Search Results (110)

Steel dust is a waste generated during steelmaking in an electric arc furnace (EAF), which contains a high proportion of iron-bearing compounds, leading to the inclusion of this waste as a resource in the circular economy for steelmaking. In addition to the limitation related to granulation (the waste must be processed to obtain larger particle sizes), a limiting factor is the increasingly high Zn content due to the low-quality ferrous charge. For the recycling of steelmaking dust, preliminary processing is necessary to reduce zinc. The paper presents, in addition to qualitative characterization of steel dust, laboratory experiments on the compositional changes associated with zinc redistribution applying the hydrometallurgical leaching process in an alkaline environment, using sodium hydroxide (NaOH). The changes in the chemical composition were identified and evaluated using X-ray fluorescence (XRF) and energy-dispersive X-ray spectroscopy (EDX). The experiments consisted of treating steel dust samples with 5 M NaOH at 25, 70, 80 and 90 °C for 60 min, using solid-to-liquid ratios of 10, 15, and 25 g/L. The results indicate a reduction in ZnO content ranging from 4.52% to 16.82%, as determined from Na₂O-free normalization data. Room-temperature samples show only marginal changes in ZnO content. The XRF and EDX analyses indicate a moderate and condition-dependent redistribution of zinc in the solid phase after alkaline treatment, as evaluated using Na₂O-free normalized data. These values are derived exclusively from solid-phase measurements (XRF/EDX) and do not include zinc in the leachate; therefore, true zinc extraction efficiency cannot be determined. The research results attest to the viability and efficiency (as a solid-phase compositional transformation process) using NaOH as a leaching agent for the studied steel dust, thus providing a potential pathway for improved waste recycling in the steel industry. Full article

The choice of brass as the substrate due to its widespread use in soft non-ferrous industrial components such as bearings and electrical connectors creates the primary basis of novelty in this study. While prior tribological studies on titanium aluminum nitride (TiAlN) coatings is primarily focused on hard substrates such as steel and WC–Co, this work addresses the research gap by presenting a systematic investigation of the combined influence of sputtering power and working pressure on TiAlN coatings deposited on brass. Application of TiAlN coatings on brass surfaces was accomplished using magnetron sputtering. Within the scope of this study, the influence of sputtering power and working pressure on the tribological and structural attributes of TiAlN films is evaluated. The analysis of surface morphology is carried out using scanning electron microscopy (SEM), while structural characteristics revealed a progressive increment in the intensity of the (103) and (107) peaks with variation in deposition parameters. An analysis was conducted to evaluate the tribological properties of the TiAlN coating using a pin-on-disk tribometer. The study involved varying the speeds, loads, and sliding lengths. The optimized condition achieved wear reduction as high as 22% compared to uncoated brass at a sliding distance of 785 m, which highlights the strong dependence of wear performance on deposition parameters. The wear rates of TiAlN-coated brass ranged between 1.03 × 10⁻³ and 5.87 × 10⁻⁴ mm³/Nm depending on parameters like load, sliding distance and speed. Conversely, TiAlN-coated brass pins prepared at varying power showed wear rates ranging from 1.83 × 10⁻⁴ to 5.87 × 10⁻⁴ mm³/Nm. These findings demonstrate that optimization of TiAlN coating parameters on brass can significantly enhance wear resistance, which ultimately improves the durability and performance of engineering components in tribological applications. Full article

As a clean and renewable energy source, wind energy offers lower development and utilization costs than solar energy, making it the most promising renewable option. However, the carbon footprint of offshore wind power and its external impacts on cross-regional carbon emissions have not been investigated sufficiently. Using the provinces of Guangdong and Jiangsu as case studies, this study employs socioeconomic and environmental statistical data. It applies the environmentally extended multi-regional input–output (EE-MRIO) method to quantify cross-regional environmental spillover effects associated with offshore wind power development. The findings show that China’s power structure has been continuously optimized, with offshore winds achieving leapfrog growth since 2010. Through a “local consumption” model, offshore wind power in Guangdong and Jiangsu has effectively replaced coal-fired generation, substantially reducing carbon emissions locally and in neighboring areas. Jiangsu has reduced CO₂ emissions by 16.72 million tons annually, and Guangdong by about 7.23 million tons annually. Furthermore, offshore wind development drives the green transformation of upstream industries (e.g., steel, non-ferrous metals, and chemicals). It extends carbon-reduction benefits to resource-rich regions such as the Northwest and North China. As major manufacturing hubs, both provinces lowered the embodied carbon intensity of their export products by using clean electricity, thereby indirectly reducing the national carbon footprint through cross-regional trade. This study offers scientific insights to help policymakers optimize offshore wind layouts, facilitate coordinated regional emission reductions, and advance sustainable energy transitions. Full article

