Search Results (16)

The extensive distribution of quaternary sediments and the extraction of underground resources in the Yellow River Delta (YRD) have resulted in significant land subsidence, which accelerates relative sea level (RSL) rise and heightens the risk of coastal inundation. This study uses Sentinel-1A (S1A) imagery and the time-series synthetic aperture radar interferometry (TS-InSAR) method to obtain subsidence information for the YRD. By integrating data from groundwater level monitoring wells, hydrogeological conditions, extensometer monitoring, and drilling wells, we analyze the causes of subsidence and the deformation response to the groundwater level changes in the corresponding aquifers. For the first time in the YRD, this study introduces the high accuracy CoastalDEM v2.1 digital elevation model, combined with absolute sea level (ASL) data, to construct a coastal inundation simulation. This simulation maps the land inundation caused by RSL rise along the YRD in different scenarios. The results indicate significant subsidence bowls in coastal and inland regions, primarily attributed to shallow brine and deep groundwater extraction, respectively. The main subsidence layers in inland towns have been identified, and residual deformation has been observed. Currently, land subsidence has caused a maximum elevation loss of 141 mm/yr in coastal YRD areas, significantly contributing to RSL rise. Seawater inundation simulations suggest that if subsidence continues unabated, 12.84% of the YRD region will be inundated by 2100, with 8.74% of the built-up areas expected to be inundated. Compared to global warming-induced ASL rise, ongoing subsidence is the primary driver of inundation in the YRD coastal areas. Full article

The Shitangwan earth fissure is a resultant geological hazard due to prolonged groundwater depletion and land subsidence in Wuxi, China, since the 1980s. Initially observed in 1991, the earth fissure experienced continuous development over the next several decades. Employing a diverse array of techniques, including field monitoring via multilayered borehole extensometers, earth fissure monitoring for lateral and vertical movements, advanced geophysical exploration, and conventional geological investigations, this study aims to mitigate the risks associated with land subsidence and earth fissures. It is found that the groundwater has recovered to the levels in the 1980s, land subsidence and earth fissuring have ceased, and the earth fissuring is closely linked to the land subsidence. A bedrock ridge and a river course are underlying porous Quaternary sediments beneath the earth fissure. The formation of the earth fissure is the result of a combination of factors, including spatial and temporal variations in strata compression, rugged bedrock terrain, and the heterogeneity of the strata profile. Land subsidence is primarily attributed to the deep pumping aquifer and its adjacent aquitards, which are responsive to groundwater recovery with a time lag of a decade, and the land rebound accounts for 2% of the accumulated land subsidence. Estimations suggest that the depth of the earth fissure may have reached the bedrock ridge. The mechanism of the earth fissuring is the coupled effect of tension from the rotation of shallow soil strata along the bedrock ridge and shearing of strata driven by the differential compression of deep strata below the ridge level. Full article

The hydrogeological study of the Rharb coastal basin, located in the semi-arid northwest region of Morocco, focuses on its two aquifers: the Plio-Quaternary aquifer characterized by high-quality water with salt concentrations ranging from 0.4 to 2 g/L, and the Upper Quaternary aquifer, with lower water quality (2 to 6 g/L). The deep aquifer is overexploited for agricultural purposes. This overexploitation has led to declining piezometric levels and the worsening of the oceanic intrusion phenomenon. The study aims to develop a numerical model for a period of 15 years, from 1992/93 to 2006/07 for monitoring groundwater quantity and quality, considering recharge, exploitation, and basin characteristics. A hydrodynamic model based on storage coefficient calibration identifies overexploitation for irrigation, increasing from 93 Mm³ in 1993 to 170 Mm³ in 2007, as the primary driver of declining water levels. A hydrodispersive model highlights higher salt concentrations in the shallow aquifer (up to 6 g/L), high nitrate concentrations due to human activity, and pinpoints areas of seawater intrusion approximately 500 m from the shoreline. Although the deeper aquifer remains relatively preserved, negative hydraulic balances from −15.4 Mm³ in 1993 to −36.6 Mm³ in 2007 indicate an impending critical period. Full article

