Search Results (36)

The direct discharge of cationic surfactants into environmental matrices has exponentially increased due to their wide application in many products. These compounds and their degraded products disrupt microbial dynamics, hinder plant survival, and affect human health. Therefore, there is an urgent need to develop electroanalytical assessment techniques for their identification, determination, and monitoring. In our study, ZnO-PANI nanocomposites were electrodeposited on a glassy carbon electrode (GCE), followed by the immobilization of laccase enzymes and the electrodeposition of polypyrrole (PPy), to form a biosensor that was used for the detection of CTAB. A UV-Vis analysis showed bands corresponding to the π-π* transition of benzenoid and quinoid rings, π-polaron band transition and n-π*polaronic transitions associated with the extended coil chain conformation of PANI, and the presence and interaction of ZnO with PANI and type 3 copper in the laccase enzymes. The FTIR analysis exhibited peaks corresponding to N-H and C-N stretches and bends for amine, C=C stretches for conjugated alkenes, and a C-H bend for aromatic compounds. A high-resolution scanning electron microscopy (HRSEM) analysis proved that PANI and ZnO-PANI were deposited as fibres with hairy topography resulting from covalent bonding with the laccase enzymes. The modified electrode (PPy-6/GCE) was used as a platform for the detection of CTAB with three linear ranges of 0.5–100 µM, 200–500 µM, and 700–1900 µM. The sensor displayed a high sensitivity of 0.935 μA μM⁻¹ cm⁻², a detection limit of 0.0116 µM, and acceptable recoveries of 95.02% and 87.84% for tap water and wastewater, respectively. Full article

This study presents the synthesis, characterization, and evaluation of hybrid hydrogels based on calcium alginate (Ca-Alg) and synthetic nanoclay LaponiteRD (Lap), with an emphasis on their swelling and sorption properties. The motivation behind the development of these hybrid hydrogels stems from the need for sustainable materials with enhanced mechanical strength, swelling properties, and sorption capacity for environmental remediation and controlled-release applications. Synthesis methods for the ionotropically cross-linked Ca-Alg hydrogel and Alg–Lap composite hydrogels, based on Alg and Lap in the form of granules and fibres, have been developed. The Fourier-transform infrared spectroscopy (FTIR), Energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD) analyses of composite hydrogels confirmed the successful incorporation of Lap into the Ca-Alg matrix, indicating strong interactions between the polymer and clay, which enhanced the structural integrity of the hydrogels. The morphology of the surface and pore structure of nanocomposites were studied using Scanning Electron Microscopy (SEM). The swelling behaviour of the nanocomposites was largely dependent on the concentrations of Lap and the cross-linking agent (CaCl₂), with higher concentrations leading to more rigid, less swellable structures due to the increased cross-linking density. The sorption studies, specifically with Fe(II) ions, demonstrated that the hybrid hydrogels possess a large sorption capacity, with Lap contributing to selective sorption at lower Fe(II) ion concentrations and Alg enhancing overall capacity at higher concentrations. This suggests that the synergistic interaction between Alg and Lap not only improves mechanical stability but also tailors the sorption properties of the hydrogels. These findings position the Alg-Lap hydrogels as promising materials for a range of environmental applications, including wastewater treatment, heavy metal ion removal, and the design of advanced filtration systems. The study’s insights into the tunability of these hydrogels pave the way for further research into their use in diverse fields such as biomedicine, agriculture, and industrial water management. Full article

The implementation of a machine learning approach to predict vibration suppression, as derived from nanocomposite laminates with piezoelectric shunted systems, is studied in this article. Datasets providing the vibration response and vibration attenuation are developed using parametric finite element simulations. A graphene/fibre-reinforced laminate cantilever beam is used in those simulations. Parameters, including the graphene and fibre reinforcements content, as well as the fibre angles, are among the inputs. Output is the vibration suppression achieved by the piezoelectric shunted system. Artificial Neural Networks are trained and tested using the derived datasets. The proposed methodology can be used for a fast and accurate prediction of the vibration response of nanocomposite laminates. Full article