To achieve both a high material removal rate and excellent surface quality, this paper proposes a solid-phase Fenton chemo-mechanical lapping (SF-CML) method. Using high-purity type 316 stainless-steel as the research object, a solid lapping tool containing Fe₃O₄ microparticles was employed in synergy with an H₂O₂-based slurry. Under locally high-pressure and high-temperature conditions, Fe²⁺ ions are released, which in turn catalyze the generation of highly reactive hydroxyl radicals (·OH). These radicals promote the formation of an oxide layer on the workpiece surface, which is continuously removed through mechanical action. The results show that at pH 2.5 and an H₂O₂ concentration of 0.05 wt%, SF-CML achieves the best processing performance, with an MRR of 16.64 μm/min and a Sa as low as 20.95 nm. XPS, EPR, and other characterization methods collectively provided evidence for the oxidation of the sample surface and the existence of ferrous ions and hydroxyl radicals in the slurry, thereby confirming the effectiveness of the solid-phase Fenton reaction. Compared with conventional homogeneous Fenton CMP and pure mechanical lapping, SF-CML not only significantly improves removal efficiency but also effectively enhances surface quality. This method avoids the problems of easy precipitation and low removal efficiency commonly encountered in traditional homogeneous Fenton systems, providing a new technical pathway for high-efficiency precision processing of metallic materials. Full article

Ultra-precision machining of ferrous alloys remains challenging because conventional diamond tools suffer severe thermochemical wear, whereas ultrasonic vibration-assisted cutting requires complex and costly equipment. This study investigates single-crystal sapphire as an alternative cutting-tool material for ultra-precision machining of both non-ferrous and ferrous metals. A sapphire tool was fabricated from a polished wafer, laser-shaped into an equilateral triangular insert, vacuum-brazed onto a tungsten carbide carrier, and finished by ultra-fine grinding to yield a well-defined cutting edge. Ultra-precision turning experiments were conducted on copper and 420 stainless steel using a Moore Nanotech 350FG lathe, and the performance of the sapphire tool was benchmarked against conventional diamond (copper) and cubic boron nitride (CBN) tools (stainless steel) under comparable cutting conditions. Surface roughness (Ra) and topography were characterized using an optical surface profiler, while scanning electron microscopy and atomic force microscopy were employed to assess tool wear and cutting-edge geometry. The sapphire tool produced mirror-like surfaces with average surface roughness (Ra) values of 6.4 nm on copper and 39.1 nm on 420 stainless steel, compared with 1.3 nm for diamond on copper and 92.9 nm for CBN on stainless steel. Across both materials, sapphire generated regular, stable tool marks and exhibited minimal wear, with no catastrophic edge degradation or clear evidence of severe chemical interaction with the steel workpiece. These results demonstrate that sapphire is a viable tool material for extending diamond turning-level surface quality to stainless steel without ultrasonic assistance. Full article

Laser surface hardening is a technique that improves various mechanical characteristics of different materials. The methods are being extensively used in the automobile, aerospace, tool manufacturing, and construction industries for various components. The present review highlights the hardness and hardened surface depth improvement of different steels and non-ferrous alloys in as-bought and pre-heat treatment conditions. Diode and fibre lasers have rendered higher surface hardness and hardened depth, while consuming higher power. Nd:YAG lasers have resulted in a precise increase in hardness and a very minimal 0.8 in ferrous and 2 mm in surface-hardened depth of non-ferrous alloys, proving a better efficiency. The pre-heat treatments are selected to enhance mechanical properties and reduce the deformations and defects. An increase of 300.43 and 282.38% of surface hardness due to laser hardening as compared to the core material of AISI 420 was observed using a high-power diode laser. A huge 281.41% of increase in surface hardness was observed for ICD-5 tool steel using Nd:YAG lasers. The annealing pre-heat treatment has also affected the hardenability, resulting in high hardness. Non-ferrous alloys such as titanium and A356 alloys have recorded 200 and 125% increase in surface hardness compared to their core using Nd:YAG lasers. Full article

