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19 pages, 13404 KiB  
Article
A New Bronze Age Productive Site on the Margin of the Venice Lagoon: Preliminary Data and Considerations
by Cecilia Rossi, Rita Deiana, Gaia Alessandra Garosi, Alessandro de Leo, Stefano Di Stefano, Sandra Primon, Luca Peruzzo, Ilaria Barone, Samuele Rampin, Pietro Maniero and Paolo Mozzi
Land 2025, 14(7), 1452; https://doi.org/10.3390/land14071452 - 11 Jul 2025
Viewed by 457
Abstract
The possibility of collecting new archaeological elements useful in reconstructing the dynamics of population, production and commercial activities in the Bronze Age at the edge of the central-southern Venice Lagoon was provided between 2023 and 2024 thanks to an intervention of rescue archaeology [...] Read more.
The possibility of collecting new archaeological elements useful in reconstructing the dynamics of population, production and commercial activities in the Bronze Age at the edge of the central-southern Venice Lagoon was provided between 2023 and 2024 thanks to an intervention of rescue archaeology planned during some water restoration works in the Giare–Mira area. Three small excavations revealed, approximately one meter below the current surface and covered by alluvial sediments, a rather complex palimpsest dated to the late Recent and the early Final Bronze Age. Three large circular pits containing exclusively purified grey/blue clay and very rare inclusions of vegetable fibres, and many large, fired clay vessels’ bases, walls and rims clustered in concentrated assemblages and random deposits point to potential on-site production. Two pyro-technological structures, one characterised by a sub-circular combustion chamber and a long inlet channel/praefurnium, and the second one with a sub-rectangular shape with arched niches along its southern side, complete the exceptional context here discovered. To analyse the relationship between the site and the natural sedimentary succession and to evaluate the possible extension of this site, three electrical resistivity tomography (ERT) and low-frequency electromagnetic (FDEM) measurements were collected. Several manual core drillings associated with remote sensing integrated the geophysical data in the analysis of the geomorphological evolution of this area, clearly related to different phases of fluvial activity, in a framework of continuous relative sea level rise. The typology and chronology of the archaeological structures and materials, currently undergoing further analyses, support the interpretation of the site as a late Recent/early Final Bronze Age productive site. Geophysical and geomorphological data provide information on the palaeoenvironmental setting, suggesting that the site was located on a fine-grained, stable alluvial plain at a distance of a few kilometres from the lagoon shore to the south-east and the course of the Brenta River to the north. The archaeological site was buried by fine-grained floodplain deposits attributed to the Brenta River. The good preservation of the archaeological structures buried by fluvial sediments suggests that the site was abandoned soon before sedimentation started. Full article
(This article belongs to the Special Issue Archaeological Landscape and Settlement II)
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30 pages, 1096 KiB  
Article
The Emergence and Spread of Relic Veneration in Medieval China: A Study with a Special Focus on the Relics Produced by Miracles
by Zhiyuan Chen
Religions 2025, 16(5), 652; https://doi.org/10.3390/rel16050652 - 20 May 2025
Viewed by 864
Abstract
Miracle tales are almost the sole source for the investigation of the emergence and spread of the relic cult in the early phase of Chinese Buddhism. The earliest excavated relic casket dates back to 453 CE, over four centuries after Buddhism was introduced [...] Read more.
