Search Results (12)

Geopolymers possess good mechanical properties and durability, and their partial replacement of traditional Portland cement is noteworthy for promoting the development of low-carbon building materials. To clarify the influence mechanism of the mechanical properties of slag-fly ash-based geopolymer mortar, this paper investigated the hydration heat, composition, and morphology of hydration products with various contents and moduli of waterglass. The results showed that the compressive strength of geopolymer mortar increased with increasing waterglass content, and first rose and then fell as the waterglass modulus raised, while its flexural strength increased and then decreased with the growth in both. The compressive and flexural strength of geopolymer mortar with 1.2-modulus waterglass at 20 wt% cured for 28 days were 88.4 MPa and 9.0 MPa, respectively. The hydration temperature and cumulative hydration heat of geopolymer mortar was elevated with the increase in waterglass content, and declined with the rising waterglass modulus. The hydration products of the geopolymer consisted of dense amorphous and flocculent structures wrapped around each other. The microstructure of the geopolymer cured for 3 days was loose when the content of 1.4-modulus waterglass was 5 wt%. The relative areas of the flocculation in the geopolymer cured for 28 days increased while the waterglass modulus was greater than 1.4, forming an interface with the dense amorphous structure generated during the early hydration stage, leading to a decrease in its mechanical properties. Therefore, it is recommended for slag-fly ash geopolymer mortar that the waterglass modulus is between 1.2 and 1.4 and its content is no less than 10 wt% to ensure suitable mechanical properties. This study also provided a referenceable time period for the pouring and operation of the engineering application of slag-fly ash-based geopolymer repair mortar. Full article

This study aimed to investigate the feasibility of using geopolymer paste (GP) as an adhesive agent for (i) anchoring steel bars in concrete substrates, (ii) repairing concrete, and (iii) repairing limestone and granite masonry blocks commonly found in historic buildings. In this investigation, seven cement-free GP mixes were developed with different combinations of binder materials (slag, silica fume, and metakaolin). The mechanical properties, adhesive performance, and production cost of the developed GP mixes were compared to those of a commercially epoxy adhesive mortar (EAM). The results obtained from this study indicated that the use of GPs enhanced the bonding between steel bars and concrete substrates, achieving bonding strengths that were 19.7% to 49.2% higher than those of control specimens with steel bars directly installed during casting. In concrete repairs, the GPs were able to restore about 60.6% to 87.9% of the original capacity of the control beams. Furthermore, GPs exhibited a promising performance in repairing limestone and granite masonry blocks, highlighting their potential suitability for masonry structures. The best adhesive performance was observed when a ternary binder material system consisting of 70% slag, 20% metakaolin and 10% silica fume was used. This combination, compared to the investigated EAM, showed comparable adhesive properties at a significantly low cost, indicating the viability of GPs as a cost-effective, eco-friendly adhesive agent. Full article

The degradation of concrete and reinforced concrete structures is a significant technical and economic challenge, requiring continuous repair and rehabilitation throughout their service life. Geopolymers (GPs), known for their high mechanical strength, low shrinkage, and durability, are being increasingly considered as alternatives to traditional repair materials. However, there is currently a lack of understanding regarding the interface bond properties between new geopolymer layers and old concrete substrates. In this paper, using advanced computational techniques, including quantum mechanical calculations and stochastic modeling, we explored the adsorption behavior and interaction mechanism of aluminosilicate oligomers with different Si/Al ratios forming the geopolymer gel structure and calcium silicate hydrate as the substrate at the interface bond region. We analyzed the electron density distributions of the highest occupied and lowest unoccupied molecular orbitals, examined the reactivity indices based on electron density functional theory, performed Mulliken charge population analysis, and evaluated global reactivity descriptors for the considered oligomers. The results elucidate the mechanisms of local and global reactivity of the oligomers, the equilibrium low-energy configurations of the oligomer structures adsorbed on the surface of C-(A)-S-H(I) (100), and their adsorption energies. These findings contribute to a better understanding of the adhesion properties of geopolymers and their potential as effective repair materials. Full article

