Search Results (23)

Refractory high-entropy alloys (HEAs) are promising candidates for next-generation nuclear applications, particularly fusion reactors, due to their excellent high-temperature mechanical properties and irradiation resistance. Here, the microstructure and mechanical behavior were investigated for an equimolar WTaTiVZr HEA, designed from a palette of low-activation elements. The as-cast alloy exhibited a dendritic microstructure composed of W-Ta rich dendrites and Zr-Ti-V rich inter-dendritic regions, both possessing a body-centered cubic (BCC) crystal structure. Room temperature bulk compression tests showed ultra-high strength of around 1.6 GPa and plastic strain ~6%, with fracture surfaces showing cleavage facets. The alloy also demonstrated excellent high-temperature strength of ~650 MPa at 500 °C. Scratch-based fracture toughness was ~38 MPa√m for the as-cast WTaTiVZr HEA compared to ~25 MPa√m for commercially used pure tungsten. This higher value of fracture toughness indicates superior damage tolerance relative to commercially used pure tungsten. These results highlight the alloy’s potential as a low-activation structural material for high-temperature plasma-facing components (PFCs) in fusion reactors. Full article

This study investigates how Zr doping influences the deformation behavior of Cu-Zr/Al₂Cu/Al composites through molecular dynamics simulations. The impact of Zr content (ranging from 0 to 0.8 wt%) and strain rate on phase evolution, dislocation dynamics, and fracture mechanisms under vertical and horizontal tensile loading was examined. The results indicate that Zr doping achieves a balance between strength and plasticity by means of solute drag, amorphization, and phase competition. At a Zr concentration of 0.2 wt%, the formation of the body-centered cubic (BCC) phase reached a peak (22.04% at ε = 0.11), resulting in a maximum tensile strength of 9.369 GPa while maintaining plasticity due to limited face-centered cubic (FCC) decomposition. A moderate Zr content of 0.6 wt% maximizes strength through amorphization but significantly diminishes plasticity due to excessive FCC-to-BCC transitions. Higher Zr concentrations (0.8 wt%) lead to solute supersaturation, which suppresses phase transitions and slightly reduces toughness by causing hexagonal close-packed (HCP) phase accumulation. The strain rate markedly enhances both strength and plasticity in vertical loading by accelerating dislocation interactions. Vertical tensile deformation initiates brittle fracture, whereas horizontal loading results in ductile failure through sequential load transfer from Al₂Cu layers to Al/Cu interfaces, ultimately causing interfacial decohesion. These findings underscore the essential roles of Zr content and strain rate in modulating phase transformations and interface responses. The research offers a framework for creating gradient Zr-doped or multi-scale composites with optimized strength, plasticity, and damage tolerance suitable for aerospace and electronics applications, where trace Zr additions can reinforce Cu matrices. Full article

The development of FeCrAl alloys has commenced for use as nuclear fuel cladding material, intended to serve as an enhanced accident-tolerant alternative to Zr-based alloys. In this study, the Fe-13Cr-4Al alloy, specifically designed for advanced accident-tolerant fuel (ATF) cladding, was carefully prepared through vacuum induction melting and hot-working processes. Mechanical properties and serrated flow behavior of this alloy were investigated through tensile tests at temperatures ranging from 200 to 800 °C. Intriguingly, serrations emerged within a specific temperature range, accompanied by unique mechanical behavior characteristics indicative of dynamic strain aging (DSA). Additionally, the alloy’s fracture modes showed a transition from a mix of ductile and cleavage fracture features to fully ductile fracture as the temperature increased. This study offers insights into the mechanical properties and serration behaviors of FeCrAl alloys, highlighting their potential for use in nuclear fuel cladding. Full article

With the development of high-efficiency gas turbine engines and increasing inlet temperatures, the performance of thermal barrier coatings (TBCs) for hot-section components has been more severely challenged. The doping of multi-element rare earth elements significantly improves the thermodynamic properties and chemical compatibility of thermal barrier coatings so that the application performance of coatings in high-temperature environments is enhanced considerably. In this work, the doped coatings prepared by REYSZ (RE = La, Sm, Nd) were investigated and characterized in terms of crystal structure, elastic properties, and thermal–mechanical properties based on the first-principles approach, combined with various empirical and semi-empirical formulations, and a predictive model for resistance to CMAS corrosion based on machine learning approaches. The results showed that the tetragonal phase REYSZ material was mechanically stable, had a large strain damage tolerance, and was not easy to fracture under applied loads and thermal shocks. In terms of CMAS corrosion resistance, the NdYSZ interfacial model had a lower surface energy (3.130 J/m²) and Griffith fracture energy (6.934 J/m²) compared with the conventional YSZ model, and Nd₂O₃ had the potential to improve the CMAS corrosion resistance of zirconia-based material for thermal barrier coatings. By evaluating the machine learning prediction models, the regression coefficients of the two algorithms were 0.9627 and 0.9740, and both these two prediction models showed high prediction accuracy and strong robustness. Ultimately, this work presented a novel mechanism–data hybrid method, which would facilitate the efficient development of TBC new materials for anti-CMAS corrosion. Full article

