Search Results (10)

The corrosion behaviors in chloride environment of two commercial low-alloy steel bars were studied. Through cyclic wetting tests, accelerated corrosion experiments ranging from 1 to 576 h were conducted on low-alloy bars and original bars. Techniques such as OM, SEM, EDS, AFM, and XRD were employed to characterize the corrosion emergence and expansion behaviors of these bars in a simulated marine wetting and sun exposure environment. The designed low-alloy corrosion-resistant rebar achieved a 500 MPa yield strength. In each corrosion cycle, its corrosion loss and rate were lower than those of same-strength ordinary rebars. Analysis of the rust layer’s macro and micro morphology and alloy element distribution revealed alloy elements had little effect at corrosion initiation. In later corrosion, their enrichment led to a denser rust layer, effectively blocking corrosion expansion and chloride salt infiltration. After 72 h of accelerated corrosion, the corrosion rate growth of both bars slowed. The inner rust layer’s electrochemical potential increased, and local corrosion pits turned into uniform corrosion. The inner rust layer of the rebar formed more stable chromic acid with ionic compounds, reducing corrosion sensitivity. This study offers insights into steel bar corrosion and alloy element roles, guiding the preparation of low-alloy corrosion-resistant steel bars. Full article

Austenitic stainless steels, such as 304 and 304L, are extensively utilized in diverse industries due to their favorable properties, including biocompatibility, high durability, ductility, toughness at cryogenic temperatures, and excellent corrosion resistance. Additionally, these steels exhibit notable resistance to fatigue and oxidation. Despite these advantages, they are challenging to machine due to characteristics such as high work hardening, built-up edge formation, and low heat conductivity. The material 304L distinguishes itself from material 304 through its lower carbon content, making it more resistance to corrosion. 304L is experiencing a consistent rise in industrial demand. It is anticipated that this advanced material will progressively supersede 304 in various applications. The variability in alloy compositions and surface integrity of blanks can influence the tool wear and may even lead to abrupt tool breakage, necessitating supervision during machining operations. This study delves into the correlation between the alloy compositions, micro structure, surface integrity, and machinability of these special steels, focusing on turning processes. Various blanks of 304 and 304L in the form of bars, sourced from different manufacturers, were utilized in the study. These blanks exhibited slight variations in alloy composition (albeit within the standard range) and differed in the state of surface integrity characterized by variations in microstructure, grain size, microhardness, and residual stress. All blanks (across this array of materials) were subjected to turning using the same tool specifications and sets of machining parameters for comparative analysis. Various machinability indicators, including cutting forces, surface roughness, burr formation, tool wear, and chip morphology, were thoroughly examined. The findings highlight that the key factors influencing machinability include the microhardness of the surface and the residual stress state in the subsurface of the bars before the turning process. In contrast, changing the alloy composition within the standard range has hardly any effect on the machinability of these steels. The machinability of the examined specimens was adversely affected when the hardness exceeded 350 HV from the surface up to 2 mm below the surface and simultaneously the surface compressive residual stress exceeded −130 MPa. Full article

The present research investigates the influence of surface roughness imparted by cold surface finishing processes on the localized corrosion resistance of stainless steel. Five different alloys were studied: ferritic AISI 430, martensitic AISI 430F, austenitic AISI 303, AISI 304L, and AISI 316L. It was demonstrated that the grinding process, executed on previously cold drawn bars, leads to an improvement in corrosion resistance according to the results obtained with electrochemical tests, namely, potentiostatic and potentiodynamic tests in chloride-rich environments, the salt spray test, and long-term exposure in urban and marine atmospheres. This allowed us to establish a trend among the different alloys regarding the resistance to pitting corrosion, which was assessed according to pitting potentials, critical chloride contents, and pitting initiation time. All the tests confirmed that surface finishing, as well as alloy chemical composition, is an important factor in controlling the corrosion resistance of stainless steel. Full article

