Search Results (35)

The hornblende gabbro investigated in this study crops out in northwestern Elazığ, eastern Türkiye, within the Southeastern Anatolian Orogenic Belt (SAOB), where Late Cretaceous ophiolitic, volcanic, plutonic, and metamorphic units are widely exposed. This study examines the petrology, whole-rock geochemistry, Sr–Nd isotopic composition, mineral chemistry, and crystallisation conditions of these gabbroic bodies to constrain their petrogenesis and tectonomagmatic significance. Field observations show that the rock occurs as rounded to sub-rounded blocks with fresh inner cores and altered outer rims. Petrographic and XRD data indicate that the fresh gabbro mainly consists of plagioclase and amphibole, whereas the altered outer rims contain quartz and minor secondary phases. Whole-rock geochemical data classify the samples as low- to medium-K, tholeiitic, and predominantly metaluminous gabbro. Primitive mantle-normalised trace-element patterns display enrichment in large-ion lithophile elements and depletion in high-field-strength elements, whereas chondrite-normalised REE patterns show slight LREE enrichment, relatively flat HREE patterns, and weak Eu anomalies. Sr–Nd isotopic compositions are characterised by positive εNd_(T) values (+4.4 to +5.3) and moderately radiogenic initial ⁸⁷Sr/⁸⁶Sr ratios (0.704792–0.705344), indicating a predominantly mantle-derived magma source affected by subduction-related modification, with limited crustal contribution. Mineral chemistry data show that amphiboles belong to the calcic amphibole group and plot in the magnesio-hornblende field. Amphibole thermobarometric calculations yielded temperatures of 873–991 °C and pressures of 1.49–3.26 kbar, corresponding to crystallisation depths of 5.1–15.3 km. Overall, the results indicate that the hornblende gabbro was derived from a mafic magma generated from a spinel lherzolite mantle source and crystallised in a subduction-related tectonomagmatic setting. Full article

The Felbertal tungsten mineralisation in the Tauern Window (Eastern Alps) is hosted by the Early Paleozoic Habach Complex belonging to the Lower Schieferhülle. In predominantly mafic meta-volcanic rocks, mostly amphibolites, green amphibole crystallised in assemblages with plagioclase, epidote, chlorite, sphene and quartz. Microstructural features and preferential orientation of the amphiboles define planar-linear structures of finite strain and indicate that their crystallisation is coeval to the main deformation event. Amphibole crystals display core-to-rim zonations with increasing ^IVAl, ^VIAl, Na and Ti and decreasing Si, covering actinolite over magnesio-hornblende to tschermakite compositions. Amphibole zonations and assemblages are similar to metabasites in the classical Barrovian mineral zones in the Dalradian of Scotland and typical of a prograde metamorphism from the greenschist over epidote-amphibolite to the lower amphibolite facies. Amphibole endmember geothermobarometry defines an early P-T path segment from 400 °C/2 kbar to 540 °C/6 kbar, and a consecutive later P-T path segment from ~500–540 °C/6 kbar to maximal P-T conditions of ~620–640 °C/7–8 kbar. As Carboniferous granitoid intrusions within the Habach Complex underwent penetrative ductile deformation, an Alpine Tertiary age of the lower amphibolite facies metamorphism, as observed in other parts of the Lower Schieferhülle, appears suitable. Full article

