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Keywords = gasoline port fuel injection

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18 pages, 12334 KB  
Article
A Deep Learning Method for the Prediction of Pollutant Emissions from Internal Combustion Engines
by Federico Ricci, Massimiliano Avana and Francesco Mariani
Appl. Sci. 2024, 14(21), 9707; https://doi.org/10.3390/app14219707 - 24 Oct 2024
Cited by 1 | Viewed by 2811
Abstract
The increasing demand for vehicles is leading to a rise in pollutant emissions across the world. This decline in air quality is significantly impacting public health, with internal combustion engines being a major contributor to this concerning trend. Ever-stringent regulations demand high engine [...] Read more.
The increasing demand for vehicles is leading to a rise in pollutant emissions across the world. This decline in air quality is significantly impacting public health, with internal combustion engines being a major contributor to this concerning trend. Ever-stringent regulations demand high engine efficiency and reduced pollutant emissions. Therefore, every automobile company requires rigorous methods for accurately estimating engine emissions. The implementation of advanced technologies, including machine learning methods, has proven to be a promising solution. The present work aims to develop an artificial intelligence-based model to estimate the pollutant emissions produced by an internal combustion engine under varying operating conditions. Experimental activities have been conducted on a single-cylinder spark ignition research engine with gasoline port fuel injection under both stationary and dynamic operating conditions. This work explores different artificial intelligence architectures and compares their performance in order to determine the best approach for the presented task. These structures have been trained and tested based on data obtained from the engine control unit and fast emission analyzer. The main target is to evaluate the possibility of applying the presented artificial intelligence predictive model as an on-board virtual tool in the estimation of emissions in real driving conditions. Full article
(This article belongs to the Special Issue Applications of Artificial Intelligence in Transportation Engineering)
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15 pages, 2371 KB  
Article
Evaluation of Two Particle Number (PN) Counters with Different Test Protocols for the Periodic Technical Inspection (PTI) of Gasoline Vehicles
by Anastasios Melas, Jacopo Franzetti, Ricardo Suarez-Bertoa and Barouch Giechaskiel
Sensors 2024, 24(20), 6509; https://doi.org/10.3390/s24206509 - 10 Oct 2024
Cited by 2 | Viewed by 1747
Abstract
Thousands of particle number (PN) counters have been introduced to the European market, following the implementation of PN tests during the periodic technical inspection (PTI) of diesel vehicles equipped with particulate filters. Expanding the PN-PTI test to gasoline vehicles may face several challenges [...] Read more.
Thousands of particle number (PN) counters have been introduced to the European market, following the implementation of PN tests during the periodic technical inspection (PTI) of diesel vehicles equipped with particulate filters. Expanding the PN-PTI test to gasoline vehicles may face several challenges due to the different exhaust aerosol characteristics. In this study, two PN-PTI instruments, type-examined for diesel vehicles, measured fifteen petrol passenger cars with different test protocols: low and high idling, with or without additional load, and sharp accelerations. The instruments, one based on diffusion charging and the other on condensation particle counting, demonstrated good linearity compared to the reference instrumentation with R-squared values of 0.93 and 0.92, respectively. However, in a considerable number of tests, they registered higher particle concentrations due to the presence of high concentrations below their theoretical 23 nm cut-off size. The evaluation of the different test protocols showed that gasoline direct injection engine vehicles without particulate filters (GPFs) generally emitted an order of magnitude or higher PN compared to those with GPFs. However, high variations in concentration levels were observed for each vehicle. Port-fuel injection vehicles without GPFs mostly emitted PN concentrations near the lower detection limit of the PN-PTI instruments. Full article
(This article belongs to the Section Physical Sensors)
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16 pages, 4541 KB  
Article
Optimising the Particulate Emission Characteristics of a Dual-Fuel Spark Ignition Engine by Changing the Gasoline Direct Injection Strategy
by Xiang Li, Siyue Liu, Wanzhong Li, Yiqiang Pei, Xuewen Zhang, Peiyong Ni, Zhijun Peng and Chenxi Wang
Sustainability 2024, 16(19), 8713; https://doi.org/10.3390/su16198713 - 9 Oct 2024
Viewed by 1513
Abstract
In the current global scenario, it is essential to find more effective and practical solutions to mitigate the problem of particulate emissions from vehicles. In this research, particulate emission characteristics with changing GDI pressure or applying a split GDI strategy with different second [...] Read more.
