Search Results (38)

The transition toward sustainable and decentralized energy solutions necessitates the development of innovative bioelectronic systems capable of harvesting and converting renewable energy. Here, we present a novel photo-bioelectrochemical fuel cell architecture based on a biohybrid anode integrating laser-induced graphene (LIG), poly(3,4-ethylenedioxythiophene) (PEDOT), and isolated thylakoid membranes. LIG provided a porous, conductive scaffold, while PEDOT enhanced electrode compatibility, electrical conductivity, and operational stability. Compared to MXene-based systems that involve complex, multi-step synthesis, PEDOT offers a cost-effective and scalable alternative for bioelectrode fabrication. Thylakoid membranes were immobilized onto the PEDOT-modified LIG surface to enable light-driven electron generation. Electrochemical characterization revealed enhanced redox activity following PEDOT modification and stable photocurrent generation under light illumination, achieving a photocurrent density of approximately 18 µA cm⁻². The assembled photo-bioelectrochemical fuel cell employing a gas diffusion platinum cathode demonstrated an open-circuit voltage of 0.57 V and a peak power density of 36 µW cm⁻² in 0.1 M citrate buffer (pH 5.5) under light conditions. Furthermore, the integration of a charge pump circuit successfully boosted the harvested voltage to drive a low-power light-emitting diode, showcasing the practical viability of the system. This work highlights the potential of combining biological photosystems with conductive nanomaterials for the development of self-powered, light-driven bioelectronic devices. Full article

In this study, platinum (Pt) nanocatalysts were synthesized via a sol-gel method over the non-stoichiometric, Magnéli phase titanium oxides (TinO_2n−1) at varying Pt loadings (10–40 wt.%). Their structural and morphological properties were characterized, and after preliminary electrochemical screening, the catalysts were integrated into commercially available gas diffusion electrodes (GDEs) with a three-layer structure to enhance mass transport and catalyst utilization. Membrane electrode assemblies (MEAs) were fabricated using a Nafion^® 117 polymer membrane and tested in a laboratory PEM cell under controlled conditions. The electrochemical activity toward the hydrogen reduction reaction (HRR) was evaluated at room temperature and at elevated temperatures to determine the catalytic efficiency and stability. The optimal Pt loading was determined to be 30 wt.%, achieving a current density of approximately 0.12 A cm⁻² at 0.25 V, demonstrating a balance between catalyst efficiency and material utilization. The chronoamperometry tests showed minimal degradation over prolonged operation, suggesting that the catalysts were durable. These findings highlight the potential of Pt-based catalysts supported on Magnéli phase titanium oxides (TinO_2n−1) for efficient HRRs in electrochemical hydrogen pumps/compressors, offering a promising approach for improving hydrogen compression efficiency and advancing sustainable energy technologies. Full article

This study presents the integration and evaluation of commercially available gas diffusion electrodes (GDEs), specifically designed for high-temperature polymer electrolyte membrane fuel cells (HT-PEMFCs) within membrane electrode assemblies (MEA) for electrochemical hydrogen pump/compressor applications (EHP/C). Using Nafion 117 as a solid polymer electrolyte, the MEAs were analyzed for cell efficiency, hydrogen evolution, and hydrogen oxidation reactions (HER and HOR) under differential pressure up to 16 bar and a temperature ranging from 20 °C to 60 °C. Key properties of the GDEs, such as electrode thickness and conductivity, were investigated. The catalytic layer was characterized via XRD and EDX analyses to assess its surface and bulk composition. Additionally, the effects of increasing MEA’s geometric size (from 1 cm² to 5 cm²) and hydrogen crossover phenomena on the efficiency were examined in a single-cell setup. Electrochemical performance tests conducted in a single electrochemical hydrogen pump/compressor cell under hydrogen flow rates from 36.6 Ml·min⁻¹·cm⁻² to 51.3 mL·min⁻¹ cm⁻² at atmospheric pressure provided insights into the optimal operational parameters. For a double-stage application, the MEAs demonstrated enhanced current densities, achieving up to 0.6 A·cm⁻² at room temperature with further increases to 1 A·cm⁻² at elevated temperatures. These results corroborated the single-cell data, highlighting potential improvements in system efficiency and a reduction in adverse effects. The work underscores the potential of HT-PEMFC-based GDEs for the integration of MEAs applicable to advanced hydrogen compression technologies. Full article