The solid structure of industrial sinter comprises seven mineral associations (A, B, C, D, Ds, E, N) which have different relative abundances of key minerals, textures and spatial relationships to micro-macropores and hematite nuclei. Among the key characteristics of the mineral associations: (MA), MA-A comprises abundant SFCA-I microplates with hematite; MA-B consists of disseminated fine-grained magnetite in a network of SFCA-III microplates; MA-C is similar to MA-B but contains patches of dendritic SFCA-III with larnite and minor glass; MA-D comprises magnetite surrounded by coarse prisms of SFCA within glass; MA-Ds, a subtype of MA-D, includes SFCA with secondary skeletal hematite; MA-E consists of anhedral to skeletal magnetite or hematite in a matrix of glass; and MA-N comprises unmelted hematite nuclei from iron ore feedstock. SFCA-III and SFCA-I are dominant in MA-B and MA-A, respectively, whilst magnetite is the most common mineral in MA-C, MA-D/Ds and MA-E. Low-temperature sintering samples are largely of MA-A to MA-D (62 area %), which contain higher combined levels of SFCA-SFCA-III and lower levels of magnetite-dominant MA-E (12.6 area %), whereas high-temperature/magnetite sintering examples had high levels of magnetite-dominant MA-E (31.6 area %) and MA-D/Ds (52.1 area %) and low levels of MA-A to MA-C (8.9 area %). It is proposed that the formation of each MA is controlled by the peak sintering temperature attained, the dwell time at higher temperature which adversely allows fractional crystallisation to tie up more Fe in magnetite rather than forming SFCA phases during cooling, and especially a slower rate of cooling which promotes the formation of more SFCA family phases at lower temperatures. However, local variations in chemistry inherited from raw material granulation and assimilation during sintering of Si-rich gangue or ore nuclei are also important. Full article

Post-collisional Cu-Au-Ni-Co-Pt-Pd-Sc porphyry [Duck Creek porphyry system (DCPS)] with overlying Au-Te-Bi-W-HRE epithermal mineralisation [Highway epithermal system (HES)] has been discovered in the core of the Mitakoodi anticline, southwest of Cloncurry. Xenotime and monazite geochronology indicate mineralisation occurred between ~1490 and 1530 Ma. Host rock lithologies show widespread potassic and/or propylitic to phyllic alteration. Paragenesis of porphyry sulphides indicates early crystallisation of pyrite, followed by chalcopyrite, with bornite forming by hydrothermal alteration of chalcopyrite. Cu sulphides also show the effect of supergene oxidation alteration with rims of covellite, digenite and chalcocite. Redox conditions deduced from the V/Sc systematics indicate that the DCPS contains both highly oxidised (typical of porphyries) and reduced lithologies, typical of plume-generated tholeiitic and alkaline suites. Ni/Te and Cu/Te systematics plot within the fields defined by epithermal and porphyry deposits. Duck Creek chalcophile and highly siderophile element (Cu, MgO and Pd) systematics resemble data from porphyry mineral systems, at Cadia, Bingham Canyon, Grasberg, Skouries, Kalmakyr, Elaisite, Assarel and Medet. SAM geophysical inversion models suggest the presence of an extensive porphyry system below the HES. A progressive increase in molar Cu/Au ratios with depth from the HES to the DCPS supports this conclusion. Three metal sources contributed to the linked DCPS-HES viz., tholeiitic ferrogabbro, potassic ultramafic to mafic system and an Fe and Ca-rich alkaline system. The latter two imparted non-crustal superchondritic Nb/Ta ratios that are characteristic of many deposits in the eastern Mount Isa Block. The associated tholeiite and alkaline magmatism reflect mantle plume upwelling through a palaeo-slab window that had accreted below the eastern flank of the North Australian craton following west-verging collision by the Numil Terrane. Discovery of this linked mineral system provides a new paradigm for mineral exploration in the region. Full article

Due to the significant increase in consumerism, the amount of household appliance waste has been growing, particularly in the form of glass. This study explores the possibility of using this glass (HAGw) as a replacement additive in cement-based products. The article examines the properties of HAGw, including its chemical composition (XRF), mineral composition (XRD), particle morphology, and size distribution. Scanning electron microscopy (SEM) analysis revealed that HAGw particles could partially crystallise, forming needle-shaped minerals. When replacing 10%, 20%, and 30% of cement with dispersive HAGw, the rate of cement hydration remains unchanged; however, the amount of heat released decreases proportionally to the amount of waste used. Thermogravimetric analysis indicated that substituting a part of the cement with HAGw reduces the amount of portlandite over longer curing periods, indicating the pozzolanic activity of the glass, while the quantity of calcium silicate hydrates (C-S-H) remains similar to the control sample. In the microstructure of the samples, numerous agglomerates of glass particles are formed, increasing the porosity of the cement matrix and reducing its strength. However, over time, the surface of the glass particles begins to dissolve, leading to the formation of new cement hydrates that gradually fill the voids. This process enhances cement density, increases the ultrasonic pulse velocity, and improves compressive strength, particularly after 90 days, compared to the properties of the samples at 7 and 28 days of curing. Full article

