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23 pages, 1069 KB  
Article
Sectoral Dynamics of Sustainable Energy Transition in EU27 Countries (1990–2023): A Multi-Method Approach
by Hasan Tutar, Dalia Štreimikienė and Grigorios L. Kyriakopoulos
Energies 2026, 19(2), 457; https://doi.org/10.3390/en19020457 (registering DOI) - 16 Jan 2026
Abstract
This study critically examines the sectoral dynamics of renewable energy (RE) adoption across the EU-27 from 1990 to 2023, addressing the persistent gap between electricity generation and end-use sectors. Utilizing Eurostat energy balance data, the research employs a robust multi-methodological framework. We apply [...] Read more.
This study critically examines the sectoral dynamics of renewable energy (RE) adoption across the EU-27 from 1990 to 2023, addressing the persistent gap between electricity generation and end-use sectors. Utilizing Eurostat energy balance data, the research employs a robust multi-methodological framework. We apply the Logarithmic Mean Divisia Index (LMDI) decomposition to isolate driving factors, and the Self-Organizing Maps (SOM) of Kohonen to cluster countries with similar transition structures. Furthermore, the Method of Moments Quantile Regression (MMQR) is used to estimate heterogeneous drivers across the distribution of RE shares. The empirical findings reveal a sharp dichotomy: while the share of renewables in the electricity generation mix (RES-E-Renewable Energy Share in Electricity) reached approximately 53.8% in leading member states, the aggregated share in the transport sector (RES-T) remains significantly lower at 9.1%. This distinction highlights that while power generation is decarbonizing rapidly, end-use electrification lags behind. The MMQR analysis indicates that economic growth drives renewable adoption more effectively in countries with already high renewable shares (upper quantiles) due to established market mechanisms and grid flexibility. Conversely, in lower-quantile countries, regulatory stability and direct infrastructure investment prove more critical than market-based incentives, highlighting the need for differentiated policy instruments. While EU policy milestones (RED I–III-) align with progress in power generation, they have failed to accelerate transitions in lagging sectors. This study concludes that achieving climate neutrality requires moving beyond aggregate targets to implement distinct, sector-specific interventions that address the unique structural barriers in transport and thermal applications. Full article
25 pages, 5324 KB  
Article
An Integrated Risk-Informed Multicriteria Approach for Determining Optimal Inspection Periods for Protective Sensors
by Ricardo J. G. Mateus, Rui Assis, Pedro Carmona Marques, Alexandre D. B. Martins, João C. Antunes Rodrigues and Francisco Silva Pinto
Sensors 2026, 26(1), 213; https://doi.org/10.3390/s26010213 - 29 Dec 2025
Viewed by 332
Abstract
Equipment failure is the leading cause of industrial operational disruption, with unplanned downtime accounting for up to 11% of manufacturing revenue, highlighting the need for effective proactive maintenance strategies, such as protective sensors that can detect potential failures in critical equipment before a [...] Read more.
Equipment failure is the leading cause of industrial operational disruption, with unplanned downtime accounting for up to 11% of manufacturing revenue, highlighting the need for effective proactive maintenance strategies, such as protective sensors that can detect potential failures in critical equipment before a functional failure occurs. However, sensors are also subject to hidden failures themselves, requiring periodic failure-finding inspections. This study proposes a novel integrated multimethodological approach combining discrete event simulation, Monte Carlo, optimization, risk analysis, and multicriteria decision analysis methods to determine the optimal inspection period for protective sensors subject to hidden failures. Unlike traditional single-objective models, this approach evaluates alternative inspection periods based on their risk-informed overall values, considering multiple conflicting key performance indicators, such as maintenance costs and equipment availability. The optimal inspection period is then selected considering uncertainties and the intertemporal, intra-criterion, and inter-criteria preferences of the organization. The approach is demonstrated through a case study at the leading Portuguese electric utility, replacing previous empirical inspection standards that did not consider economic costs and uncertainties, supported by an open, transparent, auditable, and user-friendly decision support system implemented in Microsoft Excel using only built-in functions and modeled based on the principles of probability management. The results identified an optimal inspection period of 90 h, representing a risk-informed compromise distinct from the 120 h interval suggested by cost minimization alone, highlighting the importance of integrating organizational preferences into the decision process. A sensitivity analysis confirmed the robustness of this solution, maintaining validity even as the organizational weight for equipment availability ranged between 35% and 82%. The case study shows that the proposed approach enables the identification of inspection intervals that lead to quantitatively better maintenance cost and availability outcomes compared to empirical inspection standards. Full article
(This article belongs to the Section Fault Diagnosis & Sensors)
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64 pages, 6020 KB  
Article
Logistics Performance and the Three Pillars of ESG: A Detailed Causal and Predictive Investigation
by Nicola Magaletti, Valeria Notarnicola, Mauro Di Molfetta, Stefano Mariani and Angelo Leogrande
Sustainability 2025, 17(24), 11370; https://doi.org/10.3390/su172411370 - 18 Dec 2025
Viewed by 617
Abstract
This study investigates the complex relationship between the performance of logistics and Environmental, Social, and Governance (ESG) performance, drawing upon the multi-methodological framework of combining econometrics with state-of-the-art machine learning approaches. Employing Instrumental Variable (IV) Panel data regressions, viz., 2SLS and G2SLS, with [...] Read more.