In the current global scenario, it is essential to find more effective and practical solutions to mitigate the problem of particulate emissions from vehicles. In this research, particulate emission characteristics with changing GDI pressure or applying a split GDI strategy with different second injection timings were initially explored in a Dual-Fuel Spark Ignition (DFSI) engine, which employs Ethanol Port Injection (EPI) plus Gasoline Direct Injection (GDI). The experimental results show that by increasing GDI pressure (PGDI) from 5.5 MPa to 18 MPa, ignition delay (θF) shows a small decrease of 0.68 degrees. The parameters, such as maximum in-cylinder temperature (TMI) and exhaust gas temperature (TEG), each increase by 53.75 K and 13.84 K. An apparent reduction of 59.5% and 36.26% was achieved for the concentrations of particulate number (NP) and particulate mass (MP), respectively. Particulate emissions are effectively reduced by a split GDI strategy with an appropriate range of second injection timing (tGDI2). Under tGDI2 = −260 °CA, NP and MP concentrations exhibit a relatively lower level. However, by delaying tGDI2 from −260 °CA to −140 °CA, there is an increase of more than 60% in NP concentration. The research findings help offer new and valuable insights into optimising particulate number and mass emissions from DFSI engines. Moreover, the findings could contribute novel and valuable insights into the optimisation of particulate emission characteristics in DFSI engines. Full article
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5 pages, 789 KB  
Proceeding Paper
Optimization of Performance, Emissions, and Vibrations of a Port Fuel Injection Spark Ignition Engine Operated with Gasoline Ethanol Methanol Blends Using Response Surface Methodology
by Sekhar Chinthamreddy, Domakonda Vinay Kumar and Shaik Subani
Eng. Proc. 2024, 66(1), 40; https://doi.org/10.3390/engproc2024066040 - 24 Jul 2024
Cited by 1 | Viewed by 946
Abstract
IC Engines have played a vital role in past years and will in future years too. The only way that engines are made popular is the power they produce, which is useful in the transportation sector, with which humans’ daily lives become easier [...] Read more.
IC Engines have played a vital role in past years and will in future years too. The only way that engines are made popular is the power they produce, which is useful in the transportation sector, with which humans’ daily lives become easier concerning time and effort. The only issues with these engines are the depletion of fossil fuels and harmful emissions. To regulate these threats, in the current study an SI engine is modified to duel fuel mode in such a way that the engine runs with hydrogen gas at different flow rates along with air. Engine speed is varied from 1800 to 3400 rpm under constant load by letting an ethanol, methanol, and gasoline mixture enter into the cylinder. Performance parameters like brake thermal efficiency, HC emissions, and vibrations produced from the engine are in agreement with the blended fuels used in this study. Full article
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14 pages, 2927 KB  
Article
A Complete Assessment of the Emission Performance of an SI Engine Fueled with Methanol, Methane and Hydrogen
by Francesco Catapano, Silvana Di Iorio, Agnese Magno, Paolo Sementa and Bianca Maria Vaglieco
Energies 2024, 17(5), 1026; https://doi.org/10.3390/en17051026 - 22 Feb 2024
Cited by 6 | Viewed by 1835
Abstract
This study explores the potentiality of low/zero carbon fuels such as methanol, methane and hydrogen for motor applications to pursue the goal of energy security and environmental sustainability. An experimental investigation was performed on a spark ignition engine equipped with both a port [...] Read more.