Fersmite ([Ca,Ce,Na][Nb,Ta,Ti]₂[O,OH,F]₆) from the Mount Brussilof magnesite deposit, British Columbia, Canada occurs as accessory brittle, black, submetallic to vitreous lustre, acicular to platy crystals up to 2 cm long, developed in sparry dolomite, which lines cavities in sparry magnesite. Fersmite also occurs as smaller crystals (<3 mm) enclosed by dolomite, where it is commonly fractured or broken, formed during the final stage of dolomite crystallisation. Electron microprobe (WDS) major element data indicate that the grains confirmed to be fersmite by X-ray diffraction contain >50% Nb and are atypically Ta-poor. Fersmite contains significant U and Th (up to 4700 ppm and 6 wt.%, respectively) and therefore is a viable mineral for U-Pb geochronology. A series of laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) spot analyses and maps were collected on fersmite grains. Although the fersmite grains have considerable common Pb and have experienced Pb loss, the U-Pb spot data suggest growth or pervasive resetting at ca. 190 Ma. Some ⁴⁰Ar/³⁹Ar ages (two of four samples) are consistent with the ~190 Ma U-Pb date. Electron microprobe and LA-ICP-MS mapping indicate that the fersmite is middle to heavy rare earth element-rich. The ~190 Ma fersmite age estimate provides an approximate upper time constraint on the age of sparry magnesite mineralisation, sparry dolomitisation, and, indirectly, on the formation of MVT deposits in the Kicking Horse Rim area and possibly elsewhere in southeastern British Columbia. Full article

Silicocarnotite, Ca₅[(PO₄)(SiO₄)](PO₄), was first described from slag over 140 years ago. In 2013, it was officially recognised as a mineral after being discovered in the larnite–gehlenite hornfels of the pyrometamorphic Hatrurim Complex. This paper describes the composition and structure of V-bearing silicocarnotite, crystals of which were found in a thin paralava vein cutting through the gehlenite hornfels. A network of thin paralava veins a few centimetres thick is widespread in the gehlenite hornfels of the Hatrurim Basin, Negev Desert, Israel. These veins, typically coarse crystalline rock and traditionally referred to as paralava, have a symmetrical structure and do not contain glass. Silicocarnotite in the paralava, whose primary rock-forming minerals are gehlenite, flamite, Ti-bearing andradite, rankinite and pseudowollastonite, was a relatively late-stage high-temperature mineral, crystallising at temperatures above 1100 °C. It formed from the reaction of a Si-rich residual melt with pre-existing fluorapatite. A single-crystal structural study of silicocarnotite (Pnma, a = 6.72970(12) Å, b = 15.5109(3) Å, c = 10.1147(2) Å) suggests that the phenomenon of Ca1 position splitting observed in this mineral is most likely related to the partial ordering of Si and P in the T2O₄ tetrahedrons. Raman studies of silicocarnotite with varying vanadium content have shown that phases with V₂O₅ content of 3–5 wt.% exhibit additional bands at approximately 864 cm⁻¹, corresponding to vibrations of ν₁(VO₄)³⁻. Full article