This study investigates the complex relationship between the performance of logistics and Environmental, Social, and Governance (ESG) performance, drawing upon the multi-methodological framework of combining econometrics with state-of-the-art machine learning approaches. Employing Instrumental Variable (IV) Panel data regressions, viz., 2SLS and G2SLS, with data from a balanced panel of 163 countries covering the period from 2007 to 2023, the research thoroughly investigates how the performance of the Logistics Performance Index (LPI) is correlated with a variety of ESG indicators. To enrich the analysis, machine learning models—models based upon regression, viz., Random Forest, k-Nearest Neighbors, Support Vector Machines, Boosting Regression, Decision Tree Regression, and Linear Regressions, and clustering, viz., Density-Based, Neighborhood-Based, and Hierarchical clustering, Fuzzy c-Means, Model-Based, and Random Forest—were applied to uncover unknown structures and predict the behavior of LPI. Empirical evidence suggests that higher improvements in the performance of logistics are systematically correlated with nascent developments in all three dimensions of the environment (E), social (S), and governance (G). The evidence from econometrics suggests that higher LPI goes with environmental trade-offs such as higher emissions of greenhouse gases but cleaner air and usage of resources. On the S dimension, better performance in terms of logistics is correlated with better education performance and reducing child labor, but also demonstrates potential problems such as social imbalances. For G, better governance of logistics goes with better governance, voice and public participation, science productivity, and rule of law. Through both regression and cluster methods, each of the respective parts of ESG were analyzed in isolation, allowing us to study in-depth how the infrastructure of logistics is interacting with sustainability research goals. Overall, the study emphasizes that while modernization is facilitated by the performance of the infrastructure of logistics, this must go hand in hand with policy intervention to make it socially inclusive, environmentally friendly, and institutionally robust. Full article
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48 pages, 2294 KB  
Systematic Review
Evolution of Risk Analysis Approaches in Construction Disasters: A Systematic Review of Construction Accidents from 2010 to 2025
by Elias Medaa, Ali Akbar Shirzadi Javid and Hassan Malekitabar
Buildings 2025, 15(20), 3701; https://doi.org/10.3390/buildings15203701 - 14 Oct 2025
Cited by 1 | Viewed by 1926
Abstract
Structural collapses are a major threat to urban safety and infrastructure resilience and as such there is growing research interest in understanding the causes and improving the prediction of risk to prevent human and material losses. Whether caused by fires, earthquakes or progressive [...] Read more.
