Search Results (31)

To address the limitations of traditional hardened concrete road surfaces in coal mine tunnels, which are prone to damage and entail high maintenance costs, this study proposes using modular concrete blocks composed of fly ash and coal gangue as an alternative to conventional materials. These blocks offer advantages including ease of construction and rapid, straightforward maintenance, while also facilitating the reuse of substantial quantities of solid waste, thereby mitigating resource wastage and environmental pollution. Initially, the mineral composition of the raw materials was analyzed, confirming that although the physical and chemical properties of Liangshui Well coal gangue are slightly inferior to those of natural crushed stone, they still meet the criteria for use as concrete aggregate. For concrete blocks incorporating 20% fly ash, the steam curing process was optimized with a recommended static curing period of 16–24 h, a temperature ramp-up rate of 20 °C/h, and a constant temperature of 50 °C maintained for 24 h to ensure optimal performance. Orthogonal experimental analysis revealed that fly ash content exerted the greatest influence on the compressive strength of concrete, followed by the additional water content, whereas the aggregate particle size had a comparatively minor effect. The optimal mix proportion was identified as 20% fly ash content, a maximum aggregate size of 20 mm, and an additional water content of 70%. Performance testing indicated that the fabricated blocks exhibited a compressive strength of 32.1 MPa and a tensile strength of 2.93 MPa, with strong resistance to hydrolysis and sulfate attack, rendering them suitable for deployment in weakly alkaline underground environments. Considering the site-specific conditions of the Liangshuijing coal mine, ANSYS 2020 was employed to simulate and analyze the mechanical behavior of the blocks under varying loads, thicknesses, and dynamic conditions. The findings suggest that hexagonal coal gangue blocks with a side length of 20 cm and a thickness of 16 cm meet the structural requirements of most underground mine tunnels, offering a reference model for cost-effective paving and efficient roadway maintenance in coal mines. Full article

Prestressed concrete railroad ties are the global standard for railway infrastructure due to their structural stability, durability, and cost-effective maintenance. However, their long-term performance is often compromised by premature deterioration. This study investigates the degradation of prestressed concrete railways ties from a Brazilian rail line after ten years of natural exposure, emphasizing critical implications for infrastructure maintenance. Two groups of ties, separated by 30 km, were analyzed through physical property assessments, petrography, X-ray diffraction (XRD), and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS). The results reveal that deterioration was driven by the combined effects of alkali–silica reaction (ASR) and sulfate attack, confirmed by the presence of (N, C)ASH gels, ettringite crystallization, and cryptocrystalline materials within cracks and voids. Prestressing-induced stresses and environmental moisture further accelerated degradation, leading to a 66% reduction in mechanical strength in the T1 group. These findings demonstrate that internal swelling reactions and moisture exposure synergistically accelerate deterioration in prestressed concrete ties, particularly in low-prestress, poorly drained zones. Full article

Salt lakes and the surrounding saline soils distributed across northwestern China and Inner Mongolia impose severe physicochemical corrosion on cement-based concrete. Understanding the corrosion products and mechanisms are crucial scientific and technological factors in ensuring the durability and service life of concrete structures in these regions. In this study, various analytical techniques—including X-ray diffraction, thermogravimetric–differential thermal analysis, X-ray fluorescence, and scanning electron microscopy coupled with energy-dispersive spectroscopy—were employed to systematically analyze the corrosion products of ordinary Portland cement (OPC) and high-performance concrete (HPC) specimens after eight years of field exposure in the Qarhan Salt Lake area of Qinghai. The study provided an in-depth understanding of the physicochemical corrosion mechanisms involved. The results showed that, after eight years of exposure, the corrosion products comprised both physical corrosion products (primarily sodium chloride crystals), and chemical corrosion products (associated with chloride, sulfate, and magnesium salt attacks). A strong correlation could be observed between the chemical corrosion products and the strength grade of the concrete. In C25 OPC, the detected corrosion products included gypsum, monosulfate-type calcium sulfoaluminate (AFm), Friedel’s salt, chloro-ettringite, brucite, magnesium oxychloride hydrate 318, calcium carbonate, potassium chloride, and sodium chloride. In C60 HPC, the identified corrosion products included Kuzel’s salt, Friedel’s salt, chloro-ettringite, brucite, calcium carbonate, potassium chloride, and sodium chloride. Among them, sulfate-induced corrosion led to the formation of gypsum and AFm, whereas chloride-induced corrosion resulted in chloro-ettringite and Friedel’s salt. Magnesium salt corrosion contributed to the formation of brucite and magnesium oxychloride hydrate 318, with Kuzel’s salt emerging as a co-corrosion product of chloride and sulfate attacks. Furthermore, a conversion phenomenon was evident between the sulfate and chloride corrosion products, which was closely linked to the internal chloride ion concentration in the concrete. As the chloride ion concentration increased, the transformation sequence of sulfate corrosion products occurred in the following order: AFm → Kuzel’s salt → Friedel’s salt → chloro-ettringite. There was a gradual increase in chloride ion content within these corrosion products. This investigation into concrete durability in salt-lake ecosystems offers technological guidance for infrastructure development and material specification in hyper-saline environments. Full article