Miracle tales are almost the sole source for the investigation of the emergence and spread of the relic cult in the early phase of Chinese Buddhism. The earliest excavated relic casket dates back to 453 CE, over four centuries after Buddhism was introduced to China. Through a critical textual analysis of Ji Shenzhou Sanbao Gantonglu, it is evident that the initial form of relic veneration was based on miraculous responses. Legends about imperial relic worship before the 3rd century are all later fabrications. Two archeological finds—the alleged relic murals in a Han tomb at Horinger, Inner Mongolia, and the stūpa-shaped bronze vessel in Gongyi, Henan—are not directly related to relic veneration. Based on the available evidence, it is tentatively concluded that relic worship first emerged around the 3rd century in the vicinity of Luoyang, the capital of the Western Jin, and later spread to the south of the Yangtze River after the Yongjia chaos. The early worshippers included both monks and lay Buddhists, such as merchants and lower-ranking officials. Royal interest in relics did not arise until the 5th century. The rise of relic veneration in China occured two or three centuries later than that in Gandhāra, from which Chinese Buddhism was significantly influenced. Compared to the cult of images or scriptures, relic veneration also emerged relatively late in China. The reluctance to adopt relics as worship objects can be partly explained by (the mahāyāna) Buddhist doctrines and the Chinese cultural mentality. Full article
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19 pages, 12490 KiB  
Article
Feasibility Exploration and Research Examples of On-Site Metallographic Inspection Methods in the Analysis of Bronze Artifacts—A Case Study of Ming Jiajing Bronze Lions and the Shang Bronze Tripod Vessel with Cicada Designs
by Kaige Zhang, Cheng Liu, Siyu Zhang, Ruihua Cui and Yi Li
Metals 2025, 15(2), 209; https://doi.org/10.3390/met15020209 - 17 Feb 2025
Cited by 1 | Viewed by 839
Abstract
This study explores a new microdestructive on-site metallographic inspection technique for analyzing metal artifacts. In the current archeometrical work, the metallographic analysis of metal artifacts requires mechanical sampling, which not only damages the integrity of the artifacts but also brings cold working effects [...] Read more.
This study explores a new microdestructive on-site metallographic inspection technique for analyzing metal artifacts. In the current archeometrical work, the metallographic analysis of metal artifacts requires mechanical sampling, which not only damages the integrity of the artifacts but also brings cold working effects to the metallographic structure during the sampling process, making the information inaccurate. This study designed a set of detailed on-site metallographic inspection methods for bronze artifacts, including grinding, sealing, polishing, etching, replicating, cleaning, and other steps. After verifying its safety through simulation experiments, the method was applied to several precious bronze artifacts, including two Ming Dynasty bronze lions from the Xi’an Beilin Museum and a Shang Bronze Tripod Vessel with Cicada Designs from the China Bronze Ware Museum. The metallographic findings show that the in situ metallographic technique can flexibly and accurately reveal the metallographic texture and process information of each localized part of the bronze artifacts, e.g., the heat-affected zone of the coins on the surface of the Ming Dynasty bronze lions proved the casting-inlay process, and the different heat texture of each foot of the Shang Bronze Tripod Vessel with Cicada Designs proved the chronological sequence of its two historical restorations. This study provides a novel approach to the process analysis of bronze artifacts, a method that can provide significant advantages in analyzing the processing techniques of precious and intact artifacts. Full article
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28 pages, 10508 KiB  
Article
Interdisciplinary Analysis and the Role of Experiments in Raw Materials and Technology Identification for Prehistoric Pottery in the Bistrița River Basin (Romania)
by Ana Drob, Neculai Bolohan, Viorica Vasilache, Bogdan-Gabriel Rățoi and Mihai Brebu
Heritage 2024, 7(9), 5120-5147; https://doi.org/10.3390/heritage7090242 - 13 Sep 2024
Viewed by 1610
Abstract
The paper presents an interdisciplinary study based on an experimental model for investigating clay sources to identify prehistoric human behavior regarding resources. The study focuses on the Middle Bronze Age (1955/1773–1739/1614 cal. BC) settlement of Siliştea-Pe Cetățuie in eastern Romania, where archaeological [...] Read more.