Interpretation of ⁴⁰Ar/³⁹Ar dates of alkali feldspar and U-Pb dates of apatite depends on the dominant mechanism of isotopic transport in these minerals, which can be either diffusion or fluid-assisted dissolution-reprecipitation. To clarify the contributions of these processes, we have conducted a holistic study of alkali feldspar, apatite and other minerals from the Mt. Isa Inlier in NE Australia. Mineral characterisation by electron microscopy, optical cathodoluminescence imaging and element mapping reveal a complex interplay of textures resulting from magmatic crystallisation, deuteric recrystallisation, local deformation with subsequent higher-temperature alteration, and finally ubiquitous low-temperature alteration. U-Pb and Pb isotopic data for zircon, apatite, fluorite and alkali feldspar suggest that the latter event occurred at ~300 Ma and was associated with fluid-assisted exchange of Pb isotopes between minerals in the same rock, causing some apatite grains to have ²⁰⁷Pb-corrected U-Pb dates that exceed their crystallisation age. However, this event had no unequivocal effect on the ⁴⁰Ar/³⁹Ar or Rb-Sr systematics of the alkali feldspar, which were disturbed by higher-temperature alteration at ~1450 Ma. The age of the latter event is derived from Rb-Sr data. ⁴⁰Ar/³⁹Ar dates are very scattered and suggest that ⁴⁰Ar redistribution proceeded by diffusion in the presence of traps in some places and by dissolution-reprecipitation with variable amounts of recycling in other places. Our results demonstrate the complex effects that interaction with limited amounts of fluids can have on ⁴⁰Ar/³⁹Ar dates of alkali feldspar and U-Pb dates of apatite and thereby reinforce previous critique of their suitability for thermochronological reconstructions. We further identify and discuss potential implications for noble gas geochronology of groundwaters and fission track dating of apatite. Full article

In recent years, the demand for lithium, essential to the high-tech and battery sectors, has increased rapidly. The majority of lithium carbonate is now sourced from continental brines in Latin America, owing to the lower production costs and reduced environmental impact. In Europe, often overlooked but promising lithium resources could include highly mineralized underground waters. Therefore, this study investigates the enrichment of these low-grade solutions (<100 mg/L Li) through evaporation followed by solvent extraction (SX) processes under specific conditions. The effectiveness and the technical feasibility of lithium extraction were evaluated using binary synthetic, multicomponent semi-synthetic, and real brine samples. The popular tributyl phosphate/methyl isobutyl ketone (TBP/MIBK) system, supplemented with FeCl₃ and AlCl₃ as co-extractants, was employed as the organic phase. Evaporation resulted in significant lithium losses (up to 80%), reduced to ~10% by washing the crystallisate obtained during evaporation with ethanol. The results from SX tests revealed differences between the synthetic and real brines. While the synthetic brines exhibited satisfactory lithium extraction yields (91%), the real brines showed a significantly lower extraction efficiency (~32%), rendering the tested system ineffective. Solid phase precipitation during the SX trials was observed for both the synthetic and real brines, which were concentrated before the SX stage, highlighting the challenges in lithium-recovery processes. However, semi-synthetic brine trials yielded promising results, with a satisfactory extraction efficiency (76%), and the absence of physical problems (emulsion, long disengagement, etc.). This reveals the importance of the chemical composition of brines and emphasizes the need for varied procedural approaches in lithium-recovery processes. Full article

The Weilasituo Li–polymetallic deposit, located on the western slope of the southern Great Xing’an Range in the eastern Central Asian Orogenic Belt, is hosted by quartz porphyry with crypto-explosive breccia-type Li mineralisation atop and vein-type Sn-Mo-W-Zn polymetallic mineralisation throughout the breccia pipe. This study introduces new data on multistage quartz and mica in situ trace elements; the study was conducted using laser ablation inductively coupled plasma mass spectrometry and ⁴⁰Ar/³⁹Ar dating of zinnwaldite to delineate the metallogenic age and genesis of Li mineralisation. Zinnwaldite yields a plateau age of 132.45 ± 1.3 Ma (MSWD = 0.77), representing Early Cretaceous Li mineralisation. Throughout the magmatic–hydrothermal process, quartz trace elements showed Ge enrichment. Li, Al, and Ti contents decreased, with Al/Ti and Ge/Ti ratios increasing, indicating increased magmatic differentiation, slight acidification, and cooling. Mica’s rising Li, Rb, Cs, Mg, and Ti contents and Nb/Ta ratio, alongside its falling K/Rb ratio, indicate the magma’s ongoing crystallisation differentiation. Fractional crystallisation primarily enriched Li, Rb, and Cs in the late melt. Mica’s high Sc, V, and W contents indicate a high f_O2 setting, with a slightly lower f_O2 during zinnwaldite formation. Greisenisation observed Zn, Mg, and Fe influx from the host rock, broadening zinnwaldite distribution and forming minor Zn vein orebodies later. Late-stage fluorite precipitation highlights a rise in F levels, with fluid Sn and W levels tied to magma evolution and F content. In summary, the Weilasituo Li–polymetallic deposit was formed in an Early Cretaceous extensional environment and is closely related to a nearby highly differentiated Li-F granite. During magma differentiation, rare metal elements such as Li and Rb were enriched in residual melts. The decrease in temperature and the acidic environment led to the precipitation of Li-, Rb-, and W-bearing minerals, and the increased F content in the late stage led to Sn enrichment and mineralisation. Fluid metasomatism causes Zn, Mg, and Fe in the surrounding rock to enter the fluid, and Zn is enriched and mineralised in the later period. Full article