This study explores the potentiality of low/zero carbon fuels such as methanol, methane and hydrogen for motor applications to pursue the goal of energy security and environmental sustainability. An experimental investigation was performed on a spark ignition engine equipped with both a port fuel and a direct injection system. Liquid fuels were injected into the intake manifold to benefit from a homogeneous charge formation. Gaseous fuels were injected in direct mode to enhance the efficiency and prevent abnormal combustion. Tests were realized at a fixed indicated mean effective pressure and at three different engine speeds. The experimental results highlighted the reduction of CO and CO2 emissions for the alternative fuels to an extent depending on their properties. Methanol exhibited high THC and low NOx emissions compared to gasoline. Methane and, even more so, hydrogen, allowed for a reduction in THC emissions. With regard to the impact of gaseous fuels on the NOx emissions, this was strongly related to the operating conditions. A surprising result concerns the particle emissions that were affected not only by the fuel characteristics and the engine test point but also by the lubricating oil. The oil contribution was particularly evident for hydrogen fuel, which showed high particle emissions, although they did not contain carbon atoms. Full article
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12 pages, 1385 KB  
Article
Emission Characteristics of Particle Number from Conventional Gasoline and Hybrid Vehicles
by Ying Zhang, Xinping Yang and Mingliang Fu
Sustainability 2024, 16(1), 12; https://doi.org/10.3390/su16010012 - 19 Dec 2023
Cited by 7 | Viewed by 1730
Abstract
Vehicular particle number (PN) emissions have garnered increasing attention. In this study, nine light-duty vehicles, involving conventional internal combustion engine gasoline vehicles (ICEVs) and hybrid electric vehicles (HEVs), underwent testing on a chassis dynamometer to elucidate key factors influencing PN emissions. We found [...] Read more.
Vehicular particle number (PN) emissions have garnered increasing attention. In this study, nine light-duty vehicles, involving conventional internal combustion engine gasoline vehicles (ICEVs) and hybrid electric vehicles (HEVs), underwent testing on a chassis dynamometer to elucidate key factors influencing PN emissions. We found that with more stringent emission standards Gasoline Direct Injection (GDI) vehicles exhibited a reduction in PN emission factors. Higher PN emissions for GDI vehicles than vehicles with Multi-Port Fuel Injection (PFI) engines were observed; meanwhile, HEV showed lower PN emissions than ICEVs. PN emissions for cold start consistently exceeded warm start across vehicles with different standards and technologies. Notably, China VI HEV exhibited a substantial 19.2-fold increase in PN emissions for cold start compared to warm start. Analysis on a second-by-second basis revealed that cold-start emissions concentrated in low speed, while warm-start emissions were prominent in extra-high speed. Concerning vehicle specific power (VSP), the lowest mean PN emission rate occurred during idle conditions. PN emissions for China IV-VI ICEVs with GDI engines would increase with the increasing VSP, whereas China VI ICEVs with PFI engines and HEV with GDI engines showed varied patterns of PN emissions, especially under cold start. Our study would further facilitate formulating effective strategies for vehicular PN emissions. Full article
(This article belongs to the Special Issue Aerosols and Air Pollution)
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15 pages, 6477 KB  
Article
Effect of Hydrogen-Rich Syngas Direct Injection on Combustion and Emissions in a Combined Fuel Injection—Spark-Ignition Engine
by Zhen Shang, Yao Sun, Xiumin Yu, Ling He and Luquan Ren
Sustainability 2023, 15(11), 8448; https://doi.org/10.3390/su15118448 - 23 May 2023
Cited by 8 | Viewed by 2785
Abstract
To utilize the high efficiency of gasoline direct injection (GDI) and solve the high particulate number (PN) issue, hydrogen-rich syngas has been adopted as a favorable sustainable fuel. This paper compares and analyzes the effects of the injection configurations (GDI, gasoline port injection [...] Read more.