In this study, mono- and bimetallic platinum (Pt), palladium (Pd) and Pt-Pd nanoparticles were synthesized using the wet sol–gel method, employing a carbon-based XC72R as catalytic carrier. The overall metal content was set at 40 wt.% at varying Pt:Pd ratios. Characterization of the morphology and surface structure was conducted through scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), Brunauer–Emmett–Teller (BET) and X-ray diffraction (XRD) analyses. The electrochemical performance and catalytic activity against the hydrogen evolution reaction (HER) were assessed in a three-electrode cell for screening purposes, as well as in a prototype cell of an electrochemical hydrogen pump/compressor (EHP/C) where the catalysts served as cathodes, while the anode was Pt/XC72 40% wt. with 0.38 mg_Pt·cm⁻² within a membrane electrode assembly (MEA) with a 180 µm thick Nafion 117 proton-conductive membrane. The results obtained indicated superior catalytic activity of the bimetallic catalysts in comparison to the pure metal samples. Further electrochemical tests in an EHP/C cell at varying differential pressures in the range of 0–3 bar revealed stable behavior and high current density, reaching approximately 0.7 A cm⁻² at 60 °C. The accelerated durability tests performed demonstrated excellent stability of the synthesized composite catalysts. These findings underscore the potential of Pt-Pd nanoparticles as efficient catalysts with sustainable performance for electrochemical hydrogen pumping/compressing applications. Full article

With the growing interest in reducing CO₂ emissions to combat climate change, humanity is turning to green or renewable sources of electricity. There are numerous issues associated with the development of these sources. One of the key aspects of renewable energy sources is their problematic controllability, namely the control of energy production over time. Renewable sources are also associated with issues of recycling, utilization in different geographical zones, environmental impact within the required area, and so on. One of the most discussed issues today, however, is the question of efficient use of the energy produced from these sources. There are several different approaches to storing renewable energy, e.g., supercapacitors, flywheels, batteries, PCMs, pumped-storage hydroelectricity, and flow batteries. In the commercial sector, however, mainly due to acquisition costs, these options are narrowed down to only one concept: storing energy using an electrochemical storage device—batteries. Nowadays, lithium-ion batteries (LIBs) are the most widespread battery type. Despite many advantages of LIB technology, the availability of materials needed for the production of these batteries and the associated costs must also be considered. Thus, this battery type is not very ideal for large-scale stationary energy storage applications. Sodium-ion batteries (SIBs) are considered one of the most promising alternatives to LIBs in the field of stationary battery storage, as sodium (Na) is the most abundant alkali metal in the Earth’s crust, and the cell manufacturing process of SIBs is similar to that of LIBs. Unfortunately, considering the physical and electrochemical properties of Na, different electrode materials, electrolytes, and so on, are required. SIBs have come a long way since they were discovered. This review discusses the latest developments regarding the materials used in SIB technology. Full article

The electrochemical corrosion of a single-suction centrifugal water pump impeller made of gray cast iron operating at 85 °C was investigated in two industrial water media, i.e., groundwater extracted from a borehole and treated wastewater. Open circuit potential (OCP) measurement plus potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) techniques elucidated the electrochemical corrosion performance and inductively coupled plasma-optical emission spectroscopy (ICP-OES) characterized the water samples. The retired and brand-new impellers were studied using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and visual and metallographic examinations. Impeller trailing edges were vulnerable to corrosion damage due to increased total fluid pressure, velocity, and temperature. The groundwater was more contaminated with Ca, Mg, Na, Si, and S elements and possessed higher conductivity, pH, and suspended solids than the treated wastewater. The impeller was more susceptible to graphitic corrosion in the groundwater due to emerging microgalvanic cells. A kinetic control electrochemical mechanism was elucidated as the corrosion rate-controlling step in the wastewater. A mixed kinetic and diffusion control mechanism was predominant in the groundwater because a short Warburg impedance element emerged. This study showcased the significance of integrated industrial water management and treatment strategies to protect pumps’ integrity and uptime in critical industrial units implementing a zero-liquid discharge program. Full article

Anion exchange membrane electrolysis, which combines the advantages of both alkaline electrolysis and proton-exchange membrane electrolysis, is a promising technology to reduce the cost of hydrogen production. The present work focused on the study of the electrochemical phenomena of AEM electrolysis and the investigation of the key factors of the AEM hydrogen production system. The numerical model is established according to electrochemical reactions, polarization phenomena, and the power consumption of the balance of plant components of the system. The effects of operation parameters, including the temperature and hydrogen pressure of the electrolyzer, electrolyte concentration, and hydrogen supply pressure on the energy efficiency are studied. The basic electrochemical phenomena of AEM water electrolysis cells are analyzed by simulations of reversible potential and activation, and ohmic and concentration polarizations. The results reveal that increasing the operating temperature and hydrogen production pressure of the AEM electrolyzer has positive effects on the system’s efficiency. By conducting an optimization analysis of the electrolyzer temperature—which uses the heat energy generated by the electrochemical reaction of the electrolyzer to minimize the power consumption of the electrolyte pump and heater—the AEM system with an electrolyzer operating at 328 K and 30 bar can deliver hydrogen of pressure up to 200 bar under an energy efficiency of 56.4%. Full article

