Search Results (14,847)

Global land use is changing rapidly, particularly in the tropics, where human populations have had relatively high growth rates in recent decades. This has resulted in wildlife increasingly living in or using anthropogenic environments, which often have different thermal properties in comparison to natural habitats. For example, materials used for buildings, such as concrete and brick, typically absorb, retain and radiate more heat than vegetated surfaces. The mosaic of man-made and natural areas formed when anthropogenic environments expand is therefore likely to generate microhabitats with different thermal properties. Here, we investigated the association between microhabitats and the body surface temperature of wild banded mongooses (Mungos mungo), a social mammal living in equatorial Uganda. After controlling for the significant effects of air temperature, humidity, time of day and body contact, we found that mongooses had the highest body surface temperatures when present on anthropogenic substrates, such as discarded roofing straw and refuse, while mongooses present on building materials, dead vegetation and bare soil had intermediate body surface temperatures. In contrast, mongooses had the lowest body surface temperatures when present in more natural, vegetated habitats. Although our study is relatively small scale and limited in scope, our results indicate that anthropogenic modifications to natural environments may result in hotter microhabitats, which may in turn impact space use, movement and thermoregulation in wildlife. We hope that our study encourages further research into this understudied but emerging topic. Full article

The emergence of membrane boundaries represents a decisive transition in the origin of life, yet the molecular nature of the earliest abiotic membranes remains uncertain. Existing models based on simple fatty acids, while experimentally tractable, often lack the environmental robustness required under fluctuating prebiotic conditions. Furthermore, the absence of clear pathways linking primitive amphiphiles to later phospholipid systems highlights the need for chemically continuous intermediate frameworks. Here, we explore borate-bridged amphiphile–carbohydrate conjugates as plausible intermediates between simple prebiotic surfactants and modern lipid bilayers. These conjugates arise from low-molecular-weight polyols—including glycerol, butane-1,2,3,4-tetraol, pentane-1,2,3,4,5-pentaol, and hexane-1,2,3,4,5,6-hexitol—reacting with long-chain alkyl ethers and borate species under alkaline conditions, enabling reversible coupling to ribose and other vicinal diol-containing sugars. This chemistry integrates three essential properties for early compartmentalization: hydrolytically robust ether-linked hydrophobic domains, multivalent and highly hydrated headgroups, and environmentally responsive borate coordination. Comparative physicochemical analysis suggests that single-tail alkylglycerol derivatives preferentially form micelles and interfacial films, while di- and tri-tail tetritol and pentitol conjugates favor lamellar assemblies and vesicle formation across realistic prebiotic pH and salinity ranges. Hexitol-based systems, particularly those bearing three hydrophobic chains, may act as membrane-stabilizing components that enhance rigidity and reduce permeability under extreme conditions. We propose that heterogeneous mixtures dominated by two-tail polyol diethers, supplemented by tri-tail stabilizers and surface-active alkylglycerols, could provide mechanically robust, pH-tunable, and sugar-decorated abiotic membranes. Such borate-mediated amphiphiles offer a chemically coherent framework linking carbohydrate stabilization, ether lipid persistence, and dynamic self-assembly, potentially representing a transitional stage in the evolutionary pathway from primitive amphiphilic films to biologically encoded membranes. Full article