To utilize the high efficiency of gasoline direct injection (GDI) and solve the high particulate number (PN) issue, hydrogen-rich syngas has been adopted as a favorable sustainable fuel. This paper compares and analyzes the effects of the injection configurations (GDI, gasoline port injection combined with GDI (PGDI), and gasoline port injection combined with hydrogen-rich syngas direct injection (PSDI)) and fuel properties on combustion and emissions in a spark-ignition engine. The operational points were fixed at 1800 rpm with a 15% throttle position, and the excess air ratio was 1.1. The conclusions show that PSDI gained the highest maximum brake thermal efficiency (BTE) at the MBT point, and the maximum BTE for GDI was only 94% of that for PSDI. PSDI’s CoVIMEP decreased by 22% compared with GDI’s CoVIMEP. CO and HC emissions were reduced by approximately 78% and 60% from GDI to PSDI among all the spark timings, respectively, while PSDI emitted the highest NOX emissions. As for particulate emissions, PSDI emitted the highest nucleation-mode PN, while GDI emitted the lowest. However, the accumulation-mode PN emitted from PSDI was approximately 52% of that from PGDI and 5% of that from GDI. This study demonstrates the benefits of PSDI for sustainability in vehicle engineering. Full article
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13 pages, 3825 KB  
Article
Off-Cycle Emissions of Particle Number from Gasoline and DPF Diesel Passenger Cars in High-Load Conditions
by Hiroyuki Yamada, Taichi Kimura, Hidenori Konno and Yoshinori Kondo
Atmosphere 2023, 14(4), 732; https://doi.org/10.3390/atmos14040732 - 18 Apr 2023
Viewed by 2337
Abstract
To evaluate regulated gases and solid particle number (SPN) emissions in high-load off-cycle conditions, two diesel vehicles with a diesel particulate filter (DPF) and a urea selective catalytic reduction (SCR) system, respectively, and four gasoline port fuel injection (PFI) vehicles were tested with [...] Read more.
To evaluate regulated gases and solid particle number (SPN) emissions in high-load off-cycle conditions, two diesel vehicles with a diesel particulate filter (DPF) and a urea selective catalytic reduction (SCR) system, respectively, and four gasoline port fuel injection (PFI) vehicles were tested with the worldwide light-duty test cycle, including an extra-high (Ex-hi) phase. All the tested vehicles were developed for the Japanese market and did not comply with the Ex-hi phase. All vehicles exhibited higher CO2 emissions in the Ex-hi phase than in low, the mid and high phases. Increased NOx and SPN10-23 emissions were observed with the DPF vehicle. These increased emissions were due to the occurrence of passive regeneration of the DPF, and the urea SCR system was stopped as a result. The small gasoline PFI cars showed increased CO and SPN emissions in the Ex-hi phase. These emissions were due to enrichment control, which occurred in a quite high load operation condition. The feature of higher emissions with enrichment control differed from that observed in a warming-up process in the cold-start mode. SPN23 increased mainly in the warming-up process, whereas SPN10-23 increased in the Ex-hi phase with enrichment control. Hybrid vehicles seem to have fewer opportunities to show the enrichment control due to motor assist. Full article
(This article belongs to the Special Issue Vehicle Emissions: New Challenges and Potential Solutions)
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25 pages, 3700 KB  
Article
A Simulation Study of the Effect of HCNG Fuel and Injector Hole Number along with a Variation of Fuel Injection Pressure in a Gasoline Engine Converted from Port Injection to Direct Injection
by Javad Zareei, José Ricardo Nuñez Alvarez, Yolanda Llosas Albuerne, María Rodríguez Gámez and Ángel Rafael Arteaga Linzan
Processes 2022, 10(11), 2389; https://doi.org/10.3390/pr10112389 - 14 Nov 2022
Cited by 6 | Viewed by 2500
Abstract
The number of injector holes and the fuel-injection pressure in an internal combustion engine can affect engine performance and exhaust emissions. Conversion of a port-injection gasoline engine to an HCNG direct-injection engine improves engine performance and exhaust emissions. In addition, increasing the injection [...] Read more.