High performance ferritic (HiperFer) stainless steels constitute a new class of low-cost, heat resistant, hardenable materials which combine high creep and fatigue strength with increased steam oxidation and wet corrosion resistance. The fundamental relationships regarding the alloy composition, microstructure, and resulting mechanical properties are largely known and already published, while relevant commercialization issues, such as the effect of processing on the microstructure, have not yet been addressed. The current paper outlines the impact of the forming parameters on the resulting microstructure and the achievable creep properties. Thermomechanical treatment is demonstrated as an effective method for increasing the creep strength for a given chemical composition. This may constitute a key enabler for cost savings in component production, e.g., for the simple machining of “drop-in” turbine blades or bolts from forged bar stock material. Full article

Reinforced concrete (RC) walls are extensively used in high-rise buildings to resist lateral loads, while ensuring an adequate level of ductility. Durability problems, including corrosion of conventional steel reinforcements, necessitate exploring alternative types of reinforcement. The use of glass fiber reinforced polymer (FRP) bars is a potential solution. However, these bars cannot be used in seismic applications because of their brittleness and inability to dissipate seismic energy. Superelastic shape memory alloy (SMA) is a corrosion-free material with high ductility and unique self-centering ability. Its high cost is a major barrier to use in construction projects. The clear advantage of utilizing both SMA and FRP to achieve durable self-centering structures has motivated the development of a composite SMA-FRP bar. This paper investigates the hybrid use of FRP bars and either SMA bars or composite SMA-FRP in concrete shear walls. An extensive parametric study was conducted to study the effect of different design parameters on the lateral performance of hybrid RC walls. The seismic behavior of the hybrid walls was then examined. The hybrid walls not only solved the durability problem but also significantly improved the seismic performance. Full article

Geothermal process equipment and accessories are usually manufactured from low-alloy steels which offer affordability but increase the susceptibility of the materials to corrosion. Applying erosion-corrosion-resistant coatings to these components could represent an economical solution to the problem. In this work, testing of two newly developed laser metal deposited high-entropy alloy (LMD-HEA) coatings—CoCrFeNiMo_0.85 and Al_0.5CoCrFeNi, applied to carbon and stainless steels—was carried out at the Hellisheidi geothermal power plant. Tests in three different geothermal environments were performed at the Hellisheidi site: wellhead test at 194 °C and 14 bar, erosion test at 198 °C and 15 bar, and aerated test at 90 °C and 1 bar. Post-test microstructural characterization was performed via Scanning Eletron Microscope (SEM), Back-Scattered Electrons analysis (BSE), Energy Dispersive X-ray Spectroscopy (EDS), optical microscopy, and optical profilometry while erosion assessment was carried out using an image and chemical analysis. Both the CoCrFeNiMo_0.85 and Al_0.5CoCrFeNi coatings showed manufacturing defects (cracks) and were prone to corrosion damage. Results show that damage in the CoCrFeNiMo_0.85-coated carbon steel can be induced by manufacturing defects in the coating. This was further confirmed by the excellent corrosion resistance performance of the CoCrFeNiMo_0.85 coating deposited onto stainless steel, where no manufacturing cracks were observed. Full article

The corrosion behaviour of a new titanium-based alloy, with nickel, molybdenum and zirconium as the main alloying elements, was studied in a simulated geothermal environment at various phase conditions of a corrosive fluid. Corrosion testing of carbon steel was also conducted for comparison. Both materials were tested at an elevated temperature between 180 and 350 °C and at a 10 bar gauge pressure in H₂O containing HCl, H₂S, and CO₂ gases with an acidic condensate of pH = 3. The study found that the titanium alloy demonstrated good corrosion resistance in a single- and multiphase geothermal environment. In the testing volume, where the boiling of testing fluid occurred, the carbon steel was prone to localized damage of oxide, sulphide and chloride corrosion products. In the superheated testing volume, a homogeneous oxide corrosion layer was observed on the carbon steel. In the testing volume where condensation of the testing fluid occurred, a sulphide layer with an oxide sublayer was formed on the carbon steel. Full article