The paper presents an interdisciplinary study based on an experimental model for investigating clay sources to identify prehistoric human behavior regarding resources. The study focuses on the Middle Bronze Age (1955/1773–1739/1614 cal. BC) settlement of Siliştea-Pe Cetățuie in eastern Romania, where archaeological materials from the Costișa and Monteoru cultures were discovered. Standard criteria for macroscopic analysis and analytical techniques, such as optical microscopy (OM), Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDX), Micro-Fourier Transform Infrared Spectroscopy (µ-FTIR), and thermal analysis (DTA and TG), were used to investigate the ceramic material from multiple points of view. The results showed that there were no significant differences between the ceramics of the two communities. Putting together the data obtained from macroscopic and physico-chemical analyses helped in partially reconstructing ancient human behaviors related to the production and use of ceramic vessels. Full article
(This article belongs to the Special Issue Recent Progress in Cultural Heritage Diagnostics)
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25 pages, 10086 KiB  
Article
Continuity and Innovation in Pottery Technology: The Karst Region (North-East Italy) from Neolithic to Early Bronze Age
by Federico Bernardini, Manuela Montagnari Kokelj, Matteo Velicogna, Nicolò Barago, Davide Lenaz, Angelo De Min and Elena Leghissa
Heritage 2024, 7(6), 2959-2983; https://doi.org/10.3390/heritage7060139 - 4 Jun 2024
Cited by 1 | Viewed by 1960
Abstract
This paper explores the development of pottery technology in the Trieste Karst region (North-East Italy) from the Neolithic to the Early Bronze Age (EBA). It also seeks to identify cultural links with other areas by examining potentially imported vessels. Archaeometric analyses (X-ray diffraction [...] Read more.
This paper explores the development of pottery technology in the Trieste Karst region (North-East Italy) from the Neolithic to the Early Bronze Age (EBA). It also seeks to identify cultural links with other areas by examining potentially imported vessels. Archaeometric analyses (X-ray diffraction and optical microscopy) reveal significant differences between Neolithic ceramics (Danilo–Vlaška Group) and the majority of Late Copper Age (LCA)/Early Bronze Age (EBA) pottery (primarily associated with the Ljubljana Culture and a few with the Cetina Culture). Neolithic pottery displays consistent characteristics across all vessel types, including coarse grain, prevalent sparry calcite temper, and the absence of grog. In contrast, most LCA and EBA vessels exhibit distinct features such as very fine-grained paste, no sparry calcite, notable use of grog temper, higher quartz, muscovite, and flint content. Notably, from a technological perspective, the analyzed Cetina vessels bear a strong resemblance to the majority of LCA ceramics. The differences between Neolithic and LCA/EBA vessels clearly suggest the use of new raw materials, recipes, and techniques, likely reflecting changes in cultural and social contexts and potential connections with the core area of the Ljubljana Culture. Full article
(This article belongs to the Section Archaeological Heritage)
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18 pages, 7702 KiB  
Article
Design Ritual into Modern Product: A Case Study of Chinese Bronze Ware
by Jun Wu, Wenzhe Luo, Jiaru Chen, Rungtai Lin and Yanru Lyu
Sustainability 2023, 15(17), 12747; https://doi.org/10.3390/su151712747 - 23 Aug 2023
Cited by 6 | Viewed by 3920
Abstract
Bronze wares make up some of the most important bronze artifacts in ancient China’s Xia, Shang and Western Zhou dynasties. They carry rich historical, cultural and artistic information. In order to enable modern people to reflect on the ancient through products, an important [...] Read more.
Bronze wares make up some of the most important bronze artifacts in ancient China’s Xia, Shang and Western Zhou dynasties. They carry rich historical, cultural and artistic information. In order to enable modern people to reflect on the ancient through products, an important research topic that must be considered is how to carry out innovative designs with bronze ware and how to add value to the development of cultural creative industries so as to promote sustainable cultural development. This study puts forward a research framework for the innovative design of bronze ware. Based on analysis of relevant cases, such as a purple copper antique wine vessel, the “Qing Niao” (“Blue Bird”) asking love wine cup and the HIBIKI ware wine glass, the study summarizes the innovative design strategy of modern transformation design of bronze ware. From the perspectives of functional attributes, cultural symbols, cultural identity and emotional resonance, the study finally proposes three design ideas: antiqued design, simplified design and reconstructed design. The study presents a research model which still needs to be verified in future studies. We hope that the model can integrate the principles of sustainability into the modern transformation design of cultural relics. Full article
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10 pages, 9559 KiB  
Article
Scientific Research on a Gold- and Silver-Inlaid Bronze Zun from the Han Dynasty
by Dan Liu, Xiaolong Tian, Dong Zhang, Xianjing Zhou, Nana Li and Yajun Zhao
Coatings 2023, 13(9), 1480; https://doi.org/10.3390/coatings13091480 - 22 Aug 2023
Cited by 1 | Viewed by 2105
Abstract
The bronze Zun was one of the more prevalent high-class wine containers of the Han dynasty, representing the highest level of decoration in bronze at the time. However, little has been reported about its technical characteristics and scientific value. In this paper, the [...] Read more.
