Search Results (276)

This paper reports on the high performance of a thick-waveguide guided mode resonance (GMR) sensor. Theoretical calculations revealed that when light incidents on the grating and excites the negative first-order diffraction order, by increasing the waveguide thickness, both a high sensitivity and high figure of merit (FOM) can be obtained. Experimentally, we achieved a sensitivity of 1255.78 nm/RIU, a resonance linewidth of 0.59 nm at the resonance wavelength of 535 nm, an FOM as high as 2128 RIU⁻¹, and a detection limit as low as 1.74 × 10⁻⁷ RIU. To our knowledge, this performance represents the highest comprehensive level for current GMR sensors. Additionally, the use of a microfluidic hemisphere and polymer materials effectively reduces the liquid consumption under oblique incidence and the fabrication cost in practical application. Overall, the proposed GMR sensor exhibits great potential in label-free biosensing. Full article

Stimuli-responsive polymers (SRPs) have garnered significant attention in recent decades due to their immense potential in biomedical and environmental applications. When these SRPs are grafted onto magnetic nanoparticles, they form multifunctional nanocomposites capable of various complex applications, such as targeted drug delivery, advanced separations, and magnetic resonance imaging. In this study, we employed a one-step hydrothermal method using 3-aminopropyltrimethoxysilane (APTES) to synthesize APTES-modified Fe₃O₄ nanoparticles (APTES@Fe₃O₄) featuring reactive terminal amine groups. Subsequently, via two consecutive surface-initiated atom transfer radical polymerizations (SI-ATRP), pH- and temperature-responsive polymer blocks were grown from the Fe₃O₄ surface, resulting in the formation of poly(itaconic acid)-block-poly(N-isopropyl acrylamide) (PIA-b-PNIPAM)-grafted nanomagnetic particles (PIA-b-PNIPAM@Fe₃O₄). To confirm the chemical composition and assess how the particle morphology and size distribution of these SRP-based nanocomposites change in response to ambient pH and temperature stimuli, various characterization techniques were employed, including transmission electron microscopy, differential light scattering, and Fourier transform infrared spectroscopy. The results indicated successful synthesis, with PIA-b-PNIPAM@Fe₃O₄ demonstrating sensitivity to both temperature and pH. Full article

Conjugated polymers (CPs) offer many attractive features for photodiodes and photovoltaics, including solution processability, ease of scale-up, light weight, low cost, and mechanical flexibility. CPs have a wide range of energy gaps; thus, the choice of the specific polymer determines the optimum operational wavelength range. However, there are relatively few CPs with a strong absorption in the blue region of the spectrum where the human eye is most sensitive (440 to 470 nm) and none with an energy gap at 2.75 eV (450 nm), which corresponds to the peak of the CIE-1931 z(λ) color-matching function and the dominant blue light emission wavelength in computer and smartphone displays. Blue-light detectors in this wavelength range are important for light hazard control, sky polarization studies, and for blue-light information devices, where 450 nm corresponds to the principal emission of GaN-based light sources. We report on a new CP called Atums Green (AG), which shows promising characteristics as a blue-light photodetection polymer optimized for exactly this range of wavelengths centered around 450 nm. We built and measured a simple photodetector made from spin-coated films of AG and showed that its photosensitivity can be improved by the addition of asphaltene, a low-cost carbonaceous waste product. Full article

Background/Objectives: In recent years, increasing attention has been paid to the stabilization of natural biologically active compounds in order to expand their application in the food, pharmaceutical, and cosmetic industries. Such compounds, such as polyphenols, essential fatty acids, or vitamins, are extremely sensitive to environmental factors. This study aims to review the spray-drying-based microencapsulation technology and its application for stabilizing sensitive biologically active substances. Methods: This article systematically analyzes the main steps of the spray-drying microencapsulation process and discusses traditional and innovative wall materials, including natural polymers (polysaccharides and proteins), as well as new raw material sources (e.g., yeast cells, canola and pea protein isolates, and hemicelluloses). It also examines the potential of these systems for the stimulated release of active ingredients. Results: This review provides a comprehensive overview of the main stages of the spray-drying process and critically examines both conventional (e.g., maltodextrin and gum Arabic) and innovative wall materials (e.g., plant-based proteins and food industry by-products). Studies show that using different wall materials can achieve high encapsulation efficiency, improve the stability of biologically active substances, and control their release. Various compounds have been successfully microencapsulated—polyphenols, essential oils, carotenoids, fatty acids, and vitamins—protecting them from oxidation, light, and temperature. The review identifies key factors that can enhance product quality, increase encapsulation yield, and reduce processing costs and energy input—offering meaningful insights for optimizing the microencapsulation process. Conclusions: Spray-drying-based microencapsulation is an advanced technology that effectively protects sensitive active ingredients and allows for wider industrial food, pharmaceutical, and cosmetic applications. In the future, more attention is expected to be paid to personalized formulations, stimulated release systems, and sustainable wall materials from by-products. Full article