The number of injector holes and the fuel-injection pressure in an internal combustion engine can affect engine performance and exhaust emissions. Conversion of a port-injection gasoline engine to an HCNG direct-injection engine improves engine performance and exhaust emissions. In addition, increasing the injection pressure helps to increase engine performance. In this study, AVL Fire software was used to perform simulation by certain adjustments. The injection pressure was applied in mods of 15, 20, and 25 bars, the injector holes numbers were 3 and 6, the compression ratio changed from 10:1 to 14:1, and the amount of hydrogen enrichment to natural gas was in mods of 10%, 20%, 30%, and 40%. This paper discusses the items above with regard to power, torque, combustion chamber pressure, fuel conversion efficiency, and exhaust emissions. The result determined that increasing the number of injector holes improves the performance engine and reduces CO emission so that the contour plots confirmed the balanced distribution of temperature and pressure. According to obtained results, maximum engine performance improved from 2.5% to 5% at different speeds and 30% added hydrogen, 25 bar injection pressure, and 6-hole injectors. The amount of CO decreased by approximately 30%, and NOx increased by about 10%. Full article
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15 pages, 5884 KB  
Article
Numerical Study on Hydrogen–Gasoline Dual-Fuel Spark Ignition Engine
by Mahdi Aghahasani, Ayat Gharehghani, Amin Mahmoudzadeh Andwari, Maciej Mikulski, Apostolos Pesyridis, Thanos Megaritis and Juho Könnö
Processes 2022, 10(11), 2249; https://doi.org/10.3390/pr10112249 - 1 Nov 2022
Cited by 12 | Viewed by 3021
Abstract
Hydrogen, as a suitable and clean energy carrier, has been long considered a primary fuel or in combination with other conventional fuels such as gasoline and diesel. Since the density of hydrogen is very low, in port fuel-injection configuration, the engine’s volumetric efficiency [...] Read more.
Hydrogen, as a suitable and clean energy carrier, has been long considered a primary fuel or in combination with other conventional fuels such as gasoline and diesel. Since the density of hydrogen is very low, in port fuel-injection configuration, the engine’s volumetric efficiency reduces due to the replacement of hydrogen by intake air. Therefore, hydrogen direct in-cylinder injection (injection after the intake valve closes) can be a suitable solution for hydrogen utilization in spark ignition (SI) engines. In this study, the effects of hydrogen direct injection with different hydrogen energy shares (HES) on the performance and emissions characteristics of a gasoline port-injection SI engine are investigated based on reactive computational fluid dynamics. Three different injection timings of hydrogen together with five different HES are applied at low and full load on a hydrogen–gasoline dual-fuel SI engine. The results show that retarded hydrogen injection timing increases the concentration of hydrogen near the spark plug, resulting in areas with higher average temperatures, which led to NOX emission deterioration at −120 Crank angle degree After Top Dead Center (CAD aTDC) start of injection (SOI) compared to the other modes. At −120 CAD aTDC SOI for 50% HES, the amount of NOX was 26% higher than −140 CAD aTDC SOI. In the meanwhile, an advanced hydrogen injection timing formed a homogeneous mixture of hydrogen, which decreased the HC and soot concentration, so that −140 CAD aTDC SOI implied the lowest amount of HC and soot. Moreover, with the increase in the amount of HES, the concentrations of CO, CO2 and soot were reduced. Having the HES by 50% at −140 CAD aTDC SOI, the concentrations of particulate matter (PM), CO and CO2 were reduced by 96.3%, 90% and 46%, respectively. However, due to more complete combustion and an elevated combustion average temperature, the amount of NOX emission increased drastically. Full article
(This article belongs to the Special Issue Energy and Green Technology)
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12 pages, 4319 KB  
Article
Experimental Study on the Effects of Hydrogen Injection Strategy on the Combustion and Emissions of a Hydrogen/Gasoline Dual Fuel SI Engine under Lean Burn Condition
by Shiyi Pan, Jinhua Wang, Bin Liang, Hao Duan and Zuohua Huang
Appl. Sci. 2022, 12(20), 10549; https://doi.org/10.3390/app122010549 - 19 Oct 2022
Cited by 7 | Viewed by 4531
Abstract
Hydrogen addition can improve the performance and extend the lean burn limit of gasoline engines. Different hydrogen injection strategies lead to different types of hydrogen mixture distribution (HMD), which affects the engine performance. Therefore, the present study experimentally investigated the effects of hydrogen [...] Read more.
