found to decrease as time passed after the Fukushima accident. The results of this study may help develop countermeasures against reputational damage to food products after future nuclear disasters. Full article

The emergence of online purchase platforms makes products containing radioactive materials more accessible to consumers. These products are gaining popularity and are widely available and easily accessible in the market today. This study examined how consumer’s psychological factors affect their decision of purchasing products containing radioactive materials in the market. Based on the protective action decision model (PADM) and the heuristic-systematic model (HSM), this study proposed a model to add to the literature on consumer awareness of risky products. In particular, this study investigated which type of regulatory focus message (promotion-focused advertisement or prevention-focused advertisement) is significant in moderating the effects of radiation safety knowledge and product knowledge on risk perception when purchasing products containing radioactive materials. The relationship between consumers’ risk perception and information seeking, which leads to the purchase intention of such products was also investigated. Advertisements with varying regulatory focus messages were randomly distributed to participants to determine whether consumers are more influenced by promotion-focused advertisement or prevention-focused advertisement to mitigate the risk of purchasing products containing radioactive materials. The results revealed that promotion-focused advertising messages evoked a positive effect on consumers’ radiation safety knowledge and product knowledge toward risk perception. However, prevention-focused regulatory advertising messages did not moderate the relationships between both radiation safety knowledge and product knowledge on consumers’ risk perception. This study offers guidelines for manufacturers, sellers, and marketers of products containing radioactive materials, and, importantly, for the government to devise strategies in designing effective social marketing advertisement for business, environmental and societal benefits. Full article

The geological disposal in deep bedrock repositories is the preferred option for the management of high-level radioactive waste (HLW). In some of these concepts, carbon steel is considered as a potential canister material and bentonites are planned as backfill material to protect metallic waste containers. Therefore, a 1D radial reactive transport model has been developed in order to better understand the processes occurring during the long-term iron-bentonite interaction. The numerical model accounts for diffusion, aqueous complexation reactions, mineral dissolution/precipitation and cation exchange at a constant temperature of 25$°\mathrm{C}$ under anoxic conditions. Our results suggest that Fe is sorbed at the montmorillonite surface via cation exchange in the short-term, and it is consumed by formation of the secondary phases in the long-term. The numerical model predicts precipitation of nontronite, magnetite and greenalite as corrosion products. Calcite precipitates due to cation exchange in the short-term and due to montmorillonite dissolution in the long-term. Results further reveal a significant increase in pH in the long-term, while dissolution/precipitation reactions result in limited variations of the porosity. A sensitivity analysis has also been performed to test the effect of selected parameters, such as corrosion rate, diffusion coefficient and composition of the bentonite porewater, on the corrosion processes. Overall, outcomes suggest that the predicted main corrosion products in the long-term are Fe-silicate minerals, such phases thus should deserve further attention as a chemical barrier in the diffusion of radionuclides to the repository far field. Full article

Natural and artificial ionizing radiation can be harmful to human health when they come into contact with people and the environment. Transport of naturally occurring radioactive materials (NORMs) and consumer products containing NORM in the public domain is inevitable owing to their potential applications. This study evaluates the dose and risk to the public from transport accidents of NORM and consumer products. Radiological and physical data were obtained from previous literature. The median and maximum values of radioactivity concentration were applied to consumer products and NORM data, which serve as an input. An external dose rate at 1 m from a transported shipment was calculated using Microshield^® Pro version 12.11 code, which serves as input to RADTRAN 6 code. Based on developed transport accident scenarios, a RADTRAN 6 code was used to estimate collective dose and risk. The sensitivity analysis was conducted by considering the variation of release, aerosol, and respirable fractions of radionuclides at 0.1%, 1%, 10%, and 100% from the transported shipment during an accident, respectively. The results of dose and risk to the general public because of the damage of the shipment container following a fire accident are below the annual regulatory limits of 1 man-Sv recommended by IAEA transport regulation of 2018. The sensitivity results of all NORMs and associated consumer products are also below the regulatory limits. Therefore, radiological safety can be ensured in the event of a transport accident involving the transit of NORM and consumer products containing NORM. Full article

Naturally occurring radioactive materials (NORMs) are long-lived radioactive elements such as uranium, thorium, and potassium, and theirdecay products. They are abundant in natural rocks and minerals. In this study, we conducted a radiological dose assessment of the disposal of consumer products (CPs) containing NORMs at landfills and incinerators in South Korea. Household wastes were categorized as combustible and noncombustible on the basis of activity concentrations (ACs) ranging below and above 1 Bq/g, respectively. Analysis data were obtained from previous literature and the Nuclear Safety and Security Commission (NSSC) of South Korea, and statistical analysis was performed using an interval plot and 95% confidence interval of mean for each category as an input. Using RESRAD computer codes for noncombustible CPs with AC below and above 1 Bq/g, we found out that the dose rate was below and above 1 mSv/y, respectively. The RESRAD-OFFSITE results showed that the dose incurred during the study period for both ranges of AC was all below the public dose limit of 1 mSv/y. NORM and LegacY Site Assessment (NORMALYSA) code was used to validate the result of the RESRAD-ONSITE code, and the results showed that the dose was equal to and above 1 mSv/y for ACs below and above 1 Bq/g, respectively. HotSpot code was used for dose evaluation to offsite residents from incineration of combustible CPs, and the resulting dose was below 1 mSv/y. These findings can be used as a guideline for managing public exposure from landfill sites with varying ACs ranges. Therefore, the competent authority should ensure that criteria and protection measures are established for people who live within a distance of 10 km from incinerators and landfill sites that are contaminated with consumer products containing NORMs. Full article