Accurate detection of chlorophyll-a (Chl-a) is critical for monitoring water quality in inland waters, where high concentrations of coloured dissolved organic matter (CDOM) complicate retrieval process. Reliable Chl-a estimation depends on the precise determination of the phytoplankton absorption coefficient (a_ph). This study evaluates Chl-a detection from in situ a_ph measurements and assesses the accuracy of phytoplankton absorption retrieval from Sentinel-2/MSI (S2) and Sentinel-3/OLCI (S3) using the Case-2-Regional-Coast-Colour (C2RCC) processor across diverse optical water types (OWTs) in boreal lakes. OWTs were classified based on remote sensing reflectance features, representing Clear, Moderate, Turbid, Very Turbid, and Brown conditions. CDOM absorption strongly influenced the underwater light field, particularly in Brown and Turbid waters. Linear relationships between a_ph and Chl-a were generally strong across OWTs, with improved relationships in the red spectral region (670 nm). Satellite-derived a_pig estimates showed a weak relationship with in situ data (R² = 0.26–0.45). Both sensors overestimated small a_ph values, while S3 underestimated larger ones. S2 underestimated a_ph in Clear and Brown OWTs, with median absolute percentage differences near 100% for all OWTs. These findings emphasize the challenges posed by bio-optical complexity in boreal lakes and highlight the need for OWT-specific algorithms to improve satellite-based absorption and Chl-a retrieval accuracy. Full article

Cascade reservoirs on the Drina River (Bosnia and Herzegovina) are heavily modified water bodies that require reliable biological tools for assessing trophic status and ecological potential. Under the Water Framework Directive (WFD), assessments of surface water ecological status and potential rely on biological quality elements, since aquatic communities integrate and respond to prevailing environmental conditions and thus serve as reliable indicators of water quality. This study aims to (i) describe phytoplankton diversity, biomass, and functional-group composition along the Drina reservoir cascade, (ii) examine monthly changes across the studied reservoirs, (iii) determine trophic status and ecological potential, and (iv) provide a preliminary estimate of total phosphorus thresholds that may support future setting of ecological potential boundaries. Phytoplankton composition and functional groups were analysed in three longitudinally connected reservoirs of the Drina River during four monthly surveys in 2024. A total of 80 phytoplankton taxa were recorded, with diatoms dominating most of the study period. The highest biomasses were recorded for Fragilaria crotonensis, Dinobryon divergens, Acanthoceras zachariasii and Sphaerocystis sp., while the dominant functional groups were P, E, A, and F. Phytoplankton assemblage structure showed moderate spatial differentiation among the reservoirs. Mean chlorophyll a and Carlson’s Trophic State Index indicated eutrophic conditions in the Višegrad Reservoir and mesotrophic conditions in the Perućac and Zvornik reservoirs, while biomass showed a pronounced summer maximum, particularly in Perućac. Ecological potential was generally classified as good or better, except for a moderate classification in the Zvornik Reservoir in late summer. The good/moderate TP boundary was estimated at 39 µg L⁻¹, linking EQR-based ecological assessment with the onset of eutrophic conditions. Overall, this study represents the first application of the phytoplankton functional group approach in cascade reservoirs in Bosnia and Herzegovina and may provide a valuable basis for the development of a phytoplankton-based monitoring framework in lakes and reservoirs, which is currently lacking. Full article

Home has been recognized as a health infrastructure through hospital-at-home, home care, and direct-to-consumer wellness and fitness products. However, the patient home environment has been largely overlooked by healthcare as a means to improve therapy outcomes for difficult-to-treat chronic conditions, such as migraine; high-impact pain; and treatment-resistant depression, anxiety, or insomnia. Growing research evidence enables the formulation of a therapeutic home environment standard consisting of three pillars: biophilic design, indoor environmental quality, and intentional self-care spaces that serve as habit cues and foster sleep hygiene, stress management, relaxation, physical activity, and social interactions. Together, these environmental and behavioral interventions can transform real-world inputs into clinical benefits through autonomic, circadian, and emotional regulation. We also highlight the converging roles of self-management, self-efficacy, self-regulation, and self-compassion in sustaining patient engagement and healing at home. The applicability of the therapeutic home environment as an adjunct is illustrated in the case of chronic migraine, a debilitating neurological condition commonly associated with comorbidities. Current challenges in achieving migraine freedom with FDA-approved pharmacotherapies, neuromodulation devices, and digital health technologies are underscored by the high prevalence of refractory, chronic, episodic, and pediatric migraine. Perspectives on developing a personalized, multimodal cure for migraine are illustrated through a hypothetical drug + digital combination therapy comprising anti-CGRP drugs and an AI-powered digital health platform that promotes daily self-care practices within the therapeutic home environments. In conclusion, achieving sustained freedom from high-morbidity conditions requires end-to-end care ecosystems that integrate pharmacological, cognitive, behavioral, and environmental interventions into real-world settings. Full article