Concrete structures in marine environments are subjected to severe conditions that significantly compromise their durability and service life. Exposure to chloride penetration, sulfate attack, and physical erosion accelerates deterioration, leading to extensive maintenance requirements and high associated costs. To address these challenges, significant advancements in surface coatings and inspection technologies have been developed to enhance the longevity of concrete structures. This review examines recent progress in protective surface coatings that mitigate environmental damage and explores state-of-the-art inspection techniques for assessing structural integrity. By providing a comprehensive analysis of innovative materials, coating applications, and non-destructive evaluation methods, this paper aims to equip researchers and industry professionals with effective strategies for preserving concrete infrastructure in marine environments. Full article

For concrete structures in marine or groundwater environments, sulfate attack is a major factor contributing to the degradation of concrete performance. This paper analyzes the existing literature on the chemical reactions and physical crystallization effects of sulfate attack on cement-based materials, summarizing the degradation mechanisms of corroded concrete. Experiments have been conducted to study the performance evolution of concrete under sulfate attack, considering both external environmental factors and internal factors of the cement-based materials. External environmental factors, such as the temperature, humidity, concentration, and type of sulfate solutions, wet-dry cycles, freeze-thaw cycles, chloride coupling effects, and stray currents significantly impact sulfate attack on concrete. Internal factors, including internal sources of corrosion, the chemical composition of the cement, water-cement ratio, and the content of C-S-H gel and Ca(OH)₂, influence the density and sulfate resistance of the cement-based materials. Additionally, five typical methods for enhancing the sulfate resistance of concrete are summarized. Finally, the paper identifies current challenges in the study of corroded concrete and proposes directions for future research. Full article

In salt lake areas, the cast-in-situ concrete structure has been corroded by the combination of sulfate and chloride for a long time. The incorporation of basalt fiber materials into concrete helps to improve the durability of concrete. In this paper, experiments were conducted to study the corrosion deterioration mechanisms of basalt fiber-reinforced cast-in-situ concrete under sulfate, chloride, and combined attack. The appearance, size, mass, flexural, and compressive strength of specimens were investigated during the immersion period to determine the changes in the physical and mechanical properties of specimens. Moreover, the microstructure and mineral changes of specimens during the immersion period were observed by Scanning Electron Microscope (SEM), Energy Dispersive Spectrometer (EDS), X-ray diffraction (XRD), and Thermogravimetric (TG)/ Derivative Thermogravimetric (DTG) analyses. Results show that premixed chloride has a significant detrimental influence on the strength development of cast-in-situ concrete, with concrete powder spalling occurring on the surface of the specimen. Severe corrosion degradation of specimens occurs under the external sulfate and internal chloride combined attack, resulting in lower flexural and compressive strength. The compressive strength and flexural strength of the corroded specimens decreased by 15.4% and 24.8%, respectively, compared with the control group at 28 days. Moreover, premixed basalt fiber has a beneficial influence on cast-in-situ concrete. When the basalt fiber content is 0.5%, the flexural strength of the specimen is increased by 16.2%. The filling and bridging effect of basalt fiber alleviates the negative effects caused by corrosion. In addition, increasing fiber content is beneficial for enhancing its effectiveness when the fiber content is less than 0.5%. This paper provides a valuable reference for the application of basalt fiber-reinforced cast-in-situ concrete under the condition of sulfate–chloride compound corrosion. Full article