Mesoporous silica nanoparticles (MSNs) are gaining popularity in nanomedicine due to their large surface area, variable pore size, great biocompatibility, and chemical adaptability. In recent years, the combination of smart polymeric materials with MSNs has transformed the area of regulated drug administration, particularly under stimuli-responsive settings. Polymer-modified MSNs provide increased stability, longer circulation times, and, most crucially, the capacity to respond to diverse internal (pH, redox potential, enzymes, and temperature) and external (light, magnetic field, and ultrasonic) stimuli. These systems allow for the site-specific, on-demand release of therapeutic molecules, increasing treatment effectiveness while decreasing off-target effects. This review presents a comprehensive analysis of recent advancements in the development and application of polymer-functionalized MSNs for stimuli-triggered drug delivery. Key polymeric modifications, including thermoresponsive, pH-sensitive, redox-responsive, and enzyme-degradable systems, are discussed in terms of their design strategies and therapeutic outcomes. The synergistic use of dual or multiple stimuli-responsive polymers is also highlighted as a promising avenue to enhance precision and control in complex biological environments. Moreover, the integration of targeting ligands and stealth polymers such as PEG further enables selective tumor targeting and immune evasion, broadening the potential clinical applications of these nanocarriers. Recent progress in stimuli-triggered MSNs for combination therapies such as chemo-photothermal and chemo-photodynamic therapy is also covered, emphasizing how polymer modifications enhance responsiveness and therapeutic synergy. Finally, the review discusses current challenges, including scalability, biosafety, and regulatory considerations, and provides perspectives on future directions to bridge the gap between laboratory research and clinical translation. Full article

Food contact polymers require thermochromic pigments to provide temperature-sensitive visual cues for consumer safety and product integrity. However, their susceptibility to ultraviolet (UV) degradation limits long-term application. This study investigates the UV resistance of food-grade thermochromic polypropylene blends under simulated indoor and outdoor UV exposure for 500 and 1000 h. Visual properties, colorimetric (CIE L*a*b*) measurements, mechanical testing (tensile and impact), and mass variation analysis were performed to assess photostability and material integrity. Exposure to UV led to progressive discoloration (ΔE*_ab up to 34.07) and significant mechanical deterioration. Tensile strain at break decreased by 48.67%, and notched impact strength dropped by 44.15% after 1000 h of UV exposure. No measurable mass loss occurred, indicating degradation was confined to surface-level oxidation rather than bulk material erosion or leaching. These findings highlight the need for optimal pigment loading and UV stabilization to extend the shelf life of thermochromic food packaging materials in light-exposed storage and retail environments. The study offers a framework for improving the long-term reliability of smart packaging in the food industry. This work uniquely integrates optical, mechanical, and mass loss analyses to evaluate thermochromic packaging degradation under extended UVA exposure. Full article

Optical–chemical sensors based on optical fibers can be made in reflection or transmission schemes. In the reflection scheme, the sensing area is typically present at the end of the fiber, and the light source and the detector are placed on the same side of the fiber. This approach can be exploited to achieve chemical probes useful in several application fields where remote sensing is required. In this work, to obtain an extrinsic optical fiber chemical sensor in a reflection scheme, two optical fibers are used to monitor a chemically sensitive region achieved by a C-shaped waveguide with a molecularly imprinted polymer (MIP) as a core between the optical fibers. The proposed micrometer-sized probe is developed and tested as a proof of concept via a MIP for 2-Furaldehyde (2-FAL) detection of interest in food and industrial applications. The experimental results of the proposed sensing approach showed several advantages, such as a nanomolar detection limit and an ultra-wide concentration detection range due to different kinds of MIP recognition sites in the optical path between the fibers. Full article