Hydrogen addition can improve the performance and extend the lean burn limit of gasoline engines. Different hydrogen injection strategies lead to different types of hydrogen mixture distribution (HMD), which affects the engine performance. Therefore, the present study experimentally investigated the effects of hydrogen injection strategy on the combustion and emissions of a hydrogen/gasoline dual-fuel port-injection engine under lean-burn conditions. Four different hydrogen injection strategies were explored: hydrogen direct injection (HDI), forming a stratified hydrogen mixture distribution (SHMD); hydrogen intake port injection, forming a premixed hydrogen mixture distribution (PHMD); split hydrogen direct injection (SHDI), forming a partially premixed hydrogen mixture distribution (PPHMD); and no hydrogen addition (NHMD). The results showed that 20% hydrogen addition could extend the lean burn limit from 1.5 to 2.8. With the increase in the excess air ratio, the optimum HMD changed from PPHMD to SHMD. The maximum brake thermal efficiency was obtained with an excess air ratio of 1.5 with PPHMD. The coefficient of variation (COV) with NHMD was higher than that with hydrogen addition, since the hydrogen enhanced the stability of ignition and combustion. The engine presented the lowest emissions with PHMD. There were almost no carbon monoxide (CO) and nitrogen oxides (NOx) emissions when the excess air ratio was, respectively, more than 1.4 and 2.0. Full article
(This article belongs to the Special Issue Combustion and Combustion Diagnostic Techniques)
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12 pages, 3807 KB  
Article
Performance Estimation of a Downsized SI Engine Running with Hydrogen
by Enzo Galloni, Davide Lanni, Gustavo Fontana, Gabriele D’Antuono and Simone Stabile
Energies 2022, 15(13), 4744; https://doi.org/10.3390/en15134744 - 28 Jun 2022
Cited by 13 | Viewed by 2757
Abstract
Hydrogen is a carbon-free fuel that can be produced in many ways starting from different sources. Its use as a fuel in internal combustion engines could be a method of significantly reducing their environmental impact. In spark-ignition (SI) engines, lean hydrogen–air mixtures can [...] Read more.
Hydrogen is a carbon-free fuel that can be produced in many ways starting from different sources. Its use as a fuel in internal combustion engines could be a method of significantly reducing their environmental impact. In spark-ignition (SI) engines, lean hydrogen–air mixtures can be burnt. When a gaseous fuel like hydrogen is port-injected in an SI engine, working with lean mixtures, supercharging becomes very useful in order not to excessively penalize the engine performance. In this work, the performance of a turbocharged PFI spark-ignition engine fueled by hydrogen has been investigated by means of 1-D numerical simulations. The analysis focused on the engine behavior both at full and partial load considering low and medium engine speeds (1500 and 3000 rpm). Equivalence ratios higher than 0.35 have been considered in order to ensure acceptable cycle-to-cycle variations. The constraints that ensure the safety of engine components have also been respected. The results of the analysis provide a guideline able to set up the load control strategy of a SI hydrogen engine based on the variation of the air to fuel ratio, boost pressure, and throttle opening. Furthermore, performance and efficiency of the hydrogen engine have been compared to those of the base gasoline engine. At 1500 and 3000 rpm, except for very low loads, the hydrogen engine load can be regulated by properly combining the equivalence ratio and the boost pressure. At 3000 rpm, the gasoline engine maximum power is not reached but, for each engine load, lean burning allows the hydrogen engine achieving much higher efficiencies than those of the gasoline engine. At full load, the maximum power output decreases from 120 kW to about 97 kW, but the engine efficiency of the hydrogen engine is higher than that of the gasoline one for each full load operating point. Full article