The sand–gravel brine deposit in the Mahai Basin is a newly discovered large-scale potassium–bearing brine deposit. The potassium–bearing brine is primarily found at depths exceeding 150 m within the porous alluvial and fluvial sand–gravel reservoir of the Middle to Lower Pleistocene. This deposit is characterized by a relatively shallow water table, moderate–to–strong aquifer productivity, high salinity, and a KCl content that meets the conditions for exploitation, with the advantage of reduced salt crystallization during well mining, making it a potential reserve base for potash development. A geochemical analysis of the sand–gravel brine revealed consistent trends for the major ions K⁺, Na⁺, Mg²⁺, Cl⁻, and SO₄²⁻ along the east–west axis of the alluvial fan, while Ca²⁺ showed an opposite trend compared to Mg²⁺. Along the exploration lines from north to south, the concentrations of the main ions gradually increase. The brine is enriched in Na⁺ and Cl⁻ ions, while SO₄²⁻ and HCO₃⁻ are depleted. In the K⁺-Na⁺-Mg²⁺/Cl⁻-H₂O (25 °C) quaternary phase diagram, the brine falls within the halite stability field, with the hydrochemical type classified as chloride type. The brine coefficient characteristics indicate a multi-source origin involving residual evaporation, salt rock leaching, and metamorphic sedimentary brine. Comparison studies of the ionic composition and isotopic signatures (δD, δ¹⁸O, δ³⁷Cl, and δ⁷Li) of deep sand–gravel brines in the study area with interstitial and confined brines in the southern depression suggest similar geochemical characteristics between them. The genetic analysis of the deposit proposes that during the basin tectonic evolution, the potassium-rich interstitial and confined brines originally located in the southern depression of the Mahai Basin were displaced under compressional forces and migrated northward as the depositional center shifted, eventually backfilling into the loose alluvial and fluvial sand and gravel reservoirs at the front of the Saishiteng Mountains, forming the deep sand–gravel brine deposits in the foreland. Full article

The present study examines the water quality in the Quaternary Mio-Plio-Quaternary aquifer of the mining basin of Gafsa using a hydrochemical approach and multivariate statistical methods, to assess groundwater mineralization processes. Results from the analysis of groundwater quality collected during the winter (January 2020) and summer (June 2021) seasons reveal a pronounced stability in geochemical parameters, emphasizing a noteworthy consistency in water composition between the two seasons, with the dominance of the Na-Ca-Mg-SO4-Cl facies, in addition to the fact that all year round these concentrations are beyond their respective WHO limits. Despite the intensive extractive and transformation phosphate industry, the prolonged interaction of water with geological formations is the primary factor controlling their high mineralization. This results from the dissolution of carbonates (calcite, dolomite), gypsum, and halite. The results of the PCA represent two correlation classes. Class 1 comprises major elements sulfate, chloride, sodium, magnesium, and calcium strongly correlated with electrical conductivity (EC) and total dissolved solids (TDS). This correlation is indicative of the water mineralization process. Class 2 includes major elements nitrate and potassium weakly correlated with (TDS) and (EC) As regards heavy metals, their concentrations fall consistently below their respective potability standards established by the WHO across all water sampling points. Meanwhile, fluoride (F-) concentrations exhibited values ranging from (1.6 mg·L⁻¹ to 2.9 mg·L⁻¹) in the winter of January 2020 and (1 to 2.9 mg·L⁻¹) in the summer of June 2021, surpassing its WHO limit (1.5 mg·L⁻¹) in almost all water samples. These findings allow us to conclude that the high mineralization of these waters is acquired due to the dissolution of carbonates (calcite, dolomite), gypsum, and halite due to their prolonged interaction with the geological formations. The deterioration of groundwater quality in the Gafsa mining basin associated with phosphate extraction and processing activities appears to be primarily due to the intensive exploitation of deep-water resources. Full article

Geochemical tracers have the potential to provide valuable insights for constructing conceptual models of groundwater flow, especially in complex geological contexts. Nevertheless, the reliability of tracer interpretation hinges on its integration into a robust geological framework. In our research, we concentrated on delineating the groundwater flow dynamics in the Innisfil Creek watershed, located in Ontario, Canada. We amalgamated extensive hydrogeological data derived from a comprehensive 3D geological model with the analysis of 61 groundwater samples, encompassing major ions, stable water isotopes, tritium, and radiocarbon. By seamlessly incorporating regional physiographic characteristics, flow pathways, and confinement attributes, we bolstered the efficiency of these tracers, resulting in several notable findings. Firstly, we identified prominent recharge and discharge zones within the watershed. Secondly, we observed the coexistence of relatively shallow and fast-flowing paths with deeper, slower-flowing channels, responsible for transporting groundwater from ancient glacial events. Thirdly, we determined that cation exchange stands as the predominant mechanism governing the geochemical evolution of contemporary water as it migrates toward confined aquifers situated at the base of the Quaternary sequence. Fourthly, we provided evidence of the mixing of modern, low-mineralized water originating from unconfined aquifer units with deep, highly mineralized water within soil–bedrock interface aquifers. These findings not only contribute significantly to the development a conceptual flow model for the sustainable management of groundwater in the Innisfil watershed, but also offer practical insights that hold relevance for analogous geological complexities encountered in other regions. Full article