Structural collapses are a major threat to urban safety and infrastructure resilience and as such there is growing research interest in understanding the causes and improving the prediction of risk to prevent human and material losses. Whether caused by fires, earthquakes or progressive failures due to overloads and displacements, these events have been the focus of investigation over the past 15 years. This systematic literature review looks at the use of formal risk analysis models in structural failures between 2010 and 2025 to map methodological trends, assess model effectiveness and identify future research pathways. From an initial database of 139 documented collapse incidents, only 42 were investigated using structured risk analysis frameworks. A systematic screening of 417 related publications yielded 101 peer-reviewed studies that met our inclusion criteria—specifically, the application of a formal analytical model. This discrepancy highlights a significant gap between the occurrence of structural failures and the use of rigorous, model-based investigation methods. The review shows a clear shift from single-method approaches (e.g., Fault Tree Analysis (FTA) or Finite Element Analysis (FEA)) to hybrid, integrated models that combine computational, qualitative and data-driven techniques. This reflects the growing recognition of structural failures as socio-technical phenomena that require multi-methodological analysis. A key contribution is the development of a strategic framework that classifies models by complexity, data requirements and cost based on patterns observed across the reviewed papers. This framework can be used as a practical decision support tool for researchers and practitioners to select the right model for the context and highlight the strengths and limitations of the existing approaches. The findings show that the future of structural safety is not about one single “best” model but about intelligent integration of complementary context-specific methods. This review will inform future practice by showing how different models can be combined to improve the depth, accuracy and applicability of structural failure investigations. Full article
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17 pages, 5565 KB  
Article
Green Mild Acid Treatment of Recycled Concrete Aggregates: Concentration Thresholds for Mortar Removal While Avoiding Degradation of Original Limestone Aggregate and Concrete
by Shunquan Zhang and Yifan Zhang
Materials 2025, 18(15), 3673; https://doi.org/10.3390/ma18153673 - 5 Aug 2025
Viewed by 829
Abstract
While acetic acid has proven effective as a mild acidic treatment for removing adhered mortar from recycled concrete aggregate (RCA) surfaces, its potential for dissolving damage to the surface of the original natural coarse aggregate (NCA) within the RCA and its impact on [...] Read more.
While acetic acid has proven effective as a mild acidic treatment for removing adhered mortar from recycled concrete aggregate (RCA) surfaces, its potential for dissolving damage to the surface of the original natural coarse aggregate (NCA) within the RCA and its impact on the resultant concrete properties require careful consideration. This investigation systematically evaluates the effects of varying concentrations of dilute acetic acid solutions, commonly used in RCA treatment protocols, through a multi-methodological approach that includes comprehensive physical characterization, stylus and 3D optical profilometry, scanning electron microscopy (SEM), and nanoindentation analysis. The results show that even dilute acid solutions have an upper concentration limit, as excessive acid concentration, specifically 0.4 M, induces significant textural dislocations on NCA surfaces, creating millimeter-scale erosion pits that increase aggregate water absorption by 18.5%. These morphological changes significantly impair concrete workability and reduce compressive strength performance. Furthermore, microstructural analysis reveals a 45.24% expansion in interfacial transition zone (ITZ) thickness, accompanied by notable reductions in elastic modulus and microhardness characteristics. In practical RCA treatment applications, for RCA containing limestone-based NCA, it is recommended to use acetic acid concentrations between 0.1 and 0.3 M to avoid substantial physical and microstructural degradation of aggregates and concrete. Full article
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23 pages, 5352 KB  
Article
Events and Festivals as Strategic Tools for Understanding and Assessing the Symbolic Reconfiguration of the World Urban System
by Roberto Díez-Pisonero
Urban Sci. 2025, 9(6), 223; https://doi.org/10.3390/urbansci9060223 - 13 Jun 2025
Cited by 1 | Viewed by 5730
Abstract
The growing importance of the symbolic dimension in urban globalisation has led cities to compete not only in economic terms, but also in cultural and symbolic arenas. In this context, events and festivals have emerged as strategic tools for building reputation, attracting global [...] Read more.
The growing importance of the symbolic dimension in urban globalisation has led cities to compete not only in economic terms, but also in cultural and symbolic arenas. In this context, events and festivals have emerged as strategic tools for building reputation, attracting global audiences, and projecting soft power. This study introduces an updated version of the Synthetic Index of Events and Festivals (SIEF), which evaluates the positioning of 150 cities based on their capacity to host significant cultural and sporting events. Using a multi-methodological approach that combines an extensive literature review with a statistical analysis of data from various international organisations, the findings reveal a complex urban hierarchy. Globally multifunctional cities coexist with secondary or globalising ones that gain symbolic visibility through thematic specialisation. This study also identifies synergies between different event types and provides evidence of thematic clusters within the global urban network. The results underscore the importance of incorporating cultural indicators into global urban studies and position events as a privileged lens through which to examine the symbolic reconfiguration of the contemporary urban system. Full article
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42 pages, 15664 KB  
Article
Multimethodological Approach for the Evaluation of Tropospheric Ozone’s Regional Photochemical Pollution at the WMO/GAW Station of Lamezia Terme, Italy
by Francesco D’Amico, Giorgia De Benedetto, Luana Malacaria, Salvatore Sinopoli, Arijit Dutta, Teresa Lo Feudo, Daniel Gullì, Ivano Ammoscato, Mariafrancesca De Pino and Claudia Roberta Calidonna
AppliedChem 2025, 5(2), 10; https://doi.org/10.3390/appliedchem5020010 - 20 May 2025
Cited by 2 | Viewed by 3035
Abstract
The photochemical production of tropospheric ozone (O3) is very closely linked to seasonal cycles and peaks in solar radiation occurring during warm seasons. In the Mediterranean Basin, which is a hotspot for climate and air mass transport mechanisms, boreal warm seasons [...] Read more.