For damage tolerance design in engineering components, the fracture toughness value, K_IC, of the material is essential. However, obtaining specimens of sufficient thickness from stir friction welded plates is challenging, and often, the experimental test values do not meet the necessary criteria, preventing the experimental fracture toughness, K_q, from being recognized as plane strain fracture toughness K_IC. The fracture toughness K_q of 2195 Al–Li alloy welding seams with different thicknesses was measured on the forward and backward sides. Microstructure characterization was conducted by scanning electron microscope (SEM). The results indicated minimal significant differences in grain size between the advancing and retreating sides of the weld nugget zone. In specimens of the same thickness, fracture toughness measurements along the normal direction of the joint cross-section showed a high similarity between the advancing and retreating sides of the weld nugget zone. Utilizing the quantitative relationships between fracture toughness and sample thickness derived from both the fracture K and G criteria, it is possible to predict the fracture toughness of thick plates using thin plates. This study employs these relationships to calculate the fracture toughness K_IC of 2195 aluminum–lithium alloy friction stir welds. The K_IC values obtained are 41.65 MPa·m^1/2 from the fracture K criterion and 43.54 MPa·m^1/2 from the fracture G criterion. Full article

Nowadays, powder-based manufacturing processes are recognized as cost-efficient methods frequently employed for producing parts with intricate shapes and tight tolerances in large quantities. However, like any manufacturing method, powder-based technologies also have several disadvantages. One of the most significant issues lies in the degree of porosity. By modifying the morphology of the gas-atomized spherical 17-4PH stainless steel powder via prior ball milling and then raising both the pressure of cold compaction (1.6 GPa) and sintering temperature (1275 °C), the porosity could be reduced considerably. In our novel powder metallurgical (PM) experimental process, an exceptionally high green density of 92% could be reached by employing die wall lubrication instead of internal lubrication and utilizing induction heating for rapid sintering. After sintering (at temperatures of 1200, 1250, and 1275 °C), the samples aged in the H900 condition were then mechanically tested (Charpy impact, HV hardness, and tensile tests) as a function of porosity. Sintering at 1275 °C for one hour enabled porosity reduction to below 4%, resulting in 1200 MPa yield strength and 1350 MPa ultimate tensile strength with significant (16%) fracture strain. These values are comparable to those of the same alloy products fabricated via ingot metallurgy (IM) or additive manufacturing (AM). Full article

Stress relaxation cracking (SRC) is considered one of the major failure mechanisms for 347H stainless steel welds at elevated service temperatures or during post weld heat treatment (PWHT), especially within the heat-affected zone (HAZ). This work focuses on the characterization of SRC susceptibility within 347H physically simulated arc welded HAZ at elevated temperatures. A four-step SRC thermomechanical test in combination with finite element modeling (FEM) of the welding and testing processes is developed to establish a susceptibility map for HAZ. The test first runs a thermal cycle with three different peak temperatures (1335, 1275, and 1150 °C) to duplicate representative HAZ subzone microstructures, followed by time-to-failure examination under a variety of pre-stress (260–600 MPa) and pre-strain conditions (0.03–0.19) as a function of reheat temperatures between 750 and 1050 °C. With the aid of FEM, SRC susceptibility maps are generated to identify the threshold stress, plastic strain, and creep strain as a function of test temperature. It was found out that HAZ subzone with a lower peak temperature (1150 °C) appears to be slightly less susceptible to SRC than the other two subzones that experienced higher peak temperatures. Generally, time-to-fracture reduces with increasing initially applied stress and strain for all test temperatures. The pre-stress thresholds decrease from about 500 to 330 MPa as the testing temperature increases from 800 to 1050 °C, while the corresponding initial plastic strain thresholds reduces from 0.15 to 0.06. The SRC susceptibility was also evaluated through the Larson–Miller Parameter (LMP) analysis as a function of plastic strain, initial stress and starting stress upon reaching the testing temperature, respectively. The 1050 °C test with a high pre-applied strain (0.1) exhibits an extremely short time to failure (t = 3 s) that lies outside the general trend in LMP analysis. Additionally, it was identified that a plastic strain above 0.07 is identified to significantly reduce the bulk creep strain tolerance to fracture and therefore increases SRC susceptibility. Hardness measurement and fractography analysis indicated that the strain aging of niobium carbonitrides and other potential phases in conjunction with intergranular precipitates contributes to an increase in microhardness and increased intergranular cracking susceptibility. Full article