Elevated temperatures are frequently encountered in numerous occupational settings such as iron and steel foundries, non-ferrous metal foundries, brick and ceramic manufacturing plants, glass production facilities, rubber factories, electrical power plants, bakeries, laundries, chemical processing sites, mining operations, smelting plants, and steam tunnels. Employees working in these environments are at risk of developing various health issues and injuries, including ocular complications, due to prolonged exposure to heat and the physical demands of handling heavy materials. This study focuses on examining the pressure within the eye’s anterior chamber, referred to as Intraocular Pressure (IOP), and its association with the cornea’s biomechanical characteristics, with particular attention to corneal temperature. Our methodology is grounded in the principles of the first law of thermodynamics. The findings reveal a link between the temperature of the eye’s anterior chamber and the biomechanical behaviour of the cornea. Specifically, IOP serves as an indicator of the cornea’s elasticity and its optical properties as influenced by temperature variations. We investigated how the cornea’s elastic energy, or the work it performs, varies with temperature changes. The results show that an increase in temperature corresponds to a reduction in the work exerted by the cornea. The corneal temperature is affected by both the ambient environment and the temperature of the aqueous humour within the anterior chamber. This indicates a relationship between the mechanical work done by the cornea and the pressure exerted by the fluid in the eye’s front segment. Furthermore, our study identified a correlation between corneal thickness and IOP, which our modelling approach successfully quantifies. Utilizing the first law of thermodynamics, we calculated the work performed by the anterior chamber against the cornea’s internal surface. Temperature fluctuations influence the secretion, drainage, and flow characteristics of the aqueous humour, thereby impacting IOP and associated ocular conditions. These insights are valuable for devising strategies aimed at preventing eye injuries among workers exposed to high-temperature environments. Full article

The present study examines the physicochemical degradation and elemental contamination of marine distillate diesel fuels, which were stored in land-based tanks in operational conditions. Forty-one (41) samples, in compliance with ELOT ISO 8217:2024 were analyzed for crucial physicochemical properties. Stepwise regression identified magnesium (Mg) (positive) and chromium (Cr) (negative) as significant viscosity predictors (R² = 0.269, p = 0.003, VIF < 2), while calcium (Ca), Phosphorus (P), zinc (Zn), copper (Cu), lead (Pb) and Ferrous (Fe) were excluded due to multicollinearity. Strong correlations (r > 0.85) between element pairs (Cu-Pb) (r = 0.996), Ca-Zn (r = 0.897), and P-Ca (r = 0.888) indicate common sources from lubricant additives (ZDDP) and brass corrosion, with individual correlations recorded for Ca (showing r = 0.679, p < 0.001), P (r = 0.722, p < 0.001), and Zn (r = 0.595, p < 0.001). The results revealed that fuels stored in carbon steel tanks under high-humidity conditions for over six (6) months recorded higher metal loads than those in stainless steel tanks with regular periodic supply. The FAME content in the studied samples ranged from 6.7 to 7.1% v/v and showed no significant correlation with degradation indicators (p > 0.05). The narrow FAME range examined precludes definitive conclusions regarding specific biodiesel effects. The threshold of 0.2 mg/kg, as set by manufacturers’ guidelines to protect injectors, was exceeded in the coastal carbon steel tank samples with eight (8) months of storage under high-humidity conditions and in the coastal carbon steel tank samples with nine (9) months of storage under high-humidity conditions examined. The current study offers a systematic correlation between viscosity and elemental contamination for marine distillate fuels under operational storage conditions regarding real-world samples. Full article