The photochemical production of tropospheric ozone (O3) is very closely linked to seasonal cycles and peaks in solar radiation occurring during warm seasons. In the Mediterranean Basin, which is a hotspot for climate and air mass transport mechanisms, boreal warm seasons cause a notable increase in tropospheric O3, which unlike stratospheric O3 is not beneficial for the environment. At the Lamezia Terme (code: LMT) World Meteorological Organization—Global Atmosphere Watch (WMO/GAW) station located in Calabria, Southern Italy, peaks of tropospheric O3 were observed during boreal summer and spring seasons, and were consequently linked to specific wind patterns compatible with increased photochemical activity in the Tyrrhenian Sea. The finding resulted in the introduction of a correction factor for O3 in the O3/NOx (ozone to nitrogen oxides) ratio “Proximity” methodology for the assessment of air mass aging. However, some of the mechanisms driving O3 patterns and their correlation with other parameters at the LMT site remain unknown, despite the environmental and health hazards posed by tropospheric O3 in the area. In general, the issue of ozone photochemical pollution in the region of Calabria, Italy, is understudied. In this study, the behavior of O3 at the site is assessed with remarkable detail using nine years (2015–2023) of data and correlations with surface temperature and solar radiation. The evaluations demonstrate non-negligible correlations between environmental factors, such as temperature and solar radiation, and O3 concentrations, driven by peculiar patterns in local wind circulation. The northeastern sector of LMT, partly neglected in previous works, yielded higher statistical correlations with O3 than expected. The findings of this study also indicate, for central Calabria, the possibility of heterogeneities in O3 exposure due to local geomorphology and wind patterns. A case study of very high O3 concentrations reported during the 2015 summer season is also reported by analyzing the tendencies observed during the period with additional methodologies and highlighting drivers of photochemical pollution on larger scales, also demonstrating that near-surface concentrations result from specific combinations of multiple factors. Full article
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22 pages, 7358 KB  
Article
A Top-Down, Multi-Method and Multi-Scale Approach to Studying the Byzantine–Umayyad Settlement of Umm ar-Rasas (Amman, Jordan)
by Marilena Cozzolino, Francesca Di Palma, Roberto Gabrielli, Paolo Mauriello and Giuseppe Scardozzi
Heritage 2025, 8(5), 177; https://doi.org/10.3390/heritage8050177 - 17 May 2025
Viewed by 1727
Abstract
The present study constitutes the latest in a series of investigations conducted between 2021 and 2023 as part of the ongoing, multidisciplinary research project at the UNESCO archaeological site of Umm ar-Rasas in Amman Governorate, Jordan, which began in 2013. Building on the [...] Read more.
The present study constitutes the latest in a series of investigations conducted between 2021 and 2023 as part of the ongoing, multidisciplinary research project at the UNESCO archaeological site of Umm ar-Rasas in Amman Governorate, Jordan, which began in 2013. Building on the foundations of previous studies, this latest research offers a comprehensive analysis of the region, with a special focus on pinpointing the boundaries of the Byzantine–Umayyad settlement. The delineation of these boundaries has hitherto been the subject of theoretical discourse only, thus rendering this study a significant addition to the field. An innovative multi-dimensional, multi-methodological, and multi-scalar approach has been adopted, incorporating the capabilities of remote sensing technologies, archaeological surveys, laser scans, and geophysical prospecting to facilitate a shared interpretation of the results. This approach has culminated in the establishment of a probable configuration of the northern limits, which is truly remarkable. Full article
(This article belongs to the Section Archaeological Heritage)
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24 pages, 5336 KB  
Article
Influence of High-Density Community Spaces on the Walking Activity of Older Adults: A Case Study of Macau Peninsula
by Xiangyu Chen, Ning Wang and Hua Tang
Buildings 2025, 15(9), 1505; https://doi.org/10.3390/buildings15091505 - 30 Apr 2025
Cited by 3 | Viewed by 1786
Abstract
Macau’s aging communities face growing challenges in meeting the needs of older residents due to rising population density and extremely limited land resources. The concentration of outdated residential buildings—home to a substantial older adult population—exacerbates issues related to age-associated physical decline. For seniors [...] Read more.