Tor sinensis is an emerging aquaculture species in China, yet the effect of dietary protein on its hepatic and intestinal health remains unexplored. This study evaluated the effects of five diets designed to be isoenergetic and isolipidic with graded protein levels (28% to 40%) on juvenile T. sinensis (initial weight: 10 ± 0.4 g) over 60 days. Growth performance improved with increasing protein up to 34%, beyond which it plateaued. Regression analysis indicates that the optimal dietary protein level for both weight gain and specific growth rate is 34.3%. Hepatic antioxidant enzyme activities (SOD and CAT) were highest in the 34% protein group, while triglyceride content was lowest. Histological examination revealed minimal hepatocyte swelling, nuclear displacement, and lipid droplet accumulation at this protein level. Intestinal trypsin activity and villus morphology (height, width, and muscular thickness) were also optimized at 34% protein, though lipase and amylase activities remained unaffected. These findings demonstrate that a 34% dietary protein level supports optimal growth, enhances liver antioxidant capacity, and improves intestinal structure and function in juvenile T. sinensis, providing critical insights for its formulated feed development. Full article

In the context of green energy, the use of lake reeds is becoming an increasingly important factor. Therefore, research into the availability of reeds, determining their area in lakes, predicting the potential biomass volume and calculating the carbon footprint are important. Currently, there have been no significant research results on the availability of reeds and the assessment of the sustainability of reed products in Latvia. However, these aspects are crucial for the development of reed products, as they help to assess their market potential and environmental impact. The main goal of this work is to develop a method for modeling the distribution of lake reeds in order to predict their availability in the future, which would allow assessment of the volume of biomass and its impact on the environment. This research develops an integrated GIS–LCA framework that combines Sentinel-2 satellite data, machine learning-based classification, biomass estimation, and carbon footprint modeling. Using Lake Cirma as a case study, the classification results show that reed stands occupy 2.18–3.51 percent of the lake area in certain years, corresponding to approximately 1158–1861 tons of biomass. The framework enables quantification of harvesting potential while considering ecological constraints that limit annual extraction to approximately 50% of total biomass. The proposed GIS–LCA framework provides a replicable methodology for assessing reed biomass availability and environmental performance across lake ecosystems. It supports evidence-based decision-making for sustainable reed resource management and contributes to the development of low-carbon bioeconomy pathways in line with EU climate and bioeconomy strategies. Full article

Freshwater scarcity is a major global issue faced by various regions, and the most common portable water sources globally are estuaries, canals, dams, lakes, and rivers. Existing water resources function as the best sinks for the frequent release of effluents from industrial and residential activities. This common practice often results in water pollution, a deterioration in marine biodiversity, and possible health risks for human populations. This study employed standard analytical methods in assessing the physicochemical and microbial characteristics of water samples collected from the Sundays River estuary in Eastern Cape Province (ECP), South Africa (SA). Microbiological assessment revealed that during the spring season, presumptive Escherichia coli (E. coli) colony counts were 1 cfu/100 mL, while total coliforms (TCs) and fecal coliforms (FCs) were recorded at 42.67 cfu/100 mL and 1 cfu/100 mL, respectively. In the summer season, fecal coliform (FC) counts reached 3.5 cfu/100 mL, while Enterococcus levels were higher, ranging up to 77.75 cfu/100 mL. Furthermore, the average standards of physicochemical parameters assessed in water obtained from both spring and summer seasons ranged as follows: pH (8.71–9.31), temperature (20.98–22.21 °C), turbidity (10–35.55 FNU), total alkalinity (22.25–94.00 mg/L), oxidation–reduction potential (ORP) (8.05–151.6 mV), electrical conductivity (EC) (13,915–40,260 uS/cm), salinity (8.07–25.78 psu), dissolved oxygen (DO) (6.79–7.39 mg/L), total dissolved solids (TDSs) (6960.6–20,125 mg/L), and biochemical oxygen demand (BOD) (0.11–2.94 mg/L). The levels of TDS, EC, turbidity, and salinity in the Sundays River estuary water exceeded the World Health Organization (WHO) guidelines of 2017, rendering the water unfit for even recreational purposes. Additionally, the bacterial levels identified in this study were above the values set by the South Africa Department of Water Affairs (SA-DWAF). The identified microorganisms are perceived as essential indicators of fecal contamination and have the potential to multiply in the environment. Possible pollution may be a result of various municipal effluents consistently discharged into the waterbody. Full article