(This article belongs to the Special Issue Hydrogen-Fuelled Spark-Ignition Engines)
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15 pages, 2991 KB  
Article
Reproducibility of the 10-nm Solid Particle Number Methodology for Light-Duty Vehicles Exhaust Measurements
by Tero Lähde, Barouch Giechaskiel, Giorgio Martini, Joseph Woodburn, Piotr Bielaczyc, Daniel Schreiber, Mathias Huber, Panayotis Dimopoulos Eggenschwiler, Corrado Fittavolini, Salvatore Florio, Leonardo Pellegrini, Norbert Schuster, Ulf Kirchner, Hiroyuki Yamada, Jean-Claude Momique, Richard Monier, Yitu Lai, Timo Murtonen, Joonas Vanhanen, Athanasios Mamakos, Christos Dardiotis, Yoshinori Otsuki and Jürgen Spielvogeladd Show full author list remove Hide full author list
Atmosphere 2022, 13(6), 872; https://doi.org/10.3390/atmos13060872 - 26 May 2022
Cited by 5 | Viewed by 2908
Abstract
Many countries worldwide have introduced a limit for solid particles larger than 23 nm for the type approval of vehicles before their circulation in the market. However, for some vehicles, in particular for port fuel injection engines (gasoline and gas engines) a high [...] Read more.
Many countries worldwide have introduced a limit for solid particles larger than 23 nm for the type approval of vehicles before their circulation in the market. However, for some vehicles, in particular for port fuel injection engines (gasoline and gas engines) a high fraction of particles resides below 23 nm. For this reason, a methodology for counting solid particles larger than 10 nm was developed in the Particle Measurement Programme (PMP) group of the United Nations Economic Commission for Europe (UNECE). There are no studies assessing the reproducibility of the new methodology across different laboratories. In this study we compared the reproducibility of the new 10 nm methodology to the current 23 nm methodology. A light-duty gasoline direct injection vehicle and two reference solid particle number measurement systems were circulated in seven European and two Asian laboratories which were also measuring with their own systems fulfilling the current 23 nm methodology. The hot and cold start emission of the vehicle covered a range of 1 to 15 × 1012 #/km with the ratio of sub-23 nm particles to the >23 nm emissions being 10–50%. In most cases the differences between the three measurement systems were ±10%. In general, the reproducibility of the new methodology was at the same levels (around 14%) as with the current methodology (on average 17%). Full article
(This article belongs to the Special Issue Traffic Related Emission)
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21 pages, 1394 KB  
Article
Detailed Speciation of Non-Methane Volatile Organic Compounds in Exhaust Emissions from Diesel and Gasoline Euro 5 Vehicles Using Online and Offline Measurements
by Baptiste Marques, Evangelia Kostenidou, Alvaro Martinez Valiente, Boris Vansevenant, Thibaud Sarica, Ludovic Fine, Brice Temime-Roussel, Patrick Tassel, Pascal Perret, Yao Liu, Karine Sartelet, Corinne Ferronato and Barbara D’Anna
Toxics 2022, 10(4), 184; https://doi.org/10.3390/toxics10040184 - 8 Apr 2022
Cited by 18 | Viewed by 4849
Abstract
The characterization of vehicle exhaust emissions of volatile organic compounds (VOCs) is essential to estimate their impact on the formation of secondary organic aerosol (SOA) and, more generally, air quality. This paper revises and updates non-methane volatile organic compounds (NMVOCs) tailpipe emissions of [...] Read more.