The south-eastern Gorny Altai is one of the most hazardous seismogenic area in the north of Central Asia. We present a synthesis of field, ²³⁰Th-U geochronological, mineralogical and geochemical data collected on seven Quaternary travertines. All travertines occur within the zones of active faults that border the Chuya and Kurai intermontane basins. Travertine cement mainly comprises calcite (with minor amounts of aragonite), which cements alluvial, alluvial fan, and colluvial deposits. The results of ²³⁰Th-U dating suggest that deposition of the travertines was triggered by large paleoearthquakes in the last eight thousand years. Several stages of travertine formation with ages 9–11 ka BP correspond to the known period of strong paleoseismicity in the region (8–16 ka BP). The 123 ka BP travertine resulted from a slip triggered by the Middle Pleistocene deglaciation, while that of 400 ka BP represents seismic motions likely associated with the main Cenozoic orogenic phase. All travertine forming events fall within warm and wet climatic phases (interglacials). Large earthquakes activated faults and caused a rapid rise along them of ambient-temperature bicarbonate groundwater, which was previously sealed in deep-seated Upper Neoproterozoic–Paleozoic limestone-dolostone aquifers. Rapid CO₂ degassing of the spring water was the most important control of calcite or aragonite precipitation. Such travertines represent an important tool for paleoseismological research in seismically active regions. Full article

Wuhan and its surrounding areas have obvious geothermal spring outcrops, which are unexplored potential geothermal resources. The degree of geothermal resource development in Wuhan is low, and there is a lack of systematic research on their hydrochemical characteristics and formation mechanism. The Wuhan area is bounded by the Xiang-Guang fault, the South Qinling-Dabie orogenic belt in the north, and the Yangtze landmass in the south, with Silurian and Quaternary outcrops and little bedrock outcrops. The Silurian is the main water barrier in the region, which separates the upper Triassic and Paleogene as shallow aquifers and the lower Cambrian and Ordovician as deep aquifers. Different strata are connected by a series of fault structures, which constitute Wuhan’s unique groundwater water-bearing system. Eleven geothermal water (23~52 °C) and six surface water samples (around 22 °C) were collected from the study area. The geothermal water in the study area is weakly alkaline, with a pH of 7.04~8.24. The chemical type of geothermal water is mainly deep SO₄²⁻ with a higher TDS and shallow HCO₃⁻ type water with a lower TDS. Isotopic analysis indicates that atmospheric precipitation and water-rock interaction are the main ionic sources of geothermal water. The chemical composition of geothermal water is dominated by ion-exchange interactions and the dissolution of carbonates and silicates. The characteristic coefficients, correlation analysis, water chemistry type, recharge elevation, geothermal water age, reservoir temperature, and cycle depth were also analyzed. The performance was similar in the same geothermal reservoir, which could be judged as an obviously deep and shallow geothermal fluid reservoir, and the genetic conceptual model of Wuhan geothermal was preliminarily deduced. DXR-8 and DXR-9 had the best reservoir conditions, hydrodynamic conditions, rapid alternation of water bodies, and large circulation depth, which is a favorable location for geothermal resource development and will bring considerable economic and social benefits. Full article

Groundwater is an important freshwater resource in the world and serves as the main source of water for mining areas in Northern China. Coal mining may cause changes in water quality. As such, to identify ways to prevent water contamination, this study investigates the hydrogeochemical processes and transport paths of a complex aquifer system in the Sunan mining area in Northern China. Using the APFS-MLR model, a geographic information system (GIS) spatial analysis, and a hydrochemical correlation analysis method, this study identifies the potential mineral phases in groundwater, the spatial distribution of mineral reactions, and the contribution rate of these reactions to hydrochemical variables. Inverse modeling is used to verify hydrogeochemical process. The study reveals the relationship between multiple aquifers and four hydrological transport paths. Here, Path 1 and Path 2 show that the Quaternary aquifer, Carboniferous aquifer, and Ordovician aquifer are recharging the Permian aquifer through mineral dissolution and precipitation, cation exchange, and sulfate reduction. On the other hand, Path 3 and Path 4 show that tthe connections of Carboniferous and Ordovician limestone aquifers are dominated by the dissolution and precipitation of minerals and cation exchange, and that they are mainly recharged by the Quaternary aquifer. In the future, the water level of the Permian aquifer may rise somewhat after mining ends, and the mixing of water from the Permian aquifer, Quaternary aquifer, Carboniferous aquifer, and Ordovician aquifer could cause cross-pollution. In addition, sewage produced by human activities may recharge the deep water through the shallow water, polluting the deep karst water. As such, measures should be taken to reduce the hydraulic connection between Permian mine water and karst aquifers. The results of this study may benefit water quality predictions and treatment approaches in other complex multi-layer aquifer areas in the world. Full article