Microalgae and cyanobacteria are photosynthetic microorganisms capable of removing nutrients from eutrophic waters and producing biomass. Therefore, the aim of this study was to evaluate the bioremediation performance of three microalgae and one cyanobacterium native to Lake Xochimilco and to assess their potential for biofuel production (biodiesel and biogas) from biomass generated. In photobioreactors, ammonium (96.61–97.06%), nitrate (82.4–100%), and phosphate (83.95–89.71%) were effectively removed from the lake water. The specific growth rates ranged from 0.041 to 0.144 d⁻¹ and biomass productivities from 0.016 to 0.049 g L⁻¹ d⁻¹, with high biomass yield on the substrate. The estimated CO₂ fixation rates ranged from 0.024 to 0.092 g L⁻¹ d⁻¹. Chlorella sp. achieved the highest yield of fatty acid methyl esters (FAMEs) with 91.24% of the extracted lipids. Overall, saturated FAMEs were predominant in the biodiesel; however, the presence of monounsaturated FAMEs such as methyl palmitoleate and methyl oleate enhances their fluidity and oxidative stability. Synechocystis sp. and Chlorella sp. produced the most biogas using biomass after lipid extraction, at 429.5 L kg⁻¹ VS and 404.9 L kg⁻¹ VS, respectively, with over 60% biomethane. These strains represent a sustainable and promising possibility for water bioremediation and generating biofuels. Full article

Carbon capture and storage (CCS) is widely regarded as a viable pathway for reducing greenhouse gas emissions; however, large-scale deployment remains constrained by project economics and policy uncertainty. This study presents a life cycle costing assessment of a proposed CCS retrofit at the Hunter Unit 3 coal-fired power plant in Emery County, Utah, encompassing carbon capture, transport, and subsurface storage. Results indicate that the project appears economically favorable under the assumptions of this screening-level analysis and under current policy conditions, with an estimated break-even time of approximately five years. The analysis identifies a large upfront capital investment exceeding $600,000,000, offset by planned revenue from federal tax credits totaling several billion dollars over the project lifetime. Sensitivity analyses show that project economics are dominated by capture costs and annual mass of CO₂ sequestration rates, while storage and transport costs play secondary roles. A synthetic policy-perturbation analysis of the $85/ton tax credit further demonstrates that policy volatility materially increases uncertainty in investment returns. These results highlight both the economic potential of CCS retrofits at existing power plants and the critical role of stable long-term policy in enabling investment. Full article

