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Keywords = quantum Otto engine

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22 pages, 665 KB  
Article
Operational Constraints in Quantum Otto Engines: Energy-Gap Modulation and Majorization
by Sachin Sonkar and Ramandeep S. Johal
Entropy 2025, 27(6), 625; https://doi.org/10.3390/e27060625 - 12 Jun 2025
Viewed by 1747
Abstract
The performance of a quantum Otto engine is analyzed with regard to the constraints on the modulation of energy gaps relative to the changes in probability distributions at the two given heat reservoirs. We performed a detailed analysis with a generic three-level system [...] Read more.
The performance of a quantum Otto engine is analyzed with regard to the constraints on the modulation of energy gaps relative to the changes in probability distributions at the two given heat reservoirs. We performed a detailed analysis with a generic three-level system (3LS), which serves as a non-trivial working medium with two energy gaps. A three-level Otto engine becomes feasible if at least one energy gap shrinks during the first quantum adiabatic stage. The operating regimes are derived for each allowed energy gap modulation, and majorization is observed to play a crucial role in determining the engine operation. This results in an enhanced Otto efficiency when the probability distributions fulfill the majorization condition. Finally, we show that our formalism applies to a swap engine based on a working medium composed of two 3LSs. Full article
(This article belongs to the Special Issue Advances in Quantum Thermodynamics)
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12 pages, 660 KB  
Article
Quantum Otto Heat Engine Using Polar Molecules in Pendular States
by Xiang Li, Zhaoxi Sun, Yu-Yan Fang, Xiao-Li Huang, Xinning Huang, Jin-Fang Li, Zuo-Yuan Zhang and Jin-Ming Liu
Molecules 2024, 29(23), 5617; https://doi.org/10.3390/molecules29235617 - 27 Nov 2024
Cited by 2 | Viewed by 2770
Abstract
Quantum heat engines (QHEs) are established by applying the principles of quantum thermodynamics to small−scale systems, which leverage quantum effects to gain certain advantages. In this study, we investigate the quantum Otto cycle by employing the dipole−dipole coupled polar molecules as the working [...] Read more.
Quantum heat engines (QHEs) are established by applying the principles of quantum thermodynamics to small−scale systems, which leverage quantum effects to gain certain advantages. In this study, we investigate the quantum Otto cycle by employing the dipole−dipole coupled polar molecules as the working substance of QHE. Here, the molecules are considered to be trapped within an optical lattice and located in an external electric field. We analyze the work output and the efficiency of the quantum Otto heat engine (QOHE) as a function of various physical parameters, including electric field strength, dipole−dipole interaction and temperatures of heat baths. It is found that by adjusting these physical parameters the performance of the QOHE can be optimized effectively. Moreover, we also examine the influences of the entanglement and relative entropy of coherence for the polar molecules in thermal equilibrium states on the QOHE. Our results demonstrate the potential of polar molecules in achieving QHEs. Full article
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18 pages, 1904 KB  
Article
Computational Issues of Quantum Heat Engines with Non-Harmonic Working Medium
by Andrea R. Insinga, Bjarne Andresen and Peter Salamon
Entropy 2024, 26(5), 359; https://doi.org/10.3390/e26050359 - 25 Apr 2024
Viewed by 2397
Abstract
In this work, we lay the foundations for computing the behavior of a quantum heat engine whose working medium consists of an ensemble of non-harmonic quantum oscillators. In order to enable this analysis, we develop a method based on the Schrödinger picture. We [...] Read more.
In this work, we lay the foundations for computing the behavior of a quantum heat engine whose working medium consists of an ensemble of non-harmonic quantum oscillators. In order to enable this analysis, we develop a method based on the Schrödinger picture. We investigate different possible choices on the basis of expanding the density operator, as it is crucial to select a basis that will expedite the numerical integration of the time-evolution equation without compromising the accuracy of the computed results. For this purpose, we developed an estimation technique that allows us to quantify the error that is unavoidably introduced when time-evolving the density matrix expansion over a finite-dimensional basis. Using this and other ways of evaluating a specific choice of basis, we arrive at the conclusion that the basis of eigenstates of a harmonic Hamiltonian leads to the best computational performance. Additionally, we present a method to quantify and reduce the error that is introduced when extracting relevant physical information about the ensemble of oscillators. The techniques presented here are specific to quantum heat cycles; the coexistence within a cycle of time-dependent Hamiltonian and coupling with a thermal reservoir are particularly complex to handle for the non-harmonic case. The present investigation is paving the way for numerical analysis of non-harmonic quantum heat machines. Full article
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30 pages, 1352 KB  
Article
Work Fluctuations in Ergotropic Heat Engines
by Giovanni Chesi, Chiara Macchiavello and Massimiliano Federico Sacchi
Entropy 2023, 25(11), 1528; https://doi.org/10.3390/e25111528 - 9 Nov 2023
Cited by 2 | Viewed by 2048
Abstract
We study the work fluctuations in ergotropic heat engines, namely two-stroke quantum Otto engines where the work stroke is designed to extract the ergotropy (the maximum amount of work by a cyclic unitary evolution) from a couple of quantum systems at canonical equilibrium [...] Read more.