In order to optimize the application of desert sand autoclaved bricks in rural construction in Xinjiang, this study focuses on the research and development of MU15-grade desert sand autoclaved bricks. Experimental investigations were conducted to examine the relationship between the water absorption rate of desert sand autoclaved bricks and the duration of water absorption while analyzing the impact of the water absorption rate on the compressive strength of these bricks. Additionally, experimental research was carried out to evaluate the appearance, compressive strength, and pore structure of autoclaved bricks after sulfate erosion. The results indicate the following. (1) With an increasing immersion time, the water absorption rate of desert sand-based autoclaved bricks initially rises and then declines, reaching approximately 14.74% when immersed for 4 h, which is close to the saturation water absorption rate. (2) The compressive strength of desert sand-based autoclaved bricks gradually decreases with an increasing water absorption rate, reaching its lowest point when saturation is attained, with a strength loss rate of approximately 33.18%. (3) Finally, after sulfate erosion, cracks and detachment appear on the surface of desert sand-based autoclaved bricks, and these cracks extend and propagate with the continuous accumulation of eroded products. Simultaneously, this process leads to an increase in the proportion of harmful pores by 0.96%, thereby causing a deterioration in strength. Through data analysis, a decay curve of the compressive strength erosion coefficient of desert sand-based autoclaved bricks with the number of sulfate erosion cycles was established, with good accuracy. This study provides theoretical references and technical support for the performance characteristics of desert sand-based autoclaved bricks and their application in rural construction in Xinjiang. Full article

This paper comprehensively summarizes moisture transport, ion transport, and mechanical damage models applied to concrete under sulfate attack and drying–wetting cycles. It highlights the essential aspects and principles of each model, emphasizing their significance in understanding the movement of moisture and ions, as well as the resulting mechanical damage within the concrete during these degradation processes. The paper critically analyzes the assumptions made in each model, shedding light on their limitations and implications for prediction accuracy. Two primary challenges faced by current models under sulfate attack and drying–wetting cycles are identified: the limited consideration of the coupled effects of chemical and physical attacks from sulfate, and the unclear mechanism of the sulfate attacks. Future research directions are proposed, focusing on exploring the transport mechanism of sulfate ions under various driving forces and further clarifying the crystallization process and expansion damage mechanism in concrete pores. Addressing these research directions will advance our understanding of sulfate attack under drying–wetting cycles, leading to improved models and mitigation strategies for enhancing the durability and performance of concrete structures. Full article

The building sector’s sustainability requires construction and demolition waste (CDW) to contribute to the circular economy. Among the CDW, recycled concrete aggregates (RA) have been mainly studied to replace natural aggregates. Still, the approval of their use in regulations and standards is slower. Some barriers to the adoption of RA are related to the durability of recycled aggregate concrete (RAC). However, their physical and mechanical properties have been extensively studied. The durability risks associated with sulfate attacks have been solved for conventional concrete. However, sulfate attack on recycled concrete still raises numerous unsolved questions. In this literature review, the experience of sulfate attack on RAC is compiled and analyzed using a compressive framework highlighting the most relevant aspects of the new matrix in RAC and the old matrix of RA to support its relevance to the damaging sulfate process. Suggestions for further research are presented to understand the full extent of this issue and contribute to incorporating and extending recycled aggregates into existing regulations. Full article

The combination of water management and urban planning can promote the sustainable development of cities, which can be achieved through buildings’ absorption and utilization of pollutants in water. Sulfate ions are one of the important pollutants in water, and concrete is an important building material. The absorption of sulfate ions by concrete can change buildings’ bearing capacity and sustainability. Nevertheless, given the complex and heterogeneous nature of concrete and a series of chemical and physical reactions, there is currently no efficient and accurate method for predicting mechanical performance. This work presents a deep learning model for establishing the relationship between a water environment and concrete performance. The model is constructed using an experimental database consisting of 1328 records gathered from the literature. The utmost essential parameters influencing the compressive strength of concrete under a sulfate attack such as the water-to-binder ratio, the sulfate concentration and type, the admixture type and percentage, and the service age are contemplated as input factors in the modeling process. The results of using several loss functions all approach 0, and the error between the actual value and the predicted value is small. Moreover, the results also demonstrate that the method performed better for predicting the performance of concrete under water pollutant attacks compared to seven basic machine learning algorithms. The method can serve as a reference for the integration of urban building planning and water management. Full article