The characterization of vehicle exhaust emissions of volatile organic compounds (VOCs) is essential to estimate their impact on the formation of secondary organic aerosol (SOA) and, more generally, air quality. This paper revises and updates non-methane volatile organic compounds (NMVOCs) tailpipe emissions of three Euro 5 vehicles during Artemis cold urban (CU) and motorway (MW) cycles. Positive matrix factorization (PMF) analysis is carried out for the first time on proton transfer reaction time-of-flight mass spectrometer (PTR-ToF-MS) datasets of vehicular emission. Statistical analysis helped to associate the emitted VOCs to specific driving conditions, such as the start of the vehicles, the activation of the catalysts, or to specific engine combustion regimes. Merged PTR-ToF-MS and automated thermal desorption gas chromatography mass spectrometer (ATD-GC-MS) datasets provided an exhaustive description of the NMVOC emission factors (EFs) of the vehicles, thus helping to identify and quantify up to 147 individual compounds. In general, emissions during the CU cycle exceed those during the MW cycle. The gasoline direct injection (GDI) vehicle exhibits the highest EF during both CU and MW cycles (252 and 15 mg/km), followed by the port-fuel injection (PFI) vehicle (24 and 0.4 mg/km), and finally the diesel vehicle (15 and 3 mg/km). For all vehicles, emissions are dominated by unburnt fuel and incomplete combustion products. Diesel emissions are mostly represented by oxygenated compounds (65%) and aliphatic hydrocarbons (23%) up to C22, while GDI and PFI exhaust emissions are composed of monoaromatics (68%) and alkanes (15%). Intermediate volatility organic compounds (IVOCs) range from 2.7 to 13% of the emissions, comprising essentially linear alkanes for the diesel vehicle, while naphthalene accounts up to 42% of the IVOC fraction for the gasoline vehicles. This work demonstrates that PMF analysis of PTR-ToF-MS datasets and GC-MS analysis of vehicular emissions provide a revised and deep characterization of vehicular emissions to enrich current emission inventories. Full article
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13 pages, 2043 KB  
Article
Concepts for Hydrogen Internal Combustion Engines and Their Implications on the Exhaust Gas Aftertreatment System
by Stefan Sterlepper, Marcus Fischer, Johannes Claßen, Verena Huth and Stefan Pischinger
Energies 2021, 14(23), 8166; https://doi.org/10.3390/en14238166 - 6 Dec 2021
Cited by 65 | Viewed by 11859
Abstract
Hydrogen as carbon-free fuel is a very promising candidate for climate-neutral internal combustion engine operation. In comparison to other renewable fuels, hydrogen does obviously not produce CO2 emissions. In this work, two concepts of hydrogen internal combustion engines (H2-ICEs) are [...] Read more.
Hydrogen as carbon-free fuel is a very promising candidate for climate-neutral internal combustion engine operation. In comparison to other renewable fuels, hydrogen does obviously not produce CO2 emissions. In this work, two concepts of hydrogen internal combustion engines (H2-ICEs) are investigated experimentally. One approach is the modification of a state-of-the-art gasoline passenger car engine using hydrogen direct injection. It targets gasoline-like specific power output by mixture enrichment down to stoichiometric operation. Another approach is to use a heavy-duty diesel engine equipped with spark ignition and hydrogen port fuel injection. Here, a diesel-like indicated efficiency is targeted through constant lean-burn operation. The measurement results show that both approaches are applicable. For the gasoline engine-based concept, stoichiometric operation requires a three-way catalyst or a three-way NOX storage catalyst as the primary exhaust gas aftertreatment system. For the diesel engine-based concept, state-of-the-art selective catalytic reduction (SCR) catalysts can be used to reduce the NOx emissions, provided the engine calibration ensures sufficient exhaust gas temperature levels. In conclusion, while H2-ICEs present new challenges for the development of the exhaust gas aftertreatment systems, they are capable to realize zero-impact tailpipe emission operation. Full article
(This article belongs to the Special Issue Hydrogen-Fuelled Spark-Ignition Engines)
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