We study the work fluctuations in ergotropic heat engines, namely two-stroke quantum Otto engines where the work stroke is designed to extract the ergotropy (the maximum amount of work by a cyclic unitary evolution) from a couple of quantum systems at canonical equilibrium at two different temperatures, whereas the heat stroke thermalizes back the systems to their respective reservoirs. We provide an exhaustive study for the case of two qutrits whose energy levels are equally spaced at two different frequencies by deriving the complete work statistics. By varying the values of temperatures and frequencies, only three kinds of optimal unitary strokes are found: the swap operator U1, an idle swap U2 (where one of the qutrits is regarded as an effective qubit), and a non-trivial permutation of energy eigenstates U3, which indeed corresponds to the composition of the two previous unitaries, namely U3=U2U1. While U1 and U2 are Hermitian (and hence involutions), U3 is not. This point has an impact on the thermodynamic uncertainty relations (TURs), which bound the signal-to-noise ratio of the extracted work in terms of the entropy production. In fact, we show that all TURs derived from a strong detailed fluctuation theorem are violated by the transformation U3. Full article
(This article belongs to the Special Issue Thermodynamic Uncertainty Relations)
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16 pages, 3981 KB  
Article
Multilayer Graphene as an Endoreversible Otto Engine
by Nathan M. Myers, Francisco J. Peña, Natalia Cortés and Patricio Vargas
Nanomaterials 2023, 13(9), 1548; https://doi.org/10.3390/nano13091548 - 5 May 2023
Cited by 6 | Viewed by 2756
Abstract
We examine the performance of a finite-time, endoreversible Otto heat engine with a working medium of monolayer or multilayered graphene subjected to an external magnetic field. As the energy spectrum of multilayer graphene under an external magnetic field depends strongly on the number [...] Read more.
We examine the performance of a finite-time, endoreversible Otto heat engine with a working medium of monolayer or multilayered graphene subjected to an external magnetic field. As the energy spectrum of multilayer graphene under an external magnetic field depends strongly on the number of layers, so too does its thermodynamic behavior. We show that this leads to a simple relationship between the engine efficiency and the number of layers of graphene in the working medium. Furthermore, we find that the efficiency at maximum power for bilayer and trilayer working mediums can exceed that of a classical endoreversible Otto cycle. Conversely, a working medium of monolayer graphene displays identical efficiency at maximum power to a classical working medium. These results demonstrate that layered graphene can be a useful material for the construction of efficient thermal machines for diverse quantum device applications. Full article
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13 pages, 2617 KB  
Article
Enhanced Efficiency at Maximum Power in a Fock–Darwin Model Quantum Dot Engine
by Francisco J. Peña, Nathan M. Myers, Daniel Órdenes, Francisco Albarrán-Arriagada and Patricio Vargas
Entropy 2023, 25(3), 518; https://doi.org/10.3390/e25030518 - 17 Mar 2023
Cited by 5 | Viewed by 3656
Abstract
We study the performance of an endoreversible magnetic Otto cycle with a working substance composed of a single quantum dot described using the well-known Fock–Darwin model. We find that tuning the intensity of the parabolic trap (geometrical confinement) impacts the proposed cycle’s performance, [...] Read more.
We study the performance of an endoreversible magnetic Otto cycle with a working substance composed of a single quantum dot described using the well-known Fock–Darwin model. We find that tuning the intensity of the parabolic trap (geometrical confinement) impacts the proposed cycle’s performance, quantified by the power, work, efficiency, and parameter region where the cycle operates as an engine. We demonstrate that a parameter region exists where the efficiency at maximum output power exceeds the Curzon–Ahlborn efficiency, the efficiency at maximum power achieved by a classical working substance. Full article
(This article belongs to the Special Issue Quantum Control and Quantum Computing)
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16 pages, 1226 KB  
Article
Performance of Quantum Heat Engines Enhanced by Adiabatic Deformation of Trapping Potential
by Yang Xiao, Kai Li, Jizhou He and Jianhui Wang
Entropy 2023, 25(3), 484; https://doi.org/10.3390/e25030484 - 10 Mar 2023
Cited by 2 | Viewed by 3022
Abstract
We present a quantum Otto engine model alternatively driven by a hot and a cold heat reservoir and consisting of two isochoric and two adiabatic strokes, where the adiabatic expansion or compression is realized by adiabatically changing the shape of the potential. Here, [...] Read more.