Stretchable ionogels, as soft ion-conducting materials, have generated significant interest. However, the integration of multiple functions into a single ionogel, including temperature tolerance, self-adhesiveness, and stability in diverse environments, remains a challenge. In this study, a new class of fluorine-containing ionogels was synthesized through photo-initiated copolymerization of fluorinated hexafluorobutyl methacrylate and butyl acrylate in a fluorinated ionic liquid 1-butyl-3-methyl imidazolium bis (trifluoromethylsulfonyl) imide. The resulting ionogels demonstrate good stretchability with a fracture strain of ~1300%. Owing to the advantages of the fluorinated network and the ionic liquid, the ionogels show excellent stability in air and vacuum, as well as in various solvent media such as water, sodium chloride solution, and hexane. Additionally, the ionogels display impressive wide temperature tolerance, functioning effectively within a wide temperature range from −60 to 350 °C. Moreover, due to their adhesive properties, the ionogels can be easily attached to various substrates, including plastic, rubber, steel, and glass. Sensors made of these ionogels reliably respond to repetitive tensile-release motion and finger bending in both air and underwater. These findings suggest that the developed ionogels hold great promise for application in wearable devices. Full article

In the shipbuilding, construction, automotive, and aerospace industries, welding is still a crucial manufacturing process because it can be utilized to create massive, intricate structures with exact dimensional specifications. These kinds of structures are essential for urbanization considering they are used in applications such as tanks, ships, and bridges. However, one of the most important types of structural damage in welding continues to be fatigue. Therefore, it is necessary to take this phenomenon into account when designing and to assess it while a structure is in use. Although traditional methodologies including strain life, linear elastic fracture mechanics, and stress-based procedures are useful for diagnosing fatigue failures, these techniques are typically geometry restricted, require a lot of computing time, are not self-improving, and have limited automation capabilities. Meanwhile, following the conception of machine learning, which can swiftly discover failure trends, cut costs, and time while also paving the way for automation, many damage problems have shown promise in receiving exceptional solutions. This study seeks to provide a thorough overview of how algorithms of machine learning are utilized to forecast the life span of structures joined with welding. It will also go through their drawbacks and advantages. Specifically, the perspectives examined are from the views of the material type, application, welding method, input parameters, and output parameters. It is seen that input parameters such as arc voltage, welding speed, stress intensity factor range, crack growth parameters, stress histories, thickness, and nugget size influence output parameters in the manner of residual stress, number of cycles to failure, impact strength, and stress concentration factors, amongst others. Steel (including high strength steel and stainless steel) accounted for the highest frequency of material usage, while bridges were the most desired area of application. Meanwhile, the predominant taxonomy of machine learning was the random/hybrid-based type. Thus, the selection of the most appropriate and reliable algorithm for any requisite matter in this area could ultimately be determined, opening new research and development opportunities for automation, testing, structural integrity, structural health monitoring, and damage-tolerant design of welded structures. Full article

Phase-specific damage tolerance was investigated for the AlCoCrFeNi_2.1 high entropy alloy with a lamellar microstructure of L1₂ and B2 phases. A microcantilever bending technique was utilized with notches milled in each of the two phases as well as at the phase boundary. The L1₂ phase exhibited superior bending strength, strain hardening, and plastic deformation, while the B2 phase showed limited damage tolerance during bending due to micro-crack formation. The dimensionalized stiffness (DS) of the L1₂ phase cantilevers were relatively constant, indicating strain hardening followed by increase in stiffness at the later stages and, therefore, indicating plastic failure. In contrast, the B2 phase cantilevers showed a continuous drop in stiffness, indicating crack propagation. Distinct differences in micro-scale deformation mechanisms were reflected in post-compression fractography, with L1₂-phase cantilevers showing typical characteristics of ductile failure, including the activation of multiple slip planes, shear lips at the notch edge, and tearing inside the notch versus quasi-cleavage fracture with cleavage facets and a river pattern on the fracture surface for the B2-phase cantilevers. Full article