Geopolymers have been proposed as a green alternative to Portland cement with lowered carbon footprints. In this work, a geopolymeric mortar obtained using waste materials is studied. Fly ash, a waste generated by coal combustion, is used as one of the precursors, and waste glass as lightweight aggregates (LWAs) to improve the thermal performance of the mortar. The experimental study investigates the effect of varying the alkali activating solution (AAS) amount on the workability, compressive strength, and thermal conductivity of the mortar. Indeed, AAS represents the most expensive component in geopolymer production and is the highest contributor to the environmental footprint of these materials. This research starts by observing that LWA absorbs part of the activating solution during mixing, suggesting that only a portion of the solution effectively causes the geopolymerization reactions, the remaining part wetting the aggregates. Three mixes were investigated to clarify these aspects: a reference mix with a solution content calibrated to have a plastic consistency and two others with the activating solution reduced by the amount absorbed by aggregates. In these cases, the reduced workability was solved by adding the aggregates in a saturated surface dry state in one mix and free water in the other. The experimental results evidenced that free water addiction in place of a certain amount of the solution may be an efficient way to improve thermal performance without compromising the resistance of the mortar. The maximum compressive strength reached by the mortars was about 10 MPa at 48 days, a value in line with those of repair mortars. Another finding of the experimental research is that UPV was used to follow the curing stages of materials. Indeed, the instrument was sensitive to microstructural changes in the mortars with time. The field of reference of the research is the rehabilitation of existing buildings, as the geopolymeric mortars were designed for thermal and structural retrofitting. Full article

Geopolymer, as a new type of solid waste-based inorganic cementitious material, exhibits outstanding behavior in terms of physical and chemical performance, macromechanical properties, long-lasting stability, and features potential application development tendency in the field of repair and reinforcement of existing concrete structures. This paper investigated the interfacial behavior of geopolymer mortar with OPC concrete substrate under different slag, fly ash and red mud mixing proportions, while cement mortar was used as a control group for the research. The interfacial bonding properties of the geopolymer mortar to the OPC concrete substrate were elaborated by carrying out split tensile test, double-sided shear test, and three-point bending test. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were employed to further analyze the microstructural characteristics and physical phase components of the interfacial transition zone between the geopolymer mortar and the OPC concrete substrate. The results indicated that the compressive strength of slag-fly ash-red mud-based geopolymer mortar under different mixing ratio conditions was consistently superior to that of cement mortar, where the optimum mixing ratio for the geopolymer mortar was S33F33R33. Overall, the interfacial bonding properties of the geopolymer mortar to the OPC concrete substrate gradually increased with the increment of the slag content, however, an evolutionary trend of minor enhancement followed by a gradual reduction was observed with the growth of the fly ash and red mud content. Full article

This study explored self-healing in geopolymer mortar cured at ambient temperature using polypropylene fibers and bacterial co-cultures of Bacillus subtilis and Bacillus megaterium. Damage degree, compressive strength, ultrasonic pulse velocity (UPV), strength-regain percentage, and self-healing percentage were evaluated. A full factorial design was used, which resulted in an eight-run complete factorial design with four levels in the first factor (polypropylene content: 0%, 0.25%, 0.5%, and 0.75%) and two levels in the second factor (bacteria concentration: 0 (without) and 1 (with)). The results indicate that increasing the polypropylene fiber content enhanced strength regains up to 199.97% with 0.75% fibers and bacteria. The bacteria alone improved strength-regain percentages by 11.22% through mineral precipitation. The analysis of variance (ANOVA) showed no interaction between fibers and bacteria, but both independently improved the compressive strength. Only bacterial samples exhibited positive self-healing, ranging from 16.77 to 147.18%. The analysis using a scanning electron microscope with energy dispersive X-ray (SEM-EDX) and X-ray fluorescence (XRF) also revealed greater calcite crystal formation in bacterial samples, increasing the strength-regain and self-healing percentages. The results demonstrate that polypropylene fibers and bacteria cultures could substantially enhance the strength, durability, and self-healing percentage of geopolymer mortars. The findings present the potential of a bio-based self-healing approach for sustainable construction and repair materials. Full article