Macau’s aging communities face growing challenges in meeting the needs of older residents due to rising population density and extremely limited land resources. The concentration of outdated residential buildings—home to a substantial older adult population—exacerbates issues related to age-associated physical decline. For seniors who prefer familiar environments, the spatial constraints inherent in these densely built urban areas increasingly conflict with their specific gerontological needs, indicating the urgent need for urban renewal. This study employs a multi-methodological framework to examine aging populations in Macau’s high-density urban contexts. In Phase I, questionnaire surveys combined with SPSS 26.0-based cluster analysis are employed to (1) stratify older adults according to walking behavior patterns; (2) identify subgroup-specific needs and (3) establish key demographic correlates. Based on the socio-ecological framework, Phase II implements spatial analytics through ArcGIS demarcation of pedestrian catchment areas. This phase further integrates point-of-interest (POI) distribution analysis with space syntax-derived axial map evaluations to formulate typological mobility guidelines for different age cohorts. This study outlines the community walking space requirements of older adults in Macau and explores the influence of high-density community spaces on older adults. A practical evaluation method is proposed to assess age-friendly features of urban pathways, identifying the key environmental factors and their respective impacts. These preliminary findings may inform basic planning principles and adaptive design approaches for older adult-oriented pedestrian spaces. Full article
(This article belongs to the Section Architectural Design, Urban Science, and Real Estate)
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14 pages, 1318 KB  
Article
Exploring the Application of Text-to-Image Generation Technology in Art Education at Vocational Senior High Schools in Taiwan
by Chin-Wen Liao, Hsiang-Wei Chen, Bo-Siang Chen, I-Chi Wang, Wei-Sho Ho and Wei-Lun Huang
Information 2025, 16(5), 341; https://doi.org/10.3390/info16050341 - 23 Apr 2025
Viewed by 2573
Abstract
Exploring the potential of text-to-image generation technology in Taiwanese vocational high school art courses, this study employs a conceptual framework of technology integration, creative thinking, and metacognitive abilities, focusing on its effects on teaching strategies as well as students’ digital art creation skills [...] Read more.
Exploring the potential of text-to-image generation technology in Taiwanese vocational high school art courses, this study employs a conceptual framework of technology integration, creative thinking, and metacognitive abilities, focusing on its effects on teaching strategies as well as students’ digital art creation skills and cognitive and creative development. The study was conducted through a multi-methodological approach that includes a systematic literature review plus participatory action research and qualitative analysis. The results showed that integrating text-to-image technology with education boosted students’ interest in activities such as prompt design and project creation and suited themes like landscapes and conceptual art. Testing AI tools enhanced technical proficiency (average of 3.95/5), while pedagogy shifted to project-based learning, increasing engagement. Students’ digital art skills improved from 3.26 to 3.78 (16% growth), with creativity and originality (3.82/5), style diversity, visual complexity, and divergent thinking notably advanced. The technology also fostered metacognitive skills and critical thinking, proving to be an effective teaching aid beyond a mere digital tool. This discovery provides a fresh theoretical viewpoint and instructional procedures for high school art education curricula, anchored in technology, and highlights the importance of nurturing students’ innovativeness and adaptability within the contemporary digital age. Full article
(This article belongs to the Special Issue Generative AI Technologies: Shaping the Future of Higher Education)
26 pages, 10028 KB  
Article
An African Art Re-Discovered: New Revelations on Sword Manufacture in Dahomey
by Ron Lawrence Anderson, Filomena Salvemini, Maxim Avdeev and Vladimir Luzin
Heritage 2025, 8(2), 62; https://doi.org/10.3390/heritage8020062 - 7 Feb 2025
Viewed by 3936
Abstract
Antique swords from the pre-colonial West African kingdom of Dahomey are aesthetically unique, but they also have many design features inspired by swords from Europe, the Islamic world and elsewhere. As the kingdom was famous for importing luxury European objects, this study aimed [...] Read more.