We present a quantum Otto engine model alternatively driven by a hot and a cold heat reservoir and consisting of two isochoric and two adiabatic strokes, where the adiabatic expansion or compression is realized by adiabatically changing the shape of the potential. Here, we show that such an adiabatic deformation may alter operation mode and enhance machine performance by increasing output work and efficiency, even with the advantage of decreasing work fluctuations. If the heat engine in the sudden limit operates under maximal power by optimizing the control parameter, the efficiency shows certain universal behavior, η*=ηC/2+ηC2/8+O(ηC3), where ηC=1βhr/βcr is the Carnot efficiency, with βhr(βcr) being the inverse temperature of the hot (cold) reservoir. However, such efficiency under maximal power can be produced by our machine model in the regimes where the machine without adiabatic deformation can only operate as a heater or a refrigerator. Full article
(This article belongs to the Section Statistical Physics)
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31 pages, 668 KB  
Article
Quantum Heat Engines with Complex Working Media, Complete Otto Cycles and Heuristics
by Ramandeep S. Johal and Venu Mehta
Entropy 2021, 23(9), 1149; https://doi.org/10.3390/e23091149 - 1 Sep 2021
Cited by 13 | Viewed by 4657
Abstract
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to [...] Read more.
Quantum thermal machines make use of non-classical thermodynamic resources, one of which include interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been shown earlier that the said interaction provides an enhancement of cycle efficiency, with an upper bound that is tighter than the Carnot efficiency. However, the necessary conditions governing engine performance and the relevant upper bound for efficiency are unknown for the general case of arbitrary spin magnitudes. By analyzing extreme case scenarios, we formulate heuristics to infer the necessary conditions for an engine with uncoupled as well as coupled spin model. These conditions lead us to a connection between performance of quantum heat engines and the notion of majorization. Furthermore, the study of complete Otto cycles inherent in the average cycle also yields interesting insights into the average performance. Full article
(This article belongs to the Special Issue Nonequilibrium Thermodynamics and Stochastic Processes)
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15 pages, 1419 KB  
Article
Quantum Heat Engines with Singular Interactions
by Nathan M. Myers, Jacob McCready and Sebastian Deffner
Symmetry 2021, 13(6), 978; https://doi.org/10.3390/sym13060978 - 31 May 2021
Cited by 24 | Viewed by 7617
Abstract
By harnessing quantum phenomena, quantum devices have the potential to outperform their classical counterparts. Here, we examine using wave function symmetry as a resource to enhance the performance of a quantum Otto engine. Previous work has shown that a bosonic working medium can [...] Read more.
By harnessing quantum phenomena, quantum devices have the potential to outperform their classical counterparts. Here, we examine using wave function symmetry as a resource to enhance the performance of a quantum Otto engine. Previous work has shown that a bosonic working medium can yield better performance than a fermionic medium. We expand upon this work by incorporating a singular interaction that allows the effective symmetry to be tuned between the bosonic and fermionic limits. In this framework, the particles can be treated as anyons subject to Haldane’s generalized exclusion statistics. Solving the dynamics analytically using the framework of “statistical anyons”, we explore the interplay between interparticle interactions and wave function symmetry on engine performance. Full article
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47 pages, 5007 KB  
Article
Quantum Finite-Time Thermodynamics: Insight from a Single Qubit Engine
by Roie Dann, Ronnie Kosloff and Peter Salamon
Entropy 2020, 22(11), 1255; https://doi.org/10.3390/e22111255 - 4 Nov 2020
Cited by 47 | Viewed by 6417
Abstract
Incorporating time into thermodynamics allows for addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model in order to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin [...] Read more.
Incorporating time into thermodynamics allows for addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model in order to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction, and thermalization in the presence of external driving. We construct various finite-time engine cycles that are based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production. Full article
(This article belongs to the Special Issue Finite-Time Thermodynamics)
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14 pages, 1935 KB  
Article
The Quantum Friction and Optimal Finite-Time Performance of the Quantum Otto Cycle
by Andrea R. Insinga
Entropy 2020, 22(9), 1060; https://doi.org/10.3390/e22091060 - 22 Sep 2020
Cited by 26 | Viewed by 4332
Abstract
In this work we considered the quantum Otto cycle within an optimization framework. The goal was maximizing the power for a heat engine or maximizing the cooling power for a refrigerator. In the field of finite-time quantum thermodynamics it is common to consider [...] Read more.