The present study assesses the effectiveness of the indole-type alkaloid Yohimbine (YHB) as a green corrosion inhibitor for OLC52 carbon steel and Al in 0.25/0.25 mol L⁻¹ acetic acid/potassium acetate solutions relevant for de-icing applications. Electrochemical techniques, including cyclic and linear sweep voltammetry, chronoamperometry, and electrochemical impedance spectroscopy have been combined with the evaluation of adsorption isotherms and molecular modeling calculations. YHB significantly decreases the corrosion rate for both metals, attaining inhibitory efficiencies of up to 95% for OLC52 and 91% for Al at 298 K, while maintaining high protection efficiency even at higher temperatures. The Langmuir adsorption model and the values of $∆G_{ads}^o$ between −31 and −41 kJ mol⁻¹ indicate a spontaneous adsorption process defined by a mixed physicochemical mechanism, resulting in the formation of a compact protective film. Quantum molecular descriptors support the ability of YHB molecules to interact with metal surfaces via donor–acceptor interactions and electrostatic interactions. The findings demonstrate the potential of YHB as an environmentally friendly inhibitor for the protection of ferrous and non-ferrous alloys in mildly acidic acetic/acetate media used in de-icing solutions. Full article

Shipbuilding and offshore structures employ a wide range of metallic materials, from standard and high-strength steels to non-ferrous aluminium and titanium alloys. While welding remains the dominant joining method, the reliable joining of dissimilar metals still presents significant challenges. The explosion welding (EXW) technique has been increasingly adopted over traditional methods for joining dissimilar metallic materials, due to the advantage of avoiding constraints related to metallurgical incompatibility. The EXW is a solid-state joining process in which an explosive detonation provides the energy required to drive two metal surfaces into high-velocity collision, producing a metallurgical bond. This process results in partial melting at the wavy interface and the formation of intermetallic properties, which can lead to cracking when exposed to dynamic loading. A well-established application in shipbuilding is the connection of an aluminium superstructure to steel decks. This study evaluates the mechanical behaviour of aluminium–steel explosion-welded joints for ship structures. The examined joints comprise ASTM A516 Gr55 structural steel, clad by explosion welding with AA5086 aluminium alloy using an intermediate layer of AA1050 commercially pure aluminium. Tensile tests were carried out using full-field techniques, such as digital image correlation (DIC) and infrared thermography (IRT). Full article

This study evaluates the corrosion behavior of N80 production tubing steel under high-temperature, high-pressure (HTHP) conditions representative of CO₂-based geothermal exploitation in depleted hydrocarbon reservoirs. We developed a staged laboratory protocol that simulates (i) an early multiphase production window (oil + formation brine + supercritical CO₂), (ii) the same environment with the originally developed non-commercial inhibitor (INH), and (iii) a later stabilized stage dominated by near-anhydrous supercritical CO₂ (scCO₂) with trace brine and oil. Corrosion was quantified by gravimetric mass-loss, complemented by multi-scale surface characterization (2D/3D optical profilometry) and microscopic cross-section analysis. In the early multiphase scenario unprotected N80 experienced severe attack (mass-loss rate ≈ 0.67 mm·year⁻¹) with both uniform corrosion and incipient pitting beneath ferrous-carbonate deposits. Addition of an inhibitor at 5000 ppmv reduced mass loss by more than an order of magnitude (to ≈0.09 mm·year⁻¹, ≈97% inhibition) and substantially limited pitting. Under stabilized, near-dry scCO₂ conditions, corrosion was negligible (≈0.0016 mm·year⁻¹). Multi-scale imaging linked observed morphologies (porous FeCO₃ scales, under-deposit pits) to measured rates and supported stage-specific mitigation recommendations. The novelty of this work lies in the integrated, staged HTHP experimental approach and in providing quantitative, actionable inputs for material selection, inhibitor deployment, and monitoring strategies for CCS–EGS projects that reuse depleted hydrocarbon reservoirs. Full article