Among the most significant causes of concrete degradation is ESA (external sulfate attack). The majority of studies are currently conducted on samples that have been saturated and matured. Concrete structures, however, are exposed to the environment once the formwork has been removed. The purpose of this study is to determine what effects early exposure to external sulfates may have on degradation mechanisms. Microstructure, physical, and chemical behavior are monitored using a variety of experimental techniques, including NMR (²⁷Al and ²⁹Si), ICP, XRD, MIP, and SEM. Based on expansion measurements, mature Portland cement paste, unlike the early-age case, degraded rapidly due to the presence of compressed ettringite and gypsum, highlighted by SEM analysis. During ESA, sulfate ions diffuse through the cement matrix and are bound by chemical agents. Chemical analyses indicate that the chemical mechanism varies with the duration of curing. At an early age, external sulfates and aluminates are the most important reagents. For matured cases, these reagents include external sulfates, calcium derived from CH dissolution, and aluminates derived from the total dissolution of AFm. Full article

This paper aimed to analyze the reduction in the ballast layer permeability simulated in a laboratory in saturated conditions by the presence of rock dust as a contaminant of three types of rocks explored in different deposits in the northern region of the state of Rio de Janeiro, Brazil, through laboratory testing relating the physical properties of rock particles before and after sodium sulfate attack. Sodium sulfate attack is justified by the proximity of some sections of the planned EF-118 Vitória-Rio railway line to the coast and of the sulfated water table to the ballast bed, which could degrade the material used and compromise the railway track. Granulometry and permeability tests were performed to compare ballast samples with fouling rates of 0, 10, 20, and 40% rock dust by volume. A constant head permeameter was used to analyze hydraulic conductivity and establish correlations between the petrography and mercury intrusion porosimetry of the rocks, namely two types of metagranite (Mg1 and Mg3) and a gneisse (Gn2). Rocks, such as Mg1 and Mg3, with a larger composition of minerals susceptible to weathering according to petrography analyses, tend to be more sensitive to weathering tests. This, in conjunction with the climate in the region studied, with average annual temperature and rainfall of 27 °C and 1200 mm, could compromise track safety and user comfort. Additionally, the Mg1 and Mg3 samples showed greater percentage variation in wear after the Micro-Deval test, which could damage the ballast due to the considerable changeability of the material. The mass loss caused by abrasion due to the passage of rail vehicles was assessed by the Micro-Deval test, with Mg3 (intact rock) declining from 8.50 ± 1.5 to 11.04 ± 0.5% after chemical attack. However, Gn2, which exhibited the greatest mass loss among the samples, showed no significant variation in average wear, and its mineralogical characteristics remained almost unchanged after 60 sodium sulfate cycles. These aspects, combined with its satisfactory hydraulic conductivity rate, indicate that Gn2 is suitable for use as railway ballast in the EF-118 railway line. Full article

Sulfate attack is one of the non-negligible factors that induces deterioration in the performance and life cycle of soil stabilizers. In this paper, the degradation mechanism of the durability of slag–fly-ash-based geopolymer stabilized soft soil (hitherto referred to as SF-GSSS) under the sodium sulfate (Na₂SO₄) and magnesium sulfate (MgSO₄) attack environment is comparatively investigated, and the slag/fly ash ratios are set to S10F0, S9F1, S8F2, and S7F3. The SF-GSSS was fully immersed in a 2.5% Na₂SO₄ solution and 2.5% MgSO₄ solution, respectively, to characterize the deterioration rules via visual observations, an unconfined compressive strength (UCS) test, and by mass change. The effect of sulfate on the microstructural characteristics of the SF-GSSS were determined by different microanalytical means, such as by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the SF-GSSS immersed in a MgSO₄ solution displayed significant physical deterioration, but not when in a Na₂SO₄ solution. The mass growth of the SF-GSSS when immersed in a Na₂SO₄ solution was significantly lower than when it was immersed in a MgSO₄ solution at the same immersion age. The rate of strength loss was lowest for S9F1 and highest for S7F3 at the end of immersion, regardless of its immersion in Na₂SO₄ or MgSO₄ solutions. Full article