The bronze Zun was one of the more prevalent high-class wine containers of the Han dynasty, representing the highest level of decoration in bronze at the time. However, little has been reported about its technical characteristics and scientific value. In this paper, the samples were selected for analysis based on scientific analysis, following the principle of “minimal intervention”, and a bronze Zun from the Han dynasty in the Gansu Provincial Museum collection was studied using ultra-deep field microscopy, X-ray flaw detection, X-ray fluorescence spectrometry (XRF), scanning electron microscopy (SEM), and energy spectrometry (EDS). The results show that the gold and silver decoration on the bronze is inlaid rather than gilt. Secondly, the body and lid of the vessel are molded in one shot, with the bird-head-shaped and animal-foot-shaped components cast separately and then attached to the lid and body. Thirdly, the corrosion of the bronze Zun is characterized by the copper matrix being corroded first and most severely, followed by the silver and, finally, the gold. The high purity of the gold wire embedded in this bronze Zun, the fine width of gold wire (154–190 μm), and the magnificent decoration show the excellent processing technology level of the precious metal and the high aesthetic level of ancient man during the Han dynasty. The results of the analysis of this bronze Zun can provide an essential reference for research on bronze vessels of the same type, the techniques of gold and silver misalignment, and the development of the history of bronze manufacture and technology during the Han dynasty. Full article
(This article belongs to the Special Issue Coatings for Cultural Heritage: Cleaning, Protection and Restoration)
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22 pages, 7078 KiB  
Article
Technological and Functional Approaches Applied to Miniature Vessels with Pigment Traces: Two Middle Bronze Age Case Studies from Eastern Subcarpathians of Romania
by Ana Drob, Viorica Vasilache and Neculai Bolohan
Appl. Sci. 2023, 13(4), 2093; https://doi.org/10.3390/app13042093 - 6 Feb 2023
Cited by 1 | Viewed by 2212
Abstract
Vessels with a special shape have always been a point of interest for pottery studies, especially from the perspective of the distinct functionality that these pots would have had. The ceramic typologies made for the miniature finds specific to the Middle Bronze Age [...] Read more.
Vessels with a special shape have always been a point of interest for pottery studies, especially from the perspective of the distinct functionality that these pots would have had. The ceramic typologies made for the miniature finds specific to the Middle Bronze Age in the Eastern Carpathian area include a series of such vessels attributed to the Costișa communities. Currently, the role of these pots is still under debate, being classified as ritual or special, which led to two case studies focused on investigating these miniatures. The analyzed vessels come from the Piatra Neamț—Bâtca Doamnei and Siliștea—Pe Cetățuie settlements (Neamț County), where these containers were discovered with traces of pigment or in association with colored minerals. These findings led to a series of questions related to their use, as it is known that in the Middle Bronze Age there are not many archaeological discoveries that explain the presence of pigments in the studied area. In this sense, multiplication of information was achieved by performing detailed analyses, such as optical microscopy (texture and surface details), colorimetry CIE L*a*b* (color investigation), SEM-EDX (elemental composition) and µ-FTIR (chemical compounds). The results of the interdisciplinary study led to new data on the nature of the pigment and the method of preparation, and also clues on the source of the raw material. Thus, these items illustrate the special use of miniature vessels and their probable functions. Full article
(This article belongs to the Special Issue New Materials and Advanced Procedures of Obtaining and Processing II)
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12 pages, 4020 KiB  
Article
An Insight into a Shang Dynasty Bronze Vessel by Nuclear Techniques
by Filomena Salvemini, Zeljko Pastuovic, Attila Stopic, Min-Jung Kim and Sue Gatenby
Appl. Sci. 2023, 13(3), 1549; https://doi.org/10.3390/app13031549 - 25 Jan 2023
Cited by 5 | Viewed by 3674
Abstract
A bronze wine vessel attributed to 1600–1046 B.C., Shang dynasty in China, an object from the East Asian Collection of the Museum of Applied Arts and Sciences in Sydney (Australia), was studied using a non-destructive scientific analytical protocol based on the synergic combination [...] Read more.