Cellulose/silica nanocomposites, synthesised through the sol–gel technique, have garnered significant attention for their unique properties and diverse applications. The distinctive characteristics of these nanocomposites are influenced by a range of factors, including the cellulose-to-silica ratio, precursor concentration, pH, catalysts, solvent selection, temperature, processing techniques, and agitation. These variables play a pivotal role in determining the nanocomposites’ structure, morphology, and mechanical properties, facilitating tailoring for specific applications. Studies by Raabe et al. and Barud et al. demonstrated well-deposited silica nanoparticles within the interstitial spaces of cellulosic fibres, achieved through TEOS precursor hydrolysis and the subsequent condensation of hydroxyl groups on the cellulose fibre surface. The introduction of TEOS established a robust affinity between the inorganic filler and the polymer matrix, emphasising the substantial impact of TEOS concentration on the size and morphology of silica nanoparticles in the final composites. The successful functionalisation of cellulose fibres with the TEOS precursor via the sol–gel method was reported, resulting in reduced water uptake and enhanced mechanical strength due to the strong chemical interaction between silica and cellulose. In research conducted by Feng et al., the silica/cellulose composite exhibited reduced weight loss compared to the pristine cellulose matrix, with the integration of silica leading to an elevated temperature of composite degradation. Additionally, Ahmad et al. investigated the effects of silica addition to cellulose acetate (CA) and polyethylene glycol membranes, noting an increase in Young’s modulus, tensile strength, and elongation at break with silica incorporation. However, concentrations exceeding 4% (w/v) resulted in significant phase separations, leading to a decline in mechanical properties. Full article

The realm of composite materials continues to evolve, with researchers pushing the boundaries of understanding and application. This Special Issue published in the Journal of Composites Science encapsulates the essence of these advancements, presenting a curated collection of research articles that highlight the latest developments in the characterization and modelling of composites. The diversity of the covered topics ranges from a foundational understanding of composite behaviours to the application of cutting-edge modelling techniques. Each contribution offers a fresh perspective, expanding our knowledge of composites and setting the stage for future explorations in this dynamic domain. Full article

Reinforcement of silica aerogels, remarkable lightweight mesoporous materials with outstanding insulation performance, is still a challenging research topic. Among the strategies used to overcome their brittleness, one of the most effective is the manufacturing of aerogel composites with embedded fibres. In this work, the incorporation of nanofibres together with microfibres in a tetraethoxysilane–vinyltrimethoxysilane matrix is investigated for the first time for the development of novel aerogel nanocomposites. The nanofibres, synthesized from different aramid fibres, including Kevlar^® pulp, Technora^®, Teijinconex^® and Twaron^® fibres, were used in different combinations with microaramids and the resulting nanocomposites were thoroughly investigated for their physicochemical and thermomechanical features. The properties depended on the type and amount of the nano/microfibre used. While the microfibres exhibited low interaction with the silica matrix, the higher surface of the nanofibres ensured increased contact with the gel matrix. A low bulk density of 161 kg m⁻³ and thermal conductivity of 38.3 mW m⁻¹ K⁻¹ (Hot Disk^®) was achieved when combining the nanofibres obtained from Kevlar^® pulp with the Technora^® or Teijinconex^® long fibres. The nanofibres showed higher dispersion and random orientation and in combination with microfibres led to the improvement by a factor of three regarding the mechanical properties of the aerogel nanocomposites reinforced only with microfibres. The scale-up process of the samples and simulated tests of thermal cycling and vacuum outgassing successfully conducted indicate good compliance with space applications. Full article

A wearable and stretchable strain sensor with a gauge factor above 23 was prepared using a simple and effective technique. Conducting nanocomposite strands were prepared from styrene-b-(ethylene-co-butylene)-b-styrene triblock copolymer (SEBS) and carbon black (CB) through a solvent-processing method that uses a syringe pump. This novel nanocomposite preparation technique is a straightforward and cost-effective process and is reported in the literature for the first time. The work included two stages: the flexible nanocomposite preparation stage and the piezoresistive sensor stage. Depending on its molecular structure, the thermoelastic polymer SEBS is highly resilient to stress and strain. The main aim of this work is to fabricate a highly flexible and piezoresistive nanocomposite fibre/strand. Among the prepared composites, a composite corresponding to a composition just above the percolation threshold was selected to prepare the strain sensor, which exhibited good flexibility and conductivity and a large piezoresistive effect that was linearly dependent on the applied strain. The prepared nanocomposite sensor was stitched onto a sports T-shirt. Commercially available knee and elbow sleeves were also purchased, and the nanocomposite SEBS/CB strands were sewn separately on the two sleeves. The results showed a high sensitivity of the sensing element in the case of breathing activity (normal breathing, a 35% change, and deep breathing at 135%, respectively). In the case of knee and elbow movements, simultaneous measurements were performed and found that the sensor was able to detect movement cycles during walking. Full article

Globally, electricity demand rises by 1.8% per year; according to the American Energy Information Administration, global energy demand will increase by 47% over the next 30 years, driven by demographic and economic growth. Global demand for electricity is growing faster than renewable energy sources. Electricity production from renewable sources (i.e., biomass energy, geothermal energy, hydro energy, solar energy, tidal energy, wind energy) is on its way to strong growth around the world over the next dozen years. With the increasing demand for energy, new technologies and materials are being developed to replace exhaustible traditional construction materials. This article aims to provide a comprehensive overview of the research into the application of composite materials in mainstream power generation. The main energy generation technologies, i.e., photovoltaic panels, wind turbines, fuel cells, and biogas generators, were analysed and discussed. The review presented in this article also covers the latest achievements and prospects for the use of composite materials in energy generation devices. Full article