Static immersion tests of potential injection pipe steels 42CrMo4, X20Cr13, X46Cr13, X35CrMo4, and X5CrNiCuNb16-4 at T = 60 °C and ambient pressure, as well as p = 100 bar were performed for 700–8000 h in a CO₂-saturated synthetic aquifer environment similar to CCS sites in the Northern German Basin (NGB). Corrosion rates at 100 bar are generally lower than at ambient pressure. The main corrosion products are FeCO₃ and FeOOH with surface and local corrosion phenomena directly related to the alloy composition and microstructure. The appropriate heat treatment enhances corrosion resistance. The lifetime reduction of X46Cr13, X5CrNiCuNb16-4, and duplex stainless steel X2CrNiMoN22-5-3 in a CCS environment is demonstrated in the in situ corrosion fatigue CF experiments (axial push-pull and rotation bending load, 60 °C, brine: Stuttgart Aquifer and NGB, flowing CO₂: 30 L/h, +/− applied potential). Insulating the test setup is necessary to gain reliable data. S-N plots, micrographic-, phase-, fractographic-, and surface analysis prove that the life expectancy of X2CrNiMoN22-5-3 in the axial cyclic load to failure is clearly related to the surface finish, applied stress amplitude, and stress mode. The horizontal grain attack within corrosion pit cavities, multiple fatigue cracks, and preferable deterioration of austenitic phase mainly cause fatigue failure. The CF life range increases significantly when a protective potential is applied. Full article

Reinforced concrete bridge columns often endure significant damages during earthquakes due to the inherent deficiencies of conventional materials. Superior properties of the new materials such as shape memory alloy (SMA) and ultra-high-performance concrete (UHPC), compared to the reinforcing steel and the normal concrete, respectively, are needed to build a new generation of seismic resistant columns. Application of SMA or UHPC in columns has been separately studied, but this paper aims to combine the superelastic behavior of NiTi SMA and the high strength of UHPC, in order to produce a column design with minimum permanent deformation and high load tolerance subjected to strong ground motions. Additionally, the excellent corrosion resistance of NiTi SMA and the dense and impermeable microstructure of UHPC ensure the long-term durability of the proposed earthquake resistant column design. The seismic performance of four columns, defined as steel reinforced concrete (S-C), SMA reinforced concrete (SMA-C), SMA reinforced UHPC (SMA-UHPC), and reduced SMA reinforced UHPC (R-SMA-UHPC) is analyzed through a loading protocol with up to 4% drift cycles. The use of NiTi SMA bars for the SMA reinforced columns is limited to the plastic hinge region where permanent deformations happen. All the columns have 2.0% reinforcement ratio, except the R-SMA-UHPC column that has a 1.33% reinforcement ratio to optimize the use of SMA bars. Unlike the S-C column that showed up to 68% residual deformation compared to peak displacement during the last loading cycle the SMA reinforced columns did not experience permanent deformation. The SMA-C and R-SMA-UHPC columns showed similar strengths to the S-C column, but with about 5.0- and 6.5-times larger ductility, respectively. The SMA-UHPC column showed 30% higher strength and 7.5 times larger ductility compared to the S-C column. Full article

In this study, the pitting behaviour of a new corrosion-resistant alloy steel (CR) is compared to that of low-carbon steel (LC) in a simulated concrete pore solution with a chloride concentration of 5 mol/L. The electrochemical behaviour of the bars was characterised using linear polarisation resistance (LPR) and electrochemical impedance spectroscopy (EIS). The pitting profiles were detected by reflective digital holographic microscopy (DHM), scanning electron microscopy (SEM), and the chemical components produced in the pitting process were analysed by X-ray energy dispersive spectroscopy (EDS). The results show that the CR bars have a higher resistance to pitting corrosion than the LC bars. This is primarily because of the periodic occurrence of metastable pitting during pitting development. Compared to the pitting process in the LC bars, the pitting depth grows slowly in the CR bars, which greatly reduces the risk of pitting. The possible reason for this result is that the capability of the CR bars to heal the passivation film helps to restore the metastable pits to the passivation state. Full article