The geopolymer uses fly ash, slag, and other solid wastes as raw materials and is widely used in building repair, but it is brittle and can be made tougher by incorporating fibers. In this study, polyvinyl alcohol (PVA) fibers, polyoxymethylene (POM) fibers, and polypropylene (PP) fibers were incorporated into the geopolymer mortar repair material, and the geopolymer was tested by changing the amount of fibers incorporation as well as the type. The effect of different fibers on the geopolymer mortar repair material was analyzed by comparing the flexural strength, compressive strength, flexural toughness, shrinkage, and bonding properties with cement mortar of different samples. The geopolymer was analyzed by Diffraction of X-rays (XDR) and Scanning Electron Microscopy (SEM) to further understand the hydration products and microstructure of the geopolymer. The results showed that the incorporation of fibers reduced the flexural strength and increased the compressive strength of the geopolymer mortar repair material; the mechanical properties of the geopolymer mortar repair material decreased with the increase in fiber incorporation, and the best mechanical properties of the geopolymer mortar repair material incorporated with 1.0% PP fibers; the toughening effect of PVA fiber was best when the amount of fiber incorporated was the same; the shrinkage properties of the geopolymer were good and had little effects on the building repair; the bonding properties of repaired specimens repaired with geopolymer mortar repair materials depended on the bonding area of the fracture surface, and the bonding area was enhanced with the increase in fiber incorporation; the XRD pattern showed that the hydration products of the geopolymer were mainly CaCO₃ and C–S–H gels. Full article

This study conducts a scientometric review on the use of geopolymer mortar and composites in different construction applications. It aims to analyze the findings of past research and reveal the research constituents, development trends, and knowledge gaps. The Scopus database was employed to retrieve the relevant publications, while Bibliometrix was used to conduct the statistical analyses. Results revealed a steady and gradual increase in the number of publications after 2013, as the annual growth rate increased from 23.9% to 45.2% between the timeframes 2003–2013 and 2014–2022, respectively. The analysis highlighted that many authors collaborated on different construction applications of geopolymers regardless of geographic location. Meanwhile, Construction and Building Materials, China, and Universiti Malaysia Perlis were found to be the predominant journal, country, and institution, respectively. The scientometric analysis showed that the most frequently investigated applications for geopolymer mortars and composites were fire resistance, corrosion protection, and repair. Research gaps highlighted that other applications are not as well investigated despite the promising performance of the geopolymer composites, including 3D printing, heavy metals absorption, environmental protection, and underwater applications. Future research is required to assess the use of other alumina and silica-rich binders in geopolymers while also exploring their lifecycle assessment and economic impact. Full article

This study aimed to assess the feasibility of utilizing geopolymer for repairing reinforced concrete beams. Three types of beam specimens were fabricated: benchmark specimens without any grooves, rectangular-grooved beams, and square-grooved beams. The repair materials employed included geopolymer material, and epoxy resin mortar, while carbon fiber sheets were used as reinforcement in select cases. The repair materials were applied to the rectangular and square-grooved specimens, with the carbon fiber sheets attached to the tension side of the specimens. To evaluate the flexural strength of the concrete specimens, a third-point loading test was conducted. The test results indicated that the geopolymer exhibited higher compressive strength and shrinkage rate compared to the epoxy resin mortar. Furthermore, the specimens reinforced with carbon fiber sheets demonstrated even greater strength than the benchmark specimens. In terms of flexural strength under cyclic third-point loading tests, the carbon fiber-reinforced specimens exhibited the ability to withstand over 200 cycles of repeated loading at 0.8 times the ultimate load. In contrast, the benchmark specimens could only withstand seven cycles. These findings highlight that the use of carbon fiber sheets not only enhances compressive strength but also improves resistance to cyclic loading. Full article