Many researchers use fiber to improve the cracking resistance of asphalt mixtures, but research concerning the effects of fiber on fracture behavior is limited. The fracture behavior of asphalt mixtures with various fiber types (basalt fiber, glass fiber, and polyester fiber) and contents (0.1%, 0.2%, 0.3%, 0.4%, and 0.5%) has been studied using the indirect tensile asphalt cracking test (IDEAL-CT) in conjunction with digital image correlation (DIC) technology. The evaluation indexes used in the test included crack initiation energy (G_if), crack energy (G_f), splitting tensile strength (R_T), cracking tolerance index (CT_index), and the real-time tensile strain (E_xx) obtained using digital image correlation technology. The results showed that despite the fiber type, the increase of fiber content resulted in first, an increase, and then, a decrease of the cracking resistance of asphalt mixtures, indicating the presence of optimum fiber content—specifically, 0.4%, 0.3%, and 0.3% for basalt fiber, glass fiber, and polyester fiber, respectively. The development of real-time tensile strain, obtained based on digital image correlation technology, could be divided into two stages: slow-growth stage and rapid-expansion stage. In addition, asphalt mixture with basalt fiber presented the best cracking resistance at both the slow-growth and rapid-expansion stages. This research is helpful in understanding the effects of fiber type and content on the fracture behavior of asphalt mixtures and has certain reference significance for the application of fiber in asphalt mixtures. Full article

The failure of plasma-sprayed thermal barrier coatings (TBCs) during service is usually related to the cracking behavior. In this study, plasma-sprayed TBCs were prepared with two kinds of agglomerated sintered yttria-stabilized zirconia (YSZ) powders with different particle sizes. The evolution of mechanical properties and crack propagation behavior of the coatings during the whole life stage were studied by a thermal shock test. The effect of powder particle size on the cracking behavior of the TBCs during thermal shock was analyzed from the aspect of pore structure, mechanical properties, and stress state of the coatings. The crack propagation and coalescence in the direction parallel to the substrate in the coating is the main factor leading to the spalling failure of the coating during thermal shock. Although the coating prepared by fine YSZ has higher fracture toughness, the lower strain tolerance will increase the cracking driving force on the crack tip of the coating during thermal shock, and the cracks in the coating propagate merge at a faster rate during thermal shock. The larger porosity and pore size of the coating prepared by coarse YSZ help the coating suffer less thermal stress during thermal shock. Although the existence of pores reduces the fracture toughness of the coating to a certain extent, the increase of strain tolerance reduces the crack growth rate in the coating, so the coating has a longer life. Full article

Skin is the largest organ of many animals. Its protective function against hostile environments and predatorial attack makes high mechanical strength a vital characteristic. Here, we measured the mechanical properties of bass fish skins and found that fish skins are highly ductile with a rupture strain of up to 30–40% and a rupture strength of 10–15 MPa. The fish skins exhibit a strain-stiffening behavior. Stretching can effectively eliminate the stress concentrations near the pre-existing holes and edge notches, suggesting that the skins are highly damage tolerant. Our measurement determined a flaw-insensitivity length that exceeds those of most engineering materials. The strain-stiffening and damage tolerance of fish skins are explained by an agent-based model of a collagen network in which the load-bearing collagen microfibers assembled from nanofibrils undergo straightening and reorientation upon stretching. Our study inspires the development of artificial skins that are thin, flexible, but highly fracture-resistant and widely applicable in soft robots. Full article

As a new highly damage-tolerant structural material, the TC21 titanium alloy has been widely used in aerospace applications. Inertial friction welding (IFW) is a form of pressure welding technology with less welding parameters and high welding joint performance, which is especially suitable for the connection of rotors of aero-compressors and engines. In this paper, inertia friction welding of TC21 titanium alloys was successfully carried out, and the microhardness, tensile properties and low cycle fatigue (LCF) behaviors of IFW joints were studied. Based on the mechanical parametric results of the tensile test, the true stress–strain curves of the IFW joint of TC21 titanium alloys are obtained by further calculation. Based on the LCF test results under different strain amplitudes, life prediction of IFW joints was investigated. The results of the LCF test show that there is no obvious cyclic hardening and cyclic softening of the IFW joints. Moreover, the fracture morphology of LCF samples under high strain amplitude (0.9%) and low strain amplitude (0.6%) was observed. The results show that the fatigue cracks initiate and propagate at multiple points in the LCF samples, and the transient fracture zone is larger under high strain amplitude. However, under low strain amplitude, a fatigue crack nucleates and propagates at a single point, and the crack propagation zone is larger. Full article

It is crucial to assess the bond strength of the cement–formation interface while developing novel cements for efficient zonal isolation. An integrated method is presented to investigate the failure mechanism in cement and formation rock under downhole reservoir temperature and pressure conditions using a triaxial experimental setup. The acoustic emission count, strain, and velocity data aid in inferring the fracture process that led to the failure of a specimen. Although most specimens investigated exhibit the three dominant events of compaction, multi-cracking, and sliding, there are variations in the basic structure of each specimen. Furthermore, the insight obtained about the internal structure of the specimen points to its strength and damage tolerance, both of which are vital requirements for bonding. This method can distinguish between a standard cement and modified cement very effectively and help in pairing the appropriate cement formulation for a formation rock. Full article