Aquatic ecosystems worldwide are increasingly threatened by invasive species, with water hyacinth [Eichhornia crassipes (Mart.) Solms] being among the most destructive aquatic weeds. Despite numerous regional studies, a global assessment integrating climatic and hydrological drivers remains lacking. Here, we assessed current and future invasion risks across 55,945 freshwater lakes using the maximum entropy (MaxEnt) model. Climatic variables and key aquatic parameters, including biological oxygen demand (BOD), water depth, and discharge, were incorporated under two shared socioeconomic pathways (SSP2-4.5 and SSP5-8.5). Annual mean temperature, annual precipitation, and BOD were the strongest predictors of habitat suitability. Under current conditions, 5524 lakes, primarily in tropical and subtropical regions, were identified as being suitable habitats, with medium-sized lakes exhibiting the highest proportional suitability (16.54%). Although small lakes were most frequently classified as suitable due to their abundance, larger lakes showed higher suitability intensity. Future projections indicated marked habitat expansion, especially under SSP5-8.5, with suitable lake surface area increasing to 18.12% by 2061–2080. Moreover, 543 currently unsuitable lakes, including Lake Erie, Lake Huron, and Lake Ontario, were projected to face elevated invasion risk, particularly in Africa, South Asia, Southeast Asia, and North America. This global, lake-specific assessment supports early warning, targeted management, and climate-responsive policy planning. Full article

The Mahu Sag, a hydrocarbon-rich depression within the Junggar Basin, hosts significant petroleum resources. Here, the Permian Fengcheng Formation shale oil reservoirs have emerged as a primary exploration target. This study investigates fracture development within these alkaline lacustrine shales, a critical factor governing hydrocarbon migration and accumulation. Through integrated petrographic and geochemical analyses, we elucidate a multifactorial fracture formation mechanism driven by the interplay of alkaline minerals, stress, and fluids. Two distinct fracture types were identified: bedding-complex fracture veins (BCFVs) and Y-shaped high-angle fracture veins (Y-HFVs). Both fracture types result from alkaline fluid–rock interactions, which induce fracture opening along specific orientations, alter fracture angles, and control aperture width and final morphology. Alkaline mineral assemblages further influence fracture evolution via dissolution–precipitation cycles. Concurrently, these assemblages preserve hydrocarbons by inhibiting the thermal maturation of organic matter, as evidenced by variations in fluid inclusion fluorescence. The fracture networks act as crucial migration pathways, with the BCFV containing higher-maturity hydrocarbons (indicated by blue-green fluorescence) and the Y-HFV retaining less mature fluids (indicated by yellow-green fluorescence). This study presents the first systematic characterization of the multifactorial controls on fractures in alkaline lake environments, proposing a cooperative “alkaline minerals–stress–fluids” mechanism. These findings provide a new framework for understanding fracture development in alkaline lacustrine shales and offer valuable insights for shale oil exploration in analogous depositional settings. Full article

An integrated analysis incorporating total organic carbon (TOC) content measurement, X-ray diffraction (XRD), scanning electron microscopy (SEM), and gas adsorption experiments was performed on core samples from Well FY1-4 of the upper-fourth Shahejie Formation (Es₄) in the Minfeng Sag. To address the lack of systematic research on the pore and fractal characteristics of organic-rich low-maturity shales in the Minfeng Sag (against the preponderance of studies on high-maturity shales), this study characterized the lithofacies, reservoir space and pore fractal features of the target low-maturity shale interval and clarified the sedimentary controls on lithofacies and key factors regulating pore fractal heterogeneity. The results reveal that the shale in the Es₄ of the study area exhibits low thermal maturity, with six distinct lithofacies identified. Organic-rich laminated calcareous shale lithofacies (RL-1) and organic-rich laminated calcareous/argillaceous mixed shale lithofacies (RL-2) represent the most favorable lithofacies, which are dominated by large mesopores and macropores. Their reservoir spaces were primarily composed of intergranular pores, intragranular pores, and organic pores, whereas the other lithofacies are dominated by small mesopores. The pore surface fractal dimension (D) was calculated using the Frenkel–Halsey–Hill (FHH) model based on low-temperature N₂ adsorption (LTNA) data. The meso-macropore system shows higher heterogeneity than the micropore system (D₂ > D₁). Both D₁ and D₂ exhibit a weak negative correlation with TOC and carbonate content and a positive correlation with clay content. In the initial depositional stage of the Es₄, the arid climate, weak terrigenous input, shallow lake depth, and high salinity resulted in the strongly reducing saline depositional environment with relatively low organic matter enrichment. As the climate became progressively humid in the middle and late stages, hydrodynamic conditions intensified, leading to a lithofacies transition from mixed shales to argillaceous calcareous shales. Increased TOC and carbonate contents reduce the pore fractal dimension of shale. Smaller fractal dimensions directly indicate a simple pore structure and regular pore surface in the shale oil reservoir of the Minfeng Sag, where reservoir space is dominated by large pores such as intercrystalline pores and dissolved pores. Such pore characteristics are more favorable for the enrichment of shale oil. Full article

