Search Results (6)

For the first time, based on the joint application of the fine-porous and cell models, a theoretical analysis of the changing transport and structural characteristics of heterogeneous polymeric ion-exchange membranes (IEMs) MK-40, MA-40, and MA-41 after exposure to elevated temperatures in water and aggressive media (H₂SO₄ and NaOH solutions), as well as after long-term processing in electrodialyzers of various types, was carried out. The studied membranes are composites of ion-exchange polymers with polyethylene and nylon reinforcing mesh. The external influences provoke the aging of IEMs and the deterioration of their characteristics. The transport properties of IEMs are quantitatively described using five physicochemical parameters: counterion diffusion and equilibrium distribution coefficients in the membrane, characteristic exchange capacity, which depends on the microporosity of ion-exchanger particles, and macroscopic porosity at a known exchange capacity of IEMs. Calculations of the physicochemical parameters of the membranes were performed according to a specially developed fitting technique using the experimental concentration dependences of integral diffusion permeability and specific electrical conductivity, and their model analogs. This made it possible to identify and evaluate changes in the membrane micro- and macrostructure and examine the process of artificial aging of the IEM polymer material due to the abovementioned external impacts. Full article

Bacterial cellulose (BC) has become a universal biomaterial owing to its intrinsic properties. BC fibers are composed of microfibers with a diameter of 3–4 nm into fiber bundles with a thickness of 40–60 nm, and interweave with each other to form a well-developed ultra-fine network structure. Polylactic acid (PLA) has good mechanical properties and excellent biocompatibility and biodegradability. Therefore, PLA has been widely applied in tissue engineering. Addressed herein is a novel type of PLA/BC (PLA/BC) composite scaffold prepared by 3D printing (3D), 3D modeling of the required porous membrane material support established in the computer, and decomposition of the model into 5 layer 20 μM sheets. The range of PLA loadings assessed in this work was 1.0 wt.%, 1.5 wt.%, and 2.0 wt.%, and its physicochemical properties and biological properties were characterized and evaluated. Tensile strength of PLA/BC composite scaffolds increased to 66.49 MPa compared to that of a pure BC film (25.61 MPa). Hydrophilicity was tunable with the amount of added PLA. In this paper, the effects of 3D round hole and stripe surface topology on cell growth behavior were characterized. Schwann cells (SCs) adhered to the surface of the 3D composite membrane successfully, and their proliferation rate on the surface of the regular circular pore and stripe structure was better than that of the smooth surface. Erythrocyte fixation and platelet adhesion experiments showed that the 3D composite scaffold had excellent blood compatibility. Further degradation studies showed that loose structures appeared after 1 week, and structural defects began after 3 weeks. The in vitro degradation results showed that the degradation rate of the BC membrane in simulated body fluid after 6 weeks was 14.38%, while the degradation rate of the PLA/BC composite scaffold was 18.75%. Full article

A novel bilayer cation-exchange membrane—consisting of a thick layer of a pristine perfluorinated membrane MF-4SC (Russian equivalent of Nafion^®-117) and a thinner layer (1 μm) of the membrane, on a base of glassy polymer of internal microporosity poly(1-trimethylsilyl-1-propyne) (PTMSP)—was prepared and characterized. Using the physicochemical characteristics of one-layer membranes MF-4SC and PTMSP in 0.05 M HCl and NaCl solutions, the asymmetric current–voltage curves (CVC) of the bilayer composite were described with good accuracy up to the overlimiting regime, based on the “fine-porous membrane” model. The MF-4SC/PTMSP bilayer composite has a significant asymmetry of CVC that is promising for using it in electromembrane devices, such as membrane detectors, sensors, and diodes. Full article

A numerical study is conducted to compare the current most popular flow field configurations, porous, biporous, porous with baffles, Toyota 3D fine-mesh, and traditional rectangular flow field. Operation at high current densities is considered to elucidate the effect of the flow field designs on the overall heat transfer and liquid water removal. A comprehensive 3D, multiphase, nonisothermal computational fluid dynamics model is developed based on up-to-date heat and mass transfer sub-models, incorporating the complete formulation of the Forchheimer inertial effect and the permeability ratio of the biporous layers. The porous and baffled flow field improves the cell performance by minimizing mass transport losses, enhancing the water removal from the diffusion layers. The baffled flow field is chosen for optimization owing to the simple design and low manufacturing cost. A total of 49 configurations were mutually compared in the design of experiments to show the quantitative effect of each parameter on the performance of the baffled flow field. The results elucidate the significant influence of small geometry modifications on the overall heat and mass transfer. The results of different cases have shown that water saturation can be decreased by up to 33.59% and maximal temperature by 7.91 °C when compared to the reference case which is already characterized by very high performance. The most influencing geometry parameters of the baffles on the cell performance are revealed. The best case of the 49 studied cases is further optimized by introducing a linear scaling factor. Additional geometry modifications demonstrate that the gain in performance can be increased, but at a cost of higher pressure drop and increased design complexity. The conclusions of this work aids in the development of compact and high-performance proton exchange membrane fuel cell stacks. Full article

The present work reports the performance of three types of polyethersulfone (PES) membrane in the removal of highly polluting and toxic lead Pb²⁺ and cadmium Cd²⁺ ions from a single salt. This study investigated the effect of operating variables, including pH, types of PES membrane, and feed concentration, on the separation process. The transport parameters and mass transfer coefficient (k) of the membranes were estimated using the combined film theory-solution-diffusion (CFSD), combined film theory-Spiegler-Kedem (CFSK), and combined film theory-finely-porous (CFFP) membrane transport models. Various parameters were used to estimate the enrichment factors, concentration polarization modulus, and Péclet number. The pH values significantly affected the permeation flux of the Pb²⁺ solution but only had a slight effect on the Cd²⁺ solution. However, Cd²⁺ rejection was highly improved by increasing the pH value. The rejection of the PES membranes increased greatly as the heavy metal concentration rose, while the heavy metal concentration moderately affected the permeation flux. The maximum rejection of Pb²⁺ in a single-salt solution was 99%, 97.5%, and 98% for a feed solution containing 10 mg Pb/L at pH 6, 6.2, and 5.7, for PES1, PES2, and PES3, respectively. The maximum rejection of Cd²⁺ in single-salt solutions was 78%, 50.2%, and 44% for a feed solution containing 10 mg Cd/L at pH 6.5, 6.2, and 6.5, for PES1, PES2, and PES3, respectively. The analysis of the experimental data using the CFSD, CFSK, and CFFP models showed a good agreement between the theoretical and experimental results. The effective membrane thickness and active skin layer thickness were evaluated using the CFFP model, indicating that the Péclet number is important for determining the mechanism of separation by diffusion. Full article

Three types of bi-layer hybrid nanocomposites on the base of perfluorinated cation-exchange membrane MF-4SC (Russian analogue of Nafion^®-117) were synthesized and characterized. It was found that two membranes possess the noticeable asymmetry of the current–voltage curve (CVC) under changing their orientation towards the applied electric field, despite the absence of asymmetry of diffusion permeability. These phenomena were explained in the frame of the “fine-porous model” expanded for bi-layer membranes. A special procedure to calculate the real values of the diffusion layers thickness and the limiting current density was proposed. Due to asymmetry effects of the current voltage curves of bi-layer hybrid membranes on the base of MF-4SC, halloysite nanotubes and platinum nanoparticles, it is prospective to assemble membrane switches (membrane relays or diodes) with predictable transport properties, founded upon the theory developed here. Full article