Restricted by the inherent low sensitivity of materials and complex integration technology, it is difficult for existing soft actuators (s-actuators) to simultaneously possess the advantages of flexibility, fast response, and simple manufacturing, which greatly limits their practical applications. Herein, a stretchable (ε = 200%) nanocomposite film capable of deformation and motion driven by near infrared light (NIR) was developed using multi-walled carbon nanotubes (MWCNTs) as the light absorption–photothermal conversion nanonetwork, and liquid crystal polymer (LCP) as an elastic matrix featured reversible phase transition. Furthermore, s-actuators with various deformation and motion modes have been realized employing MWCNT/LCP nanocomposite film. Based on the mechanism that photothermal-effect-regulated liquid crystal–isotropic phase transition in LCP can induce macroscopic deformation of nanocomposites, MWCNT/LCP s-actuators have completed a series of complex deformation and motion tasks such as opening the knot, “V”-shape reversible deformation (30 s per cycle), the “spring” rotating and unfolding, imitating a “caterpillar” walking in a straight line (the average speed is 13 s/mm), etc. This work provides an effective strategy for the intelligent development of s-actuators. Full article

Digital light processing (DLP) technology stands out as a groundbreaking method in the field of biomedical engineering that enables the production of highly precise structures using photopolymerizable materials. Smart materials such as shape memory polymers, hydrogels, and nanocomposites are used as ideal materials for personalized medicine applications thanks to their properties such as superior mechanical strength, biocompatibility, and sensitivity to environmental stimuli in DLP technology. The integration of these materials with DLP enables the production of functional and complex structures, especially in areas such as bone and soft tissue engineering, drug delivery, and biosensor production. However, limited material diversity, scalability problems in production processes, and technical difficulties in optimizing bioprinting parameters are among the main obstacles in this field. This study systematically examines the role of smart biomaterials in DLP-based bioprinting processes. It addresses the innovative applications of these materials in tissue engineering and regenerative medicine. It also comprehensively evaluates its contributions to biomedical applications and discusses future research areas to overcome current limitations. Full article

The photosensitive properties of smart photoactive polymers give them a wide range of potential applications across various fields. This study focuses on designing polymeric systems that incorporate hydrophilic polymers, with the primary goal of adapting these materials for biological applications. Specifically, it aims to contribute to the development of photochromic materials for optical processing, utilizing both molecular and macromolecular components. Additionally, this study evaluates the effectiveness of photoactive polymers in photodynamic therapy (PDT). It details the synthesis and characterization of photoactive copolymers derived from maleic anhydride (MAn) combined with vinyl monomers such as 2-methyl-2-butene (MB) and 1-octadecene (OD), as well as the organic compound 1-(2-hydroxyethyl)-3,3-dimethylindoline-6-nitrobenzopyran (SP). The two novel optically active alternating polymeric systems, poly(maleic anhydride-alt-octadecene) and poly(maleic anhydride-alt-2-methyl-2-butene), were functionalized with SP through an esterification process in a 1:1 monomer feed ratio, using pyridine as a catalyst. This methodology incorporated approximately 100% of the photoactive molecules into the main acrylic chain to prepare the alternating copolymers. These copolymers were characterized by UV-visible, FTIR, and 1H-NMR spectroscopy and analysis of their optical and thermal properties. When exposed to UV light, the photoactive polymer films can develop a deep blue color (566 nm in the absorption spectra). Finally, the study also assesses their capacity for photodynamic antimicrobial action in organic film. Notably, the photoactive P(MAn-alt-2MB)-PS significantly enhances the photodynamic antimicrobial activity of the photosensitizer Ru(bpy) against two bacterial strains of Staphylococcus aureus, reducing the minimum inhibitory concentration (MIC) from 2 µg/mL to 0.5 µg/mL. Therefore, 4 times less photosensitizer is required when mixed with the photoactive polymer to inhibit the growth of antibiotic-sensitive and -resistant bacteria. Full article

Acid-etched zirconia has emerged as a high-strength alternative to traditional glass ceramics for laminate veneers in aesthetic dentistry. This randomized, double-blind controlled clinical trial aimed to evaluate the one-year clinical performance of zirconia veneers etched with a hydrofluoric-nitric acid mixture and bonded using a 10-methacryloyloxydecyl dihydrogen phosphate (MDP) containing polymeric adhesive system, compared to lithium disilicate veneers. Fifty-two patients were treated with either translucent zirconia or lithium disilicate veneers, and restorations were bonded using light-cured resin-based adhesives. Clinical parameters, including veneer survival, esthetics, marginal adaptation, postoperative sensitivity, and periodontal health, were assessed using modified United States Public Health Service (USPHS) criteria and periodontal indexes at 2 weeks, 6 months, and 12 months. Both materials showed high survival rates with no statistically significant differences in clinical outcomes. One zirconia veneer debonded early but was successfully rebonded without fracture, while one lithium disilicate veneer fractured upon debonding. The findings support the viability of acid-etched zirconia veneers bonded with polymer-based adhesives as a durable and esthetic restorative option. The study highlights the clinical relevance of polymeric bonding systems in enhancing zirconia veneer performance and reinforces their role in modern adhesive dentistry. Full article