Groundwater is closely related to hydrogeological structure and hydro-lithology, which mainly refers to the spatial distributions and properties of the environment where groundwater occurs. To analyze the constraints of hydrogeological structure and hydro-lithology on regional groundwater resources in the Eastern Henan Plain, China, we reconstructed the three-dimensional (3D) hierarchical models at two scales, hydrogeological structural models and hydro-lithological models, using hydrogeological cross-sections. First, the hydrogeological structural models of four aquifer groups, corresponding to four formations of the Quaternary in the study area, were reconstructed. Second, the hierarchical hydro-lithological model was built using SIS and IK estimation under the constraint of each aquifer group model space, respectively. Compared to global model, the variograms of hierarchical model captured more spatial characteristics of lithology in each aquifer group. The IK hierarchical model presents more continuities, clear boundaries, and realistic geometric shapes of the three lithologies, excluding the banding characteristics of the IK global model. The hierarchical SIS models reproduced the lithology distribution of each aquifer group and captured small changes in the lithology, with the smallest absolute percentage errors (APEs). Third, coupling the SIS hierarchical models and the groundwater levels, the groundwater resource in the study area was estimated to have a total volume of 1.2339 × 10⁴ m³. The shallow groundwater in the study area is mainly concentrated in Hebi City and the Puyang basin of the Yellow River, and deep groundwater is mainly concentrated in the northern Anyang City and Hebi City. Finally, the possible quantities of shallow and deep groundwater recharges were estimated for future groundwater management decision in the study area. The hierarchical hydrogeological model, groundwater resource assessment, and possible groundwater recharge estimation can also provide a basis for groundwater vulnerability, groundwater extraction, and land subsidence assessment. Full article

This research aimed to investigate the spatial distribution of arsenic concentrations in shallow and deep groundwaters which were used as sources for drinking and domestic and agricultural uses. A geochemical modeling software PHREEQC was used to simulate equilibrium geochemical reactions of complex water–rock interactions to identify arsenic speciation and mineral saturation indices based on groundwater quality and hydrogeochemical conditions. In addition, the potential health risk from arsenic-contaminated groundwater consumption was assessed based on the method developed by the U.S. Environmental Protection Agency. The study area is located at the western part of the Lampang Basin, an intermontane aquifer, Northern Thailand. The area is flat and situated in a floodplain in the Cenozoic basin. Most shallow groundwater (≤10 m depth) samples from dug wells were of Ca-Na-HCO₃ and Ca-HCO₃ types, whereas deep groundwater from Quaternary terrace deposits (30–150 m depth) samples were of Na-HCO₃ and Ca-Na-HCO₃ types. High arsenic concentrations were found in the central part of the study area (Shallow groundwater: <2.8–35 mg/L with a mean of 10.7 mg/L; Deep groundwater: <2.8–480 mg/L with a mean of 51.0 mg/L). According to geochemical modeling study, deep groundwater contained toxic As(III), as the dominant species more than shallow groundwater. Arsenic in groundwater of the Lampang Basin may have been derived from leaching of rocks and could have been the primary source of the subsurface arsenic in the study area. Secondary source of arsenic, which is more significant, could be derived from the leaching of sorbed arsenic in aquifer from co-precipitated Fe-oxyhydroxides in sediments. Quantitative risk assessment showed that the average carcinogenic risk values were as high as 2.78 × 10⁻³ and 7.65 × 10⁻³ for adult and child, respectively, which were higher than the acceptable level (1 × 10⁻⁴). The adverse health impact should be notified or warned with the use of this arsenic-contaminated groundwater without pre-treatment. Full article

This paper analyzes the groundwater in the deep Quaternary aquifer of Eastern Croatia. These waters are collected at the Vinogradi Pumping Station (Osijek, Croatia) for the needs of public water supply. This research aimed to assess the impact of climate extremes, namely, high air temperatures and low rainfall, on the quantity and quality of groundwater. On the basis of data from the Vinogradi Pumping Station in the period 1987–2015, three extremely warm and low-water years were singled out. For these three years, the following were analyzed: climate diagrams, groundwater levels (in the piezometers closest to and farthest from the pumping station), and the quality of the affected groundwater. The results of this research indicate that the reaction of aquifers to the analyzed extreme climatic conditions for the observed period was manifested in the variation of the amplitude of groundwater levels by a maximum of 4–5 m. Considering the total thickness of the affected layers (60–80 m), this variation is not a concern from the point of view of water supply. As for the quality of groundwater, it was found to be of constant quality in its composition and was not affected by climatic extremes. Full article

