Search Results (12)

This article examines a hybrid generation of cryptographic keys, whose novelty lies in the fusion of a multiscale subkey generation with prime sieve and subkeys inspired by quantum mechanics. It combines number theory with techniques emulated and inspired by quantum mechanics, also based on two demons capable of dynamically modifying the cryptographic model. The integration is structured through the JDL. In fact, a specific information fusion model is used to improve security. As a result, the resulting key depends not only on the individual components, but also on the fusion path itself, allowing for dynamic and cryptographically agile configurations that remain consistent with quantum mechanics-inspired logic. The proposed approach, called quantum and prime information fusion (QPIF), couples a simulated quantum entropy source, derived from the numerical solution of the Schrödinger equation, with a multiscale prime number sieve to construct multilevel cryptographic keys. The multiscale sieve, based on recent advances, is currently among the fastest available. Designed to be compatible with classical computing environments, the method aims to contribute to cryptography from a different perspective, particularly during the coexistence of classical and quantum computers. Among the five key generation algorithms implemented here, the ultra-optimised QRNG offers the most effective trade-off between performance and randomness. The results are validated using standard NIST statistical tests. This hybrid framework can also provide a conceptual and practical basis for future work on PQC aimed at addressing the challenges posed by the quantum computing paradigm. Full article

The separation of mixtures of hydrogen isotopes is one of the greatest challenges of modern separation technology. A newly proposed separation mechanism, the quantum sieving (QS) effect, is expected to achieve high separation factors, the main desired properties for hydrogen isotope separation (HIS). Metal–organic frameworks (MOFs) and zeolites are excellent candidates to study these quantum effects because of their well-defined and tunable pore structure and the potential to introduce strong adsorption sites directly into the framework structure. This paper briefly discusses the fundamentals of QS of hydrogen isotopes in nanoporous materials, mainly including kinetic quantum sieving (KQS) and chemical affinity quantum sieving (CAQS). Recent experimental advances in the separation of hydrogen isotopes from MOFs and zeolites are highlighted. Full article

Styryl dyes are generally poor fluorescent molecules inherited from their flexible molecular structures. However, their emissive properties can be boosted by restricting their molecular motions. A tight confinement into inorganic molecular sieves is a good strategy to yield highly fluorescent hybrid systems. In this work, we compare the confinement effect of two Mg-aluminophosphate zeotypes with distinct pore systems (the AEL framework, a one-dimensional channeled structure with elliptical pores of 6.5 Å × 4.0 Å, and the CHA framework, composed of large cavities of 6.7 Å × 10.0 Å connected by eight-ring narrower windows) for the encapsulation of 4-DASPI styryl dye (trans-4-[4-(Dimethylamino)styryl]-1-methylpyridinium iodide). The resultant hybrid systems display significantly improved photophysical features compared to 4-DASPI in solution as a result of tight confinement in both host inorganic frameworks. Molecular simulations reveal a tighter confinement of 4-DASPI in the elliptical channels of AEL, explaining its excellent photophysical properties. On the other hand, a singular arrangement of 4-DASPI dye is found when confined within the cavity-based CHA framework, where the 4-DASPI molecule spans along two adjacent cavities, with each aromatic ring sitting on these adjacent cavities and the polymethine chain residing within the narrower eight-ring window. However, despite the singularity of this host–guest arrangement, it provides less tight confinement for 4-DASPI than AEL, resulting in a slightly lower quantum yield. Full article

Ethylene production has a negative environmental impact, with its separation step being one of the major contributors of pollution. This has encouraged the search for energy-efficient alternatives, among which the adsorptive separation of ethane and ethylene stands out. ZIF-8 is a molecular sieve that is potentially useful for this purpose. It is selective to ethane, an exceptional property that remains unexplained. Furthermore, the adsorption of ethane and ethylene above room temperature, such as at steam cracking process outlet temperatures, has not been addressed either. This work aims to fill this knowledge gap by combining experiments at very low volumetric fillings with density–functional theory modelling methods. Adsorption isotherms of ethane and ethylene on ZIF-8 at pressures below 0.3 bar and 311 K, 333 K, and 363 K were measured using zero-length column chromatography. The low-pressure domain of the isotherms contains information on the interactions between the adsorbate molecules and the adsorbent. This favors the understanding of their macroscopic behavior from simulations at the atomic level. The isosteric enthalpy of adsorption of ethane remained constant at approximately −10 kJ/mol. In contrast, the isosteric enthalpy of adsorption of ethylene decreased from −4 kJ/mol to values akin to those of ethane as temperature increased. ZIF-8 selectivity to ethane, estimated from ideal adsorbed solution theory, decreased from 2.8 to 2.0 with increasing pressure up to 0.19 bar. Quantum mechanical modelling suggested that ethylene had minimal interactions with ZIF-8, while ethane formed hydrogen bonds with nitrogen atoms within its structure. The findings of this research are a platform for designing new systems for the adsorptive separation of ethane and ethylene and thus, reducing the environmental impact of ethylene production. Full article