Bottom sediments in anthropogenically impacted freshwater systems represent a dynamic and poorly constrained source of secondary pollution, where heavy metal mobility, rather than total concentration, controls the release of contaminants into the water column under changing physicochemical conditions. This issue is particularly pronounced in small and medium-sized freshwater systems subjected to sustained anthropogenic pressure, where local hydrochemical conditions and sediment composition strongly influence metal speciation and remobilization dynamics. This study aims to quantitatively assess heavy metal speciation, mobility, and associated ecological risk in bottom sediments of anthropogenically impacted freshwater systems using complementary analytical approaches. The data obtained indicate a pronounced spatial heterogeneity in the total metal content, due to varying degrees of anthropogenic impact on the water bodies. The highest level of pollution was recorded in the bottom sediments of the Chizhovskoye reservoir, where Zn concentrations reach 755 mg/kg, Cr—379 mg/kg, Ni—106 mg/kg, and Cu—158 mg/kg, indicating intense technogenic influence. The bottom sediments of the Loshitsa River are characterized by elevated, but less extreme values: the content of Cu is up to 77 mg/kg, Zn—up to 263 mg/kg, and Mn—up to 418 mg/kg. In contrast to urbanized water bodies, the background site—Lake Sergeevskoye—is characterized by significantly lower concentrations of heavy metals, which confirms its representativeness as a control object. Analysis of the fractional composition showed that Zn and Mn have the largest share of mobile forms, with their concentrations in the mobile phase reaching 12–92 mg/kg and 60–116 mg/kg, respectively, especially under conditions of increased anthropogenic load. A significant portion of Cu and Zn (up to 60–70% of the total content) is associated with organic matter, indicating the important role of the organic matrix in retaining metals and their potential mobilization under changing environmental conditions. Calculation of the geoaccumulation index showed that most of the studied bottom sediments belong to the from uncontaminated to moderately contaminated class, while for Cr and Ni in the Chizhovskoye reservoir, I_geo values up to 1.9 are characteristic, corresponding to a moderate level of pollution. The results obtained indicate a significant impact of anthropogenic load on the forms of occurrence and mobility of heavy metals and highlight the role of bottom sediments as an active factor in the secondary pollution of freshwater ecosystems. Full article

Currently, there are no data and studies from Lake Vaya, Burgas city, on the status and quantity of microplastic (MP) particles in fish. This is the first study on the abundance, morphotype, size, polymer type, and color of MP in Gambusia affinis and Liza saliens from the lake. In this study, we also investigated the distribution of MPs in different parts of the fish. Within each morphological group of MPs, three size classes were recognized: 25–100 µm, 100–200 µm, and 200–500 µm. Microplastics were found in all studied fish tissues except for caviar, but in different proportions of pellets, fibers, and fragments. In our study, fibers were the most isolated, followed by irregularly shaped MPs—fragments. Two types of polymers were found—PET and PA. There are currently no studies in Lake Vaya that assess the risk of ingestion of microplastics for fish health and human health. Research shows that almost all aquatic environments worldwide are at risk of MP contamination. Laboratory and field studies highlighted that fish are particularly susceptible to MP ingestion, although freshwater species have been studied less than marine ones. The results of our study suggest that consumption of fish from Lake Vaya may expose citizens to risk. Full article