The Greater Caucasus is a part of seismically active Alpine–Himalayan orogenic belt and has been a center of significant volcanic activity during the Quaternary period. That led to the formation of the number of hydrothermal habitats, including subterranean thermal aquifers and surface hot springs. However, there are only a limited number of scientific works reporting on the microbial communities of these habitats. Moreover, all these reports concern only studies of specific microbial taxa, carried out using classical cultivation approaches. In this work, we present first culture-independent study of hydrotherms in the Republic of North Ossetia-Alania, located in the southern part of the North Caucasus. Using 16S metabarcoding, we analyzed the composition of the microbial communities of two subterranean thermal aquifers and terrestrial hot springs of the Karmadon valley. Analysis of correlations between the chemical composition of water and the representation of key taxa allowed us to identify the key factors determining the formation of microbial communities. In addition, we were able to identify a significant number of highly abundant deep phylogenetic lineages. Our study represents a first glance on the thermophilic microbial communities of the North Caucasus and may serve as a basis for further microbiological studies of the extreme habitats of this region. Full article

Groundwater is an irreplaceable resource for irrigation and drinking in the North China Plain, and the quality of groundwater is of great importance to human health and social development. In this study, using the information from 59 groups of groundwater samples, groundwater quality conditions for irrigation and drinking purposes in an agricultural region of the North China Plain were analyzed. The groundwater belongs to a Quaternary loose rock pore water aquifer. The depths of shallow groundwater wells are 20–150 m below the surface, while the depths of deep groundwater wells are 150–650 m. The sodium adsorption ratio (SAR), sodium percentage (%Na), residual sodium carbonate (RSC), magnesium hazard (MH), permotic index (PI) and electrical conductivity (EC) were selected as indexes to evaluate the shallow groundwater suitability for irrigation. What’s more, the deep groundwater suitability for drinking was assessed and the human health risk of excessive chemicals in groundwater was studied. Results revealed that SAR, Na% and RSC indexes indicated the applicability of shallow groundwater for agricultural irrigation in the study area. We found 57.1% of the shallow groundwater samples were located in high salinity with a low sodium hazard zone. The concentrations of fluorine (F⁻) in 79.0% of the deep groundwater samples and iodine (I⁻) in 21.1% of the deep groundwater samples exceeded the permissible limits, respectively. The total hazard quotient (HQ) values of fluorine in over half of the deep groundwater samples exceeded the safety limits, and the health risk degree was ranked from high to low as children, adult females and adult males. In addition to natural factors, the soil layer compression caused by groundwater over-exploitation increased the fluorine concentration in groundwater. Effective measures are needed to reduce the fluorine content of the groundwater of the study area. Full article

Alpine areas, with normally fissured bedrock outcrops, do not typically contain important hydrologic reservoirs, except for small aquifers located in Quaternary sediments. By contrast, mountainous areas affected by deep-seated gravitational slope deformations (DSGSD), especially if covered by glacial sediments, contain large aquifers and are consequently promising for water exploitation. This last geological setting is observed, for example, in the lower Dora Baltea Valley (near the confluence with the Renanchio Basin) in which the Montellina Spring is located and exhibits a very high discharge. A multidisciplinary approach (detailed geological survey of the bedrock and Quaternary cover, as well as hydrogeological research based on tracer tests, hydrochemical analyses, and water balance studies) was used, allowing for a reconstruction of the geological and hydrogeological setting of the investigated area, also considering its environmental implications. The consequent hydrogeological model derives from the coexistence of some factors. In detail, the thick glacial cover, widespread in the intermediate sector of the slope, represents an important aquifer with a slow groundwater flow to the spring. The buried glacial valley floor, hosting this cover, can convey the groundwater from the high Renanchio Basin zone towards the low sector. The loosened bedrock of the low sector, consequent to DSGSD phenomena, favors the concentration of groundwater along the contact with the underlying normal fissured bedrock outcropping at the base of the slope. Finally, the flow until the spring essentially takes place through N100° trend open fractures and trenches. Part of the Montellina Spring discharge is also fed by the low Renanchio Stream, as highlighted by fluorescein tests, essentially using NE-SW oriented open fractures on the bedrock. The results of the investigation on the Montellina Spring can provide some insight regarding the hydrological potential of other alpine areas with a similar geological setting. Full article