The aim of this research was to improve the electrical and mechanical properties of carbon-fibre-reinforced polymers (CFRP) based on thermoplastic acrylic resin ELIUM^®, by introducing single-walled carbon nanotubes (SWCNTs) into their structure. The laminates were fabricated using the infusion technique of infiltrating the carbon fabric with the mixture of acrylic resin and SWCNTs. The addition of SWCNTs improved the electrical conductivity through the thickness of the laminate by several times compared to the laminate without modification. No defects or voids were observed in the structure of the fabricated nanocomposites. The introduction of SWCNTs into the CFRP structure increased the Young’s modulus, interlaminar shear strength and impact resistance. DMA analysis showed almost no change in the glass transition temperature of the fabricated SWCNT/CFRP nanocomposites compared to the reference laminate. Full article

This study looks at how incorporating nanofiller into sisal/flax-fibre-reinforced epoxy-based hybrid composites affects their mechanical and water absorption properties. The green Al₂O₃ NPs are generated from neem leaves in a proportion of leaf extract to an acceptable aluminium nitrate combination. Both natural fibres were treated with different proportions of NaOH to eliminate moisture absorption. The following parameters were chosen as essential to achieving the objectives mentioned above: (i) 0, 5, 10, and 15% natural fibre concentrations; (ii) 0, 2, 4, and 6% aluminium powder concentrations; and (iii) 0, 1, 3, and 5% NaOH concentrations. Compression moulding was used to create the hybrid nanocomposites and ASTM standards were used for mechanical testing such as tension, bending, and impact. The findings reveal that combining sisal/flax fibre composites with nanofiller improved the mechanical features of the nanocomposite. The sisal and flax fibre hybridised successfully, with 10% fibres and 4% aluminium filler. The water absorption of the hybrids rose as the fibre weight % increased, and during the next 60 h, all of the specimens achieved equilibrium. The failed samples were examined using scanning electron Microscopic (SEM) images better to understand the composite’s failure in the mechanical experimentations. Al₂O₃ NPs were confirmed through XRD, UV spectroscope and HPLC analysis. According to the HPLC results, the leaf’s overall concentrations of flavonoids (gallocatechin, carnosic acid, and camellia) are determined to be 0.250 mg/g, 0.264 mg/g, and 0.552 mg/g, respectively. The catechin concentration is higher than the phenolic and caffeic acid levels, which could have resulted in a faster rate of reduction among many of the varying configurations, 4 wt.% nano Al₂O₃ particle, 10 wt.% flax and sisal fibres, as well as 4 h of NaOH with a 5 wt.% concentration, producing the maximum mechanical properties (59.94 MPa tension, 149.52 Mpa bending, and 37.9 KJ/m² impact resistance). According to the results, it can be concluded that botanical nutrients may be used effectively in the manufacturing of nanomaterials, which might be used in various therapeutic and nanoscale applications. Full article

Natural substances are increasingly being developed for use in health-related applications. Honey has attracted significant interest, not only for its physical and chemical properties, but also for its antibacterial activity. For the first time, suspensions of Black Forest honeydew honey and manuka honey UMF 20+ were examined for their antibacterial properties against Escherichia coli and Staphylococcus epidermidis using flow cytometry. The inhibitory effect of honey on bacterial growth was evident at concentrations of 10, 20 and 30 v/v%. The minimum inhibitory effects of both honey types against each bacterium were also investigated and reported. Electrospray ionisation (ESI) mass spectrometry was performed on both Black Forest honeydew honey and manuka honey UMF 20+. Manuka honey had a gluconic concentration of 2519 mg/kg, whilst Black Forest honeydew honey had a concentration of 2195 mg/kg. Manuka honey demonstrated the strongest potency when compared to Black Forest honeydew honey; therefore, it was incorporated into nanofiber scaffolds using pressurised gyration and 10, 20 and 30 v/v% manuka honey-polycaprolactone solutions. Composite fibres were analysed for their morphology and topography using scanning electron microscopy. The average fibre diameter of the manuka honey-polycaprolactone scaffolds was found to range from 437 to 815 nm. The antibacterial activity of the 30 v/v% scaffolds was studied using S. epidermidis. Strong antibacterial activity was observed with a bacterial reduction rate of over 90%. The results show that honey composite fibres formed using pressurised gyration can be considered a natural therapeutic agent for various medicinal purposes, including wound-healing applications. Full article