Herein, we describe a fast and highly sensitive electrochemical sensor for doxorubicin (DOX) detection based on the indium tin oxide (ITO) modified with a binary material consisting of vertically-ordered mesoporous silica films (VMSFs) and N-doped graphene quantum dots (NGQDs). VMSFs, with high permeability and efficient molecular transport capacity, is attached to the ITO electrode via a rapid and controllable electrochemical method, which can serve as a solid template for the confinement of numerous NGQDs through facile electrophoresis. By virtue of the excellent charge transfer capacity, π-π and electrostatic preconcentration effects of NGQDs, as well as the electrostatic enrichment ability of VMSF, the presented NGQDs@VMSF/ITO shows amplified electrochemical signal towards DOX with a positive charge, resulting in good analytical performance in terms of a wide linear range (5 nM~0.1 μM and 0.1~1 μM), high sensitivity (30.4 μA μM⁻¹), and a low limit of detection (0.5 nM). Moreover, due to the molecular sieving property of VMSF, the developed NGQDs@VMSF/ITO sensor has good selectivity and works well in human serum and urine samples, with recoveries of 97.0~109%, thus providing a simple and reliable method for the direct electrochemical analysis of DOX without complex sample pretreatment procedures. Full article

A simple, effective, and highly sensitive analytical approach was created and applied in this study for the accurate measurement of three β₂-agonist residues (clenbuterol, salbutamol, and ractopamine) in meat samples. In the course of the experiment, new adsorbent molecular sieves (ZMS)@nitrogen-doped carbon quantum dots (N-CQDs) composite materials were synthesized with the aid of hydrothermal synthesis. The composite adsorbent materials were prepared and characterized through scanning electron microscopy, transmission electron microscope, X-ray photoelectron spectroscopy, fluorescence, and zeta potential. Four determinants affecting the extraction and elution’s efficiency, such as the amount of adsorbent, the extraction time, desorption time, and the amount of extraction salt, were substantially optimized. The analytes were quantified by gas chromatography–mass spectrometry. Final results of the methodological validation reflected that the ZMS@N-CQDs composite materials were able to adsorb three β₂-agonist residues well and had good reproducibility. In the meantime, all analytes indicated good linearity with coefficient of determination R² ≥ 0.9908. The limit of detection was 0.7–2.0 ng·g⁻¹, the limit of quantification varied from 2.4 to 5.0 ng·g⁻¹, the precision was lower than 11.9%, and the spiked recoveries were in the range of 79.5–97.8%. To sum up, the proposed approach was quite effective, reliable, and convenient for the simultaneous analysis of multiple β₂-agonist residues. Consequently, this kind of approach was successfully applied for the analysis of such compounds in meat samples. Full article

The learning with errors (LWE) problem is one of the main mathematical foundations of post-quantum cryptography. One of the main groups of algorithms for solving LWE is the Blum–Kalai–Wasserman (BKW) algorithm. This paper presents new improvements of BKW-style algorithms for solving LWE instances. We target minimum concrete complexity, and we introduce a new reduction step where we partially reduce the last position in an iteration and finish the reduction in the next iteration, allowing non-integer step sizes. We also introduce a new procedure in the secret recovery by mapping the problem to binary problems and applying the fast Walsh Hadamard transform. The complexity of the resulting algorithm compares favorably with all other previous approaches, including lattice sieving. We additionally show the steps of implementing the approach for large LWE problem instances. We provide two implementations of the algorithm, one RAM-based approach that is optimized for speed, and one file-based approach which overcomes RAM limitations by using file-based storage. Full article

Ion transport is a significant concept that underlies a variety of technologies including membrane technology, energy storages, optical, chemical, and biological sensors and ion-mobility exploration techniques. These applications are based on the concepts of capacitance and ion transport, so a prior understanding of capacitance and ion transport phenomena is crucial. In this review, the principles of capacitance and ion transport are described from a theoretical and practical point of view. The review covers the concepts of Helmholtz capacitance, diffuse layer capacitance and space charge capacitance, which is also referred to as quantum capacitance in low-dimensional materials. These concepts are attributed to applications in the electrochemical technologies such as energy storage and excitable ion sieving in membranes. This review also focuses on the characteristic role of channel heights (from micrometer to angstrom scales) in ion transport. Ion transport technologies can also be used in newer applications including biological sensors and multifunctional microsupercapacitors. This review improves our understanding of ion transport phenomena and demonstrates various applications that is applicable of the continued development in the technologies described. Full article