To solve a number of problems in construction materials science, composites with nano and ultrafine admixtures were analyzed. Their properties were studied, taking into account the variants of homogenization and stabilization of the system. To characterize the processes of the structure formation of a new material, mathematical methods were also applied. According to the literature review, the aim of the work was formulated. The subject of this research is to conduct physico-chemical studies that characterize the processes occurring during the homogenization and stabilization of the cement system with GGBS components and to establish the effect of the admixture on the properties of the composite. To achieve this goal, an ultrafine admixture based on GGBS was obtained, and the possibility of its introduction into the cement system in the form of a stabilized suspension instead of mixing water was considered. To provide increased characteristics of cement stone modified with the ultrafine admixture, a number of tests were carried out to study homogenization and stabilization of fine slag particles in suspension. The ultrasonic processing parameters were defined to provide uniform distribution of fine slag additive in the suspension: the processing time is 15–20 min, the frequency of ultrasonic vibrations is 44 kHz, the temperature of the dispersed medium is 25 ± 2 °C. To define physical and chemical processes appearing during the introduction of fine slag into water and water-polymer dispersed medium, the mechanism of interaction between fine slag and water was studied. In addition, the mechanism of chemisorption on the surface of fine slag particles and the stabilization mechanism of ultrafine slag particles with a plasticizer was studied to form the concept of aggregate and sedimentation stability of slag particles in suspension. It was found that the stabilization of fine slag particles by a plasticizer is significantly influenced by the hardness of water. The higher the water hardness, the more plasticizer required to stabilize the fine slag particles. At the same time, it was established that the concentration of the plasticizer should not exceed the critical micelle concentration value. If it is exceeded, the plasticizer solution transforms into the micellar colloidal system, and the stabilization of fine slag suspension will not occur. The studies of homogenization and stabilization of the slag suspension allowed the authors to substantiate the possibility of uniform distribution of fine particles in the cement matrix, followed by the formation of a denser and stronger cement stone structure. Cement-sand samples based on Portland cement (OPC) and slag-Portland cement (SPC) with GGBFS admixture showed higher compressive and flexural strength characteristics in the initial hardening periods and at 28 days. It was found that modified samples are more stable in an aggressive medium. On the 90th day of exposure, the resistance coefficient was 0.9 for a modified sample based on OPC and 0.98 for a modified sample based on SPC. The increased sulfate attack resistance of the samples is due to the formation of a dense stone with reduced porosity. It is noted that the porosity of modified OPC samples decreases by 14% and by 18% for SPC-based modified samples compared to the control sample at 28 days. Due to the fact that pores in the cement stone are blocked with hydration products, which make the structure of the cement stone denser, the filtration of aggressive solutions deep into its structure is difficult. Thus, the obtained concrete based on a cement composite with ultrafine slag can be applied as a protective layer of steel reinforcement in a reinforced concrete structure. Full article

The concrete of numerous buildings and structures is at increased risk due to various kinds of aggressive pollutants. In this regard, it is necessary to implement and take additional actions, among which the so-called technological methods for concrete structure property modification are promising. These methods comprise improvement and modernization of existing technologies to produce the most effective concrete building structures before the introduction of steel reinforcement. One of the effective and proven technological and design solutions is the use of centrifuged and vibrocentrifuged concrete of an annular section with a variotropic concrete structure. The aim of the work was to study the physical and mechanical properties of variotropic concretes of annular structures when exposed to sulfate attack. As a result of the cyclic impact of sulfate attack, the mass loss of vibrocentrifuged concrete was the smallest in comparison with centrifuged (17% less) and vibrated concrete (37% less). The loss of cube and prism strength of vibrocentrifuged concrete was the smallest in comparison with centrifuged (20% and 18% less, respectively) and vibrated concrete (42% and 38% less, respectively). The sulfate attack rate, as a depth of penetration and concrete destruction, was 46% less for vibrocentrifuged concrete than for centrifuged concrete and 65% less than for vibrated concrete. Full article