In large-format pouch cells for electric vehicles, the issues of elevated and non-uniform temperatures resulting from heat generation are intensified, necessitating the use of liquid cooling systems. The design factors of the liquid cooling system influence the maximum temperature and temperature differences in the module as well as the pumping power of the cooling system. Although it is known that these design factors interact, research on these interactions and their effects is currently lacking. In this study, the individual as well as interaction effects of design factors on the performance of the liquid cooling system for a large-format pouch cell module were investigated using design of experiment and analyzed through statistical methods. Electrochemical–thermal fluid coupled analysis was used to calculate the performance according to the design factors of the liquid cooling system. The wall and channel widths are factors that directly determine the coolant flow velocity and cooling plate heat capacity, and they exhibited major effects on all three responses. Moreover, the influence of each design factor tended to change in response to variations in the other design factors. Thus, the effects of each factor individually and of interactions between factors were quantitatively compared and evaluated for significance. The width of the walls was found to contribute the most to the maximum temperature (36.00%) and pumping power (57.56%), while the width of the channels contributed the most to the temperature difference (38.24%), indicating that they are the main influencing factors. Full article

The design of an efficient thermal management system for a lithium-ion battery pack hinges on a deep understanding of the cells’ thermal behavior. This understanding can be gained through theoretical or experimental methods. While the theoretical study of the cells using electrochemical and numerical methods requires expensive computing facilities and time, the Equivalent Circuit Model (ECM) offers a more direct approach. However, upfront experimental cell characterization is needed to determine the ECM parameters. In this study, the behavior of a cell is characterized experimentally, and the results are used to build a second-order equivalent electrical circuit model of the cell. This model is then integrated with the cooling system of the battery pack for effective thermal management. The Equivalent Circuit Model estimates the internal heat generation inside the cell using instantaneous load current, terminal voltage, and temperature data. By extrapolating the heat generation data of a single cell, we can determine the heat generation of the cells in the pack. With the implementation of the ECM in the cooling system, the coolant flow rate can be adjusted to ensure the attainment of a safe operating cell temperature. Our study confirms that 14% of pumping power can be reduced when compared to the conventional constant flow rate cooling system, while still maintaining the temperature of the cells within safe limits. Full article

The sodium pump, or Na⁺/K⁺-ATPase (NKA), is an essential enzyme found in the plasma membrane of all animal cells. Its primary role is to transport sodium (Na⁺) and potassium (K⁺) ions across the cell membrane, using energy from ATP hydrolysis. This transport creates and maintains an electrochemical gradient, which is crucial for various cellular processes, including cell volume regulation, electrical excitability, and secondary active transport. Although the role of NKA as a pump was discovered and demonstrated several decades ago, it remains the subject of intense research. Current studies aim to delve deeper into several aspects of this molecular entity, such as describing its structure and mode of operation in atomic detail, understanding its molecular and functional diversity, and examining the consequences of its malfunction due to structural alterations. Additionally, researchers are investigating the effects of various substances that amplify or decrease its pumping activity. Beyond its role as a pump, growing evidence indicates that in various cell types, NKA also functions as a receptor for cardiac glycosides like ouabain. This receptor activity triggers the activation of various signaling pathways, producing significant morphological and physiological effects. In this report, we present the results of a comprehensive review of the most outstanding studies of the past five years. We highlight the progress made regarding this new concept of NKA and the various cardiac glycosides that influence it. Furthermore, we emphasize NKA’s role in epithelial physiology, particularly its function as a receptor for cardiac glycosides that trigger intracellular signals regulating cell–cell contacts, proliferation, differentiation, and adhesion. We also analyze the role of NKA β-subunits as cell adhesion molecules in glia and epithelial cells. Full article

The fungal plasma membrane H⁺-ATPase (Pma1) pumps protons out of the cell to maintain the transmembrane electrochemical gradient and membrane potential. As an essential P-type ATPase uniquely found in fungi and plants, Pma1 is an attractive antifungal drug target. Two recent Cryo-EM studies on Pma1 have revealed its hexameric architecture, autoinhibitory and activation mechanisms, and proton transport mechanism. These structures provide new perspectives for the development of antifungal drugs targeting Pma1. In this article, we review the history of Pma1 structure determination, the latest structural insights into Pma1, and drug discoveries targeting Pma1. Full article