Slags from the metallurgical recycling process are an important source of resources classified as critical elements by the EU. One example is lithium from Li-ion battery recycling. In this context, the thermodynamic properties of the recycled component system play a significant role in the formation of the Li-bearing phases in the slag, in this case, LiAlO₂. LiAlO₂ crystal formation could be engineered and result in varying sizes and occurrences by different metallurgical processing conditions. This study uses pure ingredients to provide a synthetic model material which can be used to generate the valuable phase in the slag, or so-called engineered artificial minerals (EnAMs). The aim is to investigate the crystallisation of LiAlO₂ as an EnAM by controlling the cooling conditions of the model slag to optimise the EnAM formed during crystallisation. Characterisation of the EnAMs is an important step before further mechanically processing the material to recover the valuable element Li, the Li-bearing species, respectively. Investigations are conducted using powder X-ray diffraction (XRD), X-ray fluorescence (µXRF), and X-ray Computer Tomography (XCT) on two different artificial lithium slags from MnO-Al₂O₃-SiO₂-CaO systems with different cooling temperature gradients. The result shows the different EnAM morphology along the height of the slag, which is formed under different slag production conditions in a semi-pilot scale experiment of 5 kg. Based on the different EnAM morphologies, three defined qualities of the EnAM are identified: granular, dendritic, and irregular-shape EnAM. Full article

In this work, authigenic microbial mineral formation in groundwater near the uranium sludge storage at SC Chepetsky Mechanical Plant (ChMP) (Glazov, Russia) was analysed in field and laboratory experiments using thermodynamic modelling when the microbial community was activated by a mixture of acetate, glucose and whey. It was found that the mineral basis of the barrier consisted of aggregated soil particles with freshly deposited phases of carbonate and sulphide minerals of different degrees of crystallinity. An important factor in the formation of calcium phases is microbial denitrification, which is accompanied by an increase in pH values of the medium. The main factors of uranium immobilisation in the biogeochemical barrier were revealed, including its reduction to insoluble forms of uranium dioxide, adsorption on ferrous and sulphide-ferrous minerals, as well as the formation of phosphate phases through the addition of phosphorus-containing whey and co-precipitation or co-crystallisation in calcite phases. Full article

Most recent studies consider the formation of individual pegmatite bodies to be a fast process with estimated crystal growth rates reaching a walloping 10 m/day. This opinion is presumably underpinned by the traditional way of thinking of them as the end products of magmatic fractionation. Indeed, modelling has shown that if a pegmatite-forming substance with a temperature near granitic solidus intrudes into a much colder host rock, as recorded in some outcrops, it must cool rapidly. From here, a conclusion is made that the crystallisation must likewise be rapid. However, this view is challenged by several studies that published isotopic dates supported by petrological characterisation of the analysed materials, which suggested or can be used to suggest that some minerals in pegmatites grew over millions of years. Surprisingly, such in-depth work on the geochronology of individual pegmatite bodies is relatively uncommon, so it is early to make generalisations. Here, I highlight some of the existing evidence with the aim to stimulate further research into the timescales of pegmatite crystallisation, including the use of petrologically constrained isotopic dating. Full article