A bronze wine vessel attributed to 1600–1046 B.C., Shang dynasty in China, an object from the East Asian Collection of the Museum of Applied Arts and Sciences in Sydney (Australia), was studied using a non-destructive scientific analytical protocol based on the synergic combination of nuclear techniques. Gamma spectrometry, neutron-computed tomography, and proton-induced X-ray emission (PIXE) spectroscopy were applied to gain a better insight into the structural and compositional features of the artefact to prove its authenticity. Gamma spectrometry was performed to assess the risk of excessive sample activation induced by long exposure to the neutron beam and to determine the bulk elemental composition. Based on neutron-computed tomography, the porosities and the thickness of the metal wall were evaluated and found consistent with the piece-mould casting technology adopted by craftsmen during the Shang dynasty in China. Finally, PIXE spectroscopy demonstrated the use of a ternary (copper–tin-leaded) alloy and the nature of mineralisation on the surface. Full article
(This article belongs to the Special Issue Non-destructive Techniques for Cultural Heritage Characterization)
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19 pages, 2984 KiB  
Article
Theban Glass Traditions in the 1st Millennium BCE, Greece: New LA-ICP-MS Data and Their Archaeological Implications
by Artemios Oikonomou, Maria Kaparou, Vid S. Šelih, Johannes T. van Elteren, Nikolaos Zacharias, Simon Chenery and Julian Henderson
Heritage 2023, 6(1), 705-723; https://doi.org/10.3390/heritage6010038 - 16 Jan 2023
Cited by 1 | Viewed by 3871
Abstract
Thebes, located in Boeotia in central Greece, is archaeologically and historically attested to have been an important centre ever since the Early Bronze Age. Regularly sustained glass working, testified by numerous finds in burial and settlement contexts, must have taken place since the [...] Read more.
Thebes, located in Boeotia in central Greece, is archaeologically and historically attested to have been an important centre ever since the Early Bronze Age. Regularly sustained glass working, testified by numerous finds in burial and settlement contexts, must have taken place since the Mycenaean times. In the current study, 35 samples of glass beads (30) and vessels (5), dating roughly from the 7th to 1st cent. BCE (Archaic to the Hellenistic/Early Roman era) are the subject of research. The aim was to assess some technological aspects of the assemblage, provide a chemical fingerprint for it and suggest a likely provenance, in an attempt to discuss issues of glass consumption and trade at a given era and culture. A combination of quasi-destructive techniques was applied, namely LA-ICP-MS and SEM-EDS for the identification of the major, minor and trace element composition. The results have provided evidence for different technological choices, reflected in the choice of raw materials and different origins are suggested for the subgroups identified in the course of the study. Full article
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17 pages, 3841 KiB  
Article
Unveiling the Use of Wide Horizontal Rim Vessels (Bronze Age Northwest Iberian Peninsula)
by César Oliveira, Raquel Vilaça, André Lopes Pereira and Anna Lígia Vitale
Separations 2022, 9(11), 366; https://doi.org/10.3390/separations9110366 - 10 Nov 2022
Cited by 1 | Viewed by 2543
Abstract
This paper addresses a “wide horizontal rim vessel” belonging to the collection of Fundação Sousa d’Oliveira (Azores). Although its provenance and the circumstances of its discovery are currently unknown, the authors contend that this vessel should be attributed to the Iberian Northwest and, [...] Read more.