Highly developed countries generate large volumes of industrial waste, the type and quantity of which are strongly linked to the characteristics of the industries that produce it. Industrial waste can adversely affect the environment, so its disposal and management are a major challenge. Understanding the characteristics of a given waste type (e.g., its chemical and phase composition, technical parameters and likelihood of releasing constituents into aquatic and soil environments) allows its potential economic applications to be determined. A simple application of mineral waste is in the production of artificial aggregates, which are increasingly used as a substitute for natural aggregates. In Poland, artificial aggregates are widely produced from metallurgical waste from steel and non-ferrous metallurgy, which may contain numerous components that are potentially environmentally damaging. Depending on their occurrence form (i.e., mineral composition), these contaminants have varying potential to be released into aquatic and soil environments. This study presents the results of mineral and chemical composition analyses and leachability tests conducted on aggregates produced from metallurgical waste, including slags from blast furnaces, steelmaking, Zn and Pb production, and Ni production. The studied aggregates are characterised by chemical and phase composition differences, resulting from the type of slag from which they originate. The chemical composition of blast furnace slag is dominated by CaO, SiO₂, Fe₂O₃, and MgO; steelmaking slag by CaO, Fe₂O₃, and SiO₂; Zn and Pb production slag by SiO₂, Fe₂O₃, SO₃, and CaO; and Ni production slag by SiO₂, Fe₂O₃, CaO, and Al₂O₃. The phase composition of all the tested aggregates is dominated by silicates resistant to leaching (weathering), which results in low levels of Al, Ca, Cr, Mn, Zn, Pb, Cu, As, Sr and Ni leaching, not exceeding 1.6%. Full article

Using the Kaya identity and LMDI method, this study analyzes the influence of population, GDP per capita, energy intensity, and carbon intensity on Xinjiang’s carbon emissions, and compares the effects of industrial structure, energy intensity, and carbon intensity on the industrial sectors during the Eighth to Twelfth Five-Year Plan (FYP) periods. Key findings are as follows: (1) Xinjiang’s carbon emissions center on resource- and energy-intensive sectors, emissions from sectors such as extraction of petroleum and natural gas, fuel processing, chemicals, ceramics and cement, iron and steel, and non-ferrous and power generation accounted for 62% of carbon emissions in 2015; (2) after the Sixth FYP, GDP per capita effect turned into the core driver of carbon emission growth, while the population effect played an auxiliary role. Meanwhile, the energy intensity effect exerted a marked inhibitory impact on the increase in carbon emissions, yet the restraining effect of carbon intensity was comparatively limited; (3) during the Eighth to Twelfth FYPs, carbon emission growth was mainly attributed to industrial structure effects of the mining and washing of coal, extraction of petroleum and natural gas, fuel processing, chemicals, ceramics and cement, iron and steel, non-ferrous and power generation. Energy intensity and carbon intensity effects in various industries inhibited emission growth. Based on new trends in Xinjiang’s socioeconomic development, policy recommendations proposed including promoting the low-carbon transformation of industrial structure, profound restructuring of energy consumption, and improving energy efficiency by advancing energy-saving technology. Full article

The article presents a study of the possibilities for restoring the working surfaces of molds for high-pressure casting of non-ferrous metals by laser surfacing using a filler material. Test specimens with parameters of real forming elements were manufactured. The influence of nitriding on welded layers and basic material was studied in comparison with one without nitriding. The X-ray diffraction method was used to obtain the phase composition of the surface of the samples in areas submitted to nitriding. Scanning electron microscopy (SEM) was used to determine the microstructure of the nitriding layers, welded layers and bulk material. Energy-dispersive X-ray spectrometry (EDX) was applied to investigate the chemical composition in the welded and nitrided zone. Mechanical property means of microhardness measurements were studied. Four zones were identified after nitriding in the weld area. The first zone closest to the surface with a thickness of 0.025 mm is characterized by a higher microhardness, which reaches 700 HV. The second zone, which is part of the diffusion zone, is 0.1 mm thick, and it is characterized by the same size grains with a similar shape and microhardness, which reaches 600 HV. The microhardness measured in the welded zone after nitriding is 50% greater than that without nitriding. The thickness of the diffusion zone in 1.2343 steel reaches about 0.15 mm, and the microhardness is about 900 HV near the edge, but quickly decreases to 400 HV. Full article