Environmental conservation and waste control have informed and encouraged the use of biodegradable polymeric materials over synthetic non-biodegradable materials. It has been recognized that nano-sized biodegradable materials possess relatively good properties as compared to conventional micron-sized materials. However, the strength characteristics of these materials are inferior to fossil-based non-biodegradable materials. In this study, biodegradable polylactide (PLA), reinforced with treated coconut husk particulates (CCP) for improved mechanical properties, was fabricated using an electrospinning process and representative volume element (RVE) technique, and some of the obtained mechanical properties were compared. It was observed that the electrospun CCP-PLA nanofibre composites show improved mechanical properties, and some of these mechanical properties using both techniques compared favourably well. The electrospun fibres demonstrate superior properties, mostly at 4 wt.% reinforcement. Thus, achieving good mechanical properties utilising agro waste as reinforcement in PLA to manufacture nanocomposite materials by electrospinning method is feasible and provides insight into the development of biodegradable nanocomposite materials. Full article

Ultrasound (US) image guidance is widely used for minimally invasive procedures, but the invasive medical devices (such as metallic needles), especially their tips, can be poorly visualised in US images, leading to significant complications. Photoacoustic (PA) imaging is promising for visualising invasive devices and peripheral tissue targets. Light-emitting diodes (LEDs) acting as PA excitation sources facilitate the clinical translation of PA imaging, but the image quality is degraded due to the low pulse energy leading to insufficient contrast with needles at deep locations. In this paper, photoacoustic visualisation of clinical needles was enhanced by elastomeric nanocomposite coatings with superficial and interstitial illumination. Candle soot nanoparticle-polydimethylsiloxane (CSNP-PDMS) composites with high optical absorption and large thermal expansion coefficients were applied onto the needle exterior and the end-face of an optical fibre placed in the needle lumen. The excitation light was delivered at the surface by LED arrays and through the embedded optical fibre by a pulsed diode laser to improve the visibility of the needle tip. The performance was validated using an ex-vivo tissue model. An LED-based PA/US imaging system was used for imaging the needle out-of-plane and in-plane insertions over approach angles of 20 deg to 55 deg. The CSNP-PDMS composite conferred substantial visual enhancements on both the needle shaft and the tip, with an average of 1.7- and 1.6-fold improvements in signal-to-noise ratios (SNRs), respectively. With the extended light field involving extracorporeal and interstitial illumination and the highly absorbing coatings, enhanced visualisation of the needle shaft and needle tip was achieved with PA imaging, which could be helpful in current US-guided minimally invasive surgeries. Full article

Three multifunctional smart composites for next-generation applications have been studied differently through versatile nanoindentation investigation techniques. They are used in order to determine peculiarities and specific properties for the different composites and to study the charge/matrix, charge/surface, or smart functions interactions. At first, a mapping indentation test was used to check the distribution of hardness and modulus across a large region to examine any non-uniformity due to structural anomalies or changes in properties for a carbon nanotubes (CNTs)-reinforced polypropylene (PP V-2) nanocomposite. This smart composite is suitable to be used in axial impeller fans and the results can be used to improve the process of the composite produced by injection moulding. Secondly, the interfacial properties of the carbon fibre (CF) and the resin were evaluated by a push-out method utilizing the smaller indentation tip to target the individual CF and apply load to measure its displacement under loads. This is useful to evaluate the effectiveness of the surface modification on the CFs, such as sizing. Finally, nanoindentation at different temperatures was used for the probing of the in situ response of smart shape memory polymer composite (SMPC) usable in grabbing devices for aerospace applications. Furthermore, the triggering temperature of the shape memory polymer response can be determined by observing the change of indentations after the heating and cooling cycles. Full article

Epoxy clay nanocomposites have been proven to have improved mechanical, thermal and physical properties over pristine matrix. Thus, the fields of application of epoxy–clay nanocomposites along with their hybrid glass/carbon fibre reinforced composites have grown tremendously during the last few decades. The present review paper covers the research work performed on epoxy clay nanocomposites. It includes the influence of the processing techniques and parameters on the morphology of the nanocomposite, the methods of characterization and the effects of adding nanoclay on the mechanical and physical properties of composite. The improvements in the liquid barrier properties brought about by the addition of nanoclay platelets to epoxy resin are discussed. The variation of physical and mechanical properties with nanoclay type and content are reviewed along with the effects of moisture uptake on these properties. The advances in the development, characterization and applications of hybrid glass fibre reinforced epoxy–clay nanocomposites are discussed. Findings of the research work on the influence of nanoclay addition and exposure to water laden atmospheres on the behaviour of the hybrid glass fibre epoxy–nanoclay composites are presented. Finally, the potential health and environmental issues related to nanomaterials and their hybrid composites are reviewed. Full article