Antique swords from the pre-colonial West African kingdom of Dahomey are aesthetically unique, but they also have many design features inspired by swords from Europe, the Islamic world and elsewhere. As the kingdom was famous for importing luxury European objects, this study aimed to pinpoint evidence of Dahomean sword composition and manufacture to determine scientifically whether they were being made in Dahomey, or imported. An inter-disciplinary team made up of historical archaeologists and neutron scientists examined six 19th century Dahomean swords, using a non-invasive multi-methodological approach based on neutron tomography, powder diffraction full pattern analysis and diffraction residual stress measurements. The findings suggest that, despite their foreign design influences, not only were these striking heritage objects made in Africa, they may also have been likely made from locally smelted iron–something that contradicts the assumptions of the few existing historical reports. This has important implications for studies on the kingdom, and also helps to further the long-standing debate surrounding European iron imports—not just within Dahomey, but throughout the wider West African region. Full article
(This article belongs to the Special Issue Recent Progress in Cultural Heritage Diagnostics)
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26 pages, 6131 KB  
Article
Time-Varying Impacts of Monetary Policy and Socio-Economic Factors on China’s CO2 Emissions and Ecological Footprint: A Multi-Methodological Analysis
by Yu Tang, Iftikhar Yasin and Khaliq ul Rehman
Sustainability 2024, 16(24), 10808; https://doi.org/10.3390/su162410808 - 10 Dec 2024
Cited by 3 | Viewed by 2335
Abstract
This research explores the least explored domain concerning the impact of monetary tactics on carbon dioxide emissions in China, thereby adding depth to environmental economics. The analysis spans 1982–2022 and explores the interplay between monetary instruments, ecological footprint, CO2 emissions, and factors [...] Read more.
This research explores the least explored domain concerning the impact of monetary tactics on carbon dioxide emissions in China, thereby adding depth to environmental economics. The analysis spans 1982–2022 and explores the interplay between monetary instruments, ecological footprint, CO2 emissions, and factors like human capital, GDP per capita, remittances, urbanization, and fossil fuel dependence. The investigation utilizes a multifaceted approach, including wavelet analysis techniques, like wavelet power spectrum, wavelet coherence analysis, quantile on quantile, and quantile regression. The findings unveil critical insights. The results demonstrate that monetary policy has had differing effects on emissions depending on the time. Contractionary policies are good for lowering medium- and long-term emissions, even if they cause a short-term increase in emissions. Furthermore, the study emphasizes the beneficial impact of human capital development on CO2 emissions. Fossil fuels, per capita income, and population significantly contribute to environmental damage beyond monetary policy. This research contributes original insights by integrating monetary policy and socio-economic factors in a comprehensive, multi-methodological framework, offering valuable guidance for crafting policies that balance economic growth with environmental sustainability. Full article
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15 pages, 1954 KB  
Article
A Multi-Methodological Conceptual Framework to Explore Systemic Interventions
by Alberto Paucar-Cáceres and Leila Abuabara
Systems 2024, 12(12), 527; https://doi.org/10.3390/systems12120527 - 27 Nov 2024
Cited by 1 | Viewed by 2243
Abstract
The paper proposes a ‘Systemic Multi-methodological Framework’ for multi-methodological management science/operational research (MS/OR) interventions. Based on John Mingers’ framework for mapping MS/OR methodologies/methods/techniques, we advance a systemic framework to enhance systemic intervention. The framework draws from the key elements of Robert Flood and [...] Read more.
The paper proposes a ‘Systemic Multi-methodological Framework’ for multi-methodological management science/operational research (MS/OR) interventions. Based on John Mingers’ framework for mapping MS/OR methodologies/methods/techniques, we advance a systemic framework to enhance systemic intervention. The framework draws from the key elements of Robert Flood and Mike Jackson’s and Mingers’ concepts for multi-methodological practice. We discuss both the practical difficulties of applying Mingers’ notional systems in the real world and the cultural and psychological obstacles that prevent the viability of a multi-method and multi-paradigm intervention. We discuss the insights that are useful for overcoming the obstacles inherent to a multi-methodological intervention. By proposing an original framework, we aim to contribute to the debate about increasing systemic interventions and multi-methodological practice in MS/OR. Full article
(This article belongs to the Special Issue The Systems Thinking Approach to Strategic Management)
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11 pages, 5167 KB  
Article
Unveiling the Bluish Green Chalcedony Aquaprase™—The Study of Its Microstructure and Mineralogy
by Sara Monico, Ilaria Adamo, Valeria Diella, Yianni Melas, Loredana Prosperi and Nicoletta Marinoni
Crystals 2024, 14(11), 1003; https://doi.org/10.3390/cryst14111003 - 19 Nov 2024
Cited by 1 | Viewed by 2000
Abstract
A bluish green chalcedony (a micro to crypto polycrystalline form of silica) from Africa has been marketed with the trademark AQUAPRASETM. A multimethodological approach, combining gemological analyses, thin section examination, scanning electron microscopy, X-ray powder diffraction, Raman spectroscopy, and trace elements [...] Read more.