This paper addresses a “wide horizontal rim vessel” belonging to the collection of Fundação Sousa d’Oliveira (Azores). Although its provenance and the circumstances of its discovery are currently unknown, the authors contend that this vessel should be attributed to the Iberian Northwest and, more specifically, to the Portuguese territory, in line with the highly homogenous distribution of this type of pottery. A morphological and stylistic study has been carried out establishing its singularity with regards to the decorative composition of the rim, which is without parallel amongst dozens of vessels of the same “family”. During the study of this piece, it has been possible to observe traces of soot and organic residues deposited both on its interior and exterior surfaces, which is recurrent in these vessels. The nature of these substances has never been determined in previous studies. In this article, we present and discuss the results obtained from the chromatographic analyses of the organic residue traces found on the vessel. Full article
(This article belongs to the Special Issue Analytical Chromatography Applied to Archaeology)
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26 pages, 20134 KiB  
Article
Woodland Management Practices in Bronze Age, Bruszczewo, Poland
by Marzena Kłusek and Jutta Kneisel
Forests 2021, 12(10), 1327; https://doi.org/10.3390/f12101327 - 28 Sep 2021
Cited by 3 | Viewed by 3462
Abstract
The article presents a study of wood excavated from archaeological site in Poland (2100–1650 BC). The large amount of collected samples created a unique opportunity for research because the subfossil wood was in very good preservation state. This made it possible to carry [...] Read more.
The article presents a study of wood excavated from archaeological site in Poland (2100–1650 BC). The large amount of collected samples created a unique opportunity for research because the subfossil wood was in very good preservation state. This made it possible to carry out dendrotypological analysis. This is the first such study conducted for Early Bronze Age timber originating from Poland. The main goal of the study was to determine whether the presence of strong and abrupt reductions and releases of growth, observed within tree-ring sequences, is due to natural stand dynamics, results from the influence of extreme environmental factors or whether they should be linked to specific silvicultural practices already known in ancient times. Another purpose of the study was to determine the type of forest management techniques applied to the trees growing in Bruszczewo site. The research was conducted using the dendrochronological method. In addition to the measurements of growth-ring width, the development of earlywood and latewood zones, the proportion of sapwood and the presence of specific features of tree trunks were analysed. A detailed study allowed identifying the samples originating from coppiced and shredded trees. A characteristic feature of the trees subjected to these silvicultural practices is the presence of strong and abrupt reductions and releases of growth. Moreover, coppiced trees were specified by the large proportion of sapwood in the cross-section of the stem, reduced number of sapwood rings, small and numerous earlywood vessels, diminished earlywood vessels area. In turn, shredded trees distinguished themselves by a strong reduction in the earlywood width in the years following the shredding event. The research of archaeological wood from the ancient settlement proves that during the Early Bronze Age various forest management techniques were used in this site. These treatments were aimed at improving the quality and quantity of the raw material harvested from forest areas. Full article
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16 pages, 4483 KiB  
Article
Use of Thermally Assisted Hydrolysis and Methylation (THM-GC-MS) to Unravel Influence of Pottery Production and Post-Depositional Processes on the Molecular Composition of Organic Matter in Sherds from a Complex Coastal Settlement
by Joeri Kaal, María Guadalupe Castro González, Antonio Martínez Cortizas and María Pilar Prieto Martínez
Separations 2021, 8(9), 140; https://doi.org/10.3390/separations8090140 - 1 Sep 2021
Cited by 2 | Viewed by 2849
Abstract
Ceramic fragments from the Islet of Guidoiro Areoso (NW Spain), covering a wide range of cultural periods (Neolithic to Late Bronze Age), have been studied by color analysis, elemental analysis of carbon (C) and nitrogen (N), and molecular analysis (thermally assisted hydrolysis and [...] Read more.