This work presents research on thin magnetron-sputtered platinum (Pt) films deposited over commercial gas diffusion electrodes and applied to convert and pressurize hydrogen in an electrochemical hydrogen pump. The electrodes were integrated into a membrane electrode assembly with a proton conductive membrane. Their electrocatalytic efficiency toward hydrogen oxidation and hydrogen evolution reactions was studied in a self-made laboratory test cell by means of steady-state polarization curves and cell voltage measurements (U/j and U/p_diff characteristics). The achieved current density at a cell voltage of 0.5 V, the atmospheric pressure of the input hydrogen, and a temperature of 60 °C was more than 1.3 A cm⁻². The registered increase in the cell voltage with the increasing pressure was only 0.05 mV bar⁻¹. Comparative data with commercial E-TEK electrodes reveal the superior catalyst performance and essential cost reduction of the electrochemical hydrogen conversion on the sputtered Pt films. Full article

The study provides a study on energy storage technologies for photovoltaic and wind systems in response to the growing demand for low-carbon transportation. Energy storage systems (ESSs) have become an emerging area of renewed interest as a critical factor in renewable energy systems. The technology choice depends essentially on system requirements, cost, and performance characteristics. Common types of ESSs for renewable energy sources include electrochemical energy storage (batteries, fuel cells for hydrogen storage, and flow batteries), mechanical energy storage (including pumped hydroelectric energy storage (PHES), gravity energy storage (GES), compressed air energy storage (CAES), and flywheel energy storage), electrical energy storage (such as supercapacitor energy storage (SES), superconducting magnetic energy storage (SMES), and thermal energy storage (TES)), and hybrid or multi-storage systems that combine two or more technologies, such as integrating batteries with pumped hydroelectric storage or using supercapacitors and thermal energy storage. These different categories of ESS enable the storage and release of excess energy from renewable sources to ensure a reliable and stable supply of renewable energy. The optimal storage technology for a specific application in photovoltaic and wind systems will depend on the specific requirements of the system. It is important to carefully evaluate these needs and consider factors, such as power and energy requirements, efficiency, cost, scalability, and durability when selecting an ESS technology. Full article

In this paper, we propose a sophisticated battery model for vanadium redox flow batteries (VRFBs), which are a promising energy storage technology due to their design flexibility, low manufacturing costs on a large scale, indefinite lifetime, and recyclable electrolytes. Primarily, fluid distribution is analysed using computational fluid dynamics (CFD) considering only half-cells. Based on the analysis results, a novel model is developed in the MATLAB Simulink environment which is capable of identifying both the steady-state and dynamic characteristics of VRFBs. Unlike the majority of published studies, the inherent characteristics of the flow battery, such as shunt current, ion diffusion, and pumping energy consumption, are considered. Furthermore, simplified charge transfer resistance (CTR) is taken into account based on electrochemical impedance spectroscopy (EIS) measurement results. The accuracy of the model was determined by comparing the simulation results generated by the equivalent circuit battery model developed in this study with real datasets. The obtained results indicate that the developed model has an accuracy of 3% under the sample operating conditions selected. This study can also be used to fill the gap left by the absence of the VRFB battery model in commonly used programs for renewable energy systems, such as TRNSYS. Full article

Inorganic pyrophosphatases (PPases) catalyze an essential reaction, namely, the hydrolysis of PP_i, which is formed in large quantities as a side product of numerous cellular reactions. In the majority of living species, PP_i hydrolysis is carried out by soluble cytoplasmic PPase (S-PPases) with the released energy dissipated in the form of heat. In Rhodospirillum rubrum, part of this energy can be conserved by proton-pumping pyrophosphatase (H⁺-PPase^Rru) in the form of a proton electrochemical gradient for further ATP synthesis. Here, the codon-harmonized gene hppa^Rru encoding H⁺-PPase^Rru was expressed in the Escherichia coli chromosome. We demonstrate, for the first time, that H⁺-PPase^Rru complements the essential native S-PPase in E. coli cells. ¹³C-MFA confirmed that replacing native PPase to H⁺-PPase^Rru leads to the re-distribution of carbon fluxes; a statistically significant 36% decrease in tricarboxylic acid (TCA) cycle fluxes was found compared with wild-type E. coli MG1655. Such a flux re-distribution can indicate the presence of an additional method for energy generation (e.g., ATP), which can be useful for the microbiological production of a number of compounds, the biosynthesis of which requires the consumption of ATP. Full article