A bluish green chalcedony (a micro to crypto polycrystalline form of silica) from Africa has been marketed with the trademark AQUAPRASETM. A multimethodological approach, combining gemological analyses, thin section examination, scanning electron microscopy, X-ray powder diffraction, Raman spectroscopy, and trace elements chemical analyses by LA–ICP–MS, was carried out to characterize this material from a gemological and mineralogical point of view. The chalcedony samples consist of a mixture of quartz and moganite, as shown by the X-ray powder diffraction analysis and Raman spectroscopy. “Aquaprase” showed a strong microstructural zoning in terms of grain size, from macrocrystalline to micro and crypto, and morphology. Trace element variations correlated well with the different colored areas of the samples. In particular, the main chromophore ion present in the bluish green areas of the “aquaprase” chalcedony was chromium, followed by iron and nickel, so this chalcedony could be included in the group of chromium-bearing chalcedony. Rayleigh light scattering contributed to the blue hue of the gems. Full article
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15 pages, 4943 KB  
Article
In-Depth Characterization of Natural Clays from Southeast Albania
by Altin Mele, Viviana Scognamiglio, Valeria Nocerino, Luca De Stefano, Arben Memo, Roberta G. Toro, Manuela Rossi, Francesco Baldassarre and Francesco Capitelli
Crystals 2024, 14(10), 903; https://doi.org/10.3390/cryst14100903 - 18 Oct 2024
Cited by 2 | Viewed by 2092
Abstract
Clays have been exploited in the manufacture of diverse products from ceramics to paints, pharmaceuticals, plastics, cosmetics, and more. Thus, they can be used in many industrial applications, showing good adsorbent ability thanks to their lamellar structure, high cation exchange capacity, pore size [...] Read more.
Clays have been exploited in the manufacture of diverse products from ceramics to paints, pharmaceuticals, plastics, cosmetics, and more. Thus, they can be used in many industrial applications, showing good adsorbent ability thanks to their lamellar structure, high cation exchange capacity, pore size distribution, and large surface area. For this reason, considerable attention has been paid to their in-depth characterization, for further integration in sectors such as biomedicine, construction, remediation, aerospace, and nanotechnology. For this aim, two samples of natural clays, ALO1 and PRE4, from the southeast part of Albania, were subject to a multi-methodological characterization, with the aim of addressing the use of such geomaterials in possible sensing applications. X-ray fluorescence analysis, morphological characterization of the samples, and energy-dispersive system spectroscopy pointed to an extreme mineralogical variety, with kaolinite in AL01 and montmorillonite in PRE4 as the most abundant phases. This fact was further confirmed by powder X-ray diffraction, showing a quartz content of 20%, a kaolinite content of 64%, and a muscovite content of 16% for ALO1; meanwhile, for PRE4, we found a content of quartz of 45%, a content of montmorillonite of 34.9%, and a content of clinochlore of 20%. Infrared spectroscopy and thermal analyses confirmed the presence of hydroxyl groups in both samples, suggesting a higher content in ALO1. Measurement of N2 adsorption isotherms on the clay samples yields specific surface areas of 87 m2/g for PRE4 and 32 m2/g for ALO1, pore volumes of 0.721 cm3/g for PRE4 and 0.637 cm3/g for ALO1, and similar pore sizes in the range of 6–12 nm. Electrochemical analysis highlighted a good conductivity of ALO1 and PRE4 when used for the modification of commercial carbon-based screen-printed electrodes. In detail, higher currents were registered by differential pulse voltammetry for the electrodes modified with the clays with respect to bare electrodes, as well as good repeatability of the measurements. In addition, a comparative study with nanomaterials, known for their good conductivity, was achieved, using carbon black and gold nanoparticles as a reference, showing that the conductivity of the clays was lower than but not so different from those of the reference materials. Full article
(This article belongs to the Collection Topic Collection: Mineralogical Crystallography)
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