Various geopolymer mortars (GPMs) as concrete repairing materials have become effective owing to their eco-friendly properties. Geopolymer binders designed from agricultural and industrial wastes display interesting and useful mechanical performance. Based on this fact, this research (experimental) focuses on the feasibility of achieving a new GPM with improved mechanical properties and enhanced durability performance against the aggressive sulfuric acid and sulfate attacks. This new ternary blend of GPMs can be achieved by combining waste ceramic tiles (WCT), fly ash (FA) and ground blast furnace slag (GBFS) with appropriate proportions. These GPMs were designed from a high volume of WCT, FA, and GBFS to repair the damaged concretes existing in the construction sectors. Flexural strength, slant shear bond strength, and compatibility of the obtained GPMs were compared with the base or normal concrete (NC) before and after exposure to the aggressive environments. Tests including flexural four-point loading and thermal expansion coefficient were performed. These GPMs were prepared using a low concentration of alkaline activator solution with increasing levels of GBFS and FA replaced by WCT. The results showed that substitution of GBFS and FA by WCT in the GPMs could enhance their bond strength, mechanical characteristics, and durability performance when exposed to aggressive environments. In addition, with the increase in WCT contents from 50 to 70%, the bond strength performance of the GPMs was considerably enhanced under sulfuric acid and sulfate attack. The achieved GPMs were shown to be highly compatible with the concrete substrate and excellent binders for various civil engineering construction applications. It is affirmed that the proposed GPMs can efficiently be used as high-performance materials to repair damaged concrete surfaces. Full article

It is a universal fact that concrete is one of the most employed construction materials and hence its exigency is booming at a rocket pace, which in turn, has resulted in a titanic demand of ordinary Portland cement. Regrettably, the production of this essential binder of concrete is not merely found to consume restricted natural resources but also found to be associated with emission of carbon dioxide—a primary greenhouse gas (GHG) which is directly answerable to earth heating, resulting in the gigantic dilemma of global warming. Nowadays, in order to address all these impasses, researchers are attracted to innovative Geopolymer concrete technology. However, crack development of various sizes within the concrete is inevitable irrespective of its kind, mix design, etc., owing to external and internal factors viz., over-loading, exposure to severe environments, shrinkage, or error in design, etc., which need to be sealed otherwise these openings permits CO₂, water, fluids, chemicals, harmful gases, etc., to pass through reducing service life and ultimately causing the failure of concrete structures in the long term. That is why instant repairs of these cracks are essential, but manual mends are time-consuming and costly too. Hence, self-healing of cracks is desirable to ease their maintenances and repairs. Self-healing geopolymer concrete (SHGPC) is a revolutionary product extending the solution to all these predicaments. The present manuscript investigates the self-healing ability of geopolymer paste, geopolymer mortar, and geopolymer concrete—a slag-based fiber-reinforced and a variety of other composites that endow with multifunction have also been compared, keeping the constant ratio of water to the binder. Additionally, the feasibility of bacteria in a metakaolin-based geopolymer concrete for self-healing the cracks employing Bacteria-Sporosarcina pasteurii, producing Microbial Carbonate Precipitations (MCP), was taken into account with leakage and the healing process in a precipitation medium. Several self-healing mechanisms, assistances, applications, and challenges of every strategy are accentuated, compared with their impacts as a practicable solution of autogenously-healing mechanisms while active concretes are subjected to deterioration, corrosion, cracking, and degradation have also been reviewed systematically. Full article

Waste management is emerging as one of the most troublesome and critical problems of the upcoming decades. Therefore, the utilization of industrial by-products as building materials components has been widely studied in recent years. Geopolymer concrete, with binder entirely substituted by slag or fly ash, is one of the materials, which combines positive environmental impact with satisfying mechanical parameters. Although various properties of geopolymers have been examined, the autogeneous self-healing potential of this alternative binder has not been thoroughly verified yet. This paper aims to validate whether geopolymer concrete made of alkali activated slag is capable of self-repair. Four different mortar mixes with two types of slag and varying activation parameters were investigated. The polyvinyl alcohol (PVA) fibers were added in order to control the crack width. The 1.2 × 1.2 × 6 cm beams were pre-cracked with the use of three point bending test at 7 days after casting to achieve crack opening of approximately 300 µm. The effects of various exposure conditions on the healing process were examined, i.e., lime water, different sodium silicate solutions and water. The self-healing efficiency as well as the evolution of the crack recovery was assessed by the observation of the crack surface with the use of digital optical microscope. The healed area of the crack was calculated and compared for all the specimens by applying the image processing techniques. The morphology of the healing products as well as their chemical composition were examined with the use of Scanning Electron Microscope with Energy Dispersive Spectroscopy. Full article