In this work we considered the quantum Otto cycle within an optimization framework. The goal was maximizing the power for a heat engine or maximizing the cooling power for a refrigerator. In the field of finite-time quantum thermodynamics it is common to consider frictionless trajectories since these have been shown to maximize the work extraction during the adiabatic processes. Furthermore, for frictionless cycles, the energy of the system decouples from the other degrees of freedom, thereby simplifying the mathematical treatment. Instead, we considered general limit cycles and we used analytical techniques to compute the derivative of the work production over the whole cycle with respect to the time allocated for each of the adiabatic processes. By doing so, we were able to directly show that the frictionless cycle maximizes the work production, implying that the optimal power production must necessarily allow for some friction generation so that the duration of the cycle is reduced. Full article
(This article belongs to the Special Issue Finite-Time Thermodynamics)
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11 pages, 2235 KB  
Article
Otto Engine: Classical and Quantum Approach
by Francisco J. Peña, Oscar Negrete, Natalia Cortés and Patricio Vargas
Entropy 2020, 22(7), 755; https://doi.org/10.3390/e22070755 - 9 Jul 2020
Cited by 25 | Viewed by 6144
Abstract
In this paper, we analyze the total work extracted and the efficiency of the magnetic Otto cycle in its classic and quantum versions. As a general result, we found that the work and efficiency of the classical engine is always greater than or [...] Read more.
In this paper, we analyze the total work extracted and the efficiency of the magnetic Otto cycle in its classic and quantum versions. As a general result, we found that the work and efficiency of the classical engine is always greater than or equal to its quantum counterpart, independent of the working substance. In the classical case, this is due to the fact that the working substance is always in thermodynamic equilibrium at each point of the cycle, maximizing the energy extracted in the adiabatic paths. We apply this analysis to the case of a two-level system, finding that the work and efficiency in both the Otto’s quantum and classical cycles are identical, regardless of the working substance, and we obtain similar results for a multilevel system where a linear relationship between the spectrum of energies of the working substance and the external magnetic field is fulfilled. Finally, we show an example of a three-level system in which we compare two zones in the entropy diagram as a function of temperature and magnetic field to find which is the most efficient region when performing a thermodynamic cycle. This work provides a practical way to look for temperature and magnetic field zones in the entropy diagram that can maximize the power extracted from an Otto magnetic engine. Full article
(This article belongs to the Special Issue Thermodynamics of Quantum Information)
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16 pages, 7438 KB  
Article
Magnetic Otto Engine for an Electron in a Quantum Dot: Classical and Quantum Approach
by Francisco J. Peña, Oscar Negrete, Gabriel Alvarado Barrios, David Zambrano, Alejandro González, Alvaro S. Nunez, Pedro A. Orellana and Patricio Vargas
Entropy 2019, 21(5), 512; https://doi.org/10.3390/e21050512 - 20 May 2019
Cited by 24 | Viewed by 5966
Abstract
We studied the performance of classical and quantum magnetic Otto cycle with a working substance composed of a single quantum dot using the Fock–Darwin model with the inclusion of the Zeeman interaction. Modulating an external/perpendicular magnetic field, in the classical approach, we found [...] Read more.
We studied the performance of classical and quantum magnetic Otto cycle with a working substance composed of a single quantum dot using the Fock–Darwin model with the inclusion of the Zeeman interaction. Modulating an external/perpendicular magnetic field, in the classical approach, we found an oscillating behavior in the total work extracted that was not present in the quantum formulation.We found that, in the classical approach, the engine yielded a greater performance in terms of total work extracted and efficiency than when compared with the quantum approach. This is because, in the classical case, the working substance can be in thermal equilibrium at each point of the cycle, which maximizes the energy extracted in the adiabatic strokes. Full article
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10 pages, 1134 KB  
Article
Efficiency of Harmonic Quantum Otto Engines at Maximal Power
by Sebastian Deffner
Entropy 2018, 20(11), 875; https://doi.org/10.3390/e20110875 - 15 Nov 2018
Cited by 98 | Viewed by 8801
Abstract
Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been [...] Read more.
Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon–Ahlborn efficiency. This is rather remarkable as the Curzon–Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as Curzon and Ahlborn’s original treatment. We find that for endoreversible Otto cycles in classical harmonic oscillators the efficiency at maximal power is, indeed, given by the Curzon–Ahlborn efficiency. However, we also find that the efficiency of Otto engines made of quantum harmonic oscillators is significantly larger. Full article
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36 pages, 2649 KB  
Review
The Quantum Harmonic Otto Cycle
by Ronnie Kosloff and Yair Rezek
Entropy 2017, 19(4), 136; https://doi.org/10.3390/e19040136 - 23 Mar 2017
Cited by 358 | Viewed by 21472
Abstract
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working [...] Read more.
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity.The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov–Curzon–Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero. Full article
(This article belongs to the Special Issue Quantum Thermodynamics)
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