Ceramic fragments from the Islet of Guidoiro Areoso (NW Spain), covering a wide range of cultural periods (Neolithic to Late Bronze Age), have been studied by color analysis, elemental analysis of carbon (C) and nitrogen (N), and molecular analysis (thermally assisted hydrolysis and methylation, THM-GC-MS), in order to identify the organic matter (OM) in the prehistoric pottery and reveal information on ceramic production techniques, food remains and post-depositional effects. Results showed that the strong marine influence (sherds recovered from coastal deposits) and microbial activity (recovery from waste deposits, “cuncheiros”) had a profound effect on C/N ratio and molecular composition (N-rich protein and chitin structures). Other organic ingredients originated from the material used for creating the ware (detected as pyrogenic OM) and possibly food remains (fatty acid fingerprints). Dark-colored ware was enriched in both pyrogenic OM from incomplete combustion and non-bacterial fatty acids. Fatty acid patterns could not be related to possible vessel use, and markers of aquatic resources were scarce, or absent. It is argued that THM-GC-MS of pottery fragments is useful for understanding how an archaeological deposit developed in time, what kinds of OM are present, and possibly to make a pre-selection of samples with high potential for more cost-demanding dietary molecular assessments. Full article
(This article belongs to the Special Issue Analytical Chromatography Applied to Archaeology)
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17 pages, 6018 KiB  
Article
The Interdisciplinary Approach of Some Middle Bronze Age Pottery from Eastern Romania
by Ana Drob, Viorica Vasilache and Neculai Bolohan
Appl. Sci. 2021, 11(11), 4885; https://doi.org/10.3390/app11114885 - 26 May 2021
Cited by 7 | Viewed by 3449
Abstract
Prehistoric pottery is the most abundant material discovered in archaeological sites and represents the main element of knowledge about human communities from the past. This study presents a model of interdisciplinary investigation of pottery through several types of analyses, enabling the scientific study [...] Read more.
Prehistoric pottery is the most abundant material discovered in archaeological sites and represents the main element of knowledge about human communities from the past. This study presents a model of interdisciplinary investigation of pottery through several types of analyses, enabling the scientific study of this category of artifacts. The analyses were performed on 11 ceramic fragments from the Middle Bronze Age settlement of Piatra Neamț–Lutărie, Eastern Romania, considering information about the color, production technique, type, size, functionality and category of the vessel, but also data related to ceramic paste inclusions. The samples were studied by optical microscopy (OM), scanning electron microscopy (SEM) coupled with energy-dispersive X-ray analysis (EDX) and micro-Fourier-transform infrared spectroscopy (µFTIR). The results obtained provide important information regarding pottery manufacturing technologies, such as sources of the raw materials and firing temperatures, and revealed the functionality of various vessel categories within a prehistoric settlement. Full article
(This article belongs to the Special Issue New Materials and Advanced Procedures of Obtaining and Processing)
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18 pages, 6377 KiB  
Article
Down to the Crust: Chemical and Mineralogical Analysis of Ceramic Surface Encrustations on Bronze Age Ceramics from Békés 103, Eastern Hungary
by Mark Golitko, Alyssa McGrath, Attila Kreiter, Ian V. Lightcap, Paul R. Duffy, Györgyi M. Parditka and Julia I. Giblin
Minerals 2021, 11(4), 436; https://doi.org/10.3390/min11040436 - 20 Apr 2021
Cited by 10 | Viewed by 3638
Abstract
Békés 103, a primarily Middle Bronze Age (c. 1600–1280 calBC) cemetery and settlement on the Great Hungarian Plain, has been investigated by the BAKOTA project since 2011. Ceramics from the site are covered in dense white concretions, and it has been noted during [...] Read more.
Békés 103, a primarily Middle Bronze Age (c. 1600–1280 calBC) cemetery and settlement on the Great Hungarian Plain, has been investigated by the BAKOTA project since 2011. Ceramics from the site are covered in dense white concretions, and it has been noted during compositional analyses that these vessels exhibit elevated concentrations of several potentially mobile elements in comparison to vessels from regional tell sites. Here, we use a multimethod (optical mineralogy, FT-IR, XRD, XPS, PXRF, SEM-EDS, and LA-ICP-MS) mineralogical and chemical approach to characterize the composition of surface encrustations on ceramics samples from Békés 103. We also chemically map interior paste composition using LA-ICP-MS to identify potential leaching of mobile elements into or out of vessel bodies. We demonstrate that the surface encrustations are primarily composed of calcite but also contain a variety of other mineral and organic constituents indicative of deposition of soil carbonates, phosphates, nitrates, and other inorganic and organic components. We further document the leaching of several mobile elements into ceramic pastes as well as formation of secondary calcite along void, pore, and temper boundaries. The presence of cremated bone and possibly bone ash in close vicinity to many of the studied vessels may also have contributed to the observed patterns of diagenesis. It is likely that similar post-burial processes might affect ceramics from other sites located in low-lying, seasonally inundated contexts. Full article
(This article belongs to the Special Issue Archaeological Ceramic Diagenesis)
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