Fluorescence analysis technology and ion imprinting technology are combined to prepare a copper ion fluorescence sensor. Carbon quantum dots (CQDs), with a quantum yield of 79%, were synthesized by a hydrothermal process using citric acid as the carbon source. The prepared CQDs, acting as the fluorophore, were grafted onto the surface of an SBA-15 mesoporous molecular sieve by an amidation reaction. Then, the fluorescent sensor CQDs@Cu-IIP was prepared using a surface imprinting technique with the modified SBA-15 as the substrate, copper ions as a template, tetraethoxysilane as the crosslinker, and 3-aminopropyl-3-ethoxysilane as the functional monomers. The sensor showed strong fluorescence from CQDs and high selectivity due to the presence of Cu(II)-IIP. After the detection conditions were optimized, the fluorescence intensity of the sensor had good linearity with Cu(II) concentration in a linear range of 0.25–2 mg/L and 3–10 mg/L. This CQDs@Cu-IIP was applied to the determination of traces Cu(II) in real water samples and good recoveries of 99.29–105.42% were obtained. The present study provides a general strategy for fabricating materials based on CQDs for selective fluorescence detection of heavy metals. Full article

Methane (CH₄) and nitrous oxide (N₂O) are among the most important atmospheric greenhouse gases. A gas sensor based on a tunable 7.6 μm continuous-wave external-cavity mode-hop-free (EC-MHF) quantum cascade laser (from 1290 to 1350 cm⁻¹) cavity ring-down spectroscopy (CRDS) technique was developed for the simultaneous detection of CH₄ and N₂O in ambient air with water vapor (H₂O) mostly removed via molecular sieve drying to minimize the impact of H₂O on the simultaneous measurements. Still, due to the broad and strong absorption spectrum of H₂O in the entire mid-infrared (mid-IR) spectral range, residual H₂O in the dried ambient air due to incomplete drying and leakage, if not properly accounted for, could cause a significant influence on the measurement accuracy of the simultaneous CH₄ and N₂O detection. In this paper, the impact of residual H₂O on the simultaneous CH₄ and N₂O measurements were analyzed by comparing the CH₄ and N₂O concentrations determined from the measured spectrum in the spectral range from 1311 to 1312.1 cm⁻¹ via simultaneous CH₄ and N₂O measurements and that determined from the measured spectrum in the spectral range from 1311 to 1313 cm⁻¹ via simultaneous CH₄, N₂O, and H₂O measurements. The measured dependence of CH₄ and N₂O concentration errors on the simultaneously determined H₂O concentration indicated that the residual H₂O caused an under-estimation of CH₄ concentration and over-estimation of N₂O concentration. The H₂O induced CH₄ and N₂O concentration errors were approximately linearly proportional to the residual H₂O concentration. For the measurement of air flowing at 3 L per min, the residual H₂O concentration was stabilized to approximately 14 ppmv, and the corresponding H₂O induced errors were −1.3 ppbv for CH₄ and 3.7 ppbv for N₂O, respectively. Full article

We report accurate quantum calculations of the sieving of Helium atoms by two-dimensional (2D) graphtriyne layers with a new interaction potential. Thermal rate constants and permeances in an ample temperature range are computed and compared for both Helium isotopes. With a pore larger than graphdiyne, the most common member of the $\gamma$-graphyne family, it could be expected that the appearance of quantum effects were more limited. We find, however, a strong quantum behavior that can be attributed to the presence of selective adsorption resonances, with a pronounced effect in the low temperature regime. This effect leads to the appearance of some selectivity at very low temperatures and the possibility for the heavier isotope to cross the membrane more efficiently than the lighter, contrarily to what happened with graphdiyne membranes, where the sieving at low energy is predominantly ruled by quantum tunneling. The use of more approximate methods could be not advisable in these situations and prototypical transition state theory treatments might lead to large errors. Full article

Encapsulating CdS quantum dots (QDs) into zeolitic imidazole framework-8 (ZIF-8) can offer several advantages for photocatalysis. Various types of capping agents have been used to encapsulate QDs into ZIF-8 nanopores. An effective method for encapsulating CdS QDs into ZIF-8 is to use 2-mercaptoimidazole as the capping agent. This is because 2-mercaptoimidazole is similar to the imidazolate ligands of ZIFs and can used for capping active species with simultaneous encapsulation during the crystal growth of ZIF-8. Compared to other widely used capping agents such as polyvinylpyrrolidone (PVP), using 2-mercaptoimidazole for encapsulating CdS QDs into ZIF-8 revealed photocatalytic effects along with the molecular sieving effect when using differently sized molecular redox mediators such as methyl viologen (MV²⁺) and diquat (DQ²⁺). Full article