A double-cavity Fabry-Perot (F-P) interferometer sensor based on a polymer-filled hollow core fiber (HCF) has been proposed and experimentally verified. The double cavity of the sensor is formed by filling the hollow core fiber with two kinds of polymer materials and curing these materials, with the other end of the hollow core fiber connected to a single-mode fiber (SMF). The three reflective surfaces of the sensor reflect three beams of light, which interfere to form a spectrum with an envelope. By using Fast Fourier Transform (FFT) and a Fourier filter, the spectrum of each cavity can be separated and, based on this, the demodulation matrix of the sensor can be constructed. By controlling the length of the polymer cavity, a single sensor cavity can achieve high temperature and gas pressure sensitivity, with values of 2.05 nm/°C and 17.63 nm/MPa, respectively. More importantly, the sensor can be used under an environment of 40–110 °C and 0–3.0 MPa, with simple fabrication, good robustness, and better stability and repeatability compared to similar sensors. Based on its high sensitivity and large measurement range, this sensor has broad application prospects in industrial manufacturing and harsh environmental monitoring fields. Full article

In this paper, we propose a scheme based on the spin Hall effect of light (SHEL) for characterizing aligned polymers. Poly (3-hexylthiophene) (P3HT) films were prepared via the solution shear coating method. The experimental results obtained by using SHEL indicated that the alignment of polymer chains could be enhanced by UV irradiation and was positively correlated with the irradiation time, which was consistent with the measurements of the UV–Vis spectrometer and the polarizing optical microscope (POM). Compared with other optical methods, such as POM that characterizes aligned samples using light intensity, the amplified shift in SHEL can significantly reduce technical noise and exhibit high sensitivity. Even for the weak alignment film, this method can still recognize its alignment and achieve a signal-to-noise ratio (SNR) of 30 dB. This renders SHEL a highly precise technique for studying aligned polymers, which is valuable for the development of organic electronics. Full article

The increasing rate of environmental pollution and the emergence of new infectious diseases have drawn much attention toward the area of gas sensors for air quality monitoring and early-stage disease diagnosis, respectively. Polyaniline (PANI) has become one of the extensively studied polymers in the area of chemical sensing due to its good conductivity and sensitivity at room temperature. The development of room-temperature gas sensors represents a significant leap forward in air quality monitoring by conserving energy and enhancing the feasibility of the commercial development of sensing technologies. New research shines a light on the advantages of using PANI with materials such as semiconductor metal chalcogenides, metal oxides, metal nanoparticles, and graphitic carbon materials to form composites that can sense chemicals selectively at room temperature. This review focuses on the advancements in PANI-based gas sensors, exploring the materials, mechanisms, and applications that make these sensors a promising solution for modern air quality monitoring challenges. By examining the latest research and innovations, we aim to highlight this critical technology’s potential and future directions, instilling hope and optimism in safeguarding public health and the environment. Full article

One of the main limitations of biopolymers compared to petroleum-based polymers is their weak mechanical and physical properties. Recent improvements focused on surmounting these constraints by integrating nanoparticles into biopolymer films to improve their efficacy. This study aimed to improve the properties of gelatin–chitosan-based biopolymer layers using zinc oxide (ZnO) and graphene oxide (GO) nanoparticles combined with spermidine to enhance their mechanical, physical, and thermal properties. The results show that adding ZnO and GO nanoparticles increased the tensile strength of the layers from 9.203 MPa to 17.787 MPa in films containing graphene oxide and zinc oxide, although the elongation at break decreased. The incorporation of nanoparticles reduced the water vapor permeability from 0.164 to 0.149 (g.m⁻².24 h⁻¹). Moreover, the transparency of the layers ranged from 72.67% to 86.17%, decreasing with higher nanoparticle concentrations. The use of nanoparticles enhanced the light-blocking characteristics of the films, making them appropriate for the preservation of light-sensitive food items. The thermal properties improved with an increase in the melting temperature (Tm) up to 115.5 °C and enhanced the thermal stability in the nanoparticle-containing samples. FTIR analysis confirmed the successful integration of all components within the films. In general, the combination of gelatin and chitosan, along with ZnO, GO, and spermidine, significantly enhanced the properties of the layers, making them stronger and more suitable for biodegradable packaging applications. Full article