This study aimed to investigate the antibiofilm and remineralising effects of peptide GAPI on artificial dentin caries. After creating artificial carious lesions, eighty dentine blocks were randomly assigned for treatment twice daily with GAPI (GAPI group) or deionised water (control group). Both groups underwent a 7-day biochemical cycle. Scanning electron microscopy (SEM) showed S. mutans with damaged structures that partially covered the dentine in the GAPI group. The dead–live ratios for the GAPI and control groups were 0.77 ± 0.13 and 0.37 ± 0.09 (p < 0.001). The log colony-forming units for the GAPI and control groups were 7.45 ± 0.32 and 8.74 ± 0.50 (p < 0.001), respectively. The lesion depths for the GAPI and control groups were 151 ± 18 µm and 214 ± 15 µm (p < 0.001), respectively. The mineral losses for the GAPI and control groups were 0.91 ± 0.07 gHAcm⁻³ and 1.01 ± 0.07 gHAcm⁻³ (p = 0.01), respectively. The hydrogen-to-amide I ratios for the GAPI and control groups were 2.92 ± 0.82 and 1.83 ± 0.73 (p = 0.014), respectively. SEM micrographs revealed fewer exposed dentine collagen fibres in the GAPI group compared to those in the control group. Furthermore, X-ray diffraction (XRD) patterns indicated that the hydroxyapatite in the GAPI group was more crystallised than that in the control group. This study demonstrated GAPI’s antibiofilm and remineralising effects on artificial dentin caries. Full article

The Pulai gold deposit is one of the most promising gold prospects in the Central Belt of Peninsular Malaysia. It is found within the Permian-Triassic Gua Musang sequence of metasediments and metavolcanics and in a structurally controlled NE-SW major fault. Various ore minerals, including pyrite, arsenopyrite, chalcopyrite, sphalerite, pyrrhotite, and galena are typically associated with this deposit. Four types of pyrite (Pyrite 1, Pyrite 2, Pyrite 3, and Pyrite 4) and two types of arsenopyrite (Arsenopyrite 1 and Arsenopyrite 2) were characterised based on their morphological and textural differences. In this region, gold occurs as refractory gold in the nanoparticle form and in the state of Au⁺ within the structure of sulphides of variable concentrations. Through the detailed laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) trace element mapping analysis of pyrite and arsenopyrite, the main Au-bearing sulphides were found within vein-hosted Pyrite 4 and Arsenopyrite 2 during late phase mineralisation, while Pyrite 3 had the lowest Au concentration. Two phases of Au enrichment were recorded in Pyrite 4, mainly in the core (2 to 11.7 ppm; average 1.4 ppm) and margin of the grain (0.3 to 8.8 ppm; average 1.2 ppm), whereas the highest Au content was detected in the core of Arsenopyrite 2 (0.3 to 137.1 ppm; mean 31.9 ppm). The enrichment of Au is associated with As, forming a zoning elemental pattern distribution. Other trace elements, including Co, Ni, Sb, Pb, Bi, Cu, and Zn, show systematic variation in their composition between the various types of pyrite and arsenopyrite. For early-phase sulphides, the Au enrichment localised at the margin of Pyrite 2 and Arsenopyrite 1, together with Co–Ni, Pb–Bi–Sb, and Ag in the same oriented pattern, suggesting the remobilisation and redistribution of Au in sulfides. Meanwhile, the late crystallisation phase of vein-hosted sulphides formed a rich Au–As ore zoning pattern in the core of Arsenopyrite 2 and Pyrite 4. The second phase of Au enrichment continued at the margin of Pyrite 4 through the remobilisation and precipitation of Au together with Ni, Co, Sb, Pb, Bi, Ag, and Cu. Subsequent deformation then reactivated the late fluid system with the enrichment of Sr, Ba, Rb, Ag, and Zn along the fractures and outermost rim of Pyrite 4 and Rb–Sr–Ba–Pb–Bi along the rim of Arsenopyrite 2. The Pulai gold prospect is interpreted as an orogenic-style gold mineralisation where arsenic can be used as an indicator for proximity to ore mineralisation in exploration. Full article